Material Safety Data Sheet acc. to ISO/DIS 11014

Transcription

1 R Page 1/7 1 Identification of the substance/mixture and of the company/undertaking Product identifier Article number: Details of the supplier of the safety data sheet Manufacturer/Supplier: All Printing Resources, Inc 140 W. Lake Drive Glendale Heights, IL Information department: Environment protection department. Emergency telephone number: ChemTrec: UNITED STATES 1(800) INTERNATIONAL * 2 Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: acetone H225; H319; H % ethyl acetate H225; H319; H % tetrahydrofuran H225; H319; H % Additional information: For the wording of the listed risk phrases refer to section 15. * 3 Hazards identification Classification of the substance or mixture H225 Highly flammable liquid and vapour. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. Classification according to Directive 67/548/EEC or Directive 1999/45/EC Irritant Irritating to eyes. Flammable Highly flammable. May form explosive peroxides. Vapours may cause drowsiness and dizziness. Information concerning particular hazards for human and environment: Has a narcotizing effect. Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. Label elements Labelling according to EU guidelines: The product has been classified and marked in accordance with directives on hazardous materials. Code letter and hazard designation of product: Irritant Flammable (Contd. on page 2)

2 Page 2/7 Risk phrases: Highly flammable. May form explosive peroxides. Irritating to eyes. Vapours may cause drowsiness and dizziness. (Contd. of page 1) Safety phrases: Keep out of the reach of children. Keep container in a well-ventilated place. Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. If swallowed, seek medical advice immediately and show this container or label. Classification system: NFPA ratings (scale 0-4) Health = 1 Fire = 3 Reactivity = 0 HMIS-ratings (scale 0-4) HEALTH FIRE PHYSICAL HAZARD Health = 1 Fire = 3 Physical Hazard = 0 4 First aid measures After inhalation: Overexposure, remove to fresh air and seek medical attention. After skin contact: Clean with rubbing alcohol, followed immediately by washing affected area with soap and water. Remove contaminated clothing. Wash clothing before reuse. After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: If symptoms persist consult doctor. 5 Firefighting measures Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water. For safety reasons unsuitable extinguishing agents: Water and water with full jet Protective equipment: Protective clothing and respiratory protective device. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose of contaminated material as waste in accordance with federal state and local regulations. Do not flush with water or aqueous cleansing agents (Contd. on page 3)

3 Page 3/7 Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. (Contd. of page 2) 7 Handling and storage Handling: Precautions for safe handling Open and handle receptacle with care. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Storage: Requirements to be met by storerooms and receptacles: Store in a cool location away from direct heat. Information about storage in one common storage facility: Store as flammable liquid. Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. Specific end use(s) No further relevant information available. * 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: acetone (25-50%) PEL REL TLV 2400 mg/m³, 1000 ppm 590 mg/m³, 250 ppm Short-term value: (1782) NIC-1187 mg/m³, (750) NIC-500 ppm Long-term value: (1188) NIC-475 mg/m³, (500) NIC-200 ppm BEI ethyl acetate (5-20%) PEL REL TLV 1400 mg/m³, 400 ppm 1400 mg/m³, 400 ppm 1440 mg/m³, 400 ppm tetrahydrofuran (5-20%) PEL REL TLV 590 mg/m³, 200 ppm Short-term value: 735 mg/m³, 250 ppm Long-term value: 590 mg/m³, 200 ppm Short-term value: 295 mg/m³, 100 ppm Long-term value: 147 mg/m³, 50 ppm Skin Additional information: The lists that were valid during the creation were used as basis. Personal protective equipment (see listings below) General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Breathing equipment: Use suitable respiratory protective device in case of insufficient ventilation. (Contd. on page 4)

4 Page 4/7 Protection of hands: Protective gloves Eye protection: Safety glasses with side shields. Body protection: Protective work clothing (Contd. of page 3) 9 Physical and chemical properties General Information Appearance: Form: Liquid Color: Clear Odor: Characteristic Change in condition Melting point: Boiling point: Undetermined. 55 C (131 F) Flash point: -21 C (-6 F) Ignition temperature: C (446 F) Auto igniting: Product is not selfigniting. Danger of explosion: NONE Flammable limits: Lower: 1.5 Vol % Upper: 13.0 Vol % Vapor pressure at 20 C (68 F): hpa (175 mm Hg) Specific gravity: Solubility in / Miscibility with Water: Solvent content: Organic solvents: 77.6 % Not miscible or difficult to mix. Solids content: 22.4 % Other information VOC: = 2.13 LBS/GAL WEIGHT PER GALLON: = 7.36 LBS 10 Stability and reactivity Thermal decomposition / conditions to be avoided: Keep away form extreme heat, sparks, open flames. Incompatible materials: No further relevant information available. Hazardous decomposition products: Oxides of carbon and nitrogen. 11 Toxicological information Acute toxicity: Primary irritant effect: on the skin: Irritant to skin and mucous membranes. on the eye: Irritating effect. Sensitization: Sensitizing effect through inhalation is possible with prolonged exposure. (Contd. on page 5)

5 Page 5/7 (Contd. of page 4) Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant 12 Ecological information Acquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Behavior in environmental systems: Bioaccumulative potential No further relevant information available. Additional ecological information: General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. 13 Disposal considerations Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. * 14 Transport information UN-Number DOT, ADR, IMDG, IATA UN1133 UN proper shipping name DOT, IMDG, IATA ADHESIVES ADR 1133 ADHESIVES Transport hazard class(es) DOT, IMDG, IATA Class 3 Flammable liquids. Label 3 ADR Class 3 Flammable liquids Label 3 (Contd. on page 6)

6 Page 6/7 Packing group DOT, ADR, IMDG, IATA III Environmental hazards: Marine pollutant:. Special precautions for user Warning: Flammable liquids Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. UN "Model Regulation": UN1133, ADHESIVES, 3, III (Contd. of page 5) * 15 Regulatory information Sara Section 355 (extremely hazardous substances): Section 313 (Specific toxic chemical listings): TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements. Proposition 65 Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity: (DSL) Canada Dosmestic Substance List All components of this product are on the DSL(Canada Domestic Substance list) or are exempt from DSL requirements. Cancerogenity categories EPA (Environmental Protection Agency) acetone I IARC (International Agency for Research on Cancer) None of the ingredients listed. NTP (National Toxicology Program) TLV (Threshold Limit Value established by ACGIH) acetone A tetrahydrofuran A3 MAK (German Maximum Workplace Concentration) tetrahydrofuran 4 NIOSH-Ca (National Institute for Occupational Safety and Health) OSHA-Ca (Occupational Safety & Health Administration) (Contd. on page 7)

7 Page 7/7 Product related hazard informations: The product has been classified and marked in accordance with directives on hazardous materials. (Contd. of page 6) Risk phrases: Highly flammable. May form explosive peroxides. Irritating to eyes. Vapours may cause drowsiness and dizziness. National regulations: Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. 16 Other information Although the information and recommendations set forth in this MSDS are presented in good faith and are believed to be correct as of the date of this MSDS, Royal Adhesives & Sealants makes no representations as to the completeness or accuracy thereof. Information is supplied on the condition that the persons receiving and using it will make their own determination as to the suitability for their purpose prior to use. In no event will Royal Adhesives & Sealants or any affiliate thereof be responsible for damages of any nature whatsoever resulting from the use or reliance on the information set forth in the MSDS. Department issuing MSDS: Environment protection department. Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association ICAO: International Civil Aviation Organization ACGIH: American Conference of Governmental Industrial Hygienists NFPA: National Fire Protection Association () HMIS: Hazardous Materials Identification System ()