MATERIAL SAFETY DATA SHEET. 1. Product and Company Identification

Transcription

1 MATERIAL SAFETY DATA SHEET Product Name UPC CODES Refer to Section 16 Product use Manufacturer LEGEND HMIS/NFPA Severe 4 Serious 3 Moderate 2 Slight 1 Minimal 0 1. Product and Company Identification Clearasil Stayclear Oil Free Daily Face Wash Face wash Reckitt Benckiser Morris Corporate Center IV 399 Interpace Parkway P.O. Box 225 Parsippany, NJ In Case of Emergency: Transportation Emergencies: 24 Hour Number: North America: CHEMTREC: Outside North America: Health / 1 Flammability 0 Physical Hazard 0 Personal Protection 2. Hazards Identification Emergency overview Potential short term health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms This product is regulated by the US FDA as a personal care cosmetic or over-the-counter drug. Extensive testing has been completed to show that it is safe and effective when used as directed. CAUTION CAUSES EYE IRRITATION. MAY CAUSE SKIN IRRITATION. Eye, Skin contact, Skin absorption, Inhalation, Ingestion. Causes irritation. May cause irritation. May cause respiratory tract irritation. May cause stomach distress, nausea or vomiting. Eyes. Respiratory system. Prolonged or repeated exposure can cause drying, defatting and dermatitis. Symptoms may include redness, edema, drying, defatting and cracking of the skin. 3. Composition / Information on Ingredients Ingredient(s) CAS # Percent #18130 Page 1 of 6 Issue date 01-May-2008

2 4. First Aid Measures First aid procedures Eye contact Skin contact Inhalation Ingestion Notes to physician General advice Flush with cool water. Remove contact lenses, if applicable, and continue flushing. Obtain medical attention if irritation persists. In case of skin irritation, discontinue use of product. If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. Do not induce vomiting. Rinse mouth with water, then drink one or two glasses of water. Obtain medical attention. Never give anything by mouth if victim is unconscious, or is convulsing. Symptoms may be delayed. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes. Keep out of reach of children. Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge 5. Fire Fighting Measures Not flammable by OSHA criteria. Dry chemical. Alcohol foam. Carbon dioxide. Firefighters should wear full protective clothing including self contained breathing apparatus. May include and are not limited to: Oxides of carbon. 6. Accidental Release Measures Personal precautions Methods for containment Methods for cleaning up Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re-use. 7. Handling and Storage Handling Storage Use good industrial hygiene practices in handling this material. Keep out of reach of children. Store in a closed container away from incompatible materials. #18130 Page 2 of 6 Issue date 01-May-2008

3 8. Exposure Controls / Personal Protection Exposure limits Ingredient(s) Exposure Limits TWA: 10 mg/m3 Mist: 10 mg/m3 TWA: 15 mg/m3 TWA: 10 mg/m3 TWA: 15 mg/m3 Ceiling: 2 mg/m3 Mist: 5 mg/m3 Engineering controls Personal protective equipment Eye / face protection Hand protection Skin and body protection Respiratory protection Not normally required if good ventilation is maintained. Not normally required. Not required. As required by employer code. Not normally required. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. 9. Physical & Chemical Properties Appearance Color Form Odor Odor threshold Physical state pearlescent cream. White. cream Green, Melon, Floral Liquid #18130 Page 3 of 6 Issue date 01-May-2008

4 ph Melting point Freezing point Boiling point Flash point Evaporation rate Flammability limits in air, lower, % by volume Flammability limits in air, upper, % by volume Vapor pressure Vapor density Specific gravity > 0.98 Octanol/water coefficient Solubility (H2O) Auto-ignition temperature Viscosity > 95 C (> F) 100, ,000 cps (Brookfield Spindle TF, helipath, 5 rpm, 60 C) 10. Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions Stable under recommended storage conditions. Do not mix with other chemicals. Caustics. Acids. Oxidizers. May include and are not limited to: Oxides of carbon. Hazardous polymerization does not occur. 11. Toxicological Information Component analysis - LC50 Ingredient(s) Component analysis - Oral LD50 Ingredient(s) LC50 > 2.28 Mg/L rat LD mg/kg rat mg/kg rat 2000 mg/kg rat mg/kg rat 5000 mg/kg rat 214 mg/kg rat Effects of acute exposure Eye Skin Inhalation Ingestion mg/kg rat Causes irritation. May cause irritation. May cause respiratory tract irritation. May cause stomach distress, nausea or vomiting. #18130 Page 4 of 6 Issue date 01-May-2008

5 Sensitization Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity Ecotoxicity Ecotoxicity - Freshwater Fish Species Data 12. Ecological Information Components of this product have been identified as having potential environmental concerns Hr LC50 Oncorhynchus mykiss: mg/l Hr LC50 Oryzias latipes: 150 mg/l Hr LC50 Gambusia affinis: 80.0 mg/l Hr LC50 Oryzias latipes: 118 mg/l [static] Ecotoxicity - Water Flea Data Hr EC50 Daphnia magna: >500 mg/l Hr EC50 Artemia salina: >27 mg/l Environmental effects Aquatic toxicity Persistence / degradability Bioaccumulation / accumulation Partition coefficient Mobility in environmental media Chemical fate information 13. Disposal Considerations Waste codes Disposal instructions Waste from residues / unused products Contaminated packaging Review federal, provincial, and local government requirements prior to disposal. Department of Transportation (DOT) IATA IMDG Transportation of Dangerous Goods (TDG) US Federal regulations 14. Transport Information 15. Regulatory Information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR U.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities Lb final RQ; 454 kg final RQ Occupational Safety and Health Administration (OSHA) 29 CFR hazardous chemical Yes CERCLA (Superfund) reportable quantity : #18130 Page 5 of 6 Issue date 01-May-2008

6 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Section 302 extremely hazardous substance Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No No Section 311 hazardous chemical Yes Clean Air Act (CAA) Clean Water Act (CWA) Safe Drinking Water Act (SDWA) Drug Enforcement Agency (DEA) Food and Drug Administration (FDA) State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. U.S. - California - 8 CCR Section Director's List of Hazardous Substances Present U.S. - Louisiana - Reportable Quantity List for Pollutants Lb final RQ; 454 kg final RQ U.S. - Massachusetts - Right To Know List Present (mist) Present U.S. - Minnesota - Hazardous Substance List Present (mist, dust) Present U.S. - New Jersey - Right to Know Hazardous Substance List sn 1571 U.S. - New York - Reporting of Releases Part List of Hazardous Substances Lb RQ (air); 100 lb RQ (land/water) U.S. - Pennsylvania - RTK (Right to Know) List Present Environmental hazard U.S. - Rhode Island - Hazardous Substance List Toxic (mist); Flammable (mist) Toxic; Flammable Inventory status Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory No A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Disclaimer Recommended use 16. Other Information This product should only be used as directed on the label and for the purpose intended. To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. For external use only. If excessive skin irritation develops or increases, discontinue use. Further information UPC CODES: ITEM CODE: FORMULA NUMBER: 1376/17 Issue date Effective date 01-May May-2008 Prepared by Reckitt Benckiser Regulatory Department #18130 Page 6 of 6 Issue date 01-May-2008