Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH)

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1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier THERMOLAST 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Manufacturing plastic articles via industrial processing methods, including compounding and conversion. For professional users only Details of the supplier of the safety data sheet Company name: KRAIBURG TPE GmbH & Co. KG Street: Friedrich-Schmidt-Str. 2 Place: D Waldkraiburg Telephone: +49 (8638) regulatory@kraiburg-tpe.com 1.4. Emergency telephone number Telephone: TP7LDZ SECTION 2: Hazards identification +49 (8638) (only available at office times) 2.1. Classification of the substance or mixture Regulation (EC) No 1272/2008 (CLP) As the potential hazardous ingredients, if any, are bound in the polymer matrix, it's unlikely that the product poses a risk to health and environment Label elements Regulation (EC) No 1272/2008 (CLP) Additional advice on labelling According to EC directives or the corresponding national regulations, there is no labelling obligation for this product Other hazards May cause sensitization to susceptible people. SECTION 3: Composition/information on ingredients 3.2. Mixtures Chemical characterization Preparation/mixture without hazards for human health or environment. SECTION 4: First aid measures 4.1. Description of first aid measures General information Move victim out of danger zone. After inhalation Provide fresh air. In case of irritation of the respiratory tract, seek medical advice. After contact with skin Wash with generous amount of water. Change contaminated clothing. Following contact with the melted product, quickly cool affected skin area with plenty of cold water. After contact with eyes GB - EN 1 / 5

2 Rinse eyes immediately with water or in the eye-bath carefully and thoroughly. In case of troubles or persistent symptoms, consult an ophthalmologist. After ingestion Rinse mouth thoroughly with water Most important symptoms and effects, both acute and delayed In case of skin irritation, seek medical treatment Indication of any immediate medical attention and special treatment needed No special measures are necessary. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Extinguishing materials should be selected according to the surrounding area; alcohol resistant foam, dry extinguishing powder, carbon dioxide (CO2) or water spray. Unsuitable extinguishing media High power water jet Special hazards arising from the substance or mixture Toxic fumes may occure in case of fire. Pyrolysis products, toxic Advice for firefighters In case of fire: Wear self-contained breathing apparatus SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Provide adequate ventilation. Wear respiratory protection in the presence of vapour, dust, and aerosols Environmental precautions No special environmental protection measures are necessary Methods and material for containment and cleaning up Collect mechanically. Treat the assimilated material according to the section on waste disposal Reference to other sections See protective measures under point 7 and 8. SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling No special handling instructions are necessary. Advice on protection against fire and explosion Keep away from sources of ignition - No smoking Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Store in a cool and dry place. Advice on storage compatibility Keep away from food, drink and animal feedingstuffs. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Additional advice on limit values 8.2. Exposure controls Protective and hygiene measures GB - EN 2 / 5

3 Take off contaminated clothing and wash before reuse. Wash hands before breaks and at the end of work. When using do not eat or drink. Eye/face protection Wear eye/face protection. Suitable eye protection: Framed glasses. Hand protection Wear suitable gloves. Required properties: heat-resistant. Respiratory protection Provide sufficient ventilation and punctiform suction at critical points. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Odour: solid characteristic ph-value: Changes in the physical state Melting point: > 120 C Initial boiling point and boiling range: Flash point: > 250 C Flammability Solid: Gas: Lower explosion limits: Upper explosion limits: Ignition temperature: Auto-ignition temperature Solid: Gas: Decomposition temperature: Oxidizing properties not oxidizing Vapour pressure: Density (at 20 C): 0,9 1,5 g/cm³ Water solubility: practically insoluble Solubility in other solvents Partition coefficient: Vapour density: Evaporation rate: 9.2. Other information Solid content: Bulk density: SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions 0,45 0,8 kg/dm³ Test method GB - EN 3 / 5

4 10.4. Conditions to avoid Oxidizing agents. Keep away from heat/sparks/open flames/hot surfaces. - No smoking Incompatible materials Hazardous decomposition products Carbon dioxide. Carbon monoxide. Pyrolysis products, toxic. SECTION 11: Toxicological information Information on toxicological effects Toxicocinetics, metabolism and distribution Practical experience Other observations Frequently or prolonged contact with skin may cause dermal irritation. SECTION 12: Ecological information Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment This substance does not meet the criteria for classification as PBT or vpvb Other adverse effects No symptoms known up to now. SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Waste disposal according to official state regulations. Waste disposal number of waste from residues/unused products WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of plastics, synthetic rubber and man-made fibres; wastes not otherwise specified Waste disposal number of used product WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of plastics, synthetic rubber and man-made fibres; wastes not otherwise specified Waste disposal number of contaminated packaging WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal packaging waste); mixed packaging Contaminated packaging Completely emptied packings can be re-cycled. SECTION 14: Transport information Land transport (ADR/RID) Other applicable information (land transport) GB - EN 4 / 5

5 Powered by TCPDF ( Safety Data Sheet Inland waterways transport (ADN) Other applicable information (inland waterways transport) Marine transport (IMDG) Other applicable information (marine transport) Air transport (ICAO) Other applicable information (air transport) Environmental hazards ENVIRONMENTALLY HAZARDOUS: Special precautions for user No special measures are necessary Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not a hazardous material with respect to these transportation regulations. SECTION 15: Regulatory information no Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulatory information Additional information There is no requirement for the product to be specially labelled according to EC directives or the corresponding national laws. National regulatory information Chemical safety assessment Chemical safety assessments for substances in this mixture were not carried out. SECTION 16: Other information Abbreviations and acronyms ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service LC50: Lethal concentration, 50% LD50: Lethal dose, 50% Data compared to the previous version altered. Further Information The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.) GB - EN 5 / 5