1. Substance/preparation and manufacturer/supplier identification

Transcription

1 Safety data sheet Page: 1/9 1. Substance/preparation and manufacturer/supplier identification Plantapon ACG-LC Use: surfactants Manufacturer/supplier: PT BASF Indonesia Plaza GRI, 10th & 11th Floor Jl. H.R. Rasuna Said Blok X-2 No.1 Jakarta Selatan 12950, P.O. Box 2431 Gbr., Jakarta 10024, INDONESIA Telephone: / Telefax number: / Emergency information: International emergency number: Telephone: Hazard identification Classification of the substance and mixture: Serious eye damage/eye irritation: Cat. 2A Hazardous to the aquatic environment - acute: Cat. 3 Hazardous to the aquatic environment - chronic: Cat. 3 Label elements and precautionary statement: Pictogram: Signal Word:

2 Page: 2/9 Warning Hazard Statement: Causes serious eye irritation. Harmful to aquatic life. Harmful to aquatic life with long lasting effects. Precautionary Statements (Prevention): Wear eye/face protection. Avoid release to the environment. Wash with plenty of water and soap thoroughly after handling. Precautionary Statements (Response): IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Call a POISON CENTER or doctor/physician. Precautionary Statements (Disposal): Dispose of contents/container to hazardous or special waste collection point. Other hazards which do not result in classification: No specific dangers known, if the regulations/notes for storage and handling are considered. 3. Composition/information on ingredients Chemical nature Aqueous solution based on: Isopropanol, Disodium cocoyl glutamate, Disodium L-glutamate Hazardous ingredients Disodium cocoyl glutamate Content (W/W): >= 30 % - < 50 % CAS Number: Eye Dam./Irrit.: Cat. 2A Aquatic Acute: Cat. 3 Aquatic Chronic: Cat First-Aid Measures General advice: If adverse health effects develop seek medical attention. If inhaled: not relevant. On skin contact: After contact with skin, wash immediately with plenty of water. On contact with eyes: In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. Seek medical attention if necessary. On ingestion: Rinse mouth and then drink ml of water. Note to physician:

3 Page: 3/9 Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. Hazards: No hazard is expected under intended use and appropriate handling. Treatment: Treat symptomatically. 5. Fire-Fighting Measures Suitable extinguishing media: water spray, carbon dioxide, dry powder, foam Specific hazards: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Special protective equipment: Wear a self-contained breathing apparatus. Further information: Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. 6. Accidental Release Measures Personal precautions: Use personal protective clothing. Environmental precautions: Do not discharge into drains/surface waters/groundwater. Methods for cleaning up or taking up: For small amounts: Pick up with suitable absorbent material. For large amounts: Dike spillage. Pump off product. Dispose of absorbed material in accordance with regulations. 7. Handling and Storage Handling Handle in accordance with good industrial hygiene and safety practice. Protection against fire and explosion: Take precautionary measures against static discharges. Avoid all sources of ignition: heat, sparks, open flame. Storage Suitable materials for containers: High density polyethylene (HDPE) Further information on storage conditions: Keep container tightly sealed.

4 Page: 4/9 Below temperature limit the product properties will change. The property change is reversible by stirring. Please refer to the product specific data sheet for further information. Storage stability: Storage temperature: 5-40 C Protect from temperatures below: 5 C Characteristics of the product are reversibly changed when falling below the limit temperature. Protect from temperatures above: 40 C 8. Exposure controls and personal protection Components with occupational exposure limits propan-2-ol, ; TWA value 200 ppm (ACGIHTLV) STEL value 400 ppm (ACGIHTLV) TWA value 983 mg/m3 ; 400 ppm (OEL (ID)) STEL value 1,230 mg/m3 ; 500 ppm (OEL (ID)) TWA value 983 mg/m3 ; 400 ppm (OEL (ID)) STEL value 1,230 mg/m3 ; 500 ppm (OEL (ID)) Personal protective equipment Respiratory protection: Wear respiratory protection if ventilation is inadequate. Hand protection: Suitable are protective gloves with the following specification. The recommendation is valid for laboratory conditions, specific workplace conditions must be taken into consideration separately. Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): nitrile rubber (NBR) mm coating thickness Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. No eating, drinking, smoking or tobacco use at the place of work. 9. Physical and Chemical Properties Form: Colour: Odour: liquid yellowish almost odourless ph value: (20 C) (DGF-H-III 1)

5 Page: 5/9 boiling temperature: > 100 C (1,013 hpa) Flash point: > 100 C Aqueous preparation Evaporation rate: not applicable Flammability (solid/gas): not flammable Lower explosion limit: For liquids not relevant for classification and labelling. Upper explosion limit: not determined Ignition temperature: not determined Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Explosion hazard: not explosive Fire promoting properties: not fire-propagating Density: g/cm3 (25 C) Relative vapour density (air): not applicable Solubility in water: soluble Solubility (qualitative) solvent(s): distilled water miscible in all proportions Partitioning coefficient n-octanol/water (log Pow): <= (20 C) (DIN T2; Density, pyknometer) (OECD Guideline 107) Viscosity, dynamic: Viscosity, kinematic: not determined not determined Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. No further information available. 10. Stability and Reactivity Conditions to avoid: See MSDS section 7 - Handling and storage. Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Substances to avoid: No substances known that should be avoided.

6 Page: 6/9 Hazardous reactions: None if used for intended purpose. No hazardous decomposition products known. 11. Toxicological Information Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Experimental/calculated data: LD50 (oral): > 2,000 mg/kg (OECD Guideline 401) Irritation Assessment of irritating effects: Eye contact causes irritation. Not irritating to the skin. Experimental/calculated data: Skin corrosion/irritation rabbit: (OECD Guideline 404) Serious eye damage/irritation rabbit: (OECD Guideline 405) Respiratory/Skin sensitization Assessment of sensitization: There is no evidence of a skin-sensitizing potential. Germ cell mutagenicity Assessment of mutagenicity: The chemical structure does not suggest a specific alert for such an effect. Experimental/calculated data: Ames-test Bacteria: negative (OECD Guideline 471) Carcinogenicity Assessment of carcinogenicity: The chemical structure does not suggest a specific alert for such an effect. Reproductive toxicity Assessment of reproduction toxicity: The chemical structure does not suggest a specific alert for such an effect. Developmental toxicity

7 Page: 7/9 Assessment of teratogenicity: No data was available concerning toxicity to development. Specific target organ toxicity (single exposure): Assessment of STOT single: Based on available Data, the classification criteria are not met. Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: None known Aspiration hazard No aspiration hazard expected. Other relevant toxicity information The product has not been tested. The statements on toxicology have been derived from the properties of the individual components. 12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. Toxicity to fish: LC50 > mg/l (DIN EN ISO ) Microorganisms/Effect on activated sludge: EC0 > 100 mg/l (DIN Part 27 (draft)) Chronic toxicity to aquatic invertebrates: No observed effect concentration, > mg/l Mobility Assessment transport between environmental compartments: not applicable Persistence and degradability Elimination information: (Annex III, part B) The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support

8 Page: 8/9 this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them at their direct request or at the request of a detergent manufacturer. Bioaccumulation potential Assessment bioaccumulation potential: Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is not to be expected. 13. Disposal Considerations Must be disposed of or incinerated in accordance with local regulations. 14. Transport Information Domestic transport: Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations 15. Regulatory Information Regulations of the European union (Labelling) EEC Directives: Hazard symbol(s) Xi R-phrase(s) R36 S-phrase(s) S25 S26 S39 Irritant. Irritating to eyes. Avoid contact with eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection.

9 Page: 9/9 Other regulations If other regulatory information applies that is not already provided elsewhere in this safety data sheet, then it is described in this subsection. 16. Other Information Information on intended use: This product is of industrial quality and unless otherwise specified or agreed intended exclusively for industrial use. This includes the mentioned and recommended usage. Any other intended applications should be discussed with the manufacturer. In particular this concerns the application for products that are the object of special standards and regulations. Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.