H335 - May cause respiratory irritation H315 - Causes skin irritation. Name Product identifier % GHS-US classification

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1 Date of issue: 12/07/2016 Revision date: 12/07/2016 Supersedes: 05/01/2015 SECTION 1: Identification 1.1. Identification Product form : Mixtures Product name : PermaCast FG-HS CAS No : Mixture Product code : 1018 Other means of identification : Basic Speciality 1.2. Recommended use and restrictions on use Use of the substance/mixture : Refractory 1.3. Supplier Resco Products, Inc. One Robinson Plaza, Suite Steubenville Pike Pittsburgh, PA United States SDS@RescoProducts.com Emergency telephone number Emergency number : EMERGENCY ONLY (CHEMTREC) USA & Canada Outside USA & Canada SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) GHS07 Precautionary statements (GHS-US) 2.3. Other hazards which do not result in classification 2.4. Unknown acute toxicity (GHS US) SECTION 3: Composition/Information on ingredients 3.1. Substances 3.2. Mixtures : Warning : H320 - Causes eye irritation H335 - May cause respiratory irritation H315 - Causes skin irritation : P280 - Wear Dust respirator, protective gloves, eye protection Name Product identifier % GHS-US classification Magnesium Oxide (CAS No) Not classified chromium(iii) oxide (CAS No) Not classified iron(iii) oxide (CAS No) Not classified aluminium oxide, non-fibrous (CAS No) Not classified Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures after inhalation : Allow victim to breathe fresh air. First-aid measures after skin contact : Gently wash with plenty of soap and water. First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. First-aid measures after ingestion : Do NOT induce vomiting. Get medical advice/attention if you feel unwell Most important symptoms and effects (acute and delayed) Symptoms/injuries after inhalation : Coughing Immediate medical attention and special treatment, if necessary SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire. 12/07/2016 EN (English US) Page 1

2 Unsuitable extinguishing media : No unsuitable extinguishing media known Specific hazards arising from the chemical Fire hazard : Non-flammable. Reactivity : Fire conditions may produce small amounts of hexavalent chromium and other oxidation products Special protective equipment and precautions for fire-fighters Firefighting instructions : No specific fire-fighting instructions required. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment : Wear respiratory protection. Protective gloves. Safety glasses. Emergency procedures : Avoid contact with skin. Avoid contact with eyes For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment Environmental precautions 6.3. Methods and material for containment and cleaning up For containment : Collect spillage. Methods for cleaning up : Carefully collect the spill/leftovers Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Hygiene measures : Do not eat, drink or smoke when using this product. Wash skin thoroughly with mild soap and water Conditions for safe storage, including any incompatibilities Storage conditions : Store this product in a dry location where it can be protected from the elements. Incompatible products : Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters ACGIH ACGIH TWA (mg/m³) 10 mg/m³ (Magnesium oxide; USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value; Inhalable fraction) ACGIH ACGIH TWA (mg/m³) 0.5 mg/m³ (Chromium,inorganic Cr III compounds; USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value) ACGIH ACGIH TWA (mg/m³) 5 mg/m³ (Iron oxide (Fe2O3); USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value; Respirable fraction) ACGIH ACGIH TWA (mg/m³) 1 mg/m³ (Aluminium, insoluble compounds; USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value; Respirable fraction) 8.2. Appropriate engineering controls 8.3. Individual protection measures/personal protective equipment SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance Color Odor Odor threshold ph : Granular powder. : Green Gray : odorless Melting point : > 2000 F Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) : Non flammable. 12/07/2016 EN (English US) 2/5

3 Vapor pressure Relative vapor density at 20 C Relative density : 3.2 Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties : Slightly soluble Other information SECTION 10: Stability and reactivity Reactivity Fire conditions may produce small amounts of hexavalent chromium and other oxidation products Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 dermal rabbit Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC group IARC group > 5000 mg/kg (Rat; Literature study) > 2000 mg/kg body weight (Rabbit; Literature study) > mg/kg body weight (Rat; OECD 401: Acute Oral Toxicity; Experimental value) > 5000 mg/kg (Rat; Literature study) > mg/kg body weight (Rat; Equivalent or similar to OECD 401; Experimental value) 3 - Not classifiable 3 - Not classifiable Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Symptoms/injuries after inhalation : Coughing. SECTION 12: Ecological information Toxicity EC50 Daphnia ,TLM; 96 h; Mysidacea 12/07/2016 EN (English US) 3/5

4 LC50 fish 1 Threshold limit algae 1 LC50 fish 1 > 1000 mg/l (LC50; 48 h) LC50 fish 1 EC50 Daphnia 1 Threshold limit algae 1 > 2.9 μg/l (LC50; ISO ; 96 h; Danio rerio; Static system; Fresh water; Experimental value) > mg/l (EC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Desmodesmus subspicatus; Static system; Fresh water; Read-across) > 100 mg/l (NOEC; OECD 203: Fish, Acute Toxicity Test; 96 h; Salmo trutta; Flow-through system; Fresh water; Experimental value) > 100 mg/l (NOEC; OECD 202: Daphnia sp. Acute Immobilisation Test; 48 h; Daphnia magna) > 100 mg/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Selenastrum capricornutum) Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) Biodegradability: not applicable. No (test)data on mobility of the substance available. (inorganic) Biodegradability: not applicable. Forming sediments in water. Biodegradability in soil: not applicable. Adsorbs into the soil. (inorganic) Biodegradability: not applicable. Adsorbs into the soil. Biodegradability: not applicable. No (test)data on mobility of the substance available BCF fish 1 BCF other aquatic organisms 1 Bioaccumulation: not applicable (BCF; Lepomis macrochirus) 116 (BCF) BCF other aquatic organisms 2 86 (BCF) Potential for bioaccumulation (500 BCF 5000). No bioaccumulation data available. No bioaccumulation data available Mobility in soil Other adverse effects Effect on the global warming : No known effects from this product. GWPmix comment : No known effects from this product. SECTION 13: Disposal considerations Disposal methods SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT 12/07/2016 EN (English US) 4/5

5 TDG Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section International regulations CANADA EU-Regulations National regulations US State regulations PermaCast FG-HS (Mixture) U.S. - California - Proposition 65 - Other information U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - New Jersey - Right to Know Hazardous Substance List SECTION 16: Other information Revision date : 12/07/2016 Other information This product contains chromite (Cr*+3) which may in normal use, be converted chemically to a chromate (Cr*+6) hexavalent chrome, a chemical known to the State of California to cause cancer. : Report language name. English. In the event of any conflict between English and other language versions, the English version shall prevail. SDS US (GHS HazCom 2012) This information and recommendations set forth herein are taken from sources believed to be accurate as of the date herein, however, Resco Products, Inc. makes no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assumes no liability to any user thereof. 12/07/2016 EN (English US) 5/5