Completion of the Waste Determination Profile

Transcription

1 Procedure No.: WYN Page: 1 of 12 Wyandotte Reviewed: 10/20/16 Effective: 10/21/16 Supersedes: 09/15/09 Preparer: Owner: Approver: EHS Specialist EHS Env. Team Leader EHS Hub Manager REVISION HISTORY Date Revision Number Nature of Change 05/12/10 Draft Updated existing ES procedure to promote consistency with Wyandotte W-Standards, which cover EHS documents. 10/21/16 1 Various minor revisions to update the document to current conditions.

2 Procedure No.: WYN Page: 2 of 12 Wyandotte Reviewed: 10/20/16 Effective: 10/21/16 Supersedes: 05/12/10 1. PURPOSE To ensure that individuals trained in the management of hazardous and nonhazardous wastes at the Wyandotte Site have a full understanding of the process used to document waste determinations. 2. SCOPE Any trained employee tasked with the creation of a new waste stream at the Wyandotte Site. 3. INSTRUCTIONS: 3.1. Complete Sections A&B of the Waste Determination Profile identified below as provided in Attachment I Attach Material Safety Data Sheet(s) for waste constituents(s) Make a copy of the Waste Determination Profile for your own records Forward the original to OH-MI-CAN EHS Upon receiving the BASF Waste Determination Profile and MSDS from the generator the OH-MI-CAN HUB will review and complete remaining information A sample of the waste stream may be required for analytical information and/or waste stream approval at a treatment or disposal facility. Contact OH-MI-CAN HUB for sample requirements as they apply to your waste stream The completed Waste Determination Profile will be returned to the generator with the proper label text information on page 6 for completing and ordering of preprinted labels If you have any questions contact EHS. 4. SECTION A - GENERAL INFORMATION

3 Procedure No.: WYN Page: 3 of 12 Wyandotte Reviewed: 10/20/16 Effective: 10/21/16 Supersedes: 05/12/ General Information: Enter the generating unit, department, or plant Enter the unit, department, or plant manager Enter the name of the individual knowledgeable about the waste material Enter the contact(s) Phone extension(s) Waste Stream Description Information to be completed by OH-MI-CAN HUB Enter a common name that best describes the waste Identify a location description where the waste is generated Provide a description of the process generating the waste Enter the projected waste volume indicating units used. (i.e. lbs, gal. kg) Indicate the frequency the waste is generated Shipping Information: Information to be completed by OH-MI-CAN HUB Indicate the type and size of container used for the waste. 5. SECTION B - PROPERTIES AND COMPOSITION OF THE WASTE 5.1. Physical Properties List color(s) associated with the waste material Identify any odor associated with the waste material Indicate the physical state of the waste material at room temperature and standard pressure, noting whether or not layering is applicable Indicate the relative viscosity of the waste material Enter the melting point and boiling point of the material in degrees Fahrenheit Enter the vapor pressure of the waste material Enter the specific gravity of the waste material Enter the density of the waste material in pounds per gallon or pounds per cubic yard Enter the heating value of the waste material in Btu/lb. or Btu/gal.

4 Procedure No.: WYN Page: 4 of 12 Wyandotte Reviewed: 10/20/16 Effective: 10/21/16 Supersedes: 05/12/ Indicate the applicable flash point of the waste material or enter the exact value. Indicate method used Indicate the ph of the waste material or enter the exact value Chemical Composition: Chemical name: Do not use trade names Enter specific percent or range, maximum column must be greater than or equal to 100% (include water content if applicable) CASRN: Chemical Abstracts Registry Number RQ: Reportable Quantity Enter if known Concentration Range. 6. SECTION C - REGULATORY DETERMINATION (TO BE COMPLETED BY EHS) 6.1. Solid Waste Determination Review the definition of Solid Waste and review Table 1, to determinate Solid Waste status Exclusions: A. Review the Recycle Chart 261.4(a) determine if material is exempt. B. If another specific exclusion applies not in the determination C. If material is not excluded check radio box.

5 Procedure No.: WYN Page: 5 of 12 Wyandotte Reviewed: 10/20/16 Effective: 10/21/16 Supersedes: 05/12/ Hazardous Waste Determination: Process Waste Determination A. Indicate if the waste is a process waste. B. Determine if the process waste is subject to an F or K listing Product Waste Determination A. Indicate if waste is a Commercial Chemical Product B. Determine if waste is subject to P or U listing Characteristic Waste Determination. A. Determine through review of the physical properties section if waste exhibits a Characteristic. B. Review process chemistry or submit for analysis waste to determine if waste exhibits Characteristic of Toxicity (D004- D043). C. Note all codes that are applicable Conclusions Document waste determination conclusions Attach relevant information such as MSDSs and analytical reports. 7. SECTION D - LAND DISPOSAL RESTRICTIONS: 7.1. In the Table provided list all applicable hazardous waste codes Review the Treatment Standards Table in and note all applicable Treatment Standards and or concentration limits If the waste is subject to the one-time notification under 268.7(a)(7) note here and provide reasoning Determine if waste is subject to Universal Treatment Standards If waste is subject to UTS list all known compounds from the Table in and the treatment concentration limit.

6 Procedure No.: WYN Page: 6 of 12 Wyandotte Reviewed: 10/20/16 Effective: 10/21/16 Supersedes: 05/12/10 8. SECTION E - REPORTABLE QUANTITY DETERMINATION 8.1. Provided in the Table List all constituents and or waste codes with a Federal Reportable Quantity If a mixture RQ applies calculate the mixture RQ 8.3. If a RCRA Default RQ applies (e.g. D001 RQ = 100 lbs.) list the RCRA RQ. 9. SECTION F - RCRA AIR EMISSIONS APPLICABILITY DETERMINATION 9.1. Determine through knowledge or analysis if the VOC concentration exceeds the following thresholds: Subpart BB greater than 10% Subpart CC greater than or equal to 500 ppmv Determine container or tanks compliance Level If the unit is a recycle unit document if VOC level is greater than 10 ppm Determine applicability for Subpart AA. 10. SECTION G - DOT SHIPPING INFORMATION Determine DOT shipping name and related information Determine appropriate package information. 11. SECTION H - MISCELLANEOUS INFORMATION Enter Transporter and TSD approval and contact information. 12. ADDITIONAL ANALYTICAL DATA Enter any additional analytical data supporting the waste determination.

7 Procedure No.: WYN Page: 7 of 12 Wyandotte Reviewed: 10/20/16 Effective: 10/21/16 Supersedes: 05/12/ RELATED DOCUMENTS WYN Management of Chemical Waste State of Michigan Part 111 Rules of 1994 PA Hazardous Waste Management : Attachment 1 Waste Determination Profile Form

8 Attachment 1 - Waste Determination Profile Form Waste Name: Section A General Information Generator Information: Site/Unit: Waste Date: Last Revision: Page 1 Waste Information Generator s Common Name and Description: Location (Point(s) of Generation) : Process Description: (How was the waste generated?) Waste Generation Rate: Quantity (lbs., gals, drums, etc.) Per: Rate (shift, week, one-time, etc.) Storage Information: Storage Location: Container Type: Section B Physical Properties and Composition Physical Properties: Color: Number of Phases: Odor: Odor Threshold Physical State (stp): Vapor Press Viscosity (cps): Boiling Point Melting Point: Density Flash Point NACE Rate Aqueous ph Exact: Nonaqueous Aqueous ph Range: Composition: Ensure All EPCRA 313 compounds are listed Chemical Name CASRN RQ (lbs.) Min % Max % Section C Regulatory Determination Solid Waste Determination: Material is not a Solid Waste. Stop here and go to Conclusions The waste is a Solid waste specify regulation Exclusions: Material is not excluded The waste is exempted from regulation by 40 CFR 261.4(a) Recycle Chart The waste is exempted from regulation by other clause specify regulation:

9 Attachment 1 - Waste Determination Profile Form Page 2 Process Waste: This waste is not a process waste: This waste is a process waste: Non-specific sources (including solvent use). List applicable F codes: Specific sources as defined in 40 CFR 262. List applicable K codes: The waste is a process waste, but is not listed as an F or K code. Product Waste: The waste is not a listed discarded commercial chemical product with a sole active ingredient The waste is a discarded commercial chemical product with a sole active ingredient List applicable U code: List applicable P code: Characteristically Hazardous Wastes The waste does not exhibit any of characteristics of a Hazardous Waste: The waste exhibits one of the following characteristics: D001 Ignitability (High TOC) D002 Corrosivity D003 Reactivity D004 -D0043 Toxicity (List all Toxicity D codes and concentrations): Characteristic determination by: TCLP Total Metals By Knowledge Conclusion & Determination The material is NOT a RCRA Hazardous Waste. The material is a RCRA Hazardous Waste. Rationale (if needed): Embed Analytical Reports and or MSDS By analysis: attach copy of the lab summary. By knowledge. Provide brief description: The material is a State Hazardous Waste. List Codes: Section D Land Disposal Restrictions (LDR) The material was NOT a RCRA hazardous Waste at the point of generation. LDR does not apply. The material is/was a RCRA hazardous Waste at the point of generation. List ALL applicable waste codes: Waste Code Constituent Waste Water Std Non Waste Water Std Treatment Technology / Standard Significant (Y/N) LDR One Time Notification This material was, at point of generation, a hazardous waste and has been managed under one of the exclusions outlined in 40 CFR 268(a)(7). This document is to serve as a one time notification to file.

10 Attachment 1 - Waste Determination Profile Form Page 3 Universal Treatment Standards The waste is not a characteristic waste, UTS does not apply The waste is a high TOC D001, UTS does not apply The waste is characteristically hazardous and is subject to UTS for the underlying hazardous constituents listed here: Chemical Name Concentration Wastewater Standard Non-Wastewater Standard By analysis: attach copy of the lab summary. By knowledge: provide brief description of knowledge: Section E Reportable Quantity Determination Calculate the mixture RQ for each constituent to determine the RQ requirements. Constituent RQ / Constituent % = Mixture RQ Constituent Constituent RQ Constituent % Mixture RQ NA Section F RCRA Air Emissions Applicability Subpart CC Applicable. VOC Storage Type DOT container Level 1 DOT container Level 2 Storage Tank provide tank number Subpart BB Applicability Describe applicability: Subpart AA Applicable. VOC Type of Recycle Unit Operation (i.e. still, distillation column etc.) RCRA Air Emissions not applicable

11 Attachment 1 - Waste Determination Profile Form Section G Shipping Information: EPA Hazardous Waste (If it is a hazardous waste it is a DOT hazardous material) State Hazardous Waste (List codes): State Non-Hazardous Waste (List codes): 029L DOT hazardous material For DOT Hazardous materials: DOT Shipping Name: DOT Hazard Class: DOT Identification Number (UN/NA): DOT Package Group: Reportable Quantity (lbs.): DOT Approved Package DOT Hazard Marking or Label: DOT Notes: Page 4 Section H Miscellaneous Information Transporter 1 Name: Transporter 2 Name: TSD 1 Information: TSD Facility Name: Location: TSD 2 Information: TSD Facility Name: Location: TSD 3 Information: TSD Facility Name: Location: TSD 4 Information: TSD Facility Name: Location: TSD 5 Information: TSD Facility Name: Location: Phone: Phone: Approval Number: Number: Approval Number: Number: Approval Number: Number: Approval Number: Number: Approval Number: Number:

12 Attachment 1 - Waste Determination Profile Form Section I Additional Analytical Data Metals mg/kg Arsenic (As) Mercury (Hg) Barium (Ba) Nickel (Ni) Cadmium (Cr) Selenium (Se) Chromium (Cr) Silver (Ag) Copper (Cu) Zinc (Zn) Lead (Pb) Thalium (Tl) Page 5 Other Properties various units Chlorine BTUs Bromine Halides. Organics & Other Constituents mg/kg TSD Notes This material is a hazardous waste. Sate and Federal law requires properly handling. Make certain that you have: 1. Packaged the material in the proper container: 2. Closed and secured all container openings 3. Placed the hazardous label on the container 4. Dated the container 5. Moved the container to the proper location 6. Notified Site EHS Hub Personnel This material is not a hazardous waste. Make certain that you: 1. Packaged the material in the proper container 2. Closed and secured all container openings 3. Placed the non-hazardous label on the container 4. Placed appropriate OSHA HAZCOM Label on container 5. Moved the container to the proper location 6. Notified Site EHS Hub Personnel