1. Substance/preparation and manufacturer/supplier identification. Irgazin Rubine L 4020 (old Irgazin DPP Rubine TRI)

Transcription

1 Safety data sheet Page: 1/9 1. Substance/preparation and manufacturer/supplier identification Irgazin Rubine L 4020 (old Irgazin DPP Rubine TRI) Use: pigment Manufacturer/supplier: PT BASF Indonesia Plaza GRI, 10th & 11th Floor Jl. H.R. Rasuna Said Blok X-2 No.1 Jakarta Selatan 12950, P.O. Box 2431 Gbr., Jakarta 10024, INDONESIA Telephone: / Telefax number: / Emergency information: International emergency number: Telephone: Hazard identification Classification of the substance and mixture: No need for classification according to GHS criteria for this product. Label elements and precautionary statement: The product does not require a hazard warning label in accordance with GHS criteria. Other hazards which do not result in classification: The product is under certain conditions capable of dust explosion.

2 Page: 2/9 3. Composition/information on ingredients Chemical nature organic pigment, preparation, Diketo-pyrrolo-pyrrol 4. First-Aid Measures General advice: Remove contaminated clothing. If inhaled: If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention. On skin contact: Wash thoroughly with soap and water. On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion: Rinse mouth and then drink plenty of water. Note to physician: Symptoms: No significant reaction of the human body to the product known. Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Suitable extinguishing media: dry powder, foam Unsuitable extinguishing media for safety reasons: carbon dioxide Additional information: Avoid whirling up the material/product because of the danger of dust explosion. Specific hazards: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Special protective equipment: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations.

3 Page: 3/9 6. Accidental Release Measures Personal precautions: Avoid dust formation. Use personal protective clothing. Environmental precautions: Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Methods for cleaning up or taking up: For small amounts: Pick up with suitable appliance and dispose of. For large amounts: Contain with dust binding material and dispose of. Avoid raising dust. 7. Handling and Storage Handling Breathing must be protected when large quantities are decanted without local exhaust ventilation. Protection against fire and explosion: Avoid dust formation. Dust clouds from finely particulated pigments may be hazardous (dust explosion risk). Storage Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. 8. Exposure controls and personal protection Personal protective equipment Respiratory protection: Suitable respiratory protection for lower concentrations or short-term effect: Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2) Hand protection: Chemical resistant protective gloves Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types. Eye protection: Safety glasses with side-shields.

4 Page: 4/9 Body protection: Closed footwear., Working clothes. General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is recommended. 9. Physical and Chemical Properties Form: Colour: Odour: Odour threshold: ph value: powder Blue-red odourless not determined not applicable Melting point: > 400 C (OECD Guideline 102) Boiling point: not applicable Flash point: Evaporation rate: not applicable, the product is a solid The product is a non-volatile solid. Flammability (solid/gas): not highly flammable Lower explosion limit: (UN Test N.1 (ready combustible solids)) For solids not relevant for classification and labelling. Upper explosion limit: For solids not relevant for classification and labelling. Ignition temperature: > 500 C (VDI 2263, sheet 1, 2.6) Thermal decomposition: 265 C, 40 J/g (DSC (DIN 51007)) Self ignition: Temperature: > 350 C No self ignition was observed up to the specified temperature. (Method: VDI 2263, sheet 1, 1.4.1) Self heating ability: Temperature: > 400 C (Method: VDI 2263, sheet 1, 1.3) It is not a substance capable of spontaneous heating according to UN transport regulations class 4.2. Minimum ignition energy: The product is capable of dust explosion. Explosion hazard: not explosive (VDI 2263, sheet 1, 2.1.1)

5 Page: 5/9 Fire promoting properties: not fire-propagating Vapour pressure: not applicable Relative density: (20 C) Bulk density: approx. 290 kg/m3 Relative vapour density (air): The product is a non-volatile solid. (Directive 92/69/EEC, A.3) Solubility in water: < g/l (20 C) Hygroscopy: The product has not been tested. Solubility (quantitative) : insoluble Partitioning coefficient n-octanol/water (log Pow): 4.44 (OECD Guideline 117) Viscosity, dynamic: Study does not need to be conducted. 10. Stability and Reactivity Conditions to avoid: Avoid dust formation. Avoid deposition of dust. Avoid sources of ignition. Avoid electro-static discharge. Thermal decomposition: 265 C, 40 J/g (DSC (DIN 51007)) Substances to avoid: No substances known that should be avoided. Hazardous reactions: Dust explosion hazard. Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological Information Acute toxicity LD50 rat (oral): > 2,000 mg/kg (OECD Guideline 423) LC50 (by inhalation): not determined LD50 rat (dermal): > 2,000 mg/kg (OECD Guideline 402)

6 Page: 6/9 Irritation Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404) Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405) Respiratory/Skin sensitization Mouse Local Lymph Node Assay (LLNA) mouse: Non-sensitizing. (OECD Guideline 429) Germ cell mutagenicity Assessment of mutagenicity: No mutagenic effect was found in various tests with bacteria and mammalian cell culture. The product has not been tested. The statement has been derived from the properties of the individual components. Ames-test negative (OECD Guideline 471) The product has not been tested. The statement has been derived from the properties of the individual components. Carcinogenicity Assessment of carcinogenicity: Reproductive toxicity Assessment of reproduction toxicity: Developmental toxicity Assessment of teratogenicity: Specific target organ toxicity (single exposure): Remarks: Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: No substance-specific organtoxicity was observed after repeated administration to animals. Subacute toxicity rat (OECD Guideline 407) NOAEL: 1,000 mg/kg

7 Page: 7/9 Aspiration hazard not applicable 12. Ecological Information Ecotoxicity Toxicity to fish: LC50 (96 h) > 100 mg/l, Brachydanio rerio (OECD 203; ISO 7346; 92/69/EEC, C.1, static) (based on loading rate) Aquatic invertebrates: LC50 (48 h) > 100 mg/l, Daphnia magna (OECD Guideline 202, part 1, static) (based on loading rate) Aquatic plants: EC50 (72 h) > 100 mg/l, Pseudokirchneriella subcapitata (OECD Guideline 201, static) (based on loading rate) Microorganisms/Effect on activated sludge: EC50 (3.00 h) > 100 mg/l, activated sludge (DIN EN ISO 8192-OECD /302/EEC,P. C) Chronic toxicity to fish: Chronic toxicity to aquatic invertebrates: Assessment of terrestrial toxicity: No data available concerning terrestrial toxicity. Mobility Assessment transport between environmental compartments: Persistence and degradability Elimination information: (28 d) (OECD 301B; ISO 9439; 92/69/EEC, C.4-C) Not readily biodegradable. Bioaccumulation potential Assessment bioaccumulation potential: Accumulation in organisms is not to be expected. Additional information Add. remarks environm. fate & pathway:

8 Page: 8/9 Treatment in biological waste water treatment plants has to be performed according to local and administrative regulations. Other ecotoxicological advice: Do not discharge product into the environment without control. 13. Disposal Considerations Must be disposed of or incinerated in accordance with local regulations. Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. 14. Transport Information Domestic transport: Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations 15. Regulatory Information Regulations of the European union (Labelling) Directive 1999/45/EC ('Preparation Directive'): The product does not require a hazard warning label in accordance with EC Directives. Other regulations

9 Page: 9/9 16. Other Information Due to the merger of CIBA and BASF Group all Material Safety Data Sheets have been reassessed on the basis of consolidated information. This may have resulted in changes of the Material Safety Data Sheets. In case you have questions concerning such changes please contact us at the address mentioned in Section I. Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.