: Bonide Rose Rx Systemic Drench

Transcription

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Product code : : Bonide Rose Rx Systemic Drench 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet Bonide Products, Inc Sutliff Road Oriskany, NY T (315) Emergency telephone number : Insecticide, Fungicide Emergency number : CHEMTREC - 1 (800) and/or 1 (703) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Acute Tox. 4 (Oral) H Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Warning : H302 - Harmful if swallowed : P264 - Wash hands thoroughly after handling P270 - Do not eat, drink or smoke when using this product P301+P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P330 - If swallowed, rinse mouth P501 - Dispose of contents/container to in accoprdance with local/national regulations 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients Mixture Name Product identifier % Classification (GHS-US) distillates (petroleum), hydrotreated heavy paraffinic (CAS No) Carc. 1B, H350 Tebuconazole (CAS No) Acute Tox. 4 (Oral), H302 Aquatic Chronic 2, H411 Imidacloprid (ISO), 1-(6-chloropyridin-3-ylmethyl)-Nnitroimidazolidin-2-ylidenamine (CAS No) Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Revision date: 02/17/2016 EN (English US) Page 1

2 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the person to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries : May cause cancer Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. : Store in original container. Keep container closed when not in use. : Strong bases. Strong acids. : Sources of ignition. Revision date: 02/17/2016 EN (English US) 2/5

3 SECTION 8: Exposure controls/personal protection 8.1. Control parameters USA ACGIH ACGIH TWA (mg/m³) 5 mg/m³ (Mineral oil, pure, highly and severely refined; USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value; Inhalable fraction) 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Respiratory protection : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or safety glasses. : Wear approved mask. : When using, do not eat, drink or smoke. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Dark brown liquid with brown specs. Color : Brown. Odor : Slight Insecticide type odor. Odor threshold ph : 7-8 Relative evaporation rate (butyl acetate=1) Melting point Freezing point Boiling point Flash point Self ignition temperature Decomposition temperature Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density : 1.17 Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidizing properties Explosive limits 9.2. SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Extremely high or low temperatures. Revision date: 02/17/2016 EN (English US) 3/5

4 10.5. Incompatible materials Strong acids. Strong bases Hazardous decomposition products Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Harmful if swallowed. LD50 oral rat > 5000 mg/kg body weight (Rat; OECD 401: Acute Oral Toxicity; Experimental value) LD50 dermal rabbit > 5000 mg/kg body weight (Rabbit; Experimental value; Equivalent or similar to OECD 402) LC50 inhalation rat (mg/l) > 5.53 mg/l/4h (Rat; Experimental value) Imidacloprid (ISO), 1-(6-chloropyridin-3-ylmethyl)-N-nitroimidazolidin-2-ylidenamine ( ) ATE (oral) mg/kg body weight LD50 oral rat LD50 dermal rat LC50 inhalation rat (mg/l) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms 1700 mg/kg (Rat; Literature study) > 5000 mg/kg (Rat; Literature study) > 0.8 mg/l/4h (Rat; Literature study) ph: 7-8 ph: 7-8 : Based on available data, the classification criteria are not met. SECTION 12: Ecological information Toxicity LC50 fish 1 Threshold limit algae 1 > 100 mg/l (LL50; OECD 203: Fish, Acute Toxicity Test; 96 h; Pimephales promelas; Static system; Fresh water; Experimental value) >= 100 mg/l (NOEL; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella subcapitata; Static system; Fresh water; Experimental value) LC50 fish 1 EC50 Daphnia 1 Threshold limit algae mg/l (LC50; US EPA; 96 h; Salmo gairdneri; Flow-through system) 4.2 mg/l (EC50; OECD 202: Daphnia sp. Acute Immobilisation Test; 48 h; Daphnia magna) 4.01 mg/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 96 h; Scenedesmus subspicatus) Bonide Rose Rx Systemic Drench Not readily biodegradable in water. Adsorbs into the soil. Not readily biodegradable in water. Revision date: 02/17/2016 EN (English US) 4/5

5 12.3. Bioaccumulative potential Bonide Rose Rx Systemic Drench Bioaccumulative potential Bioaccumulative potential No bioaccumulation data available. Log Pow Mobility in soil Ecology - soil Other adverse effects Not toxic to bees. : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information In accordance with DOT No dangerous good in sense of transport regulations Additional information SECTION 15: Regulatory information : Dispose in a safe manner in accordance with local/national regulations. : Avoid release to the environment. : No supplementary information available. This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION Causes moderate eye irritation. Avoid contact with eyes or clothing. Wear long-sleeved shirt, long pants, shoes, socks, and gloves made of any waterproof material. Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, or using tobacco will reduce exposure US Federal regulations International regulations US State regulations SECTION 16: : None. Full text of H-phrases: see section 16: Acute Tox. 4 (Oral) Acute toxicity (oral) Category Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category Carc. 1B Carcinogenicity Category 1B H302 Harmful if swallowed H350 May cause cancer H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects H411 Toxic to aquatic life with long lasting effects SDS US (GHS HazCom 2012) - Pesticides This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. Revision date: 02/17/2016 EN (English US) 5/5