Issuing Date: 19-Mar-2015 Revision Date: 19-Mar-2015 Version 1 1. IDENTIFICATION. Finished Product - Professional Use Only

Transcription

1 SAFETY DATA SHEET Issuing Date: 19-Mar-2015 Version 1 1. IDENTIFICATION Product Name Dolce&GabbanaTHEEYESHADOW Product ID: Product Type: Recommended Use Manufacturer Address Emergency Telephone _PROF_NG Finished Product - Professional Use Only Personal Beauty Care Product Fine Fragrances P&G Prestige Products 375 Davidsons Mill Road, Jamesburg, NJ USA pgsds.im@pg.com Transportation (24 HR) CHEMTREC (U.S./ Canada) or Mexico toll free in country: HAZARD IDENTIFICATION This product is classifed under 29CFR (d) and the Canadian Hazardous Products Regulation as follows:. Not Classified. Hazard pictograms Prevention Response Storage Disposal Hazards not otherwise classified (HNOC) Page 1 / 7

2 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients are listed according to 29CFR Appendix D and the Canadian Hazardous Products Regulation Chemical Name Synonyms Trade Secret CAS-No Weight % Talc (Mg3H2(SiO3)4) - No Mica-group minerals - No Iron oxide (Fe2O3) - No Octadecanoic acid, zinc salt (2:1) - No Titanium oxide (TiO2) - No First aid measures for different exposure routes 4. FIRST AID MEASURES Eye contact Skin contact Ingestion Inhalation Most important symptoms/effects, acute and delayed Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention immediately if irritation persists. under normal use. Not an expected route of exposure. If swallowed:. Clean mouth with water and afterwards drink plenty of water. under normal use.. Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Water. Dry chemical. Alcohol-resistant foam. Carbon dioxide (CO 2). Unsuitable Extinguishing Media Special hazard Special protective equipment for fire-fighters Specific hazards arising from the chemical. known. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Advice for emergency responders under normal use conditions. Use personal protective equipment as required. Methods and materials for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Page 2 / 7

3 Methods for cleaning up Sweep up and shovel into suitable containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible products Keep containers tightly closed in a dry, cool and well-ventilated place. known. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines. Chemical Name CAS-No ACGIH TLV OSHA PEL Mexico PEL Talc (Mg3H2(SiO3)4) TWA: 2 mg/m 3 particulate matter containing no asbestos and <1% crystalline silica, respirable (vacated) TWA: 2 mg/m 3 respirable dust <1% Crystalline silica, containing no Asbestos TWA: 20 mppcf if 1% Quartz or more, use Quartz limit Mexico: TWA 2 mg/m 3 Mica-group minerals TWA: 3 mg/m 3 respirable Iron oxide (Fe2O3) TWA: 5 mg/m 3 respirable Octadecanoic acid, zinc salt (2:1) TWA: 10 mg/m 3 except stearates of toxic metals (vacated) TWA: 3 mg/m 3 respirable dust <1% Crystalline silica TWA: 20 mppcf <1% Crystalline silica TWA: 10 mg/m 3 fume TWA: 15 mg/m 3 total dust TWA: 5 mg/m 3 respirable (vacated) TWA: 10 mg/m 3 fume and total dust Iron oxide (vacated) TWA: 5 mg/m 3 respirable regulated under Rouge TWA: 15 mg/m 3 total dust TWA: 5 mg/m 3 respirable (vacated) TWA: 10 mg/m 3 total dust (vacated) TWA: 5 mg/m 3 respirable Titanium oxide (TiO2) TWA: 10 mg/m 3 TWA: 15 mg/m 3 total dust (vacated) TWA: 10 mg/m 3 total dust Mexico: TWA 3 mg/m 3 Mexico: TWA 5 mg/m 3 Mexico: STEL 10 mg/m 3 Mexico: TWA 10 mg/m 3 Mexico: STEL 20 mg/m 3 Mexico: TWA 10 mg/m 3 Mexico: STEL 20 mg/m 3 Chemical Name CAS-No Alberta Quebec Ontario TWAEV British Columbia Talc (Mg3H2(SiO3)4) TWA: 2 mg/m 3 TWA: 3 mg/m 3 TWA: 2 mg/m 3 TWA: 2 mg/m 3 Mica-group minerals TWA: 3 mg/m 3 TWA: 3 mg/m 3 TWA: 3 mg/m 3 TWA: 3 mg/m 3 Iron oxide (Fe2O3) TWA: 5 mg/m 3 TWA: 5 mg/m 3 TWA: 10 mg/m 3 TWA: 5 mg/m 3 TWA: 10 mg/m 3 TWA: 3 mg/m 3 TWA: 5 mg/m 3 STEL: 10 mg/m 3 Octadecanoic acid, zinc salt (2:1) TWA: 10 mg/m 3 TWA: 10 mg/m 3 TWA: 10 mg/m 3 TWA: 10 mg/m 3 STEL: 20 mg/m 3 Titanium oxide (TiO2) TWA: 10 mg/m 3 TWA: 10 mg/m 3 TWA: 10 mg/m 3 TWA: 10 mg/m 3 TWA: 3 mg/m 3 Page 3 / 7

4 No relevant exposure guidelines for other ingredients Exposure controls Engineering Measures Personal Protective Equipment Eye Protection Hand Protection Skin and Body Protection Respiratory Protection 9. PHYSICAL AND CHEMICAL PROPERTIES Physical C Appearance Odor Odor threshold solid powder, Various color by product characteristic Property Values Note ph value Not Applicable Melting/freezing point Boiling point/boiling range Flash point Evaporation rate Flammability (solid, gas) Flammability Limits in Air Upper flammability limit Lower Flammability Limit Vapor pressure Vapor density Relative density Water solubility Solubility in other solvents Partition coefficient: n-octanol/water Autoignition temperature. Decomposition temperature. Viscosity of Product VOC Content (%) Products comply with US state and federal regulations for VOC content in consumer products. 10. STABILITY AND REACTIVITY Reactivity Stability Hazardous polymerization Hazardous Reactions Conditions to Avoid Materials to avoid under normal use conditions. Stable under normal conditions. Hazardous polymerization does not occur. under normal processing. under normal processing. in particular. Hazardous Decomposition Products under normal use. Page 4 / 7

5 Product Information Information on likely routes of exposure 11. TOXICOLOGICAL INFORMATION Inhalation Skin contact Ingestion Eye contact Delayed and immediate effects as well as chronic effects from short and long-term exposure Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Skin sensitization Respiratory sensitization Germ cell mutagenicity Neurological Effects Reproductive toxicity Developmental toxicity Teratogenicity STOT - single exposure STOT - repeated exposure Target Organ Effects Aspiration hazard Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component Information Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 Inhalation Iron oxide (Fe2O3) > 5000 mg/kg bw (EU > 2000 mg/kg (rabbit) - Method B.1; standard acute method; rat) Octadecanoic acid, zinc salt (2:1) > 5000 mg/kg bw (Guideline not indicated; standard acute method; rat; weight of evidence data) > 2000 mg/kg bw (Guideline not indicated; standard acute method; rabbit; weight of evidence data) mg/l air (QSAR value (QSAR Toolbox version 3.1); OECD 403; standard acute method; rat; 4 h) Ecotoxicity The product is not expected to be hazardous to the environment. 12. ECOLOGICAL INFORMATION Persistence and degradability Bioaccumulative potential Mobility Other adverse effects DISPOSAL CONSIDERATIONS Waste treatment Waste from Residues / Unused Products Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Disposal should be in accordance with applicable regional, national and local laws and Page 5 / 7

6 regulations. California Hazardous Waste Codes (non-household setting) TRANSPORT INFORMATION DOT IMDG IATA Not regulated Not regulated Not regulated U.S. Federal Regulations 15. REGULATORY INFORMATION SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS-No SARA Threshold Values % Octadecanoic acid, zinc salt (2:1) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material Food and Drug Administration (FDA) The product described in this Material Safety Data Sheet is regulated under the Federal Food, Drug, and Cosmetics Act and is safe to use as per directions on container, box or accompanying literature (where applicable) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ): Chemical Name CAS-No CWA - Reportable Quantities Octadecanoic acid, zinc salt (2:1) CWA - Toxic CWA - Priority Pollutants Pollutants X - - California Proposition 65 This product is not subject to warning labeling under California Proposition 65. U.S. State Regulations (RTK) CWA - Hazardous Substances Chemical Name CAS-No New Jersey Talc (Mg3H2(SiO3)4) X Mica-group minerals X Iron oxide (Fe2O3) X Octadecanoic acid, zinc salt (2:1) X Page 6 / 7

7 Titanium oxide (TiO2) X Chemical Name CAS-No Massachusetts Talc (Mg3H2(SiO3)4) X Mica-group minerals X Iron oxide (Fe2O3) X Octadecanoic acid, zinc salt (2:1) X Titanium oxide (TiO2) X Chemical Name CAS-No Pennsylvania Talc (Mg3H2(SiO3)4) X Mica-group minerals X Iron oxide (Fe2O3) X Octadecanoic acid, zinc salt (2:1) X Titanium oxide (TiO2) X Silica (SiO2) X Starch X International Inventories United States Product is a personal care product and regulated under FDA. Canada This product is in compliance with CEPA for import by P&G. Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory CEPA - Canadian Environmental Protection Act Perfumes contained with the products comply with appropriate IFRA guidance. 16. OTHER INFORMATION Issuing Date: Revision Date: Reason for revision 19-Mar Mar-2015 Initial Release. Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 7 / 7