SAFETY DATA SHEET FABSIL DEODORANT

Transcription

1 Revision Date 20/12/2012 Revision 2 Supersedes date 18/07/2012 SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses SHOE DEODORISER 1.3. Details of the supplier of the safety data sheet Supplier Grangers International Ltd Grange Close Clover Nook Industrial Park Alfreton Derbyshire, DE55 4QT UK +44 (0) (0) info@grangers.co.uk 1.4. Emergency telephone number +44 (0) (MON-FRI 09:00-17:00) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) F+;R12. R52/ Label elements Labelling Extremely flammable Risk Phrases Safety Phrases R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R12 Extremely flammable. A1 Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. A2 Do not spray on a naked flame or any incandescent material. S2 Keep out of the reach of children. S16 Keep away from sources of ignition - No smoking. S23 Do not breathe vapour/spray. S51 Use only in well-ventilated areas Other hazards SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures 1 / 7

2 ETHANOL 30-60% CAS-No.: EC No.: Classification (EC 1272/2008) Flam. Liq. 2 - H225 Classification (67/548/EEC) F;R11 PROPAN-2-OL 10-30% CAS-No.: EC No.: Classification (EC 1272/2008) Flam. Liq. 2 - H225 Eye Irrit. 2 - H319 STOT SE 3 - H336 Classification (67/548/EEC) F;R11 Xi;R36 R67 TRICLOSAN < 1% CAS-No.: EC No.: Classification (EC 1272/2008) Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Classification (67/548/EEC) Xi;R36/38 N;R50/53 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Ingestion Contact physician if larger quantity has been consumed. Skin contact Wash skin with soap and water. Eye contact Immediately rinse with water. Get medical attention if any discomfort continues Most important symptoms and effects, both acute and delayed Inhalation May cause an asthma-like shortness of breath. Ingestion May cause nausea, headache, dizziness and intoxication. Skin contact Prolonged or repeated contact with skin may cause redness, itching, irritation and eczema/chapping. Eye contact Irritation of eyes and mucous membranes Indication of any immediate medical attention and special treatment needed No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in doubt, GET MEDICAL ATTENTION PROMPTLY! SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media 2 / 7

3 Extinguishing media Extinguish with carbon dioxide or dry powder. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Hazardous combustion products None under normal conditions. Unusual Fire & Explosion Hazards Aerosol cans may explode in a fire Advice for firefighters Special Fire Fighting Procedures Containers close to fire should be removed or cooled with water. Protective equipment for fire-fighters Use protective equipment appropriate for surrounding materials. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Do not smoke, use open fire or other sources of ignition. Do not breathe vapour. Provide adequate ventilation Environmental precautions Do not discharge into drains, water courses or onto the ground Methods and material for containment and cleaning up Absorb with sand or other inert absorbent Reference to other sections For personal protection, see section 8. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Read and follow manufacturer's recommendations Conditions for safe storage, including any incompatibilities Keep away from heat, sparks and open flame. Aerosol cans: Must not be exposed to direct sunlight or temperatures above 50 C. Store at moderate temperatures in dry, well ventilated area Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes ETHANOL WEL 1000 ppm 1920 mg/m3 PROPAN-2-OL WEL 400 ppm 999 mg/m3 500 ppm 1250 mg/m3 WEL = Workplace Exposure Limit Exposure controls Process conditions Provide eyewash station. Engineering measures Provide adequate ventilation. 3 / 7

4 Respiratory equipment No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists. Hand protection For prolonged or repeated skin contact use suitable protective gloves. Eye protection Wear approved chemical safety goggles where eye exposure is reasonably probable. Other Protection Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact. Hygiene measures Wash promptly with soap & water if skin becomes contaminated. Skin protection Wear apron or protective clothing in case of splashes. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Odour Solubility Relative density Flash point ( C) Clear liquid. Characteristic. Perfume. Slightly soluble in water oC <0oC 9.2. Other information SECTION 10: STABILITY AND REACTIVITY Reactivity No specific reactivity hazards associated with this product Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Hazardous Polymerisation Unknown Conditions to avoid Avoid exposing aerosol containers to high temperatures or direct sunlight Incompatible materials Materials To Avoid Flammable/combustible material Hazardous decomposition products SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Inhalation May cause irritation to the respiratory system. Vapours may cause headache, fatigue, dizziness and nausea. Prolonged inhalation of high concentrations may damage respiratory system. Skin contact Prolonged and frequent contact may cause redness and irritation. Eye contact Irritating to eyes. 4 / 7

5 Route of entry Inhalation. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity No data on possible environmental effects have been found Toxicity Acute Fish Toxicity Not considered toxic to fish Persistence and degradability Degradability The product is biodegradable Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation Mobility in soil Mobility: The product is partly soluble in water. May spread in the aquatic environment Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects Not known. SECTION 13: DISPOSAL CONSIDERATIONS General information Do not puncture or incinerate even when empty Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION UN number UN No. (ADR/RID/ADN) 1950 UN No. (IMDG) 1950 UN No. (ICAO) UN proper shipping name Proper Shipping Name Proper Shipping Name Aerosols Aerosols Transport hazard class(es) ADR/RID/ADN Class 2.1 ADR/RID/ADN Class Class 2.1: Flammable gases. ADR Label No. 2 IMDG Class 2.1 ICAO Class/Division 2.1 Transport Labels 5 / 7

6 FLAMMABLE GAS Packing group ADR/RID/ADN Packing group 5F IMDG Packing group 2 ICAO Packing group N/A Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user EMS 2-13 Emergency Action Code N/A Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not relevant SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture EU Legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Revision Date 20/12/2012 Revision 2 Supersedes date 18/07/2012 Risk Phrases In Full R12 R52/53 R11 R36/38 R36 R67 R50/53 Extremely flammable. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Highly flammable Irritating to eyes and skin. Irritating to eyes. Vapours may cause drowsiness and dizziness. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 6 / 7

7 Hazard Statements In Full H319 H315 H222 H412 H225 H336 H410 H400 Causes serious eye irritation. Causes skin irritation. Extremely flammable aerosol. Harmful to aquatic life with long lasting effects. Highly flammable liquid and vapour. May cause drowsiness or dizziness. Very toxic to aquatic life with long lasting effects. Very toxic to aquatic life. 7 / 7