Version: 8.1. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

Transcription

1 Revised edition: Version: 8.1 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: XSL Poppy Red Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Coloring agent for dye and varnish industry Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 H319 Cat.: 2 Eye irritation, category 2 Causes serious eye irritation. Classification according to EC Regulation No. 67/548 or No. 1999/45 Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: GHS07-1 Signal word: Warning Hazard designation: H319 Causes serious eye irritation. 2

2 Safety designation: P264 P280 P305+P351+P338 P311 P337 Page 2 Wash thoroughly after handling. Wear protective gloves/ clothing/ eye/ face protection. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses and continue rinsing. Call a poison center or physician. If eye irritation persists: Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture Contains 1,2-Benzisothiazol-3(2H)-one This product is capable of dust explosion under certain circumstances. Chemical Characterization: Pigment Red 112, C.I Hazardous Ingredients: PGMS-Salt (H319); REACH Reg. No Maleic Acid, Polymer with diisobuten, sodium salt (H319); CLP C&L Number Sulfonic acid, C14-17-sec-Alkane-, sodium salts (Xn; R ; H ); REACH , % % % CAS-Nr: EINECS-Nr: EC-Nr: CAS-Nr: EINECS-Nr: EC-Nr: CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Remove contaminated clothes immediately. Supply fresh air. Consult physician if symptoms persist. Remove contaminated clothing. Wash off immediately with plenty of water and soap. Rinse open eyes with plenty of water for at least 15 minutes After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with water and drink plenty of water. Symptoms: 3

3 No further information available. Page Effects: Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Symptomatic treatment (decontamination, vital functions), no specific antidote known. Extingishing powder, foam Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Carbon dioxide (CO2) Special hazards: Advice for Firefighters Protective equipment: In case of fire: hazardous vapors may be released. Development of fumes/aerosol. Wear self-contained respiratory protective device Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Avoid formation of dust: risk of dust explosion. Dispose of fire debris and contaminated extinguishing water in accordance with local regulations Personal precautions: Environmental Precautions Avoid formation of dust, wear protective clothing Environmental precautions: Methods and Material for Containment and Cleaning Up Keep spills and cleaning runoff out of municipal sewers and open bodies of water. Methods and material: Small spills: Clean up with suitable appliance and dispose adequately. Large spills: Contain with dust binding material and dispose accordingly Reference to other Sections See Section 13 for information on disposal. Protective clothing, see Section Handling and Storage 4

4 7. 1. Precautions for Safe Handling Page 4 Instructions on safe handling: Respiratory protection when handling without exhaust system Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not inhale dust. Wash hands before breaks and at the end of work. Storage conditions: Store in tightly sealed containers in a dry and cool room. Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Avoid dust formation. Take measures to prevent electrostatic discharge. Dust explosion class 3 (Kst-value >300 bar m/s). 11; Combustible solids Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): none known Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Ensure adequate ventilation, especially in confined areas. Personal Protection General protective measures: Respiratory protection: The usual precautionary measures are to be adhered to when handling chemicals. Suitable respiratory protection for lower concentration or shortterm effect: particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, type P2 or FFP2). 5

5 Hand protection: Page 5 Chemical protective gloves (EN 374 (Europe), F739 (US)). Protective glove material: Eye protection: Body protection: Recommended: Protective index 6, > 480 min. of permeation time accord. EN 374. Nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinyl chloride (0.7 mm). Please note the manufacturers detailed statements, especially about the minimum thickness and the minimum breakthrough time. Safety glasses with protective shields (EN 166). Protective clothing Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Prevent from getting into the soil, surface water and sewage system. Form: Color: Odor: Odor threshold: ph-value: powder red product specific No information available. 7-9 (100 g/l) Melting temperature: > 100 C Boiling temperature: Flash point: Evaporation rate: not determined This product is a non-volatile solid. Flammability (solid, gas): > 500 C (DIN 54836) Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: no information available no information available This product is a non-volatile solid. Density: 6

6 Page 6 Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: miscible Product is not auto-ignitable. Decomposition temperature: > 75 C Viscosity, dynamic: Explosive properties: Product does not present an explosion hazard. Oxidizing properties: not oxidizing Bulk density: kg/m Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Hygroscopy: not hygroscopic 10. Stability and Reactivity Reactivity Stable if used according to specifications Chemical Stability Stable if used according to specifications Possibility of Hazardous Reactions Risk of dust explosion Conditions to Avoid Conditions to avoid: Avoid formation of dust. Thermal decomposition: Imcompatible Materials None known Hazardous Decomposition Products None if stored and handled according to specifications. 7

7 10.7. Further Information 11. Toxicological Information Information on Toxicological Effects Page 7 Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: > 5000 mg/kg (rat) No information available. No information available. Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Slight irritant effect (rabbit; OECD 404) Irritating to eyes. No information available. No information available Not sensitizing (guinea pig; OECD 406). No mutagenic effects known. No data available. No cancerogenic effect known. No information available. Repeated exposure: no information available. Single exposure: no organospecific toxicity expected. Aspiration hazard: The data refer to the properties of the individual components. Not hazardous for aqueous organisms. Bacteria toxicity: 8

8 Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Not readily biodegradable. No bioaccumulation expected. Page 8 Does not evaporate from the surface of the water to the atmosphere. Not expected to adsorb on soil. According to Annex VIII to Regulation (EC) No. 1907/2006 (REACH): this product is neither a PBT (persistent/bioaccumulative/toxic) or vpvb (very persistent/very bioaccumulative/very toxic) substance nor does it contain a PBT or vpvb substance. Water hazard class: 1, slightly hazardous Behaviour in sewage systems: Further ecological effects: Do not discharge product uncontrolled into the environment. No ecological data available AOX Value: Disposal Considerations Waste Treatment Methods Product: In accordance with current regulations, product may be taken to a waste disposal site or incineration plant, after consultation with site operator and/or with the responsible authority. European Waste Code (EWC): Uncleaned packaging: Packaging may be disposed of in the same manner as the product. Uncontaminated packaging may be recycled Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: No hazardous goods according to ADR (land transportation). IMDG/IATA: No hazardous goods according to IMDG. 9

9 Transport Hazard Classes Page 9 ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards None Special Precautions for User Not classified as a dangerous good under transport regulations. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 1, slightly hazardous for water Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment has not yet been carried out for this product. Regulation (EC) 2037/ Substances that Deplete the Ozone Layer: not regulated / 10

10 Page 10 This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.