MATERIAL SAFETY DATA SHEET

Transcription

1 Page: 1 of 7 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT INFORMATION Product Name: GAP-11 GLASS ADHESION External Keys: Distributable Material (Part #) ACDelco GLASS Primary Tradename - Distributable Material ADHESION PMRV0238 PMRV Distributable Material (Part #) MANUFACTURER INFORMATION Address: N118 W18981 Bunsen Drive USA Wisconsin Germantown Mailing Communication Lines: Phone Hour Emergency Phone Information Fax Internet Website (no MSDS) 2 INGREDIENT INFORMATION FORMULATION Ingredients: Chemical Name CAS Number Prefix Value Unit Exposure Limits ISOPROPYL ALCOHOL Range %Wt Yes PROPANE Range %Wt Yes BUTANE Range 5-8 %Wt Yes SILANE, 3-(2,3- EPOXYPROPOXY) PROPYLTRIMETHOXY Range %Wt No 3 HAZARDS IDENTIFICATION Hazards Overview: Emergency Overview: DANGER! Extremely Flammable. Contents Under Pressure. Specific Hazards: LIKELY ROUTES OF EXPOSURE: Eye contact, skin contact, ingestion, and inhalation. TARGET ORGANS: Kidney Liver Lung Brain Specific Hazards (Routes Of Exposure): Exposure Routes Exposure Duration Observation Skin Contact General Contact may dry skin causing cracks and irritation Eye Contact General Contact may cause redness, irritation, tearing, and blurred vision Inhalation General Exposure to high concentrations of vapors may cause drowsiness, breathing difficulty, respiratory irritation, or headaches. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Ingestion General May be harmful if swallowed Effects Of Overexposure: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage.

2 Page: 2 of 7 3 HAZARDS IDENTIFICATION Effects Of Overexposure: CHRONIC EFFECTS: Prolonged over-exposure to solvent ingredients may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. Reports have associated the repeated and prolonged occupational OVER-EXPOSURE to solvents with brain and nervous system damage. The deliberate misuse by concentrating and inhaling the vapors may be harmful or fatal. Medical Conditions Aggravated By Exposure: Asthma and other respiratory ailments. 4 FIRST AID MEASURES First Aid By:: Inhalation Skin Contact Eye Contact Ingestion 5 FIRE FIGHTING MEASURES Move to fresh air. Contact emergency medical support if breathing stops or is irregular. Remove contaminated clothing and wash before reuse. Wash skin with soap and water. Get medical attention if irritation develops. Immediately flush eyes with water for at least 15 minutes. If irritation develops get medical attention. Do NOT induce vomiting. Get medical attention immediately. Product Flammability: PRODUCTS OF COMBUSTION: These products are carbon oxides (CO,C02). Flash Point: < -18 C <0ºF Explosive Limits: Upper Explosive Limit (UEL) Lower Explosive Limit (LEL) Not Established Not Established Mixture Mixture Extinguishing Media: SUITABLE EXTINGUISHING MEDIA: C02 (Carbon Dioxide), dry chemical, or water fog. Non Suitable Extinguishing Media: UNSUITABLE EXTINGUISHING MEDIA: Water spray may be unsuitable. However, if water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible explosion when exposed to extreme heat. PROTECTION OF FIREFIGHTERS: Full protective equipment including self-contained breathing apparatus should be used. 6 ACCIDENTAL RELEASE MEASURES PRECAUTIONS IN CASE OF ACCIDENTAL RELEASE Personal Precautions: Use personal protection recommended in Section 8.2. Environmental Precautions: None known. SPILL OR LEAK PROCEDURES Recovery: METHODS OF CONTAINMENT: Absorb spilled liquid in suitable material. METHODS OF CLEAN-UP: Use spark-proof tools to sweep or scrape up and containerize. Disposal: Do not puncture, incinerate or place container in trash compactor. Dispose of product in accordance with Federal, State, and Local regulations. Empty containers are 95% steel; recycle where allowed. Other Precautions: OTHER INFORMATION: Ventilate the area.

3 Page: 3 of 7 7 HANDLING AND STORAGE HANDLING Safe Handling Procedures: Vapors may ignite explosively. Prevent buildup of vapors; use with adequate ventilation. Keep from sparks, heat, flame or other heat sources. Do not smoke. Turn off pilot lights, heaters, electric motors and other sources of ignition during use and until all vapors are gone. Do not puncture or incinerate (burn) container. STORAGE Storage Conditions: Store in dry, well-ventilated area and in accordance with federal, state, and local regulations. Do not expose to heat or store at temperatures above 120 F (48 C). Storage conditions should comply with NFPA 30B and OSHA If storing in cold temperatures, allow product to warm to room temperature before use. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures: ENGINEERING CONTROLS: Not generally required if product is applied in small quanti ties. If product is applied in larger quantities, provide ventilation to keep air contamination below OSHA permissible exposure limits and TLV exposure levels. EXPOSURE LIMITS Limit Values: Chemical Name CAS Number Type Value Specification Source ISOPROPYL ALCOHOL PEL- 400ppm - OSHA - Permissible Exposure Limits ISOPROPYL ALCOHOL GM OEG - ISOPROPYL ALCOHOL GM OEG - ISOPROPYL ALCOHOL TLV- ISOPROPYL ALCOHOL TLV- PROPANE PEL- (PELs) 200ppm - GM Occupational Exposure Guidelines (OEG) 400ppm - GM Occupational Exposure Guidelines (OEG) 200ppm - Threshold Limit 400ppm - Threshold Limit 400ppm - MICHIGAN 500ppm - MICHIGAN 400ppm - NEW YORK 500ppm - NEW YORK 400ppm - TENNESSEE 500ppm - TENNESSEE 1000ppm - OSHA - Permissible Exposure Limits

4 Page: 4 of 7 8 EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS Limit Values: Chemical Name CAS Number Type Value Specification Source (PELs) PROPANE GM OEG 1000ppm - GM - Occupational Exposure Guidelines (OEG) PROPANE TLV- 1000ppm - Threshold Limit PROPANE State- 1000ppm - MICHIGAN PROPANE State- 1000ppm - NEW YORK PROPANE State- 1000ppm - TENNESSEE BUTANE TLV- PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment (PPE): Eye Protection Wear safety glasses with side shields. Have eye wash facilities immediately available. Respiratory Use NIOSH-approved air-purifying respirator with organic Protection cartridge or canister if exposure cannot be controlled within applicable limits with ventilation. Hand Protection Chemical resistant gloves if contact is likely. Hygiene Measures: GENERAL HYGIENE CONSIDERATIONS: Wash thoroughly after handling. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Physical State: Liquid Color: Clear Odor: Solvent Physical State: Aerosol - Pressurized Liquid PHYSICAL PROPERTIES Changes of State: Freezing point Not Mixture Established Boiling Point Range -18 to 177 C <0 to 350º F Vapor Pressure: Approximat 50 psig = 10 C 70ºF. e Evaporation Rate: Faster than ether Specific Gravity: = = 15 C 60ºF. 1000ppm - Threshold Limit

5 Page: 5 of 7 9 PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL PROPERTIES Solubility: Water Negligible VOC: VOC = 99.6 '%' CA Total Amount Of:: Percent Volatile by Weight = 99.6 %Wt Additional Chemical and Physical Data: MIR Number (CA) = Coating Category (CA) N/A 10 STABILITY AND REACTIVITY STABILITY INFORMATION Stability Under Normal Conditions: Stable Conditions to Avoid: Keep away from heat, sparks, and flames. Incompatible Materials: Strong oxidizing agents. Hazardous Polymerization: Will not occur. STABILITY: Stable under normal conditions. HAZARDOUS DECOMPOSITION Reactions: Type of Reaction Decomposition 11 TOXICOLOGICAL INFORMATION SCIENTIFIC OBSERVATIONS Reaction Products HAZARDOUS DECOMPOSITION PRODUCTS: by fire - Carbon Dioxide and Carbon Monoxide LETHAL LIMIT VALUES Data By Chemical: Chemical Name CAS Number Exposure Type Prefix Value Unit Comment Routes ISOPROPYL oral LD50 = 4700 mg/kg ALCOHOL ISOPROPYL dermal LD50 = mg/kg ALCOHOL PROPANE oral LD50 = 1000 mg/kg PROPANE dermal LD50 = 1800 mg/kg BUTANE oral LD50 N/E BUTANE dermal LD50 N/E SILANE, 3-(2, oral LD50 N/E EPOXYPROPOXY) PROPYLTRIMETHOX Y- SILANE, 3-(2,3- EPOXYPROPOXY) PROPYLTRIMETHOX N/E

6 Page: 6 of 7 11 TOXICOLOGICAL INFORMATION SCIENTIFIC OBSERVATIONS LETHAL LIMIT VALUES Data By Chemical: Chemical Name CAS Number Exposure Type Prefix Value Unit Comment Routes Y dermal LD50 CLASSIFICATION OF INGREDIENTS Carcingenicity: Listed Carcinogen by: NTP, IARC, OSHA: Isopropyl Alcohol, Propane, N-Butane, Silane: NO. 12 ECOLOGICAL INFORMATION ENVIRONMENTAL IMPACT No data available. ECOTOXICITY No data available. 13 DISPOSAL CONSIDERATIONS Waste Disposal Information: Do not puncture, incinerate or place container in trash compactor. Dispose of product in accordance with Federal, State, and Local regulations. Empty containers are 95% steel; recycle where allowed. 14 TRANSPORT INFORMATION DOT Shipping Name: Consumer Commodity DOT Hazard Class: ORM-D US DOT (Air) Proper Shipping Name: Consumer Commodity Hazard Class: ORM-D-AIR IATA/ICAO (International Air) Proper Shipping Name: Aerosols, Flammable ID no.: UN1950 Hazard Class: 2.1 Hazard Label: Flammable Gas Packing Instruction: 203 (NOTE, must be shipped in proper U.N.-certified box!) No component of this product is listed as a Marine Pollutant (49 CFR 172,101,Appendix B). 15 REGULATORY INFORMATION LABELLING Hazard Codes: HMIS Reactivity 1 HMIS Health 2 HMIS Flammability 4 NFPA Flammability 4

7 Page: 7 of 7 15 REGULATORY INFORMATION LABELLING Hazard Codes: NFPA Health 2 NFPA Reactivity 1 NFPA assigned by General Motors Technical Review. NATIONAL REGULATIONS SARA 311/312: No SARA 313: No Immediate Health: Yes Delayed Health: Yes Fire: Yes Sudden Pressure Release: No Reactive: No Other Regulation: OSHA TSCA SARA OTHER INFORMATION This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). United States The components of this product are listed on the TSCA inventory. Isopropyl Alcohol, Propane, N-Butane, Silane: NO LISTED.