Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet 1. Identification of the material and supplier Trade name of product ADG Emergency telephone number Material uses GUARDIAN SAFE PLUS GUARDIAN SAFE PLUS Not regulated. Supplier ECOLAB PTY LTD (A.B.N ) 2 Drake Avenue, Macquarie Park NSW 2113 Customer Service phone Free Fax Number Product dilution information Machine Warewashing Detergent Use up to 5mL/L in water Date of issue 2. Hazards identification Statement of hazardous/dangerous nature Classification Risk phrases Safety phrases 30 January 2013 Not classified as hazardous according to the criteria of Safe Work Australia nor classified as dangerous goods according to the ADG Code. Not classified as hazardous according to the criteria of Safe Work Australia nor classified as dangerous goods according to the ADG Code. 3. Composition/information on ingredients Ingredient name CAS number Concentration % (w/w) sodium hypochlorite Other ingredients, determined not to be hazardous according to Safe Work Australia criteria, and not dangerous according to the ADG Code, make up the product concentration to 100%. Ingredients, determined not to be hazardous according to Safe Work Australia criteria, and not dangerous according to the ADG Code, make up the product concentration to 100%. 4. First-aid measures Eye contact Skin contact Inhalation Ingestion Rinse with plenty of running water. Get medical attention if symptoms occur. In case of contact, immediately flush skin with plenty of water. Get medical attention if symptoms occur. Wash clothing before reuse. Remove to fresh air. Get medical attention if symptoms occur. Do not induce vomiting. Rinse mouth; then drink one or two large glasses of water. Contact a doctor or a Poisons Information Centre (Phone ) Date of issue 30-January-2013 Rinse with plenty of running water. Get medical attention if symptoms occur. In case of contact, immediately flush skin with plenty of water. Get medical attention if symptoms occur. Wash clothing before reuse. Remove to fresh air. Get medical attention if symptoms occur. Do not induce vomiting. Rinse mouth; then drink one or two large glasses of water. Contact a doctor or a Poisons Information Centre (Phone ). Page 1/6

2 4. First-aid measures Notes to physician No specific treatment. Treat symptomatically. No specific treatment. Treat symptomatically. 5. Fire-fighting measures Extinguishing media Fire-fighting media and instructions Fire/explosion hazards Special protective equipment for fire-fighters Hazardous thermal decomposition products 6. Accidental release measures Use an extinguishing agent suitable for the surrounding fire. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. No specific hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Decomposition products may include the following materials carbon dioxide carbon monoxide phosphorus oxides halogenated compounds metal oxide/oxides Personal precautions Environmental precautions Methods for cleaning up Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note see Section 1 for emergency contact information and Section 13 for waste disposal. Note see section 8 for personal protective equipment and section 13 for waste disposal. 7. Handling and storage Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note see Section 1 for emergency contact information and Section 13 for waste disposal. Handling Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas Date of issue 30-January-2013 Page 2/6

3 7. Handling and storage Storage Ingredient name Engineering measures Personal protection Eyes Hands Respiratory Skin Hygiene measures Keep container tightly closed. Keep container Keep container tightly closed. Keep in a cool, well-ventilated area. container in a cool, well-ventilated area. 8. Exposure controls/personal protection Occupational exposure limits chlorine Safe Work Australia (Australia, 8/2005). PEAK 3 mg/m³ 15 minute(s). PEAK 1 ppm 15 minute(s). Exposure limits Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. 9. Physical and chemical properties Physical state Liquid. Colour Clear [Light] Odour chlorine ph 11 to 12 [Conc. (% w/w) 100%] Flash point > 100 C Product does not support combustion. Boiling point >100 C (>212 F) Relative density 1.24 to 1.26 Solubility Easily soluble in the following materials cold water and hot water. Liquid. Colourless. chlorine 9.5 to 11 > 100 C Date of issue 30-January-2013 Page 3/6

4 10. Stability and reactivity Stability Conditions to avoid Materials to avoid Hazardous decomposition products Possibility of hazardous reactions 11. Toxicological information Potential acute health effects Inhalation Ingestion Skin contact Eye contact Potential chronic health effects Carcinogenicity Mutagenicity Reproductive toxicity The product is stable. No specific data. Highly reactive or incompatible with the following materials organic materials, metals and acids. Slightly reactive or incompatible with the following materials alkalis and moisture. Mixing this product with acid or ammonia releases chlorine gas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Under normal conditions of storage and use, hazardous reactions will not occur. 12. Ecological information Ecotoxicity data Persistence/degradability Mobility Other adverse effects Not available. Not available. Not available. 13. Disposal considerations Methods of disposal The generation of waste should be avoided or minimised wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any byproducts should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilt material and runoff and contact with soil, The generation of waste should be avoided or minimised wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid Date of issue 30-January-2013 Page 4/6

5 13. Disposal considerations waterways, drains and sewers. dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. 14. Transport information Regulation UN number Proper shipping name Classes Packing group Additional information ADG Not regulated. IMDG Not regulated. Not intended for transport Regulatory information AU Classification Australia inventory (AICS) Standard for the Uniform Scheduling of Medicines and Poisons S5 Control of Scheduled Carcinogenic Substances Ingredient name No listed substance Not classified as hazardous according to the criteria of Safe Work Australia nor classified as dangerous goods according to the ADG Code. 16. Other information Prepared by Date of previous issue Change Made New product References All substances are listed on AICS or exempt. Regulatory Affairs No previous validation Not classified as hazardous according to the criteria of Safe Work Australia nor classified as dangerous goods according to the ADG Code. Schedule -ADG Code - Australian Transport of Dangerous Goods -Adopted National Exposure Standard for Atmospheric Contaminants in the Occupational Environment -Approved Criteria for Classifying Hazardous Substances -List of Designated Hazardous Substances -National Code of Practice for the Labelling of Workplace Substances -National Code of Practice for the Preparation of Material Safety Data Sheets -National Model Regulations for the Control of Scheduled Carcinogenic Substances -National Model Regulations for the Control of Workplace Hazardous Substances -Standard for the Uniform Scheduling of Medicines and Poisons Disclaimer Date of issue 30-January-2013 Page 5/6

6 16. Other information The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION Date of issue 30-January-2013 Page 6/6