SDS Number: Product name : Palmolive Naturals Milk & Honey Liquid Hand Wash :

Transcription

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Product code : B : Manufacturer or supplier's details Address : Colgate-Palmolive Pty Ltd., 345 George St, Sydney, New South Wales, Australia Telephone : CONSUMER AFFAIRS: - AU (Mon Fri 7-5) Emergency telephone number : Global-CHEMTREC CHEMTREC Australia +(61) Recommended use of the chemical and restrictions on use Recommended use : A formulated liquid hand soap SECTION 2. HAZARDS IDENTIFICATION GHS Classification Serious eye damage/eye irritation : Category 1 GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : H318 Causes serious eye damage. Precautionary statements : Prevention: P280 Wear eye protection/ face protection. Response: P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. 1 / 10

2 Other hazards which do not result in classification None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical name CAS-No. Concentration (% w/w) SODIUM LAURETH SULFATE >= 3 -< 10 COCAMIDOPROPYL BETAINE < 10 SECTION 4. FIRST AID MEASURES General advice : If poisoning occurs, immediately contact a doctor or Poisons Information Centre (Phone Australia ; New Zealand ), and follow the advice given. If inhaled : If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : If skin irritation persists, call a physician. If on skin, rinse well with water. If on clothes, remove clothes. In case of eye contact : In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Continue rinsing eyes during transport to hospital. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. Most important symptoms and effects, both acute and delayed : Causes serious eye damage. SECTION 5. FIREFIGHTING MEASURES Unsuitable extinguishing media : High volume water jet 2 / 10

3 Specific hazards during firefighting Hazardous combustion products Specific extinguishing methods Special protective equipment for firefighters : Do not allow run-off from fire fighting to enter drains or water courses. : No hazardous combustion products are known : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. : Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE Advice on protection against fire and explosion : Normal measures for preventive fire protection. Advice on safe handling : Do not breathe vapours/dust. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. To avoid spills during handling keep bottle on a metal tray. Dispose of rinse water in accordance with local and national regulations. Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. 3 / 10

4 Containers which are opened must be carefully resealed and kept upright to prevent leakage. Electrical installations / working materials must comply with the technological safety standards. Further information on storage stability : No decomposition if stored and applied as directed. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Contains no substances with occupational exposure limit values. Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Eye wash bottle with pure water Tightly fitting safety goggles Wear face-shield and protective suit for abnormal processing problems. Skin and body protection : Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : light yellow ph : 5.2 Flash point : No data available Density : g/cm3 SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. 4 / 10

5 Chemical stability : No decomposition if stored and applied as directed. Possibility of hazardous reactions : No decomposition if stored and applied as directed. Conditions to avoid : No data available SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Product: Acute oral toxicity : Acute toxicity estimate: > 2,000 mg/kg Method: Calculation method Acute oral toxicity : LD50 (Rat): 1,600 mg/kg Method: No information available. Acute inhalation toxicity : LC50 (Rabbit): > 5 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Acute toxicity estimate Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Method: Acute toxicity estimate Acute oral toxicity : LD50 (Rat): 4,900 mg/kg Method: Tested according to Annex V of Directive 67/548/EEC. Acute inhalation toxicity : Remarks: No data available Acute dermal toxicity : Remarks: No data available Skin corrosion/irritation Result : Skin irritation 5 / 10

6 Result : Skin irritation Serious eye damage/eye irritation Causes serious eye damage. Result : Risk of serious damage to eyes. Result : Moderate eye irritation Respiratory or skin sensitisation Skin sensitisation Respiratory sensitisation Exposure routes : Inhalation Result : Does not cause respiratory sensitisation. : Dermal : Does not cause skin sensitisation. Exposure routes : Inhalation Remarks : No data available : Dermal Result : Does not cause skin sensitisation. Chronic toxicity Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT - single exposure 6 / 10

7 STOT - repeated exposure Aspiration toxicity Further information Product: Remarks : This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration available safety-related information including information on individual ingredients, similar formulas and potential ingredient interactions. This review is a component of the hazard determination used to prepare the statements in Section 3 of the SDS. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Toxicity to fish : LC50 (Fish): 10.4 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates Toxicity to fish (Chronic toxicity) Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : EC50 (Daphnia (water flea)): 7.2 mg/l Exposure time: 48 h : No data available : No data available Toxicity to fish : LC50 (Brachydanio rerio (zebrafish)): 2 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna Straus): 6.5 mg/l Exposure time: 48 h Toxicity to algae : ErC50 (Desmodesmus subspicatus (green algae)): 1-10 mg/l Exposure time: 72 h M-Factor (Acute aquatic tox- : 1 7 / 10

8 icity) Toxicity to fish (Chronic toxicity) Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : No data available : NOEC (Daphnia sp. (water flea)) 0.9 mg/l Persistence and degradability Biodegradability : Result: Readily biodegradable. Biodegradability : Result: Readily biodegradable. Bioaccumulative potential Partition coefficient: n- octanol/water : log Pow: 1.62 Bioaccumulation : Bioconcentration factor (BCF): Partition coefficient: n- octanol/water : Remarks: Not applicable Mobility in soil No data available Other adverse effects Product: Additional ecological information : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Harmful to aquatic life. SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : The product should not be allowed to enter drains, water courses or the soil. 8 / 10

9 Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. SECTION 14. TRANSPORT INFORMATION ADG 7.5 NZS 5433 : NOT REGULATED. : NOT REGULATED. IATA : Not regulated. IMDG : Not regulated. ADR : NOT REGULATED. SECTION 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Standard for the Uniform Scheduling of Medicines and Poisons : No poison schedule number allocated Prohibition/Licensing Requirements : There is no applicable prohibition or notification/licensing requirements, including for carcinogens under Commonwealth, State or Territory legislation. The components of this product are reported in the following inventories: AICS : On the inventory, or in compliance with the inventory NZIoC : On the inventory, or in compliance with the inventory SECTION 16. OTHER INFORMATION Revision Date : 9 / 10

10 Date format : dd.mm.yyyy Full text of other abbreviations AICS - Australian Inventory of Chemical Substances; ANTT - National Agency for Transport by Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR - Carcinogen, Mutagen or Reproductive Toxicant; CPR - Controlled Products Regulations; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; SADT - Self- Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vpvb - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. AU / EN 10 / 10