SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 Safety data sheet Page: 1/12 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Sicopal Black K 0090 Chemical name: Iron cobalt chromite black spinel CAS Number: REACH registration number: Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: colourant for the plastics industry 1.3. Details of the supplier of the safety data sheet Company: BASF SE Ludwigshafen GERMANY Telephone: address: pigments-safety@basf.com 1.4. Emergency telephone number International emergency number: Telephone: SECTION 2: Hazards Identification 2.1. Classification of the substance or mixture According to Regulation (EC) No 1272/2008 [CLP]

2 Page: 2/12 No need for classification according to GHS criteria for this product Label elements Globally Harmonized System, EU (GHS) The product does not require a hazard warning label in accordance with GHS criteria Other hazards According to Regulation (EC) No 1272/2008 [CLP] No specific dangers known, if the regulations/notes for storage and handling are considered. SECTION 3: Composition/Information on Ingredients 3.1. Substances Chemical nature Iron cobalt chromite black spinel CAS Number: EC-Number: C.I. Pigment Black Mixtures SECTION 4: First-Aid Measures 4.1. Description of first aid measures Remove contaminated clothing. If inhaled: If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention. On skin contact: Wash thoroughly with soap and water. On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion:

3 Page: 3/12 Rinse mouth and then drink plenty of water Most important symptoms and effects, both acute and delayed Symptoms: (Further) symptoms and / or effects are not known so far 4.3. Indication of any immediate medical attention and special treatment needed Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. SECTION 5: Fire-Fighting Measures 5.1. Extinguishing media Suitable extinguishing media: dry powder, foam Unsuitable extinguishing media for safety reasons: carbon dioxide 5.2. Special hazards arising from the substance or mixture harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire Advice for fire-fighters Special protective equipment: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations. SECTION 6: Accidental Release Measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid dust formation. Use personal protective clothing Environmental precautions Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater Methods and material for containment and cleaning up For small amounts: Pick up with suitable appliance and dispose of. For large amounts: Contain with dust binding material and dispose of. Avoid raising dust Reference to other sections

4 Page: 4/12 Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13. SECTION 7: Handling and Storage 7.1. Precautions for safe handling Breathing must be protected when large quantities are decanted without local exhaust ventilation. Protection against fire and explosion: Avoid dust formation. Take precautionary measures against static discharges Conditions for safe storage, including any incompatibilities Further information on storage conditions: Keep container tightly closed and dry; store in a cool place Specific end use(s) For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed. SECTION 8: Exposure Controls/Personal Protection 8.1. Control parameters Components with occupational exposure limits : Iron cobalt chromite black spinel TWA value 2 mg/m3 (OEL (EU)) indicative 8.2. Exposure controls Personal protective equipment Respiratory protection: Suitable respiratory protection for lower concentrations or short-term effect: Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2) Hand protection: Chemical resistant protective gloves (EN 374) Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types.

5 Page: 5/12 Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) General safety and hygiene measures Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is recommended. Hands and/or face should be washed before breaks and at the end of the shift. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Form: powder Colour: black Odour: odourless Odour threshold: No applicable information available. ph value: not soluble Melting point: > 1,000 C Boiling point: not applicable Flash point: not applicable Evaporation rate: The product is a non-volatile solid. Flammability: not flammable Lower explosion limit: For solids not relevant for classification and labelling. Upper explosion limit: For solids not relevant for classification and labelling. Ignition temperature: not determined Vapour pressure: not applicable, solid with a melting temperature over 300 C Density: 4.9 g/cm3 (20 C) Relative density: 4.9 (20 C) Relative vapour density (air): The product is a non-volatile solid. Solubility in water: insoluble Solubility (quantitative) : The product has not been tested. Partitioning coefficient n-octanol/water (log Kow): not applicable (DIN EN ISO )

6 Page: 6/12 Self ignition: not self-igniting Thermal decomposition: not determined Viscosity, dynamic: Study does not need to be conducted. Explosion hazard: not explosive Fire promoting properties: not fire-propagating 9.2. Other information Self heating ability: Bulk density: Hygroscopy: Grain size distribution: It is not a substance capable of spontaneous heating. approx. 1,000 kg/m3 The product has not been tested. No data available. SECTION 10: Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated Chemical stability The product is stable if stored and handled as prescribed/indicated Possibility of hazardous reactions No hazardous reactions when stored and handled according to instructions Conditions to avoid Avoid dust formation. See MSDS section 7 - Handling and storage Incompatible materials Substances to avoid: strong oxidizing agents, strong acids, strong bases Hazardous decomposition products Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. SECTION 11: Toxicological Information Information on toxicological effects Acute toxicity

7 Page: 7/12 Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Experimental/calculated data: LD50 rat (oral): > 5,000 mg/kg LC50 rat (by inhalation): > 5 mg/l The product has not been tested. The statement has been derived from the properties of the individual components. LD50 (dermal): not determined Irritation Experimental/calculated data: Skin corrosion/irritation rabbit: non-irritant Serious eye damage/irritation rabbit: non-irritant Respiratory/Skin sensitization Experimental/calculated data: Mouse Local Lymph Node Assay (LLNA) mouse: Non-sensitizing. (OECD Guideline 429) The product has not been tested. The statement has been derived from the properties of the individual components. Germ cell mutagenicity Assessment of mutagenicity: Based on the ingredients, there is no suspicion of a mutagenic effect. Carcinogenicity Assessment of carcinogenicity: The whole of the information assessable provides no indication of a carcinogenic effect. Reproductive toxicity Assessment of reproduction toxicity: Based on the ingredients, there is no suspicion of a toxic effect on reproduction. Developmental toxicity Assessment of teratogenicity: No data available. Specific target organ toxicity (single exposure)

8 Page: 8/12 Assessment of STOT single: Based on the available information there is no specific target organ toxicity to be expected after a single exposure. Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: No data available. Aspiration hazard No aspiration hazard expected. Other relevant toxicity information The product contains heavy metals. The product is insoluble in acids or alkalies. SECTION 12: Ecological Information Toxicity Toxicity to fish: LC50 (96 h) > 1,000 mg/l, Oncorhynchus mykiss Aquatic invertebrates: EC50 (48 h) > 1,000 mg/l, Daphnia magna Persistence and degradability Assessment biodegradation and elimination (H2O): The product is virtually insoluble in water and can thus be separated from water mechanically in suitable effluent treatment plants. Elimination information: Not readily biodegradable (by OECD criteria) Bioaccumulative potential Bioaccumulation potential: Because of the product's consistency and low water solubility, bioavailability is improbable. The product contains heavy metal(s). Prevent release into the environment. Special pretreatment required Mobility in soil Assessment transport between environmental compartments: Volatility: The substance will not evaporate into the atmosphere from the water surface.

9 Page: 9/12 Adsorption in soil: low mobility in soil Results of PBT and vpvb assessment According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH): The product does not contain a substance fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vpvb (very persistent/very bioaccumulative) criteria Other adverse effects The substance is not listed in Regulation (EC) 1005/2009 on substances that deplete the ozone layer Additional information Adsorbable organically-bound halogen (AOX): This product contains no organically-bound halogen. SECTION 13: Disposal Considerations Waste treatment methods Must be disposed of or incinerated in accordance with local regulations. Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. SECTION 14: Transport Information Land transport ADR Not classified as a dangerous good under transport regulations UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards: Special precautions for None known user RID Not classified as a dangerous good under transport regulations

10 Page: 10/12 UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards: Special precautions for user None known Inland waterway transport ADN Not classified as a dangerous good under transport regulations UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards: Special precautions for None known user: Transport in inland waterway vessel Not evaluated Sea transport IMDG Not classified as a dangerous good under transport regulations UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards: Special precautions for None known user Air transport IATA/ICAO Not classified as a dangerous good under transport regulations UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards:

11 Page: 11/12 Special precautions for None known user UN number See corresponding entries for UN number for the respective regulations in the tables above UN proper shipping name See corresponding entries for UN proper shipping name for the respective regulations in the tables above Transport hazard class(es) See corresponding entries for Transport hazard class(es) for the respective regulations in the tables above Packing group See corresponding entries for Packing group for the respective regulations in the tables above Environmental hazards See corresponding entries for Environmental hazards for the respective regulations in the tables above Special precautions for user See corresponding entries for Special precautions for user for the respective regulations in the tables above Transport in bulk according to Annex II of MARPOL and the IBC Code Regulation: Shipment approved: Pollution name: Pollution category: Ship Type: Not evaluated Not evaluated Not evaluated Not evaluated Not evaluated SECTION 15: Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture If other regulatory information applies that is not already provided elsewhere in this safety data sheet, then it is described in this subsection Chemical Safety Assessment Chemical Safety Assessment not yet performed due to registration timelines

12 Page: 12/12 SECTION 16: Other Information The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. This safety data sheet is neither a Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification agreement. Identified uses in this safety data sheet do neither represent an agreement on the corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed. Vertical lines in the left hand margin indicate an amendment from the previous version.