May cause an allergic skin reaction. H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation

Transcription

1 SECTION 1: Identification 1.1. Identification Product form Product name Reveal HD Bulk Date of issue: 08/03/2018 Version: 2.0 : Mixture 1.2. Recommended use and restrictions on use Use of the substance/mixture 1.3. Supplier Manufacturer Bisco, Inc W. Irving Park Rd. Schaumburg, IL T F sales@bisco.com - : Reveal HD Bulk : For RX only 1.4. Emergency telephone number Emergency number : CHEMTREC - 24-Hour Hazmat Emergency Communications Center Domestic: Outside the U.S.: , collect calls accepted SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Skin sensitization, Category 1 H315 H319 H317 Full text of H statements : see section 16 Causes skin irritation Causes serious eye irritation May cause an allergic skin reaction 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : Hazard statements (GHS-US) Precautionary statements (GHS-US) 2.3. Other hazards which do not result in classification 2.4. Unknown acute toxicity (GHS US) : H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation : P261 - Avoid breathing vapors. P264 - Wash hands thoroughly after handling P272 - Contaminated work clothing must not be allowed out of the workplace P280 - Wear protective gloves/protective clothing/eye protection/face protection P302+P352 - If on skin: Wash with plenty of water and soap P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P321 - Specific treatment (see First aid measures on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. P363 - Wash contaminated clothing before reuse. P501 - Dispose in a safe manner in accordance with local/national regulations 07/06/2018 EN (English US) Page 1

2 SECTION 3: Composition/Information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % GHS-US classification Ytterbium Fluoride (CAS-No.) > 15 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Urethane Dimethacrylate (CAS-No.) Proprietary Skin Irrit. 2, H315 Eye Irrit. 2B, H320 STOT SE 3, H336 BisGMA (CAS-No.) Skin Irrit. 2, H315 Eye Irrit. 2B, H320 Skin Sens. 1, H317 Proprietary (CAS-No.) Proprietary 1-3 Skin Sens. 1B, H317 Tert-butyl Perbenzoate (CAS-No.) < 1 Self-react. D, H242 Org. Perox. C, H242 Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Acute 1, H400 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Call a poison center/doctor/physician if you feel unwell Most important symptoms and effects (acute and delayed) Symptoms/effects after skin contact Symptoms/effects after eye contact : Irritation. May cause an allergic skin reaction. : Eye irritation Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media 5.2. Specific hazards arising from the chemical Reactivity : Water spray. Dry powder. Foam Special protective equipment and precautions for fire-fighters Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : The product is non-reactive under normal conditions of use, storage and transport. : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapors/spray. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Mechanically recover the product. 07/06/2018 EN (English US) 2/7

3 Other information : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. Avoid breathing dust/fume/gas/mist/vapors/spray. : Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions SECTION 8: Exposure controls/personal protection 8.1. Control parameters BisGMA ( ) : Store in a well-ventilated place. Keep cool Appropriate engineering controls Appropriate engineering controls Environmental exposure controls : Ensure good ventilation of the work station. : Avoid release to the environment Individual protection measures/personal protective equipment Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Paste Color : Off-white to light yellow Odor : Almost odourless Odor threshold ph Melting point 07/06/2018 EN (English US) 3/7

4 Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties : : : Non flammable. : : : : 9.2. Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 dermal rabbit LC50 inhalation rat (ppm) LC50 inhalation rat (mg/l) LC50 inhalation rat (mg/l) > 2000 mg/kg (Rat) > 2000 mg/kg (Rat) > 20 mg/l (4 h, Rat) > 2000 mg/kg body weight (OECD 423: Acute Oral Toxicity Acute Toxic Class Method, Rat, Male/female, Experimental value) > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male/female, Experimental value) > 2.28 mg/l (Equivalent or similar to OECD 403, 4 h, Rat, Male/female, Experimental value) 07/06/2018 EN (English US) 4/7

5 LD50 dermal rabbit LC50 inhalation rat (ppm) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC group : Causes skin irritation. : Causes serious eye irritation. : May cause an allergic skin reaction. 4 - Probably not carcinogenic to humans IARC group Reproductive toxicity Specific target organ toxicity single exposure LOAEL (oral,rat) LOAEL (dermal,rat/rabbit) LOAEC (inhalation,rat,gas) LOAEC (inhalation,rat,vapour ) LOAEC (inhalation,rat,dust/mist/fume) 4 - Probably not carcinogenic to humans mg/kg body weight mg/kg body weight ppmv/4h mg/l/4h mg/l/4h LOAEL (oral,rat) LOAEL (dermal,rat/rabbit) LOAEC (inhalation,rat,gas) LOAEC (inhalation,rat,vapour ) LOAEC (inhalation,rat,dust/mist/fume) Specific target organ toxicity repeated exposure LOAEL (oral,rat,90 days) LOAEL (dermal,rat/rabbit,90 days) LOAEC (inhalation,rat,gas,90 days) LOAEC (inhalation,rat,vapour,90 days) LOAEC (inhalation,rat,dust/mist/fume,90 days) mg/kg body weight mg/kg body weight ppmv/4h mg/l/4h mg/l/4h mg/kg bodyweight/day mg/kg bodyweight/day ppmv/6h/day mg/l/6h/day mg/l/6h/day LOAEL (oral,rat,90 days) LOAEL (dermal,rat/rabbit,90 days) LOAEC (inhalation,rat,gas,90 days) LOAEC (inhalation,rat,vapour,90 days) LOAEC (inhalation,rat,dust/mist/fume,90 days) Aspiration hazard Symptoms/effects after skin contact Symptoms/effects after eye contact SECTION 12: Ecological information Toxicity Ecology - general mg/kg bodyweight/day mg/kg bodyweight/day ppmv/6h/day mg/l/6h/day mg/l/6h/day : Irritation. May cause an allergic skin reaction. : Eye irritation. : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. 07/06/2018 EN (English US) 5/7

6 LC50 fish 1 EC50 Daphnia 1 ErC50 (algae) EC50 Daphnia 1 > 100 mg/l (EU Method C.1, 96 h, Brachydanio rerio, Semi-static system, Fresh water, Experimental value) > 100 mg/l (EU Method C.2, 48 h, Daphnia magna, Static system, Fresh water, Experimental value) > 100 mg/l (EU Method C.3, 72 h, Scenedesmus subspicatus, Static system, Fresh water, Weight of evidence) 190 mg/l Persistence and degradability Persistence and degradability ThOD Persistence and degradability Readily biodegradable in water g O₂/g substance Readily biodegradable in water Bioaccumulative potential Bioaccumulative potential BCF other aquatic organisms 1 Log Pow No bioaccumulation data available. 3.2 (Estimated value) 2.1 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask Method, 21 C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4) Mobility in soil Log Koc Ecology - soil 3.23 (log Koc, Calculated value) Adsorbs into the soil. Low potential for mobility in soil Other adverse effects SECTION 13: Disposal considerations Disposal methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Other information : No supplementary information available. Transportation of Dangerous Goods Transport by sea Air transport 07/06/2018 EN (English US) 6/7

7 SECTION 15: Regulatory information US Federal regulations International regulations CANADA EU-Regulations National regulations US State regulations SECTION 16: Other information Revision date: 07/23/2018 Full text of H-phrases: H242 H315 H317 H319 H320 H336 H400 Heating may cause a fire or explosion Causes skin irritation May cause an allergic skin reaction Causes serious eye irritation Causes eye irritation May cause drowsiness or dizziness Very toxic to aquatic life SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 07/06/2018 EN (English US) 7/7