Material Safety Data Sheet

Transcription

1 NOHSC 16 Section Material Safety Data Sheet Infosafe No. AMMONIUM SULPHATE JXF9Q Issue Date August 2012 Status ISSUED by AJAXFC BS: Not classified as hazardous according to criteria of NOHSC 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Product Name AMMONIUM SULPHATE Product Code Company Name Ajax Finechem (ABN ) Address 17/21 Bay Road Taren Point NSW 2229 Emergency Tel (24 hr) Aust / (NZ): Phone Telephone/Fax Number Tel: Recommended Use Industrial application Other Names Name Product Code AMMONIUM SULPHATE 56 AMMONIUM SULPHATE 57 AMMONIUM SULPHATE 5064 AMMONIUM SULPHATE AMMONIUM SULPHATE AL AMMONIUM SULPHATE BSPAL941 Other NEW ZEALAND: Ajax Finechem (NZ) Ltd 150B Harris Road, East Tamaki, Auckland Phone (09) Fax (09) Emergency Advice (NZ): Phone HAZARDS IDENTIFICATION 1/9

2 Hazard Classification Australia: Not classified as Hazardous according to criteria of National Occupational Health & Safety Commission, Australia (NOHSC). Not classified as Dangerous Goods according to the Australian Code for the Transport of Dangerous Goods by Road and Rail. (7th edition) New Zealand: Classified as Hazardous according to the Hazardous Substances (Minimum Degrees of Hazard) Regulations 2001, New Zealand. Not Classified as Dangerous Goods for transport according to the New Zealand Standard NZS 5433:2012 Transport of Dangerous Goods on Land. HSNO Classification: 6.1D (Oral) - Substance that is acutely toxic 9.1D - Substance that is slightly harmful to the aquatic environment or is otherwise designed for biocidal action 9.3C - Substance that is harmful to terrestrial vertebrates Hazard statement codes: H302 Harmful if swallowed. H402 Harmful to aquatic life. H433 Harmful to terrestrial vertebrates. Precautionary statement codes - Prevention: P102 Keep out of reach of children. P103 Read label before use. P104 Read Safety Data Sheet before use. P264 Wash contaminated skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P273 Avoid release to the environment. Precautionary statement codes - Response: GENERAL P101 If medical advice is needed, have product container or label at hand. INGESTION P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330 Rinse mouth. P331 Do NOT induce vomiting. Precautionary statement codes - Disposal: P501 In the case of a substance that is in compliance with a HSNO approval other than a Part 6A (Group Standards) approval, a label must provide a description of one or more appropriate and achievable methods for the disposal of a substance in accordance with the Hazardous Substances (Disposal) Regulations This may also include any method of disposal that must be avoided. See Section 13 for disposal details. Safety Phrase(s)S22 Do not breathe dust. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical CharacterizationSolid Ingredients Name CAS Proportion Ammonium sulphate % 2/9

3 4. FIRST AID MEASURES Inhalation Ingestion Skin Eye First Aid Facilities If inhaled, remove affected person from contaminated area. Keep at rest until recovered. Seek medical attention. Do not induce vomiting. Wash out mouth thoroughly with water. Seek immediate medical attention. Remove all contaminated clothing immediately. Wash affected area thoroughly with soap and water. Wash contaminated clothing before reuse or discard. Seek medical attention. If in eyes, hold eyelids apart and flush the eyes continuously with running water. Remove contact lenses. Continue flushing until advised to stop by the Poisons Centre or a doctor, or for at least 15 minutes. Seek immediate medical attention. Eyewash, safety shower and normal washroom facilities. Advice to DoctorTreat symptomatically. Other For advice in an emergency, contact a Poisons Centre or a doctor at once. ( ) 5. FIRE FIGHTING MEASURES Suitable Extinguishing Media Hazards from Combustion Products Carbon dioxide, dry chemical, foam, water fog or water mist. Under fire conditions this product may emit toxic and/or irritating fumes and gases including ammonia, oxides of nitrogen, oxides of sulphur, carbon monoxide and carbon dioxide. Specific HazardsNon combustible material. Static charge build up during the handling or within process equipment could lead to ignition of flammable vapours or the increase in potential for dust explosions. Decomposition Temp. Precautions in connection with Fire Fire fighters should wear full protective clothing and selfcontained breathing apparatus (SCBA) operated in positive pressure mode. Fight fire from safe location. Unsuitable Extinguishing Media Do not use water jet. 3/9

4 6. ACCIDENTAL RELEASE MEASURES Emergency Procedures Remove all sources of ignition. Increase ventilation. Evacuate all unprotected personnel. Wear sufficient respiratory protection and full protective clothing to prevent exposure. Sweep up material avoiding dust generation or dampen spilled material with water to avoid airborne dust, then transfer material to a suitable container. Wash surfaces well with soap and water. Seal all wastes in labelled plastic containers for subsequent recycling or disposal. Dispose of waste according to the applicable local and national regulations. If contamination of sewers or waterways occurs inform the local water and waste management authorities in accordance with local regulations. 7. HANDLING AND STORAGE Precautions for Safe Handling Avoid inhalation of dust, and skin or eye contact. Use only in a well ventilated area. Keep containers sealed when not in use. Prevent the build up of dust in the work atmosphere. Establish good housekeeping practices. Remove dust accumulations on a regular basis by vacuuming or gentle sweeping to avoid creating dust clouds. Maintain high standards of personal hygiene ie. washing hands prior to eating, drinking, smoking or using toilet facilities. Conditions for Safe Storage Store in a well ventilated area away from heat and sources of ignition, out of direct sunlight and moisture. Take precautions against static electricity discharges. Use proper grounding procedures. Store away from incompatible materials such as materials that support combustion (oxidising materials). Store in suitable, labelled containers. Inspect periodically for deficiencies such as damage or leaks. Have appropriate fire extinguishers available in and near the storage area. Ensure that storage conditions comply with applicable local and national regulations. For information on the handling of Combustible dusts and grounding procedure reference should be made to Australian Standard AS/NZS 'Code of Practice for Handling Combustible Dusts'. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION National Exposure Standards The exposure limits for dust not otherwise specified are as follows: Safe Work, Australia exposure standards: Dust TWA 10 mg/m³ (inspirable fraction) New Zealand Workplace Exposure Standards (OSH): Particulates TWA 10 mg/m³ (inhalable) TWA 3 mg/m³ (respirable) TWA (Time Weighted Average): The average airborne concentration of a particular substance when calculated over a normal eighthour working day, for a five-day week. 4/9

5 Biological Limit Values No biological limits allocated. Engineering Controls Respiratory Protection Eye Protection Use with good general ventilation. If dusts are produced, local exhaust ventilation should be used. If engineering controls are not effective in controlling airborne exposure then an approved respirator with a replaceable filter should be used. Reference should be made to Australian Standards AS/NZS 1715, Selection, Use and Maintenance of Respiratory Protective Devices; and AS/NZS 1716, Respiratory Protective Devices, in order to make any necessary changes for individual circumstances. Safety glasses with side shields, chemical goggles or full-face shield as appropriate should be used. Final choice of appropriate eye/face protection will vary according to individual circumstances. Eye protection devices should conform to relevant regulations. Eye protection should conform with Australian/New Zealand Standard AS/NZS Eye Protectors for Industrial Applications. Hand Protection Wear gloves of impervious material. Final choice of appropriate gloves will vary according to individual circumstances i.e. methods of handling or according to risk assessments undertaken. Reference should be made to AS/NZS : Occupational protective gloves - Selection, use and maintenance. Body Protection Suitable protective workwear, e.g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron is recommended where large quantities are handled. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Appearance Solid White crystalline solid Odour 350 C Decomposition Temperature Melting Point 350 C Boiling Point Solubility in Water Soluble Specific Gravity1.77 ph Value 5.5 (0.1M) Vapour Pressure Vapour Density 5/9

6 (Air=1) Evaporation Rate Odour Threshold Viscosity Colour Octanol/Water Partition Coefficient Flash Point Flammability Auto-Ignition Temperature Kinematic Viscosity Dynamic Viscosity Refer to Section 9: Kinematic and Dynamic Viscosity White Not applicable Not combustible Explosion Limit - Upper Not applicable Explosion Limit - Lower Not applicable 10. STABILITY AND REACTIVITY Stability and Reactivity Chemical Stability Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Hazardous Reactions Hazardous Polymerization Refer to Section 10: Possibility of hazardous reactions Stable under normal conditions of storage and handling. Heat, open flames and other sources of ignition. Strong oxidising agents. Thermal decomposition may result in the release of toxic and/or irritating fumes including carbon monoxide, carbon dioxide, ammonia, oxides of nitrogen and oxides of sulphur. Will not occur. 6/9

7 11. TOXICOLOGICAL INFORMATION Toxicology Inhalation Ingestion Skin Eye No toxicity data available for this material. Inhalation of dusts/vapors may irritate the respiratory system. Ingestion of this product may irritate the gastric tract causing nausea and vomiting. May be irritating to skin. The symptoms may include redness, itching and swelling. May be irritating to eyes. The symptoms may include redness, itching and tearing. Chronic Effects Prolonged or repeated skin contact may cause defatting leading to dermatitis. 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence / Degradability Mobility Bioaccumulative Potential Environment Protection No ecological data available for this material. Prevent this material entering waterways, drains and sewers. 13. DISPOSAL CONSIDERATIONS Disposal Considerations The disposal of the spilled or waste material must be done in accordance with applicable local and national regulations. Product Disposal: Product wastes are controlled wastes and should be disposed of in accordance with all applicable local and national regulations. This product can be disposed through a licensed commercial waste collection service. The product should be rendered non-hazardous before being sent to a licensed landfill facility. Personal protective clothing and equipment as specified in Section 8 of this SDS must be worn during handling and disposal of this product. The ventilation requirements as specified in the same section must also be followed, and the precautions given in Section 7 of this SDS regarding handling must also be followed. Do not dispose directly into the sewerage system. Do not discharge into drains or watercourses or dispose where ground or surface waters may be affected. 7/9

8 In New Zealand, the disposal agency or contractor must comply with the New Zealand Hazardous Substances (Disposal) Regulations Further details regarding disposal can be obtained on the EPA New Zealand website under specific group standards. Container Disposal: The container or packaging must be cleaned and rendered incapable of holding any substance. It can then be disposed of in a manner consistent with that of the substance it contained. In this instance the packaging can be disposed through a commercial waste collection service. Alternatively, the container or packaging can be recycled if the hazardous residues have been thoroughly cleaned or rendered nonhazardous. In New Zealand, the packaging (that may or may not hold any residual substance) that is lawfully disposed of by householders or other consumers through a public or commercial waste collection service is a means of compliance with regulations. 14. TRANSPORT INFORMATION Transport Road and Rail Transport (Australia): Not classified as Dangerous Goods according to the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code) (7th edition). Road and Rail Transport (New Zealand): Not Classified as Dangerous Goods for transport by Road and Rail according to the New Zealand Standard NZS 5433:2012 Transport of Dangerous Goods on Land. Marine Transport (IMO/IMDG): Not classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea. Air Transport (ICAO/IATA): Not classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air. IMDG Marine Pollutant (MP) No 15. REGULATORY INFORMATION Regulatory Not classified as Hazardous according to criteria of National Occupational Health & Safety Commission (NOHSC), Australia. Not classified as a Scheduled Poison according to the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). Poisons ScheduleNot Scheduled National and or International New Zealand: Classified as Hazardous according to the New Zealand Hazardous 8/9

9 Regulatory Classified as Hazardous according to the New Zealand Hazardous Substances (Minimum Degrees of Hazard) Regulations All components of this product are listed on the New Zealand Inventory of Chemicals (NZIoC) or exempted. HSNO (CCID) Name: Ammonium sulphate HSNO Approval Number HSR OTHER INFORMATION Date of preparation or last revision of MSDS SDS Reviewed: August 2012, Supersedes: July 2007 Contact Person/Point For further information contact Tom Sadler on during business hours. In case of emergency call Australia / New Zealand IMPORTANT ADVICE: This MSDS summarizes our best knowledge of the health and safety hazard information of the product and how to safely handle and use the product in the workplace. Each user should read this MSDS and consider the information in the context of how the product will be handled and used in the workplace including its use in conjunction with other products. If clarification or further information is needed to ensure that an appropriate risk assessment can be made, the user should contact Ajax Finechem Pty Ltd. Our responsibility for products sold is subject to our standard terms and conditions, a copy of which is sent to our customers and is also available on request. End of MSDS (C) Copyright ACOHS Pty Ltd Copyright in the source code of the HTML, PDF, XML, XFO and any other electronic files rendered by an Infosafe system for Infosafe MSDS displayed is the intellectual property of Acohs Pty Ltd. Copyright in the layout, presentation and appearance of each Infosafe MSDS displayed is the intellectual property of Acohs Pty Ltd. The compilation of MSDS's displayed is the intellectual property of Acohs Pty Ltd. Copying of any MSDS displayed is permitted for personal use only and otherwise is not permitted. In particular the MSDS's displayed cannot be copied for the purpose of sale or licence or for inclusion as part of a collection of MSDS without the express written consent of Acohs Pty Ltd. Print Date: 14/08/2012 BS: /9