Aliette Super Date of Issue: 03/07/2017 Date of Previous Issue: 12/09/2012

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1 1. Identification of the Substance/Mixture and Supplier. Product name: Aliette Super Synonyms / alternative names: Application: EPA approval: Company: Telephone: Facsimile: Emergency telephone: Fungicide HSR Bayer New Zealand Limited, 3 Argus Place, Hillcrest, Auckland 0627, New Zealand (09) (24hr) 2. Hazards Identification. Hazard classification: Classification and type: Classified as hazardous according to the criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulations D Harmful if swallowed. 6.3B Causes mild skin irritation. 6.5B May cause an allergic skin reaction. 6.9B May cause damage to organs through prolonged or repeated exposure. 8.3A Causes serious eye damage. 9.1A Very toxic to aquatic life with long lasting effects. 9.3C Harmful to terrestrial vertebrates. 3. Composition/Information on Ingredients. Chemical nature Fosetyl-Aluminium. Also known as Aluminium tris (O-ethylphosphonate) Hazardous components Chemical name CAS No. Concentration (%w/w) Fosetyl-Aluminium Page 1 of 8

2 Thiram Thiabendazole First Aid Measures. General advice: Inhalation: Skin contact: Eye contact: Ingestion: Most important symptoms and effects, both acute and delayed: Notes to physician: Further information: Avoid contact with skin and eyes and inhalation of concentration or spray mist. When mixing or applying, wear protective clothing, including face shield, impervious gloves and footwear. If clothing becomes contaminated with product, remove clothing immediately. DO NOT eat, drink or smoke while using. Wash hands and exposed skin thoroughly with soap and water before meals and after work. Wash protective clothing daily after work. Move to fresh air. Keep patient warm and at rest. Call a doctor or poison control centre immediately. Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. Get medical attention if irritation develops and persists. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical attention if irritation develops and persists. Rinse mouth. Do NOT induce vomiting. Call a doctor or poison control centre immediately. No symptoms known or expected. Treatment: Treat symptomatically. There is no specific antidote. Contact the National Poisons and Hazardous Chemicals Information centre in Dunedin, PO Box 913, Dunedin. Phone 0800 POISON ( ). 5. Fire-Fighting Measures. Suitable extinguishing media: Foam, dry powder, carbon dioxide. Page 2 of 8

3 Special hazards arising from the substance or mixture: In the event of fire the following may be released: Hydrogen chloride (HCl) Hydrogen cyanide (hydrocyanic acid) Hydrogen fluoride Carbon monoxide (CO) Nitrogen oxides (NOx) Special protective equipment for firefighters: Further information: In the event of fire and/or explosion do not breathe fumes. In the event of fire, wear self-contained breathing apparatus. Contain the spread of the fire-fighting media. Do not allow run-off from fire-fighting to enter drains or water courses. 6. Accidental Release Measures. Personal precautions: Environmental precautions: Methods for cleaning up: Additional advice: Avoid contact with spilled product or contaminated surfaces. Use personal protective equipment. Do not allow to get into surface water, drains and ground water. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Apply this product as specified on the label. Use mechanical handling equipment. Clean contaminated floors and objects thoroughly, observing environmental regulations. Keep in suitable, closed containers for disposal. Information regarding safe handling: see section 7. Information regarding personal protective equipment: see section 8. Information regarding waste disposal, see section Handling and Storage. Handling: Advice on safe handling Use only in areas provided with appropriate exhaust ventilation. Hygiene measures Avoid contact with skin, eyes and clothing. Keep working clothes separately. Wash hands before breaks and immediately after handling the product. Remove soiled clothing immediately and clean thoroughly before Page 3 of 8

4 Storage: using again. Garments that cannot be cleaned must be destroyed (burnt). Requirements for storage areas and containers Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Store in a place accessible by authorized persons only. Keep away from direct sunlight. Avoid temperatures below 0 C or above 30 C. Advice on common storage Keep away from food, drink and animal feeding stuffs. Specific end uses Refer to the label and/or leaflet. 8. Exposure Control/Personal Protection. Personal protect equipment: In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply. Respiratory protection: Hand protection: Eye protection: Skin and body protection: Where insufficient ventilation, use suitable respiratory protection. Wear suitable protective gloves (e.g. Polyvinyl chloride PVC). After contamination with product change the gloves immediately. Wear CE Marked (or equivalent) nitrile rubber gloves (minimum thickness 0.40 mm). Wash when contaminated. Dispose of when contaminated inside, when perforated or when contamination outside cannot be removed. Wash hands always before eating, drinking, smoking or using the toilet. Wear goggles conforming to EN166 (Field of Use 5 or equivalent). Wear standard coverall and Type 6 suit. Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and should be professionally laundered frequently. If chemical protection suit is splashed, sprayed or significantly contaminated, decontaminate as far as possible, then carefully remove and dispose of as advised by manufacturer. 9. Physical and Chemical Properties. Page 4 of 8

5 Appearance Form: Colour: Safety Data: Flash point: Water solubility: ph: Viscosity, dynamic: Explosivity: Other information: Wettable powder Speckled off-white powder Not flammable. Soluble 3 4 (determined as a 1% emulsion in distilled water) Not known Not explosive 92/69/EEC, A.14 / OECD 113 Further safety related physical-chemical data are not known. 10. Stability and Reactivity. Reactivity: Chemical stability: Possibility of hazardous reactions: Conditions to avoid: Incompatible materials: Hazardous decomposition products: Stable under normal conditions. Stable under recommended storage conditions. No dangerous reaction known under conditions of normal use. Extremes of temperature and direct sunlight. Store only in the original container. No data available. 11. Toxicological Information. Acute oral toxicity: Acute dermal toxicity: LD 50: 28600mg/kg LD 50: >2000mg/kg Page 5 of 8

6 Acute dermal toxicity: Skin irritation: Eye irritation: Sensitization: Assessment repeated dose toxicity: Assessment mutagenicity: Assessment carcinogenicity: Assessment toxicity to reproduction: Assessment developmental toxicity: LC 50: >5.02 mg/l (Exposure time 4h) Skin irritant. Thiram is irritating to the skin. Eye irritant. Thiram is irritating to eyes. May cause sensitization by skin contact Fosetyl Aluminium did not cause specific target organ toxicity in experimental animal studies. Thiram caused specific target organ toxicity in experimental animal studies in the following organ(s): Liver, forestomach. Thiabendazole caused specific target organ toxicity in experimental animal studies in the following organ(s): Liver. Fosetyl Aluminium was not mutagenic or genotoxic in a battery of in vitro and in vivo tests. Thiram was not mutagenic or genotoxic based on the overall weight of evidence in a battery of in vitro and in vivo tests. Thiabendazole was not mutagenic or genotoxic in a battery of in vitro and in vivo tests Fosetyl Aluminium was not carcinogenic in lifetime feeding studies in rats and mice. Thiram was not carcinogenic in lifetime feeding studies in rats and mice. Thiabendazole was not carcinogenic in lifetime feeding studies in rats and mice Fosetyl Aluminium did not cause reproductive toxicity in a twogeneration study in rats. Thiram did not cause reproductive toxicity in a two-generation study in rats. Thiabendazole did not cause reproductive toxicity in a two-generation study in rats Fosetyl Aluminium did not cause developmental toxicity in rats and rabbits. Thiram caused developmental toxicity only at dose levels toxic to the dams. Thiabendazole did not cause developmental toxicity in rats and rabbits. 12. Ecological Information. Toxicity to fish: Toxicity to LC 50 Rainbow trout (Oncorhynchus myskiss) >120mg/L (96h) Test conducted with a similar formulation EC 50: 37mg/l water flea (Daphnia magna) (48h) Page 6 of 8

7 aquatic Test conducted with a similar formulation invertebrates: Toxicity to aquatic plants: Biodegradability: Bioaccumulative potential: Mobility in soil: Results of PBT and vpvb assessment: EC 50 (Scenedesmus subspicatus) 8mg/L (72h) Test conducted with a similar formulation Fosetyl Aluminium rapidly biodegradable Thiram not rapidly biodegradable Thiabendazole No data Fosetyl Aluminium Does not bioaccumulate Thiram Bioconcentration factor (BCF) 3.9 Thiabendazole Low bioaccumulation potential Fosetyl Aluminium Highly mobile in soils Thiram Immobile in soil Thiabendazole Stable Fosetyl Aluminium: This substance is not considered to be persistent, bioaccumulative and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulative (vpvb). Thiram: This substance is not considered to be persistent, bioaccumulative and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulative (vpvb). Thiabendazole No data Other adverse effects: 13. Disposal Considerations. Product disposal: Container disposal: Dispose of this product only by using according to the label, or at an approved landfill or other approved facility. Triple rinse containers. Recycle if possible. If allowed under local authority, burn if circumstances, especially wind direction permit, otherwise crush and bury in an approved local authority facility. Do not use container for any other purpose. 14. Transport Information. ADR/RID/ADN: Sea (IMDG- Code): UN3077 Environmentally Hazardous Substance, Solid, N.O.S. (thiabendazole/thiram mixture), Class 9, Packing Group III, Hazchem Code 2Z UN3077 Environmentally Hazardous Substance, Solid, N.O.S. (thiabendazole/thiram mixture), Class 9, Packing Group III, Hazchem Code 2Z Page 7 of 8

8 Air (ICAO/IATA): UN3077 Environmentally Hazardous Substance, Solid, N.O.S. (thiabendazole/thiram mixture), Class 9, Packing Group III, Hazchem Code 2Z 15. Regulatory Information. HSNO Approval Number: HSNO Controls: ACVM Registration: ACVM Controls: HSR See for controls P See for registration conditions 16. Other Information. Not applicable Registered trademark of the Bayer Group. The data given here is based on current knowledge and experience. The purpose of this Safety Data Sheet is to describe products in terms of their safety requirements. The above details do not imply any guarantee concerning composition, properties or performance of the product. Page 8 of 8