Version: 2.0. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

Transcription

1 Revised edition: Version: 2.0 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Ascorbic Acid Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Chemical for different applications. Food additive Animal feed additive Uses advised against: Details of the Supplier of the Safety Data Sheet Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: Emergency No. info@kremer-pigmente.de Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product is not classified as hazardous according to the CLP/GHS Directive. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: This product does not require classification and labelling as hazardous according to CLP/GHS. Not applicable. Signal word: Hazard designation: Safety designation: Hazardous components for labelling: Other Hazards 2

2 Composition/Information on Ingredients Substance Mixture Page 2 Chemical Characterization: Ascorbinsäure. CAS No , EINECS ; REACH Reg. No Hazardous Ingredients: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Remove contaminated clothes. Supply fresh air and seek medical advice in case of complaints. Wash off with plenty of water and soap. If irritation continues consult a physician. Rinse open eyes with plenty of water for at least 5 minutes. Seek medical attention if irritation persists After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with water and drink plenty of water. If symptoms persist consult physician. Symptoms: No further information available Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Foam, water jet Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture None known. Special hazards: Combustible material. 3

3 Dust can form explosive mixtures with air Advice for Firefighters Page 3 Protective equipment: Wear self-contained respiratory protective device. Wear suitable protective clothing Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Contaminated extinguishing water and debris should be disposed of according to local regulations Personal precautions: Environmental Precautions Do not inhale dust Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. Avoid dust formation. Clean with water. Protective clothing, see Section 8. Provide adequate ventilation. Avoid formation of dust. Do not inhale dust. Avoid contact with eyes and skin Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not eat or drink during work. Do not smoke. Keep away from foodstuffs and drinks. Storage conditions: Requirements for storage areas and containers: Store in tightly sealed containers in a dry and cool room. Protect product from direct sunlight. Protect against humidity and water. Storage temperature: < 25 C. Suitable container material: stainless steel, glass, polyethylene, polypropylene, polyvinylchloride. Unsuitable container material: aluminum, zinc, copper. Information on fire and explosion 4

4 protection: Storage class (VCI): Page 4 Take measures to prevent static electricity discharge. Risk of dust explosion Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): none known Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: No further measures, see Section 7. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Avoid contact with eyes and skin. Do not eat, drink or smoke during work. Do not inhale vapor/dust. In case of formation of dust. Dust mask (particle filter P1; EN 143). Protective gloves. The glove material has to be impermeable and resistant to the product / substance / preparation. Polyvinyl chloride (> 480 min; 0.7 mm) Nitrile rubber (480 min, 0.4 mm) Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material and dexterity. Always seek advice from glove suppliers. Safety glasses (EN 166) Body protection: Protective clothing. 5

5 Environmental precautions: 9. Physical and Chemical Properties Information on Basic Physical and Chemical Properties Page 5 Form: Color: Odor: Odor threshold: ph-value: powder white - yellowish/white odorless (50 g/l; 20 C) Melting temperature: C Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): not determined not applicable Product is combustible, but not easily flammable. no information available no information available < hpa (25 C) ca g/cm3 ca. 300 g/l (20 C) logkow (23 C) Auto-ignition temperature: 380 C Decomposition temperature: 190 C Viscosity, dynamic: Explosive properties: Oxidizing properties: not available Product is not explosive; however, an explosive dust/air mixture can be formed. none Bulk density: 6

6 not determined Further Information Page Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects No further information. Stable if used according to specifications. Stable if used according to specifications. Dust can form explosive mixtures with air. Avoid humidity. Protect from light. 190 C Oxidizing agents, bases. In case of fire: formation of toxic decomposition products mg/kg (rat) Irritant effect on skin: Irritations are possible. 7

7 Irritant effect on eyes: Dust may cause irritation. Page Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Moblity Results of PBT- und vpvp Assessment Other Adverse Effects No information available No sensitizing effects known. No data available. No data available. No data available. No data available. LC50: 1020 mg/l (96h, Oncorhynchus mykiss; OECD 203) no information available 100 % (10d); readily biodegradable (OECD 302B) Water soluble. This substance is not classified as PBT (persistent, bioaccumulative, toxic), nor as vpvb (very persistent, very bioaccumulative). Water hazard class: 8

8 Behaviour in sewage systems: Further ecological effects: Page 8 1, slightly hazardous Do not let product contaminate ground water, waterways or sewage system AOX Value: Disposal Considerations Waste Treatment Methods Product: Dispose of according to official national and local regulations. European Waste Code (EWC): Uncleaned packaging: Uncontaminated packaging may be recycled. Completely empty packaging can be disposed of with the regular waste. Uncontaminated packaging may be recycled. Suggested cleaning agent: water. Detergent can be added if necessary Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. not applicable not applicable Hazard no.: Packaging Group 9

9 ADR/RID: not applicable Page 9 IMDG: IATA: Environmental Hazards None Special Precautions for User Not classified as a dangerous good under transport regulations. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: Local regulations on chemical accidents: 1, slightly hazardous for water Does not underlie the Accident Ordinance Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.