Safety Data Sheet. Product Name :COLGATE OPTIC WHITE TOOTHPASTE (ENAMEL WHITE)

Transcription

1 Page: 1 1. Identification GHS Product Identifier Product Code Company Name Address Telephone/Fax Number Emergency phone number Recommended use the chemical and restrictions on use Other Information COLGATE OPTIC WHITE TOOTHPASTE (ENAMEL WHITE) B ColgatePalmolive Pty Ltd (ABN ) Australia: Level 14, 345 George Street, Sydney NSW 2000 Australia Tel: AUS (02) NZ: Fax: AUS (02) , NZ: AUS , NZ: Whitening Toothpaste New Zealand Address: Level 4, 45 Knights Road, Lower Hutt. 2. Hazard Identification Classification the substance or mixture Not classified as Hazardous according to the Globally Harmonised System Classification and labelling Chemicals (GHS) including Work, Health and Safety regulations, Australia Not classified as Dangerous Goods according to the Australian Code for the Transport Dangerous Goods by Road and Rail. (7th edition) 3. Composition/information on ingredients Chemical Characterization Ingredients 4. Firstaid measures Inhalation Ingestion Skin Eye contact First Aid Facilities Advice to Doctor Other Information Paste Name CAS Proportion Propylene glycol % Calcium Pyrophosphate % Glycerin % Polyethylene Glycol % Oxirane, methyl, % polymer with oxirane Polyvinylpyrrolidone % Synthetic amorphous % silica precipitated Tetrasodium <5 % pyrophosphate Hydrogen peroxide <3 % Sodium <2 % monluorophosphate LMenthol <2 % Ingredients determined not to be hazardous Balance If inhaled, remove affected person from contaminated area. Keep at rest until recovered. If symptoms develop and/or persist seek medical attention. Wash out mouth with water. If irritation develops and persists, seek medical attention. Wash affected area thoroughly with soap and water. If symptoms develop seek medical attention. If in eyes, hold eyelids apart and flush the eyes continuously with running water. Continue flushing for several minutes until all contaminants are washed out completely. If symptoms develop and persist seek medical attention. Eyewash and normal washroom facilities. Treat symptomatically. For advice in an emergency, contact a Poisons Information Centre (Phone Australia ; New Zealand 0800 POISON / ) or a doctor at Print Date: 8/09/2014

2 Page: 2 once. 5. Firefighting measures Suitable extinguishing media Hazards from Combustion Products Specific hazards arising from the chemical Decomposition Temp. Precautions in connection with Fire Use carbon dioxide, dry chemical or foam. Under fire conditions this product may emit toxic and/or irritating fumes, smoke and gases including carbon monoxide, carbon dioxide and oxides nitrogen. This product will burn if exposed to fire.. Accidental release measures Personal precautions, protective equipment and emergency procedures 7. Handling and storage Precautions for Safe Handling Conditions for safe storage, including any incompatabilities 8. Exposure controls/personal protection Occupational exposure limit values Fire fighters should wear SelfContained Breathing Apparatus (SCBA) operated in positive pressure mode and full protective clothing to prevent exposure to vapours or fumes. Water spray may be used to cool down heatexposed containers. Fight fire from safe location. This product should be prevented from entering drains and watercourses. Avoid accidents, clean up immediately. Small spill: Mop up & wash residue to drain with copious amounts water. Large spill: Wear appropriate personal protective equipment and clothing to prevent exposure. Extinguish or remove all sources ignition and stop leak if safe to do so. Increase ventilation. Evacuate all unprotected personnel. If possible contain the spill. Place inert absorbent, non combustible material onto spillage. Use clean nonsparking tools to collect the material and place into suitable labelled containers for subsequent recycling or disposal. Dispose waste according to the applicable local and national regulations. If contamination sewers or waterways occurs inform the local water and waste management authorities in accordance with local regulations. Industrial use: Avoid inhalation vapours and mists, and skin or eye contact. Use only in a well ventilated area. Keep containers sealed when not in use. Prevent the build up mists or vapours in the work atmosphere. Do not use near ignition sources. Do not pressurise, cut, heat or weld containers as they may contain hazardous residues. Maintain high standards personal hygiene by washing hands prior to eating, drinking, smoking or using toilet facilities. Industrial quantities: Store in a cool, dry, wellventilated area away from sources ignition, oxidising agents, strong acids, foodstuffs, and clothing. Keep containers closed when not in use, securely sealed and protected against physical damage. Inspect regularly for deficiencies such as damage or leaks. Have appropriate fire extinguishers available in and near the storage area. Take precautions against static electricity discharges. Use proper grounding procedures. Ensure that storage conditions comply with applicable local and national regulations. For information on the design the storeroom, reference should be made to Australian Standard AS1940 The storage and handling flammable and combustible liquids. No exposure value assigned for this specific material by Safe Work, Australia. However, the available exposure limits for ingredients are listed below: Safe Work, Australia Exposure Standards: Substance TWA STEL Notices ppm mg/m³ ppm mg/m³ Propylene glycol Print Date: 8/09/2014

3 Page: 3 Biological Limit Values Appropriate engineering controls Respiratory Protection Eye Protection Hand Protection Body Protection 9. Physical and chemical properties Form Appearance Colour Odour Decomposition Temperature Melting Point Boiling Point Solubility in Water Solubility in Organic Solvents (vapour & particulates) Glycerin 10 Synthetic amorphous silica precipitated 10 (precipitated silica) Tetrasodium pyrophosphate 5 Hydrogen peroxide TWA (Time Weighted Average): The average airborne concentration a particular substance when calculated over a normal eighthour working day, for a fiveday week. STEL (Short Term Exposure Limit): The average airborne concentration over a 15 minute period which should not be exceeded at any time during a normal eighthour workday. No biological limits allocated. No special engineering controls required. Industrial applications: Provide sufficient ventilation to keep airborne levels below the exposure limits or as low as possible. Where vapours or mists are generated, particularly in enclosed areas, and natural ventilation is inadequate, a flamepro exhaust ventilation system is required. Refer to relevant regulations for further information concerning ventilation requirements. Not required under normal conditions use. Industrial Applications: Reference should be made to Australian Standards AS/NZS 1715, Selection, Use and maintenance Respiratory Protective Devices; and AS/NZS 171, Respiratory Protective Devices. Filter capacity and respirator type depends on exposure levels and individual circumstances. Final choice appropriate breathing protection is dependent upon actual airborne concentrations and the type breathing protection required will vary according to individual circumstances. Not required under normal conditions use. However, avoid eye contact. Industrial Applications: The use safety glasses as appropriate when handling large quantities. Refer to Australian Standard AS/NZS 1337 Eye Protectors for Industrial Applications. Not required under normal conditions use. However, under industrial applications, the use gloves is recommended. Final choice is dependent on individual circumstances. Final choice appropriate gloves will vary according to individual circumstances i.e. methods handling or according to risk assessments undertaken. Reference should be made to AS/NZS 211.1: Occupational protective gloves Selection, use and maintenance. Not required under normal conditions use. However, under industrial applications suitable protective work wear, e.g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron is recommended where large quantities are handled. Paste Smooth, white, minty paste White Minty odour Print Date: 8/09/2014

4 Page: 4 Specific Gravity ph Vapour Pressure Vapour Density (Air=1) Evaporation Rate Odour Threshold Viscosity Volatile Component Partition Coefficient: noctanol/water Flash Point Flammability AutoIgnition Temperature Flammable Limits Lower Flammable Limits Upper Explosion Properties Oxidising Properties 1.27 (25 C) 8.0 in 10% slurry Nonflammable 10. Stability and reactivity Reactivity Chemical Stability Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Possibility hazardous reactions Hazardous Polymerization 11. Toxicological Information Toxicology Information Ingestion Inhalation Skin Eye Respiratory sensitisation Skin Sensitisation Germ cell mutagenicity Carcinogenicity Refer to Sec 10: Possibility hazardous reactions Stable under normal conditions storage and handling. Heat, open flames and other sources ignition. Strong oxidising agents. Under fire conditions this product may emit toxic and/or irritating fumes, smoke and gases including carbon monoxide, carbon dioxide and oxides nitrogen. Will react with incompatible materials. Will not occur. No toxicity data are available for this material. Ingestion this product may irritate the gastric tract causing nausea and vomiting. Inhalation dusts/vapors may irritate the respiratory system. May be irritating to skin. The symptoms may include redness, itching and swelling. May be irritating to eyes. The symptoms may include redness, itching and tearing. Not expected to be a respiratory sensitiser. Not expected to be a skin sensitiser. Not considered to be a mutagenic hazard. Polyvinylpyrrolidone is listed as a Group 3: Not classifiable as to carcinogenicity to humans according to International Agency for Research on Print Date: 8/09/2014

5 Page: 5 Reproductive Toxicity STOTsingle exposure STOTrepeated exposure Aspiration Hazard Cancer (IARC). Hydrogen peroxide is listed as a Group 3: Not classifiable as to carcinogenicity to humans according to International Agency for Research on Cancer (IARC). Not considered to be toxic to reproduction. Not expected to cause toxicity to a specific target organ. Not expected to cause toxicity to a specific target organ. Not expected to be an aspiration hazard. 12. Ecological information Ecotoxicity Persistence and degradability Mobility Bioaccumulative Potential Other Adverse Effects Environmental Protection 13. Disposal considerations Disposal Considerations 14. Transport information Transport Information IMDG Marine pollutant 15. Regulatory information Regulatory Information Poisons Schedule AICS (Australia) 1. Other Information Date preparation or last revision SDS Literature References No ecological data available for this material. Prevent large quantities this material entering waterways, drains and sewers. Industrial applications for large quantities: The disposal the spilled or waste material must be done in accordance with applicable local and national regulations Not classified as Dangerous Goods according to the Australian Code for the Transport Dangerous Goods by Road and Rail. (7th edition) Not classified as Dangerous Goods by the criteria the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea. Not classified as Dangerous Goods by the criteria the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air. No Not classified as Hazardous according to the Globally Harmonised System Classification and labelling Chemicals (GHS) including Work, Health and Safety regulations, Australia Not classified as a Scheduled Poison according to the Standard for the Uniform Scheduling Medicines and Poisons (SUSMP), if labelled with warnings to the following effect: (A) Do not swallow; and (B) Do not use COLGATE OPTIC WHITE TOOTHPASTE (ENAMEL WHITE) in children six years age or less Not Scheduled The listed chemicals are included in Australian Inventory Chemical Substances (AICS) or otherwise notified under NICNAS. SDS Reviewed: June 2014 Supersedes: November 2013 Preparation Safety Data Sheets for Hazardous Chemicals Code Practice. Standard for the Uniform Scheduling Medicines and Poisons. Australian Code for the Transport Dangerous Goods by Road & Rail. Model Work Health and Safety Regulations, Schedule 10: Prohibited carcinogens, Print Date: 8/09/2014

6 Page: Contact Person/Point restricted carcinogens and restricted hazardous chemicals. Workplace exposure standards for airborne contaminants, Safe work Australia. American Conference Industrial Hygienists (ACGIH). Globally Harmonised System classification and labelling chemicals. 24Hr Emergency Response Australia New Zealand End Of MSDS... Copyright ACOHS Pty Ltd Copyright in the source code the HTML, PDF, XML, XFO and any other electronic files rendered by an Infosafe system for Infosafe MSDS displayed is the intellectual property Acohs Pty Ltd. Copyright in the layout, presentation and appearance each Infosafe MSDS displayed is the intellectual property Acohs Pty Ltd. The compilation MSDS's displayed is the intellectual property Acohs Pty Ltd. Copying any MSDS displayed is permitted for personal use only and otherwise is not permitted. In particular the MSDS's displayed cannot be copied for the purpose sale or licence or for inclusion as part a collection MSDS without the express written consent Acohs Pty Ltd. Print Date: 8/09/2014