MATERIAL SAFETY DATA SHEET Drawn up / Updated on: /

Transcription

1 MATERIAL SAFETY DATA SHEET Drawn up / Updated on: / Identification of the product and the company 1.1 Product s identification Zinc Sulphate with 35% Zinc content 1.2 Application feed additive, industrial raw material 1.3 Data of Company - manufacturer Przedsiębiorstwo ARKOP Sp. z o.o Bukowno ul. Kolejowa 34 A; POLAND tel.: , fax.: REGON P Responsible person Environmental specialist Msc. Arkadiusz Krzystanek tel arkadiusz.krzystanek@arkop.pl 1.4 Emergency telephone To company: (working hours: ) Emergency: 112 Fire department: Hazards identification 2.1 Substance classification Phrases GHS Classification Acute toxicity, Category 4, orally H302: Harmful if swallowed Serious eyes damage, Category 1 H318: Causes serious eyes damage Acute aquatic toxicity, Category 1 H400: Very toxic to aquatic life Chronic aquatic toxicity, Category 1 H410: Very toxic to aquatic life with long lasting effects. EC Classification X n harmful product R22: Harmful if swallowed X i irritating product R41: Risk of serious damage to eyes N Environmentally hazardous product R50/53: Very toxic for aquatic organisms, may cause long-term adverse effects in the aquatic environment 2.2 Labelling GHS Labelling Index no: Hazard pictograms Signal word Danger Hazard statements H302: Harmful if swallowed, H318: Causes serious eyes damage, H400: Very toxic to aquatic life H410: Very toxic to aquatic life with long lasting effects. Page 1 from 8

2 Precautionary statements P270: Do not eat, drink or smoke when using this product. P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P280: Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338: IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P273: Avoid release to the environment. P391: Collect spillage. EU directives labelling Symbol(s): X n, N Warning sings: X ni Harmful product N Environmentally hazardous product R-phrases: /53: Harmful if swallowed. Risk of serious damage to eyes. Very toxic for aquatic organisms, may cause long-term adverse effects in the aquatic environment S-phrases: Keep out of the reach of children. Do not breathe dust. Wear eye/face protection. If swallowed, seek medical advice immediately and show this container or label. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instruction /Material Safety Data Sheet. EC Labelling EC Number: EC Label 2.3 Another hazards not specified 3. Composition / Information on ingredients: Synonyms: Zinc Sulphate Monohydrate Chemical formula: ZnSO 4 x H 2 O CAS Number: EC Number: Index Number: Molecular mass: 179,45 g/mol 4. First Aid Measures 4.1 First Aid Measures description After inhalation: fresh air, consult doctor if feeling unwell After skin contact: wash off with water, consult doctor if irritancy persists After eyes contact: rinse out with plenty of water, contact the doctor immediately After ingestion: give plenty of water to drink, induce vomits, contact the doctor 4.2 Most important acute and late results of exposure After inhalation: possible symptoms of metal vapours disease after long inhalation After skin contact: irritation After eyes contact: irritation, burn After ingestion: possible symptoms of poisoning after ingestion 4.3 Instructions for immediate medical aid and special treatment of victim Contact with the doctor in case victim feeling unwell after material inhalation or ingestion. Use first aid measures before doctor s arrival. Page 2 from 8

3 5. Fire-Fighting Measures 5.1 Suitable extinguishing media Use extinguishing measures appropriate to other materials stored, appropriate to local circumstances and the surrounding environment. 5.2 Specific hazards during fire fighting: non-flammable substance. Ambient fire may liberate hazardous vapours sulphuric oxides. Prevent fire extinguishing water from contaminating surface water or the ground water system. 5.3 Special protective equipment for fire-fighters: wear gas-tight protective clothing and respiratory protection equipment. Extinguish gases/vapours/mists with sprayed stream of water. Prevent fire extinguishing water from contaminating surface water or the ground water system. 6. Accidental release measures 6.1 Personal precautions, protective equipment and procedures Prevent contamination with the product. Avoid dust inhalation. Ensure appropriate ventilation. Wear protective equipment Environmental precautions. Do not empty into drains. 6.3 Methods and materials for preventing and cleaning up pollution. Pick up dry substance mechanically. Avoid dust generation. Clean up contaminated area. Forward to disposal. Prevent access to water, sewers and soil 6.4 Use protective equipment mentioned in paragraph 8. Collected material considered as waste. Proceed according to paragraph Handling and storage 7.1 Advice on safe handling - Ensure sufficient air exchange (ventilation) Act according to good manufacturing practice and general rules of safety & hygiene handling the chemical substances. Use protective equipment mentioned in paragraph 8. Do not empty into drains. Observe label precautions. 7.2 Safe storage precautions, including all information about mutual incompatibilities tightly closed containers, dry place, up to 10 layers 7.3 Further information on storage conditions without limitations. 8. Exposure controls / personal protection 8.1 Control Parameters: (NDS, NDSCh, NDSP) not specified (does not contain substances with specified allowed concentration in working place) 8.2 Exposure control: Use appropriate systems of general and exhaust ventilation ensuring concentration of the product in air below set requirements (minimal air exchange 10 times / hour). It is suggested to equip workplace with shower and water spray for eyes rinsing. Design and manufacture of personal protection measures should ensure appropriate chemical protection and exclude all potential danger and inconveniences in foreseen workplaces. Personal protective equipment: Protective equipment should be selected specifically for the working place, depending on concentration and quantity of the hazardous substances handled. The resistance of the protective clothing to chemicals should be ascertained with the respective supplier. Respiratory protection Necessary when dust are generated Recommended Filter type: Filter P2 (acc. to DIN 3181) for solid and liquid particles of harmful substances Hand protection Full contact: Page 3 from 8

4 Glove material: nitrile rubber Glove thickness: 0,11 mm Breakthrough time: >480 min Splash contact: Glove material: nitrile rubber Glove thickness: 0,11 mm Breakthrough time: >480 min The protective gloves to be used must comply with the specification of EC directive 89/686/EEC and / or resultant standard EN374, eg. KCL 741 Dermatril L (full contact), KCL 741 Dermatril L (splash contact). The breakthrough times stated above were determined by KCL in laboratory tests acc. To EN 374 with samples of the recommended glove types. This recommendation applies only to the product stated in the safety data sheet and supplied by us as well as to the purpose specified by us. When dissolving or mixing with other substances and under conditions deviating from those stated in PN-EN374-3:1999 please contact the supplier of CE-approved gloves. Eye protection Tight safety glasses Hygiene measures Change contaminated clothing. Wash hands after working with substance. Using of skin protective cream is suggested. 9. Psychical and chemical properties 9.1 Basic psychical and chemical properties Appearance: solid, fine Colour: white to cream Odour: odourless ph: 4,5 6,0 (50 g/l H 2 O as suspension, 20 C) Melting temperature: ~ 740 C (decomposition) Boiling temperature: no data available Self ignition temperature: not combustible Ignition temperature: not applicable Danger of explosion / range: not applicable low: high: Vapour pressure: no data available Density: 3,2 g/cm 3 (20 0 C) Bulk density : kg/m 3 Solubility: in water: ~ 400 g/l (20 C) in organic solvents: no data available 9.2 Another information Elimination 10. Stability and reactivity 10.1 Reactivity not reactive 10.2 Stability Stable in normal circumstances. Thermal decomposition in 240 C elimination of crystalline water, ca 600 C anhydrous substance Hazardous reactions existence - may violently react with hydrogen peroxide and magnesium 10.4 Conditions to avoid strong heating 10.5 Incompatibles materials none 10.6 Hazardous decomposition products: sulphuric oxides Page 4 from 8

5 11. Toxicological information 11.1 Toxicological results information Acute toxicity: LD 50 (orally, rat): 2949 mg/kg (anhydrous substance). Symptoms: irritation of mucosa, mouth, throat, esophagus and gastrointestinal tract. Pain, vomits, diarrhoea. Acute toxicity through inhalation Symptoms: damage of inhalation tract, inhalation may cause edema in inhalation tract Skin irritation - irritation Eye irritation - causes serious eye damage Genotoxity in vitro Ames test: Result: negative Further information After absorption: Systemic effects: pain, vomits, nausea After absorption of large quantities: blood pressure fall, cardiovascular disorders, collapse Further data Handle in accordance with good industrial hygiene and safety practice. 12. Ecological information 12.1 Toxicity Toxicity to daphnia and other aquatic invertebrates EC50 Species: Daphnia magna (Water flea) Dose: 0,15 mg/l Exposure time: 48 h Toxicity to algae IC50 Species: Pseudokirchnehella subcapitata (green algae) Dose: 0,52 mg/l Exposure time: 5 days (anhydrous substance) 12.2 Persistence and degradability - Biodegradability The methods for determining the biological degradability are not applicable to inorganic substances Bioaccumulation ability chemical safety report has not been conducted 12.4 In soil mobility chemical safety report has not been conducted 12.5 PBT vpvbc properties results chemical safety report has not been conducted 12.6 Additional adverse effects Hazard for drinking water supply. Toxic for aquatic organisms. May cause long-term adverse effects in aquatic environment. Prevent access to water, sewer and solid. Inorganic substance. Do not cause biological deficiency of oxygene. 13. Disposal considerations 13.1 Disposal methods Disposal classified and considered as hazardous. Packaging must be disposed in compliance with respective national-specific regulations or must be passed to a packaging return system. Company ARKOP Sp. z o.o. dispose or recover chemical substances & their packaging bought in Company ARKOP Sp. z o.o. Materials & packaging deliveries have to be agreed each time with the Company ARKOP Sp. z o.o. Utilization of the wastes has to be done by specialized companies. Single-use packaging should be treated as waste. Disposal of collected wastes should Page 5 from 8

6 be agreed with appropriate authorities. 14. Transport information 14.1 UN Number: UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. Labels & Stickers Transport hazard class - Class: 9, Hazard sign Packaging group - III, Packaging instructions: P, IBC, LR, R 14.5 Environment hazard Environmentally hazardous substance 14.6 Special safety precautions Special regulations. Land transport: 274, 601, CV13, V13 Cistern code: SGAV, LGBV, AT Tunnel code: E 14.7 Bulk Transport allowed specific requirements W1, BK1, BK2 Another information Land transport RID/ADR Packaging group: III. Class: 9,Tunnels E, Label number 9 Hazard sign: 90 Marine Transport Packaging group: III. Ems F-A S-F Class: 9 Air Transport UN/ID No 3077 PG III Transport - covered transport means, max. number of transported layers Regulatory information 15.1 Specific substance regulation for safety, health and environmental protection. GHS Labelling Index no: Hazard pictograms Signal word Danger Hazard statements H302: Harmful if swallowed, H318: Causes serious eyes damage, H400: Very toxic to aquatic life H410: Very toxic to aquatic life with long lasting effects. Precautionary statements P270: Do not eat, drink or smoke when using this product. P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P280: Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338: IF IN EYES: Rinse Page 6 from 8

7 continuously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P273: Avoid release to the environment. P391: Collect spillage. EU directives labelling Symbol(s): X n, N Warning sings: X ni Harmful product N Environmentally hazardous product R-phrases: /53: Harmful if swallowed. Risk of serious damage to eyes. Very toxic for aquatic organisms, may cause long-term adverse effects in the aquatic environment S-phrases: Keep out of the reach of children. Do not breathe dust. Wear eye/face protection. If swallowed, seek medical advice immediately and show this container or label. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instruction /Material Safety Data Sheet. EC labelling EC Number: EC Label Major Accident Hazard Legislation: 96/82/EC Update: 2003 Dangerous for the environment 9a Quantity 1 : 100t Quantity 2: 200 t REACH registration no: EU Legislation EC Regulation 1272/2008/EC from 16 December 2008 r for substances and mixtures classification, labelling and packaging amending and repealing directives 67/548/EECand 1999/45/EC and amending EC Regulation 1907/2006 of European Parliament and Council for registration, assessment, authorisation and applied restrictions for chemicals (REACH), creation of European Agency for Chemicals, amending directive 1999/45/EC and repealing Concuil regulation EEC 793/93 and Commission Regulation (EC) 1488/94, and Council directive 76/769 EEC and Commission directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/ EC Chemical safety assessment has not been conducted 16. Other information The information contained herein is based on our present knowledge and experiences concerning safety use of the product. The information are given in good faith. ARKOP takes no responsibility for its complete usefulness in all situation existing in transportation and trade. In case of applying the product in mixtures one assures no new hazardous substances are created. Actualisation according to amended legislation Risk phrases Index: R: R 22 Harmful if swallowed R 41 Risk of serious eyes damage R 50/53 - Very toxic to aquatic organisms; may cause long term adverse effects in the aquatic environment. H statements index: H302: Harmful if swallowed, H318: Causes serious eyes damage, H400: Very toxic to aquatic life Page 7 from 8

8 H410: Very toxic to aquatic life with long lasting effects. The information contained herein is based on our present knowledge and experiences concerning safety use of the product. The information can be only considered as advice for safe handling of the product. Main sources: ULMANN'S ENCYCLOPEDIA OF INDUSTRIAL CHEMISTRY THE MERCK INDEX, THIRTEENTH EDITION THE VAPOUR PRESSURE OF PURE SUBSTANCES, ELSEVIER, S.P.C SAFETY DATA SHEETS CIOP INORGANIC CHEMISTRY - BIELAŃSKI REGISTRY TOXIC EFFECTS OF CHEMICAL SUBSTANCES INDUSTRIAL HYGIENE AND TOXICOLOGY Page 8 from 8