SAFETY DATA SHEET Revised edition no : 0 SDS/MSDS Date : 7 / 12 / 2012

Transcription

1 Page : 1 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name Product code : D SOLUTION : 1.2. Relevant identified uses of the substance or mixture and uses advised against Use : Industrial. For professional use only Details of the supplier of the safety data sheet Company identification : 107 Wode House Road, Jehangir Villa, Colaba Mumbai INDIA 1.4. Emergency telephone number Phone nr : (9:00am - 6:00 pm) [ Office hours ] 2. Hazards identification -DSD 2.1. Classification of the substance or mixture Classification EC 67/548 or EC 1999/45 Classification : Carc. Cat. 2; R49 Muta. Cat. 2; R46 R43 R52-53 Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP) Health hazards : Carcinogenicity - Category 1A - Danger (CLP : Carc. 1A) H350 Skin sensitisation - Category 1 - Warning (CLP : Skin Sens. 1) H317 Germ cell mutagenicity - Category 1A - Danger (CLP : Muta. 1A) H340 Environmental hazards : Hazardous to the aquatic environment - Chronic hazard - Category 3 (CLP : Aquatic Chronic 3) H Label elements Labelling EC 67/548 or EC 1999/45

2 Page : 2 2. Hazards identification -DSD (continued) Symbol(s) Symbol(s) R Phrase(s) S Phrase(s) Contains êt : T : Toxic : R43 : May cause sensitization by skin contact. R46 : May cause heritable genetic damage. R49 : May cause cancer by inhalation. R52/53 : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. : S4 : Keep away from living quarters. S24 : Avoid contact with skin. S28 : After contact with skin, wash immediately with S35 : This material and its container must be disposed of in a safe way. S36/37 : Wear suitable protective clothing and gloves. S38 : In case of insufficient ventilation, wear suitable respiratory equipment. S45 : In case of accident or if you feel unwell, seek medical advice immediately ( show the label when possible). S53 : Avoid exposure - obtain special instructions before use. S59 : Refer to manufacturer/supplier for information on recovery/recycling. S61 : Avoid release to the environment. Refer to special instructions/safety data sheets. : Water - Potassium chromate Labelling Regulation EC 1272/2008 (CLP) Hazard pictograms Signal words Hazard statements Precautionary statements General Prevention Response M MÄ : Danger : H340 : May cause genetic defects. H317 : May cause an allergic skin reaction. H350i : May cause cancer by inhalation. H412 : Harmful to aquatic life with long lasting effects. : P201: Obtain special instructions before use. : P280: Wear protective gloves, protective clothing, eye protection, face protection. P261: Avoid breathing dust, fume, gas, mist, vapours, spray. P273: Avoid release to the environment. P272: Contaminated work clothing should not be allowed out of the workplace. : P302+P352: IF ON SKIN : Wash with plenty of soap and water. P308+P313: If exposed or concerned : get medical advice. P333+P313: If skin irritation or rash occurs : Get medical advice. P363: Wash contaminated clothing before reuse.

3 Page : 3 2. Hazards identification -DSD (continued) Storage Disposal considerations Special labelling Contains : P405: Store locked up. : P501: Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. : Restricted to professional users. (Substances which appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008) : Water - Potassium chromate 2.3. Other hazards Other hazards : The substance does not fulfil the criteria to be identified as PBT substance or vpvb substance according to Annex XIII of Regulation REACH. 3. Composition/information on ingredients Substance / Preparation Hazardous component(s) : Preparation. : This product is hazardous. Substance name Contents CAS No EC No Annex No REACH Ref. Classification Potassium chromate : > 0.01 < 1 % Carc. Cat. 2; R49 Muta. Cat. 2; R46 Xi; R36/37/38 R43 N; R Carc. 1B (inhal) _ H350 Muta. 1B _ H340 Eye irrit 2 _ H319 Skin Irrit. 2 _ H315 STOT SE 3 _ H335 Skin Sens. 1 _ H317 Aquatic Acute 1 _ H400 Aquatic Chronic 1 _ H410 Water : > 99 % Not classified (DSD/DPD) Not classified (GHS) 4. First aid measures 4.1. Description of first aid measures Inhalation Skin contact Eye contact Ingestion : Assure fresh air breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Get medical advice. Specific treatment (see on this label). If skin irritation or rash occurs : Wash with plenty of soap and water. Wash contaminated clothing before reuse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Obtain emergency medical attention. Do NOT induce vomiting. Rinse mouth Most important symptoms and effects, both acute and delayed

4 Page : 4 4. First aid measures (continued) Symptoms relating to use : May cause genetic defects. May cause an allergic skin reaction. May cause cancer by inhalation Indication of any immediate medical attention and special treatment needed General information : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). 5. Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Surrounding fires : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream. : Use water spray or fog for cooling exposed containers Special hazards arising from the substance or mixture Hazardous combustion products : Under fire conditions, hazardous fumes will be present Advice for fire-fighters Protection against fire Special procedures : Do not enter fire area without proper protective equipment, including respiratory protection. : Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For emergency responders For non-emergency personnel : Equip cleanup crew with proper protection. Ventilate area. : Evacuate unnecessary personnel Environmental precautions Environmental precautions : Prevent entry to sewers and public waters. Notify authorities if product enters sewers or public waters. Avoid release to the environment Methods and material for containment and cleaning up

5 Page : 5 6. Accidental release measures (continued) Clean up methods : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Store away from other materials. Collect spillage Reference to other sections See section 8. Exposure controls/personal protection 7. Handling and storage 7.1. Precautions for safe handling Handling Technical protective measures : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Avoid breathing dust, fume, gas, mist, vapours, spray. Obtain special instructions before use. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. : Provide good ventilation in process area to prevent formation of vapour Conditions for safe storage, including any incompatibilities Storage Storage - away from : Keep only in the original container in a cool, well ventilated place. Keep container closed when not in use. : Strong bases. Strong acids. Sources of ignition. Direct sunlight Specific end use(s) Specific end use(s) : None. 8. Exposure controls/personal protection 8.1. Exposure controls Personal protection Personal protection Respiratory protection Hand protection Eye protection Others =± : Avoid all unnecessary exposure. : Wear approved mask. : Wear protective gloves. : Chemical goggles or safety glasses. : When using, do not eat, drink or smoke Control parameters

6 Page : 6 8. Exposure controls/personal protection (continued) Occupational Exposure Limits 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state at 20 C : Liquid. Colour : Colorless Odour : Characteristic. Odour threshold ph value Melting point [ C] Decomposition point [ C] Critical temperature [ C] Auto-ignition temperature [ C] Flammability (solid, gas) Flash point [ C] Boiling point [ C] Initial boiling point [ C] Final boiling point [ C] Evaporation rate Vapour pressure [20 C] Vapour pressure mm/hg Vapour density Density [g/cm3] :1 Relative density, gas (air=1) Relative density, liquid (water=1) Solubility in water [% weight] Solubility in water Log Pow octanol / water at 20 C Solubility Viscosity at 40 C [mm2/s] 9.2. Other information Explosive properties Explosion limits - upper [%] Explosion limits - lower [%] Oxidising properties

7 Page : Stability and reactivity Reactivity Reactivity : Not established Chemical stability Chemical stability : Stable under recommended storage conditions Possibility of hazardous reactions Hazardous reactions : Not established Conditions to avoid Conditions to avoid : Direct sunlight. Extremely high or low temperatures Incompatible materials Materials to avoid : Strong acids. Strong bases Hazardous decomposition products Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide. 11. Toxicological information Information on toxicological effects Toxicity information Acute toxicity Inhalation Dermal Ingestion Corrosion Irritation Sensitization Mutagenicity Carcinogenicity Toxic for reproduction STOT-single exposure STOT-repeated exposure : The product has been not fully tested. The calculated risk has been done under the requirements of the EU regulations. : May cause an allergic skin reaction. : May cause genetic defects. : May cause cancer by inhalation.

8 Page : Toxicological information (continued) Aspiration hazard 12. Ecological information Toxicity Toxicity information : Harmful to aquatic life with long lasting effects Persistence - degradability Persistence - degradability : May cause long-term adverse effects in the environment Bioaccumulative potential Bioaccumulative potential : Not established Mobility in soil Mobility in soil : Not established Results of PBT and vpvb assessment Results of PBT and vpvb assessment : The substance does not fulfil the criteria to be identified as PBT substance or vpvb substance according to Annex XIII of Regulation REACH Other adverse effects Environmental precautions : Avoid release to the environment. 13. Disposal considerations Waste treatment methods General : Avoid release to the environment. Dispose in a safe manner in accordance with local/national regulations. Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. 14. Transport information Land transport (ADR-RID) Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

9 Page : Transport information (continued) UN N : 3082 H.I. nr :90 ADR - Class :9 Labelling - Transport : 9 : Miscellaneous dangerous substances and articles. à O ADR - Classification code :M6 ADR - Group : III ADR - Packing instructions : P001 R001 LP001 ADR - Limited Quantity :5 L ADR - Tunnel code : E : Passage forbidden through tunnels of category E Sea transport (IMDG) [English only]» Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. UN N : 3082 IMO-IMDG - Class or division : 9 : Miscellaneous dangerous substances and articles. IMO-IMDG - Packing group : III IMO- IMDG - Packing instructions : P001 LP01 IMO-IMDG - Limited quantities :5 L IMO-IMDG - Marine pollution : Yes EMS-Nr : F-A S-F Air transport (ICAO-IATA) [English only] Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. UN N : 3082 IATA - Class or division : 9 : Miscellaneous dangerous substances and articles. IATA - Packing group : III IATA - Passenger and Cargo Aircraft : ALLOWED - Passenger and Cargo - Packing : 964 instruction - Passenger and Cargo - Maximum : 450 L Quantity/Packing

10 Page : Transport information (continued) IATA - Cargo only : ALLOWED - Cargo only - Packing instruction : Cargo only - Maximum Quantity/ : 450 L Packing IATA - Limited Quantites : 30 kg G ERG-Nr :9L 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Safety, health and environmental : Ensure all national/local regulations are observed. regulations/legislation specific for the substance or mixture REACH Restrictions - Annex XVII : With the exception of those listed below: The components of this product are not subject to restrictions. Potassium chromate : Annex XVII REACH Authorisation - Annex XIV : The components of this product are not subject to authorization Chemical Safety Assessment Chemical Safety Assessment : It has not been carried out. 16. Other information Revision : Revision - See : * Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vpvb: very persistent and very bioaccumulative Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 List of relevant R phrases (heading 3) : R36/37/38 : Irritating to eyes, respiratory system and skin. R43 : May cause sensitization by skin contact. R46 : May cause heritable genetic damage. R49 : May cause cancer by inhalation. R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. List of full text of H-statements in :90 section 3 H315 : Causes skin irritation. H317 : May cause an allergic skin reaction. H319 : Causes serious eye irritation. H335 : May cause respiratory irritation. H340 : May cause genetic defects. H400 : Very toxic to aquatic life.

11 Page : Other information (continued) Further information H410 : Very toxic to aquatic life with long lasting effects. : None. In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation (CE) Nº 1272/2008 DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. End of document