1. Identification of the substance/mixture and of the company/undertaking

Transcription

1 Safety Data Sheet according to 1907/2006/EC, Article 31, amended by Regulation (EU) No. 453/2010 GERANIUM OIL Date: 20/06/ Identification of the substance/mixture and of the company/undertaking 1.1 Product Identifier Trade Name: Geranium Oil INCI: Pelargonium Graveolens Flower Oil Reach Registration Number: - FEMA No.: FDA No.: CoE No.: - CAS No.: EC No.: EINECS No.: Relevant identified uses of the substance or mixture and uses advised against Identified Uses: Concentrated material for manufacturing purpose only. 1.3 Details of the supplier of the safety data sheet Aromantic Ltd 17 Tytler Street Forres Moray IV36 1EL Tel: Fax: info@aromantic.co.uk 1.4 Emergency telephone number Health and Safety Executive (HSE) Chemicals Regulation Directorate 5S.1 Redgrave Court, Merton Road, Bootle, Merseyside. L20 7HS Telephone: biocidesenquiries@hse.gsi.gov.uk REACH and CLP UK CA Help Desk, Health and Safety Executive 2.3 Redgrave Court, Merton Road, L20 7HS Bootle, Merseyside 1

2 2. Hazards Identification 2.1 Classification of the substance or mixture Classification (1999/45): Xn; R65. Xi; R41, R38, R43 Classification (EC 1272/2008): Physical hazards: Not Classified. Health hazards: Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Skin Sens. 1 - H317 Asp. Tox. 1 - H304. Environmental hazards: Aquatic Chronic 3 - H Label elements Label Elements in accordance with (EC) No 1272/2008: 2.3 Other hazards Signal Word: Danger. Contains: CITRONELLOL, GERANIOL, GERANYL ACETATE, MENTHONE, CITRAL, PIN-2(3)-ENE (ALPHA-PINENES), PIN-2(10)-ENE (BETA-PINENES), LIMONENE. Hazard Statements: H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H412 Harmful to aquatic life with long lasting effects. Precautionary Statements: P261 Avoid breathing vapour/spray. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Supplementary Precautionary Statements: P264 Wash contaminated skin thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P321 Specific treatment (see medical advice on this label). P331 Do NOT induce vomiting. P332+P313 If skin irritation occurs: Get medical advice/attention. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage. P405 Store locked up. P501 Dispose of contents/container in accordance with national regulations. PBT or vpvb according to Annex XIII: No additional data available. Adverse physio chemical properties: No additional data available. Adverse effects on human health: No additional data available. 2

3 3. Composition/Information on ingredients 3.1 Substances Substances: No additional data available. 3.2 Mixtures % Citronellol Xi; R36/38. N; R51/53. R43 EC % Citronellol Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1B - H317 Aquatic Chronic 2 - H % Geraniol Xi; R41, R38. R43 EC % Geraniol Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Skin Sens. 1 - H % Linalool Xi; R36/38 EC % Linalool Skin Irrit. 2 - H315 Eye Irrit. 2 - H % Geranyl Acetate Xi; R38. N; R51/53. R43 EC % Geranyl Acetate Skin Irrit. 2 - H315 Skin Sens. 1 - H317 Aquatic Chronic 2 -H % Mentone Xn; R22. Xi; R38. R43, R52/53 EC % Mentone Acute Tox. 4 - H302 Skin Irrit. 2 - H315 Skin Sens. 1B - H317 Aquatic Chronic 3 - H % Citral Xi; R36/38. R43 EC 3

4 % Citral Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H Range Name Classification according to 1-5% PIN-2(3)-ENE (ALPHAPINENES) Xn; R65. Xi; R38. N; R50/53. R43, R10 Range Name Classification according to EC 1-5% PIN-2(3)-ENE (ALPHAPINENES) Flam. Liq. 3 - H226 Skin Irrit. 2 - H315 Skin Sens. 1B - H317 Asp. Tox. 1 - H304 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Range Name Classification according to 1-5% PIN-2(10)- ENE (BETAPINENES) Xn; R65. Xi; R38. N; R50/53. R43, R10 Range Name Classification according to EC 1-5% PIN-2(10)- ENE (BETAPINENES) Flam. Liq. 3 - H226 Skin Irrit. 2 - H315 Skin Sens. 1B - H317 Asp. Tox. 1 - H304 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Range Name Classification according to <1% Limonene Xn; R65. Xi; R38. N; R50/53. R10, R43 Range Name Classification according to EC <1% Limonene Flam. Liq. 3 - H226 Skin Irrit. 2 - H315 Skin Sens. 1 - H317 Asp. Tox. 1 - H304 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H First Aid Measures 4.1 Description of first aid measures 4

5 Inhalation: Move affected person to fresh air at once. Get medical attention if any discomfort continues. Ingestion: Rinse mouth out thoroughly with water. Give plenty of water to drink. Get medical attention immediately. Skin Contact: Remove contaminated clothes immediately and wash skin with soap & water. Get medical attention if symptoms are servere or persist after washing. Eye Contact: Rinse immediately with plenty of water. Remove any contact lenses and open eyelids, continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues 4.2 Most important symptoms and effects, both acute and delayed Symptoms and effects: Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. See Section 11 for additional information on health hazards. 4.3 Indication of any immediate medical attention and special treatment needed Special requirements: No specific recommendations. 5. Fire Fighting Measures 5.1 Extinguishing media Suitable extinguishing Media: Foam, Carbon dioxide or dry powder. Unsuitable extinguishing Media DO NOT USE: Water. 5.2 Special hazards arising from the substance or mixture Specific hazards: Toxic gases or vapours. 5.3 Advice for firefighters Special firefighting procedures/protective actions: Containers close to fire should be removed or cooled with water. Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. 6. Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions: Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots, clothing or apron, as appropriate. In case of spills, beware of slippery floors and surfaces. No smoking, sparks, flames or other sources of ignition near spillage. 6.2 Environmental precautions Environmental Precautions: Do not discharge into drains or watercourses or onto the ground. 6.3 Methods and material for containment and cleaning up Spill Clean Up Methods: 5

6 Keep combustible materials away from spillage. Eliminate all sources of ignition. Provide adequate ventilation. Contain and absorb spillage with sand, earth or other non-combustible material. The contaminated absorbent may pose the same hazard as the spilled material. Collect and place in suitable waste disposal containers and seal securely. Label the containers containing waste and contaminated materials and remove from the area as soon as possible. Wash thoroughly after dealing with a spillage. 6.4 Reference to other sections Reference to other sections: Section 8 Exposure controls/ personal protection for further information on personal precautions, Section 13 Disposal considerations for further information on waste treatment. 7. Handling and Storage 7.1 Precautions for safe handling Usage precautions: Wear protective clothing as described in Section 8 of this safety data sheet. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Wash at the end of each work shift and before eating, smoking and using the toilet. Handle all packages and containers carefully to minimise spills. 7.2 Conditions for safe storage, including any incompatibilities Storage Precautions: It is recommended to keep the product in a water tight and air tight container, in a dry, cool ( 15 C) and aired area. Keep away from heat, sparks and open flame. Protect from freezing and direct sunlight. Suitable Packaging: No additional data available. 7.3 Specific end use(s) End Uses: No additional data available. 8. Exposure Controls/Personal Protection 8.1 Control parameters Components with workplace control parameters: No exposure limits known for ingredients. 8.2 Exposure controls Protective Equipment: Process conditions: No additional data available. Engineering Measures: Provide adequate ventilation. Respiratory Equipment: 6

7 No specific recommendations. Respiratory protection may be required if excessive airborne contamination occurs. Hand Protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk assessment indicates skin contact is possible. Eye Protection: Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. The following protection should be worn: Chemical splash goggles or face shield. Other Protection: No special measures required. Hygiene Measures: No specific hygiene procedures recommended but good personal hygiene practices should always be observed when working with chemical products. Personal protection: No special measures required. Skin protection: Wear appropriate clothing to prevent any possibility of skin contact. Wear apron or protective clothing in case of contact. Environmental exposure controls: Residues and empty containers should be taken care of as hazardous waste according to local and national provisions. 9. Physical and Chemical Properties 9.1 Information on basic physical and chemical properties Appearance: Liquid. Colour: Yellow. Odour: Characteristic. Relative Density: C Flash Point ( C): >80 C Refractive Index: C Melting Point ( C): No additional data available. Boiling Point ( C): No additional data available. Vapour Pressure: No additional data available. Solubility in C: No additional data available. Auto ignition temperature ( C): No additional data available. 9.2 Other information Other Information: No additional data available. 10. Stability and Reactivity 10.1 Reactivity Reactivity: No additional data available Chemical stability Stability: Stable at normal ambient conditions Possibility of hazardous reactions Possible hazardous reactions: Will not polymerise Conditions to avoid Conditions to Avoid: Avoid heat, flames and other sources of ignition Incompatible materials Incompatible materials: Strong oxidising agents, strong acids, strong alkalis. 7

8 10.6 Hazardous decomposition products Hazardous Decomposition Products: Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. 11. Toxicological Information 11.1 Information on toxicological effects Acute Toxicity: Acute toxicity - oral ATE oral (mg/kg) 76, Skin corrosion / irritation: Irritating to skin. May cause an allergic skin reaction. Serious eye damage / irritation: Causes serious eye damage. Respiratory or skin sensitisation: No additional data available. Ingestion: May be fatal if swallowed and enters airways. Germ Cell Mutagenicity: No additional data available. Carcinogenicity: No additional data available. Reproductive toxicity: No additional data available. STOT single exposure No additional data available. STOT repeated exposure: No additional data available. Aspiration hazard: No additional data available. Photo toxicity: No additional data available. Other Information: Toxicological information on ingredients. MENTHONE Acute toxicity - oral Acute toxicity oral (LD₅₀ mg/kg): 1,600.0 Species: Rat ATE oral (mg/kg) 1, Ecological Information 12.1 Toxicity Ecotoxicity: Toxic to aquatic life with long lasting effects. Ecological information on ingredients. PIN-2(10)-ENE (BETA-PINENES) Acute aquatic toxicity LE(C)₅₀ 0.1 < L(E)C50 1 M factor (Acute) 1 Chronic aquatic toxicity M factor (Chronic) Persistence and degradability Persistence & degradability: The product is expected to be biodegradable Bioaccumulative potential Bioaccumulative Potential: The product does not contain any substances expecting to be bioaccumulating Mobility in soil 8

9 Mobility: The product is insoluble in water Results of PBT and vpvb assessment PBT Assessment Results: This product does not contain any substances classified as PBT or vpvb Other adverse effects Precautions: No additional data available. 13. Disposal Considerations 13.1 Waste treatment methods Disposal Methods: Dispose of waste product or used containers in accordance with local regulations. 14. Transport Information Warning Icon: The product is not covered by international regulations on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN number UN No Road ADR/RID: Not applicable. UN No Sea IMDG: Not applicable. UN No Air IATA: Not applicable. UN No Inland waterway ADN: Not applicable UN proper shipping name Road ADR/RID: Not applicable. Sea IMDG: Not applicable. Air IATA: Not applicable. Inland Waterway ADN: Not applicable Transport hazard class(es) Road ADR/RID: No transport hazard warning sign required. Sea IMDG: No transport hazard warning sign required. Air IATA: No transport hazard warning sign required. Inland waterway ADN: No transport hazard warning sign required Packing group Road ADR/RID: Not applicable. Sea IMDG: Not applicable. Air IATA: Not applicable. Inland waterway ADN: Not applicable Environmental hazards Environmentally hazardous substance/ marine pollutant: No Special precautions for user Precautions: Not applicable Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. 9

10 15. Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Directives: Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18th Dec 2006 Concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 199/45/EC and repealing Council Regulation Council Regulation (EEC) No793/93 and Commission Regulation (EC) No1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, and 93/105/EEC and 2000/21/EC including amendments. Statutory Instruments: The Chemicals (Hazard Information and Packaging for Supply Regulations 2009 (S.I No 716). Approved Code of Practice: Classification and Labelling of Substances and Preparations Dangerous forsupply. Safety Data Sheets for Substances and Preparations Guidance Notes: Workplace Exposure Limits EH40. CHIP for everyone HSG Chemical safety assessment Assessment information:a chemical assessment for this product has not been carried out. 16. Other Information Risk Phrases in Full: R10 Flammable. R22 Harmful if swallowed. R36/38 Irritating to eyes and skin. R38 Irritating to skin. R41 Risk of serious damage to eyes. R43 May cause sensitisation by skin contact. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. Hazard Statements in Full: H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. Other Information: None. This information is based on our present knowledge. However, this shall not constitute a guarantee 10

11 for any specific product features and shall not establish a legally valid contractual relationship. The information contained in this SDS is accurate to the best of our knowledge and has been obtained from a variety of sources. No liability can be accepted arising out of the use, application or processing of this product. It is the users responsibility to determine the safe conditions for the use of this product. Revision Date: Version:3 11