Safety Data Sheet acc. to OSHA HCS

Transcription

1 Page 1/9 1 Identification Part number: Application of the substance / the mixture Abrasive blade Details of the supplier of the safety data sheet Manufacturer/Supplier: Allied High Tech Products Inc East Pacifica Place A-RANCHO DOMINGUEZ, CA A info@alliedhightech.com Information department: Product safety department Emergency telephone number: During normal opening times: +1 (310) Chemtrec: +1 (202) Hazard(s) identification Classification of the substance or mixture GHS08 Health hazard Carc. 2 STOT RE 1 H351 Suspected of causing cancer. H372 Causes damage to organs through prolonged or repeated exposure. GHS07 Acute Tox. 4 H332 Harmful if inhaled. Skin Sens. 1 H317 May cause an allergic skin reaction. Additional information: Based on health effects for dust Label elements GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). (Contd. on page 2)

2 Page 2/9 Hazard pictograms (Contd. of page 1) GHS07 GHS08 Signal word Danger Hazard-determining components of labeling: nickel Hazard statements Harmful if inhaled. May cause an allergic skin reaction. Suspected of causing cancer. Causes damage to organs through prolonged or repeated exposure. Precautionary statements Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Specific treatment (see on this label). IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/attention. Get medical advice/attention if you feel unwell. IF ON SKIN: Wash with plenty of water. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. Classification system: NFPA ratings (scale 0-4) Health = 2 Fire = 0 Reactivity = 1 HMIS-ratings (scale 0-4) HEALTH *1 FIRE 0 REACTIVITY 1 Health = *1 Fire = 0 Reactivity = 1 Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. (Contd. on page 3)

3 Page 3/9 (Contd. of page 2) 3 Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Hazardous Components: Carc. 2, H351; STOT RE 1, H372; Skin Sens. 1, H % Non-hazardous Components: Diamond 2.5-<10% Additional information: The exact percentage or composition of the above ingredients is proprietary. 4 First-aid measures Description of first aid measures General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced. Advice for firefighters Protective equipment: Mouth respiratory protective device. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Mount respiratory protective device. Environmental precautions: Do not allow product to reach sewage system or any water course. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. (Contd. on page 4)

4 Page 4/9 See Section 13 for disposal information. (Contd. of page 3) 7 Handling and storage Handling: Precautions for safe handling Thorough dedusting. Open and handle receptacle with care. Information about protection against explosions and fires: Keep respiratory protective device available. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep receptacle tightly sealed. Store receptacle in a well ventilated area. Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: PEL Long-term value: 1 mg/m³ REL Long-term value: mg/m³ TLV Long-term value: 1.5* mg/m³ elemental, *inhalable fraction Additional information: The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Breathing equipment: Use suitable respiratory protective device when high concentrations are present. Protection of hands: Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation (Contd. on page 5)

5 Page 5/9 (Contd. of page 4) Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Solid Color: Silver-colored Odor: Odorless Odor threshold: Not determined. ph-value: Not applicable. Change in condition Melting point/melting range: Boiling point/boiling range: 1453 C (2647 F) >999 C (>1830 F) Flash point: Not applicable. Flammability (solid, gaseous): Not determined. Ignition temperature: Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Upper: Not determined. Not determined. Vapor pressure: Not applicable. Density at 20 C (68 F): 8.91 g/cm³ ( lbs/gal) Relative density Not determined. Vapor density Not applicable. Specific gravity: 8.9 Evaporation rate Not applicable. Solubility in / Miscibility with Water: Insoluble. Partition coefficient (n-octanol/water): Not determined. (Contd. on page 6)

6 Page 6/9 Viscosity: Dynamic: Kinematic: Not applicable. Not applicable. Solvent content: Organic solvents: 0.0 % VOC content: 0.0 g/l / 0.00 lb/gl Solids content: % Other information No further relevant information available. (Contd. of page 5) 10 Stability and reactivity Reactivity No further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid Keep away from acids, reducing agents and flammable materials. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: ATE (Acute Toxicity Estimates) Inhalative LC50/4 h 2.68 mg/l (rat) Dermal LD mg/kg (rat) Inhalative LC50/4 h 2.55 mg/l (rat) Primary chemical irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitization: Sensitization possible through skin contact. Additional toxicological information: Abrasive eye irritant Abrasive skin irritant Carcinogenic categories IARC (International Agency for Research on Cancer) 1 NTP (National Toxicology Program) R OSHA-Ca (Occupational Safety & Health Administration) (Contd. on page 7)

7 Page 7/9 (Contd. of page 6) 12 Ecological information Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Behavior in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Water hazard class 2 (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation: Contact waste processors for recycling information. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. 14 Transport information UN-Number DOT, ADN, IMDG, IATA not regulated UN proper shipping name DOT, ADN, IMDG, IATA not regulated Transport hazard class(es) DOT, ADN, IMDG, IATA Class not regulated Packing group DOT, IMDG, IATA not regulated Environmental hazards: Marine pollutant: No Special precautions for user Not applicable. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. UN "Model Regulation": not regulated (Contd. on page 8)

8 Page 8/9 (Contd. of page 7) 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): Section 313 (Specific toxic chemical listings): TSCA (Toxic Substances Control Act): All ingredients are listed. Proposition 65 Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity for females: Chemicals known to cause reproductive toxicity for males: Chemicals known to cause developmental toxicity: Carcinogenic categories EPA (Environmental Protection Agency) TLV (Threshold Limit Value established by ACGIH) A5 NIOSH-Ca (National Institute for Occupational Safety and Health) Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Department issuing SDS: Environment protection department. Contact: Kim Dermit Date of preparation / last revision 04/04/2016 / - Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (A) HMIS: Hazardous Materials Identification System (A) VOC: Volatile Organic Compounds (A, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent (Contd. on page 9)

9 Page 9/9 PBT: Persistent, Bioaccumulative and Toxic vpvb: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit BEI: Biological Exposure Limit Acute Tox. 4: Acute toxicity Category 4 Skin Sens. 1: Skin sensitisation Category 1 Carc. 2: Carcinogenicity Category 2 STOT RE 1: Specific target organ toxicity (repeated exposure) Category 1 (Contd. of page 8)