Safety Data Sheet Page 1 of 7 Spectracide Triazicide Insect Killer for Landscapes & Gardens Outdoor Fogger Revision date: 03/15/2017

Transcription

1 Safety Data Sheet Page 1 of 7 Section 1 - Product and Company Identification Product Identifiers: Product name: Spectracide Triazicide Insect Killer for Landscapes & Gardens Outdoor Fogger EPA reg. number: Recommended product use: Insecticide - Crawling Bug, Aerosol Details of the Supplier of the Safety Data Sheet: Manufacturer/Supplier: Chemsico Div. of United Industries Corp. P.O. Box St. Louis, MO For product information: For medical emergencies: Section 2 - Hazards Identification Conforms to Hazard Communication Standard 29 CFR GHS Classification of Substance or Mixture: Physical Hazards GHS Classification Flammable aerosol - Category 2 Contents under pressure Compressed Gasses Health Hazards GHS Classification Acute inhalation toxicity Category 4 Primary eye irritant Category 2B Primary dermal irritant Category 3 GHS Label Elements: Hazard pictogram(s): Signal word: Hazard statements: Precautionary Statements: WARNING Flammable aerosol Compressed gas contents under pressure; may burst if heated. Harmful if inhaled. Causes mild skin irritation. Causes eye irritation. Contents under pressure. Do not use or store near heat or open flame. Do not puncture or incinerate container. Exposure to temperatures above 130 F may cause bursting. Avoid breathing vapors. Use only outdoors or in a wellventilated area. If in haled: Remove person to fresh air and keep comfortable for breathing. Call a poison control center or doctor if you feel unwell. Wash thoroughly with soap and water after handling. Wear protective gloves. If on skin: Wash with plenty of

2 Safety Data Sheet Page 2 of 7 Section 3 - Composition / Information on Ingredients water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Wash hands thoroughly with soap and water after handling. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Chemical Name CAS# Weight Percent Isobutane % Petroleum distillates, hydrotreated light % Propane % Piperonyl butoxide % Pyrethrins % te: Ingredients not identified are proprietary or non-hazardous. Values are not product specification(s). reportable quantities of hazardous ingredients are present per OSHA 29 CFR toxic chemical(s) subject to reporting requirements of Section 313 of Title III and 40 CFR 372 are present. Section 4 - First Aid Measures Eye contact: Skin contact: Inhalation: Ingestion: te to Physician: General advice: Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Call a poison control center or doctor for treatment advice. Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. Call a poison control center or doctor for treatment advice. Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. special requirements ne If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Keep out of reach of children. Section 5 - Fire Fighting Measures Flammable properties: NFPA classification: Suitable extinguishing media: Unsuitable extinguishing media: Specific hazards arising from the chemical: Pressurized aerosol container NFPA level 1 aerosol Water fog, foam, CO 2, dry chemical Contents under pressure container may burst in heat of fire.

3 Safety Data Sheet Page 3 of 7 Protective equipment for firefighters: Firefighters should wear full protective clothing including self-contained breathing apparatus. Hazardous combustion products: Explosion data: Sensitivity to static discharge: Personal precautions: Section 6 - Accidental Release Measures ne known Keep unnecessary personnel away. Do not touch or walk through spilled material. Personnel precautions: For emergency responders: Environmental precautions: Methods for containment and cleaning up: Remove all sources of ignition. Wear personnel protective equipment as recommended in Section 8. Wash thoroughly after handling. If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Stop leak if without risk. Move containers from spill area. Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with earth, sand or absorbent material swept up and placed in suitable, covered, and labeled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re-use. Section 7 - Handling and Storage Precautions for safe handling: Storage: Put on appropriate personal protective equipment as recommended in Section 8. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C (122 F). Do not pierce or burn, even after use. Do not ingest. Avoid contact with skin, eyes and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical equipment. Use only nonsparking tools. Empty containers retain product residue and can be hazardous. Store in a cool, dry area away from open flame. Do not store above 50 C (122 F). Section 8 - Exposure Controls / Personal Protection Exposure guidelines: Exposure Limits OSHA PEL ACGIH TLV SupplierOEL Chemical name ppm mg/m 3 ppm mg/m 3 ppm mg/m 3

4 Safety Data Sheet Page 4 of 7 Isobutane TWA t established t established Petroleum distillates, hydrotreated light TWA t listed t listed Propane TWA t established Piperonyl butoxide TWA ne ne ne Pyrethrins TWA t listed Engineering controls: Personal protective equipment: Eye/Face protection: Skin protection: Respiratory protection: General hygiene considerations: General ventilation normally adequate. ne required. Wear protective gloves. Wash thoroughly after handling. Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Do not use product indoors. Handle in accordance with good industrial hygiene and safety practices. When using, do not eat or drink. Wash hands before breaks and immediately after handling the product. Section 9 - Physical & Chemical Properties Appearance: Color: Physical state: Odor: Odor threshold: ph: Melting point: Freezing point: Boiling point: Flash point: Flame Extension Flammability limits in air, lower, % by volume: Flammability limits in air, upper, % by volume: Vapor pressure: Vapor density: Relative 20 C: Octanol/water coefficient: Auto-ignition temperature: Decomposition temperature: Solubility: Evaporation rate: Translucent Pale yellow Pressurized liquid Mild pyrethroid 7.3 (liquid portion) >200 F (liquid portion) 0 (level 1 aerosol) (liquid portion) Miscible in water % Volatile organic compounds:

5 Safety Data Sheet Page 5 of 7 Section 10 - Chemical Stability & Reactivity Information Reactivity Conditions to avoid: Incompatible materials: Chemical stability Product stability: Do not mix with other chemicals. Avoid strong oxidizers. Stable under recommended storage conditions. Other Hazardous decomposition products: Possibility of hazardous reactions: ne known Hazardous polymerization does not occur. Section 11 - Toxicological Information Primary eye irritation: Primary skin irritation: Acute dermal: Acute inhalation: Acute oral: Sensitization: Chronic effects/ Carcinogenicity: Mutagenicity: Reproductive effects: Teratogenicity: Ecotoxicity: Causes moderate eye irritation (EPA tox. category III) Causes moderate irritation. (EPA tox. category III) LD 50 > 5000 mg/kg (EPA tox. category IV) LC mg/L (EPA tox. cateogry IV) LD 50 > 5000 mg/kg (EPA tox. category IV) t a skin sensitizer. Section 12 - Ecological Information Environmental effects: Aquatic toxicity: Persistence / degradability: Bioaccumulation / accumulation: Partition coefficient: Mobility in environmental media: Chemical fate information: ne Section 13 - Disposal Considerations Waste codes: Disposal instructions: Waste from residues / unused products: Contaminated packaging: Dispose in accordance with all applicable regulations.

6 Safety Data Sheet Page 6 of 7 Section 14 - Transportation Information U.S. Department of Transportation (DOT): UN-1950, Aerosols, Flammable, 2.1, Limited Quantity IATA: UN-1950, Aerosols, 2.1 IMDG: Section 15 - Regulatory Information 29 CFR hazardous chemical Occupational Safety and Health Administration (OSHA): CERCLA (Superfund) reportable quantity: Hazard categories UN-1950, Aerosols, Flammable, 2, Limited Quantity Superfund Amendments and Reauthorization Act of 1986 (SARA): Immediate Hazard Delayed Hazard Fire Hazard Pressure Hazard Reactivity Hazard Section 302 extremely hazardous Substance: Section 311 hazardous chemical: Clean Air Act (CAA): Clean Water Act (CWA): State regulations: FIFRA labeling: Signal word: Precautionary statements: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION Avoid contact with skin or clothing. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet. Wear long-sleeved shirt, long pants, socks and shoes, and gloves. First aid: if on skin or clothing: take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. Call a poison control center or doctor for treatment advice. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. For additional information on this pesticide product (including health concerns, medical emergencies or pesticide concerns), you may call , 24 hours per day, seven days per week.

7 Safety Data Sheet Page 7 of 7 Environmental hazards: this product is toxic to aquatic organisms, including fish and invertebrates. Do not apply directly to or near water. Drift and runoff may be hazardous to aquatic organisms in water adjacent to treated areas. See directions for use for additional precautions and requirements. This product is highly toxic to bees exposed to direct treatment on blooming crops or weeds. Do not apply this product or allow it to drift to blooming crops or weeds while bees are actively foraging the treatment area. Physical and chemical hazards: contents under pressure. Do not use or store near heat or open flame. Do not puncture or incinerate container. Exposure to temperatures above 130 F may cause bursting. tification status: California Prop. 65: Disclaimer: All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. This product does not contain any chemicals known to the state of California to cause cancer, birth defects or any other reproductive harm. Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. Section 16 - Other Information HMIS ratings: Health Hazard 1 Fire Hazard 1 Reactivity 1 Item numbers: Formula number(s): HG-26474; HG Issue date: 03/15/2017 Prepared by: Spectrum Group Division of United Industries Corp. P.O. Box St. Louis, MO (800)