SAFETY DATA SHEET Version : 2

Transcription

1 Page : 1 / 6 SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : NEUTRAGUARD NEO 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses : Antifreeze for central heating installations and frozen water installations 1.3. Details of the supplier of the : DEHON SERVICE safety data sheet 26 Avenue du Petit Parc VINCENNES Cedex France ContactFDS@climalife.dehon.com 1.4. Emergency telephone number : EMERGENCY TELEPHONE NUMBER (24h/24) : + 33 (0) Anti-poison Center : INRS/ORFILA (France) : +33 (0) Poisons Information Centre (Hungary) : Anti-poison Centre (United Kingdom) : Anti-poison Centre (Netherlands) : Anti-poison Centre (Belgium) : Anti-poison Centre (Spain) : SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification EC 67/548 or EC 1999/ : This product is not classified as a "hazardous preparation" according to European Community 45 regulations 2.2. Label elements Labelling EC 67/548 or EC 1999/45 : None 2.3. Other hazards : None under normal conditions SECTION 3 Composition/information on ingredients 3.1./3.2. Substance / Preparation : Preparation Chemical nature : Mixture containing mainly : Propylene Glycol Substance name Contents CAS No EC No Index No Ref REACH Classification Propane-1,2-diol : > 85 % Not classified. (DSD/DPD) Not classified. (GHS)

2 Page : 2 / 6 SECTION 4 First aid measures 4.1. Description of first aid measures Inhalation Skin contact Eye contact : Not specifically applicable : Rinse with water If case of redness or irritation, call a doctor : Rinse immediately and thoroughly, pulling the eyelids well away from the eye (15 minutes minimum) If irritation persists, consult an eye specialist Ingestion : Rinse mouth out with water Never attempt to induce vomiting Seek medical attention if ill effect develops Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5 Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray Carbon dioxide (CO2) Alcohol-resistant foam Powders Unsuitable extinguishing media : Strong water jet 5.2. Special hazards arising from the : May release hazardous fumes. substance or mixture 5.3. Advice for firefighters Specific fire fighting methods : Do not attempt to fight the fire without suitable protective equipment Cool down the containers exposed to heat with a water spray Protection of fire-fighters : Complete protective clothing Self-contained breathing apparatus SECTION 6 Accidental release measures 6.1. Personal precautions, protective : Keep away from ignition sources (including static discharges). equipment and emergency procedures Avoid contact with skin and eyes Do not breathe vapours 6.2. Environmental precautions : Prevent the product from entering drains 6.3. Methods and material for containment and cleaning up - Neutralization : Absorb spillage with: - inert material (sand, earth) - Disposal : Dispose of contaminated materials in accordance with current regulations 6.4. Reference to other sections : For further information refer to section 8 "Exposure controls/personal protection"

3 Page : 3 / 6 SECTION 7 Handling and storage 7.1. Precautions for safe handling Precautions : Handle in well ventilated areas Keep away from sources of ignition - No smoking. May form an explosive mixture in the presence of air Avoid any direct contact with the product Industrial hygiene : Always wash hands after handling the product Do not drink, eat or smoke in the workplace 7.2. Conditions for safe storage, including any incompatibilities Technical measures : The floor of the depot should be impermeable and designed to form a tight basin Storage conditions - Recommended : Store : - in an airtight and suitably labelled container. - in a cool, well-ventilated area - protected from humidity - away from direct sunlight - at temperature not exceeding 40 C Incompatible products : Strong oxidizing agents Packaging materials - Recommended : Stainless steel Aluminium. - Not suitable : Zinc Specific end use(s) : No data SECTION 8 Exposure controls/personal protection 8.1. Control parameters Engineering measures : Ensure good ventilation of the work station Occupational Exposure Limits : Propane-1,2-diol : United Kingdom : WEL - TWA (8h; mg/m³) : 474 Propane-1,2-diol : United Kingdom : WEL - TWA (8h; ppm) : Exposure controls Personal protection : - Respiratory protection : If the ventilation is suitable, it is not essential to wear respiratory equipment - Hand protection : Nitrile-rubber protective gloves - Eye protection : Safety goggles SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties 9.1.a. Appearance Physical state Colour 9.1.b. Odour 9.1.c. Odour threshold 9.1.d. ph 9.1.e. Melting point / Freezing point : Liquid : Red : None : (Aqueous solution - 33 g/100ml) : -60 C

4 Page : 4 / 6 SECTION 9 Physical and chemical properties (continued) 9.1.f. Initial boiling point - boiling : 139 C range 9.1.g. Flash point : > 100 C (Closed cup) 9.1.h. Evaporation rate 9.1.i. Flammability : Difficult to ignite 9.1.j. Explosion limits (lower - upper) Explosion limits - lower : 2.4 % (volume) Explosion limits - upper : 17.4 % (volume) 9.1.k. Vapour pressure 9.1.l. Vapour density 9.1.m. Density : g/cm³ at 20 C 9.1.n. Solubility -in water : Complete 9.1.o. Partition coefficient : n-octanol / : ( Propylene Glycol ) water 9.1.p. Auto-ignition temperature 9.1.q. Thermal decomposition 9.1.r. Viscosity 9.1.s. Explosive Properties : Not explosive material according to EC criteria 9.1.t. Oxidising properties : Non oxidizing material according to EC criteria 9.2. Other information SECTION 10 Stability and reactivity Reactivity Chemical stability : Stable at ambient temperature and under normal conditions of use Possibility of hazardous : No dangerous reactions known under normal conditions of use reactions Conditions to avoid : Avoid : > +40 C Moisture Incompatible materials : - strong oxidizing agents - zinc Hazardous decomposition : Incomplete combustion releases dangerous carbon monoxide, carbon dioxide and other toxic products : gases SECTION 11 Toxicological information Information on toxicological effects Acute toxicity On ingredients Propane-1,2-diol : Rabbit dermal, LD50 [mg/kg] : : Rat oral LD50 [mg/kg] : Irritation : Not irritating to rabbits on cutaneous application Not irritating to rabbits on ocular application

5 Page : 5 / 6 SECTION 11 Toxicological information (continued) Corrosivity Sensitisation Repeated dose toxicity Carcinogenicity Mutagenicity Toxicity for reproduction : No sensitizing reaction was observed for guinea pigs. SECTION 12 Ecological information Toxicity Effects on the aquatic environment On ingredients Propane-1,2-diol : 48 Hour - EC50 - Daphnia magna [mg/l] : 1000 : 72 Hour - EC50 - Algae (Selenastrum capricornutum) [mg/l] : 1000 : 96 Hours - LC50 - Fish (Pimephales Promelas) [mg/l] : Persistence and degradability : Readily biodegradable Bioaccumulative potential : Not potentially bioaccumulable Mobility in soil Results of PBT and vpvb assessment Other adverse effects Effect on sewage treatment plant : Does not affect the functioning of waste-water treatment plants SECTION 13 Disposal considerations Waste treatment methods WASTE FROM PRODUCT : Destruction/Disposal CONTAMINATED PACKAGING : Destruction/Disposal NOTE : Dispose of in accordance with relevant local regulations : Destroy at an authorised site : The user's attention is drawn to the possible existence of specific european, national or local regulations regarding disposal SECTION 14 Transport information RID/ADR/IMDG/IATA NOTE : Not regulated : The above regulatory prescriptions are those valid on the date of publication of this sheet However, given the possible evolution of transport regulations for hazardous materials, in case the present sheet is dating back to more than 12 months ago, it would be advisable to check their validity with your commercial agency

6 Page : 6 / 6 SECTION 15 Regulatory information Safety, health and environmental : Ensure all national/local regulations are observed. regulations/legislation specific for the substance or mixture France : Professional diseases(table(s) nr 84) : applicable Germany : : Water hazard class : 1 (specific classification) NOTE : : The regulatory information given in this part only indicate the principal regulations specifically applicable to the product described in the Safety Data Sheet. The cited basic Community texts are being updated and transcribed in national law. Refer to all applicable national, international and local regulations or provisions. The user's attention is drawn to the possible existence of additional provisions which complete these regulations Chemical safety assessment SECTION 16 Other information Further information : Product for professional use only For more information regarding the use of this product, please refer to our technical information or contact the sales department in your region This safety data sheet has been written in conformity with the regulation (UE) 453/2010. * Update : All chapters have been modified since the previous version This sheet complements the technical sheets but does not replace them. The information given is based on our knowledge of the product, at the time of publication. It is given in good faith. Besides, the attention of the user is drawn to the possible risks incurred by using the product for any other use than that for which it was intended. In no way does this exempt the user from knowing and applying all the regulations controlling his activity. He alone will take on the responsibility for taking the precautions involved by the use of the product. The aim of all the mandatory regulations mentionned is just to help the user to fulfil his obligations regarding the use of hazardous products. This information must not be considered exhaustive. It does not exempt the user from ensuring that other obligations than those mentioned could apply, related to the storage and use of the product, this being his sole responsibility. End of document