MATERIAL SAFETY DATA SHEET

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1 MSDS for 3-Aminopyridine Page 1 of 5 MATERIAL SAFETY DATA SHEET 1. CHEMICAL PRODUCT & MANUFACTURER S DETAILS PRODUCT NAME : 3-Aminopyridine MANUFACTURER FACTORY & REGISTERED OFFICE: Bhartiagram, Gajraula District: Jyotiba Phuley Nagar Uttar Pradesh , India PHONE NO: upto 60 Contact Department-Safety: Extension 298 FAX NO : EMERGENCY PHONE: HEAD OFFICE: Plot 1-A, Sector 16-A, Institutional Area, Noida, Uttar Pradesh India. PHONE NO: Contact department: EHS FAX NO : support@jubl.com 2. CHEMICAL IDENTIFICATION CHEMICAL NAME : 3-Aminopyriine SYNONYMS : 3-Pyridinamine,beta-Aminopyridine CHEMICAL CLASSIFICATION : Aromatic Hetrocyclic Compound CHEMICAL FORMULA : (C 5 H 4 N)NH 2 C.A.S. NO. : HAZARD IDENTIFICATION & HEALTH HAZARD Fatal if swallowed May be fatal in contact with skin May be fatal if inhaled Combustible Route of entry: inhalation, skin, ingestion Irritating to eyes and respiratory system 4. FIRST AID MEASURES Eye: Immediately flush eyes with plenty of water for at least 15 minutes by separating eyelids with fingers. Get medical help. Skin: Immediately remove contaminated clothings and shoes. Flush skin with copious amount of water for atleast fifteen minutes. Wash contaminated clothing before reuse.

2 MSDS for 3-Aminopyridine Page 2 of 5 Inhalation: Remove the affected person (s) to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Ingestion: If swallowed, wash mouth with water if conscious. Make victim drink plenty of water and induce vomiting. Call a physician 5. FIRE FIGHTING MEASURES Extinguishing media: Water spray, dry chemical powder, carbon dioxide, and chemical foam. Special fire fighting procedure: Wear protective clothing, wear self contained breathing apparatus. Unusual fire and explosion hazard: Emits toxic fumes under fire conditions. 6. ACCIDENTAL RELEASE MEASURES Evacuate the area Wear self-contained breathing apparatus, protective clothing (single piece suit) rubber boots and heavy rubber gloves Sweep up, place in a bag and hold for disposal. Ventilate area (if incident has occurred in-door) and wash spill site after material pick up is complete. Avoid raising dust 7. HANDLING AND STORAGE Keep containers tightly closed Wear suitable protective clothing, breathing apparatus, gloves and eye/face protection Use only in a chemical fume hood Do not breathe dust, vapour, mist or gas 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Avoid inhalation of Dust Avoid contact with eyes, skin and clothing Avoid prolonged/repeated exposure Wash thoroughly after handling Use only in a chemical fume hood Wear appropriate NIOSH/MSHA approved respirator, chemical resistant gloves/safety goggles and protective clothing (single piece suit) In case of contact use safety showers and eye bath for washing

3 MSDS for 3-Aminopyridine Page 3 of 5 9. PHYSICOCHEMICAL PROPERTIES & FIRE/ EXPLOSION HAZARD DATA PHYSICAL STATE : Solid APPEARANCE : Yellow to brown ODOUR : Characteristic BOILING POINT : 248 C MELTING POINT : C FLASH POINT : 124 C VAPOUR PRESSURE : Data not relevant BULK DENSITY : 0.75 g/cm 3 VAPOR DENSITY (AIR=1) : Data not relevant SOLUBILITY IN WATER : Soluble ph : 8.5 (10% solution in water) LEL : Data not applicable UEL : Data not applicable AUTO IGNITION TEMPERATURE : 628 C EXPLOSIVE SENSITIVITY TO IMPACTS : Data not available EXPLOSIVE SENSITIVITY TO STATIC ELECTRICITY : Data not available COMBUSTIBLE LIQUID FLAMMABLE MATERIAL PYROPHORIC MATERIAL EXPLOSIVE MATERIAL OXIDISER ORGANIC PEROXIDE CORROSIVE MATERIAL MOLECULAR WEIGHT : STABILITY AND REACTIVITY Stable under normal temperature & pressures Incompatible with oxidising agents, strong acids, acid chlorides, acid anhydrides Conditions to avoid - incompatible materials, dust generation Hazardous combustion or decomposition products: thermal decomposition may produce carbon monoxide and oxides of nitrogen 11. TOXICOLOGICAL INFORMATION Acute effects: May be fatal if swallowed, inhaled or absorbed through skin. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract, eyes and skin. May cause convulsions Target organs: Damage to the Nervous system

4 MSDS for 3-Aminopyridine Page 4 of TOXICOLOGICAL INFORMATION Toxicity: ORAL RAT LD50 : 21 mg/kg Carcinogenicity: Not list by ACGIH, IARC, NIOSH, NTP or OSHA RTECS # : US ECOLOGICAL INFORMATION Ecotoxicity: Bioaccumulation none or low Environmentalt readily biodegradable. 13. DISPOSAL CONSIDERATION Dissolve in a combustible liquid and burn in a chemical incinerator equipped with an afterburner and scrubber. Observe all federal, state and local environmental regulations 14. TRANSPORT INFORMATION PROPER SHIPPING NAME : Aminopyridine UN/ID NUMBER : 2671 UN HAZARD CLASS : 6.1 UN PACKING GROUP : II 15. REGULATORY INFORMATION European information EC NO. : R-23/24/25 (Toxic by inhalation/ contact with skin/ swallowed) S-36/37/39 (wear suitable protective clothing/gloves and eye/face protection) S-45 (in case of accident, if you feel unwell, seek medical advice immediately) US information Is listed in EPA TSCA chemical inventory. None of the chemicals in this product are listed under TSCA section 12b None of the chemicals in this product have an RQ under SARA Section 302 RQ None of the chemicals in this product have an TPQ under SARA Section 302 TPQ None of the chemicals in this product are reported under SARA Section 313 None of the chemicals in this product contain any class1 & class2 ozone depletors, neither contain any hazardous air pollutants under Clean Air Act None of the chemicals in this product are listed as Hazardous substances or priority pollutants or Toxic substances list under Clean Water Act

5 MSDS for 3-Aminopyridine Page 5 of OTHER INFORMATION Information contained in this MSDS is believed to be correct but no representation, guarantee or warranties of any kind are made as to its accuracy, suitability for a particular application or results to be obtained from them. This MSDS shall be used as a guide only. JUBILANT ORGANOSYS LIMITED makes no warranties expressed or implied of the adequacy of this document for any particular purpose. Document Name: 0151A02 Div 05 msds 3-Aminopyridine Date: 02-Nov-04 Revision Number: 02