Nominal Value Unit Test Method. Typical Value Unit Test Method 20 UTM nd

Size: px
Start display at page:

Download "Nominal Value Unit Test Method. Typical Value Unit Test Method 20 UTM nd"

Transcription

1 UNIPLEX 280CG UNIPLEX 280CG is a stable, clear, odorless, and non-crystalline brittle solid with a sharp softening range starting at around 93 C. It has excellent ultraviolet light stability. UNIPLEX 280CG is compatible with a broad range of resins, plasticizers and solvents. Chemical composition Sucrose Benzoate CAS Reg. No Physical form Health and safety information: Clear solid Relevant safety data and references as well as possibly necessary warning labels can be found in the safety data sheet. Specified Properties Property Hazen colour value (50% w/v in Xylene) Nominal Value Unit Test Method max UTM Turbidity min. 85 % Transmission UTM Acidity (as Benzoic acid) max. 0.3 % UTM Volatiles (o-xylene) max. 1.5 % UTM Basicity max. 1.5 meq/g UTM Additional Information Property Refractive Index n D 20 Typical Value Unit Test Method approx nd 20 UTM Specific Gravity (25 C) approx g/ml UTM_ Iodine Number max 0.01 % Softening Point approx C Ball and Ring Method These raw material properties are typical properties and, unless specifically indicated otherwise, are not to be considered as delivery specification. Technical Information , Page 1 of 6

2 Storage UNIPLEX 280CG should be kept in its tightly sealed original container in a dry place. If stored properly, the product is at least stable for one year. The product has the tendency to agglomerate. This does not affect the product quality. Soluble in all common solvents; the solubility in cold water is low. Packaging Drums Solubility General properties UNIPLEX 280 CG is a stable, clear, odourless, and non-crystalline brittle solid with a reasonably sharp softening range starting at around 93 C. It has excellent ultraviolet light stability. UNIPLEX 280CG is compatible with a broad range of resins, plasticizers, and solvents, and insoluble in water and aliphatic hydrocarbons. The UNIPLEX 280CG is specifically designed for the coating and ink industry. However, this product may also be used in numerous applications areas as indicated by the listing of compatibilities attached. In addition to usage in the formulation of clear coatings for wood, paper and metal, and in formulation of ink systems, the properties of Sucrose Benzoate indicate that it should be of interest in metallic and pigmented coatings, and heat seal coatings. UNIPLEX 280CG may be used to particular advantage in UV coating and inks. UNIPLEX 280CG improves the UV systems stability and allows easier processing. In addition, it imparts good film hardness, excellent gloss, and depth of gloss. UNIPLEX 280CG is an outstanding modifier for clear lacquers. It provides exceptional clarity with high gloss, excellent resistance to ultraviolet light, high film hardness combined with good flexibility, and excellent resistance to water and alcohol. Table 1: Viscosity Characteristics: Viscosity of Molten Sucrose Benzoate vs. Temperature Temperature Viscosity (mpas) ( C) Technical Information , Page 2 of 6

3 Table 2: Viscosity Characteristics: Solution Sucrose Benzoate in Toluene at 25 vs. Concentration Sucrose Benzoate (Weight Viscosity (mpas) %) ,000 Table 3: Solubility Acetic Acid Ethyl Acetate Acetone ETHYL CELLOSOLVE Benzene Ethylene Dichloride Benzonitrile Isophorone Butyl Acetate Methyl Benzoate BUTYL CELLOSOLVE METHYL CARBITOL CARBITOL METHYL CELLOSOLVE Carbon Tetrachloride Methyl Isobutyl Ketone Dibutyl Phthalate Methyl Ethyl Ketone Diethylene Glycol Dibenzoate Methylene Dichloride Diisobutyl Ketone Polyethylene Glycols Diethyl Ether SOLVESSO 150 Dimethyl Formamide Toluene Dioxane Tricresyl Phosphate Dipropylene Glycol Xylene (Mixed isomers) Dibenzoate Dioctyl Phthalate , Seite 3 von 6

4 Table 4: % Sucrose benzoate in resin blends RESINS 20% 50% 80% Gum Rosin N Grade C (22) CH C (37) (29) Glycerin Ester,Unmodified C CH C Glycerin Ester of Hydrogenated Rosin I I I Tall Oil Rosin SYLVAROS-90 CH I (30) CH (27) (39) Sucrose Acetate Isobutyrate C C C VINSOL Resin C C C C= Compatible I= Incompatible CH= Compatible with haze Table 5: Compatibility of sucrose benzoate in blends POLYMER 20% 50% 80% Acrylics Poly (Methyl Methacrylate) C (23) C (31) C(50) Acrylic Ester Copolymer C C C(28) (Tack) (Tack) Alkyd Resins Alkyd, Phenolic Modified C C C Amide Nylon (Alcohol Soluble) CH - - Amino Melamine-Formaldehyde C C C Urea-Formaldehyde C C C Butylated Urea-Formaldehyde C C C Butylated Benzoguanamine Formaldehyde C C C Cellulosic Ethyl Cellulose C (43) C (53) I (53) Nitrocellulose (1/2 sec. visc.) C (43) C (51) C Cellulose Acetate Butyrate C (45) C (46) C (47) Chlorinated Rubber (67% C1) C C C Congo Copal, Processed C CH CH Coumarone-Indene,Modified C C C , Seite 4 von 6

5 Table 5: Continuation POLYMER 20% 50% 80% Epoxy Ester-TEPA C C C Isobutylene I I I Polyester C C C Polyethylene I I I Styrenics Vinyl Polystyrene C (49) C C (48) PICOFLEX 100 & 105 C C C Polyvinyl Chloride 13% PVAC C (36) C (48) Polyvinyl Acetate C (35) C (47) Polyvinylidine Chloride CH CH (28) C= Compatible I= Incompatible CH= Compatible with haze C 1 (54) C (48) CH (54) A partial listing of solvents with which Sucrose Benzoate is sparingly soluble or soluble to less than 20% at 25 C is shown below. Specific solubilities are shown in some cases. Table 6: Specific solubilites Amyl Alcohol Isoamyl Alcohol APCO THINNER % at Isopropyl Alcohol 25 C Butyl Alcohol Kerosene Butyl Stearate Linseed Oil Cyclohexane Methyl Alcohol 25 C Diethylene Glycol Turpentine Ethyl Alcohol 2.3% at 25 C ULTRASENE 25 C Ethylene Glycol FREON 11 at 25 C Glycerin Heptane.less than 0.02% at 67 C , Seite 5 von 6

6 Stability 1. Ultraviolet Light Supported films of Sucrose Benzoate were prepared from toluene solution. Exposure was made using an Atlas Fade-O-Meter at approximately 60 C.Exposure time: 3000 hours. Appearance: No color change or evidence of degradation. 2. Hydrolytic Sucrose Benzoate was held in contact at 100 C with solutions shown below. Change in acidity of aqueous layer was used to determine degree of hydrolysis. Table 8: Hydrolysis Solution Hydrolyzed in 24 hours Hydrolyzed in 96 hours Water Nil Nil 5% solution HCl Nil 0.6% 5% solution Na CO % 2.3% 3. Heat Prolonged heating of Sucrose Benzoate at elevated temperatures causes darkening and increases in acidity. For example, heating for 4 hours in oven at 175 C in aluminium dishes causes gradual colour development from 60 APHA to about 3 Gardner - and 8 hours heating results in Gardner range of This 8 hour heating also causes an increase in acid number from around 0.05 to around 0.35 mg KOH/g. Temperatures below 150 C cause the Sucrose Benzoate to reach a 4 Gardner colour in less than 2 hours. Addition of small amounts of oxirane oxygen containing compounds including epoxy soybean oil, epoxy esters, liquid epoxy resins, and glycidyl phenyl ether imparts improved heat stability to Sucrose Benzoate. Registered Trademarks of LANXESS Deutschland GmbH: Edition: This information and our technical advice - whether verbal, in writing or by the way of trials - are given in good faith but without warranty, and this also applies where proprietary rights of third parties are involved. Our advice does not release you from the obligation to check its validity and to test our products as to their suitability for the intended processes and uses. The application, use and processing of our products manufactured by you on the basis of our technical advice are beyond our control and, therefore, entirely your own responsibility. Our products are sold in accordance with the current version of our General Conditions of Sale and Delivery. LANXESS Deutschland GmbH, D Leverkusen Functional Chemicals Polymer Additives , Seite 6 von 6