Material Safety Data Sheet

Transcription

1 IDENTIFICATION Material Safety Data Sheet Issue Date: July 30, 2013 Product Name: HY-CLOR LONG LIFE ALGAECIDE Classified as Hazardous according to criteria of Worksafe Australia Product Name HY-CLOR Long Life Algaecide Other Names Copper Sulphate Pentahydrate Product Codes & Size HYC4ALG01 1 LITRE X 4 HYCALGO1 1 LITRE X 6 HYCLLALG LITRES Recommended Uses Kill and control algae in swimming pools Company Name HY-CLOR AUSTRALIA PTY LIMITED Address 178 Power Street, Glendenning, NSW 2761 Tel/Fax Ph: (02) Fax: (02) Emergency Contact Number Business Hours Only (02) After hours General Information 24 Hour Emergency Contact If poisoning occurs, contact a doctor or Poisons Information Centre Australia or New Zealand HAZARDS IDENTIFICATION Hazard Statement This material is hazardous according to health criteria of NOHSC Australia Hazard Category UN Number UN Proper Shipping Name Dangerous Goods Class Packaging Group Hazchem Code Risk Phrase(s) R22 Harmful if swallowed R36/38 Irritating to eyes and skin Safety Phrase(s) S2 Keep out of reach of children S23/25 Avoid contact with skin and eyes Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport by Road and Rail. Page 1 of 5

2 Poisons Schedule (Aust) S5 This material is a Scheduled Poison S5 and must be stored, maintained and used in accordance with the relevant regulations. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Entity CAS NO PROPORTION Copper Sulphate Pentrahydrate % Inert ingredients % FIRST AID MEASURES If poisoning occurs, contact a doctor or Poisons Information Centre (Phone Australia , New Zealand ) Ingestion Eye Contact Skin Contact Inhalation Note to physician If swallowed promptly drink a large quantity of milk, gelatin solution, egg white or large quantity of water. Seek medical advice immediately. Irrigate with copious amounts of water and seek medical advice. Remove all contaminated clothing and wash skin thoroughly with soap and water. If irritation occurs seek medical advice. Wash contaminated clothing before re-use. If nasal irritation occurs seek medical advice. Treat symptomatically. FIRE FIGHTING MEASURES Hazachem Code Specific Hazards. Non combustible material. Suitable Extinguishing Equipment In case of fire, use appropriate extinguishing media most suitable for surrounding fire conditions. Use water fog or fine spray, foam, dry agent (carbon dioxide, dry chemical powder). Special Protective Equipment and precautions for fire fighting Fire fighters should wear self contained breathing apparatus and full protective clothing along with protective equipment. Fire fighting further advice Closed containers exposed to heat may explode. Incompatible with acetylene gas, aluminium powder, hydroxylamine, magnesium, moist air and sources of ignition. Hazardous decomposition products include oxides of sulphur and oxides of copper. When heated to decomposition toxic fumes of sulphur dioxide are produced. Page 2 of 5

3 ACCIDENTAL RELEASE MEASURES Small Spills Large Spills Environmental Precautions Wear protective equipment to prevent skin and eye contamination. Avoid inhalation of vapours. Wipe up with absorbent (clean rag or paper towels). Collect and seal in properly labelled containers or drums for disposal. Shut off all possible sources of ignition. Clear area of all unprotected personnel. Wear protective equipment to prevent skin and eye contamination and the inhalation of vapours. Work up wind or increase ventilation. Contain prevent run off into drains and water ways. Use absorbent (soil, san dor other inert material). Collect and seal in properly labelled containers or drums for disposal. Toxic to fish & other aquatic life forms. Do not dispose by drainage or into lakes, ponds or public water. If contamination of sewers or waterways has occurred advise local emergency services. HANDLING AND STORAGE Handling Storage Incompatibilities Avoid skin and eye contact and inhalation of vapour, mist or aerosols. Store in a cool, dry, well ventilated area. Keep containers tightly closed when not in use. Inspect regularly for deficiencies such as damage or leaks. Protect against physical damage. Store away from incompatible materials including acetylene gas, aluminium powder, hydroxylamine, magnesium, moist air and sources of ignition. Protect from direct sunlight, moisture and static discharges. Precautions for safety Ensure an eye bath and safety shower are available and ready for use. Observe good personal hygiene practices and recommended procedures. Wash thoroughly after handling. Take precautionary measures against static discharges by bonding and grounding equipment. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Standards Worksafe Australia recommends the following exposure limits: Copper, dusts and mists (as Cu) : TWA = 1 mg/m3 Copper (fume) : TWA = 0.2 mg/m3 Engineering Measures Ensure ventilation is adequate to maintain air concentrations below Exposure Standards. Use with local exhaust ventilation or while wearing appropriate respirator. Keep containers closed when not in use. Personal Protection Equipment Overalls, safety shoes, chemical goggles, gloves, respirator. Page 3 of 5

4 Biological Limit Values as per the National Model Regulations for the Control of Workplace Hazardous Substances. PHYSICAL AND CHEMICAL PROPERTIES Appearance Density Odour Solubility Boiling point ph Stability Flammability Explosiveness Viscosity Clear & brilliant blue liquid Specific gravity degrees Celsius Slight odour Soluble in water 101 degrees Celsius 1.2 (10% solution) Indefinite Aqueous solution Not flammable Non explosive ingredients 1.4 Centiposes STABILITY AND REACTIVITY Chemical Stability Conditions to Avoid Incompatible Materials This chemical is thermally stable when stored and used as directed. Elevated temperatures, direct sunlight, static discharges, moisture. Acetylene gas, aluminium powder, hydroxylamine, magnesium. Hazardous decomposition products Oxides of carbon and nitrogen, smoke and other toxic fumes. Hazardous Reactions No known hazardous reactions. TOXICOLOGICAL INFORMATION No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are: Acute Effects Swallowed Inhalation Skin Contact Eye Contact Long Term Effects Metallic taste in mouth. Burning sensation in throat and vomiting are typical effects. More severe poisoning causes irritation in digestive tract with abdominal pain, nausea, vomiting, ulceration and diarrhoea. May cause irritation of the nose and upper airways. Contact with skin may result in irritation. May cause eye irritation and inflammation. No information available for product. Acute Toxicity / Chronic Toxicity Oral LD50 = 300 mg/kg (rat); 60 mg/kg (dog) Oral LDLo 1088 mg/kg (human); 60 mg/kg (dog) Not listed as a carcinogen. Page 4 of 5

5 ECOLOGICAL INFORMATION Avoid contaminating waterways. Ecotoxicity No information available. Persistence and Degradability No information available. Mobility No information available. DISPOSAL CONSIDERATIONS Disposal Methods and Containers Refer to State / Territory Land Waste Management authority. TRANSPORT INFORMATION Road and Rail Transport Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport by Road and Rail. Marine Transport Not classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods code (IMDG Code) for transport by sea. Air Transport Not classified as Dangerous Goods by the criteria of the International air Transport Association (IATA) Dangerous goods regulations for transport by air. REGULATORY INFORMATION Poisons Schedule (Aust) S5 OTHER INFORMATION Contact Any advice, recommendation, information, assistance, or service provided by Hy-Clor Australia in relation to the goods supplied by it or their use or application is given in good faith and believed to be appropriate and reliable. However, it is provided with a disclaimer for any liability on the part of Hy-Clor Australia Pty Ltd. The customer accepts all risk and responsibility for use of the goods alone, or in combination with other products. All warranties, guarantees and conditions, other than those expressly stated, and whether implied by statute, common law, custom of the trade otherwise, are to the extent that the law permits expressly excluded. Mark Sheridan Technical Regulations Manager Telephone: Australia New Zealand Page 5 of 5