CERTIFICATE OF ANALYSIS

Transcription

1 Your Project #: VIHA LIST Your C.O.C. #: Attention:Don Buchner 24 Lions Way Qualicum Beach, BC Canada V9K 2E2 Report : 16/11/28 Report #: R Version: 1 Final MAXXAM JOB #: B6A568 Received: 16/11/18, 11:00 Sample Matrix: Water # Samples Received: Analyses Alkalinity Water (1) Chloride by Automated Colourimetry (1) Colour (True) by Kone Lab (1) Color Apparent (1) Total Coliforms & E.coli Potable W MF (1) Conductance water (1) Fluoride (1) Hardness Total (calculated as CaCO) (1) Hardness Total (calculated as CaCO) (1) Heterotropic Plate Count (MF) Potable W (1) Iron Related Bacteria (1, 2) Na, K, Ca, Mg, S by CRC ICPMS (total) (1) Na, K, Ca, Mg, S by CRC ICPMS (total) (1) Elements by CRC ICPMS (total) (1) Elements by CRC ICPMS (total) (1) Nitrogen (Total) (1) AmmoniaN (Preserved) (1) Nitrate + Nitrite (N) (1) Nitrite (N) by CFA (1) Nitrogen Nitrate (as N) (1) Nitrogen (Organic) (Cal. TKN, NH4,N/N) (1) ph Water (1, ) Sat. ph and Langelier Index (@ 4.4C) (1) Sat. ph and Langelier Index (@ 4.4C) (1) Sat. ph and Langelier Index (@ 60C) (1) Sat. ph and Langelier Index (@ 60C) (1) Sulphate by Automated Colourimetry (1) Sulphate Reducing Bacteria (1, 2) Sulphide total (1) Total Dissolved Solids (Filt. Residue) (1) Carbon (Total Organic) (1, 4) CERTIFICATE OF ANALYSIS Quantity Extracted Analyzed Laboratory Method 16/11/19 16/11/19 BBY6SOP00026 N/A 16/11/21 BBY6SOP00011 N/A 16/11/19 BBY6SOP00057 N/A 16/11/19 BBY6SOP00021 N/A 16/11/18 BBY4SOP00001 N/A 16/11/19 BBY6SOP00026 N/A BBY6SOP00048 N/A BBY WI000 N/A BBY WI000 N/A 16/11/18 BBY4SOP0000 N/A 16/11/18 BBY4SOP /11/18 BBY7SOP /11/18 BBY7SOP /11/21 BBY7SOP0000, BBY7SOP0000, BBY6SOP00016 N/A BBY6SOP00009 N/A 16/11/19 BBY6SOP00010 N/A 16/11/19 BBY6SOP00010 N/A BBY6SOP00010 N/A 16/11/24 BBY WI000 N/A 16/11/19 BBY6SOP00026 N/A BBY WI000 N/A BBY WI000 N/A BBY WI000 N/A BBY WI000 N/A 16/11/21 BBY6SOP00017 N/A 16/11/18 BBY4SOP00004 N/A 16/11/21 BBY6SOP /11/24 BBY6SOP000 N/A 16/11/21 BBY6SOP0000 Analytical Method SM 22 2 B m SM Cl E m SM C m SM B m SM m SM B m SM F C m Auto Calc Auto Calc SM SM D EPA 60A R1 m EPA 60A R1 m BCLM05,EPA60bR2m BCLM05,EPA60bR2m SM N C m SM NH G m SM NO I m SM NO I m SM NO I m Auto Calc SM H+ B m Auto Calc Auto Calc Auto Calc Auto Calc SM SO42 E m SM D SM S2 D m SM C m SM C m Page 1 of 16

2 Your Project #: VIHA LIST Your C.O.C. #: Attention:Don Buchner 24 Lions Way Qualicum Beach, BC Canada V9K 2E2 Report : 16/11/28 Report #: R Version: 1 Final MAXXAM JOB #: B6A568 Received: 16/11/18, 11:00 Sample Matrix: Water # Samples Received: Analyses Turbidity (1) CERTIFICATE OF ANALYSIS Quantity Extracted N/A Analyzed Laboratory Method 16/11/19 BBY6SOP00027 Analytical Method SM B m Reference Method suffix m indicates test methods incorporate validated modifications from specific reference methods to improve performance. * s calculated using raw data. The rounding of final results may result in the apparent difference. (1) This test was performed by Maxxam Vancouver (2) Presence/Absence Method. Number is an estimate. () The BCMOE and APHA Standard Method require ph to be analysed within 15 minutes of sampling and therefore field analysis is required for compliance. All Laboratory ph analyses in this report are reported past the BCMOE/APHA Standard Method holding time. (4) TOC present in the sample should be considered as nonpurgeable TOC. Encryption Key Please direct all questions regarding this Certificate of Analysis to your Project Manager. BC Env Customer Service, BC Environmental Customer Service Enviro.CS.BC@maxxam.ca Phone# (250) ==================================================================== This report has been generated and distributed using a secure automated process. Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section of ISO/IEC 17025:05(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page. Total Cover Pages : 2 Page 2 of 16

3 Maxxam Job #: B6A568 Report : 16/11/28 RESULTS OF CHEMICAL ANALYSES OF WATER Maxxam ID Sampling COC Number QB /11/18 08:00 QB /11/18 08:15 QB58 16/11/18 08:0 MAC AO OG WELL 1 WELL 2 WELL RDL ANIONS Nitrite (N) Calculated Parameters 1 < < < Nitrate (N) Misc. Inorganics 10 <0.0 < < Fluoride (F) Alkalinity (Total as CaCO) Alkalinity (PP as CaCO) Bicarbonate (HCO) Carbonate (CO) Hydroxide (OH) Anions Dissolved Sulphate (SO4) Dissolved Chloride (Cl) MISCELLANEOUS Apparent Colour True Colour Nutrients Col. Unit Col. Unit Total Organic Nitrogen (N) Total Ammonia (N) Nitrate plus Nitrite (N) Total Nitrogen (N) Physical Properties < < < < Conductivity ph Physical Properties us/cm ph 6.5: Total Dissolved Solids Turbidity NTU see remark 500 see remark see remark No Fill No Exceedance Grey Exceeds 1 criteria policy/level Black Exceeds both criteria/levels RDL = Reportable Detection Limit Page of 16

4 Maxxam Job #: B6A568 Report : 16/11/28 MICROBIOLOGY (WATER) Maxxam ID Sampling COC Number QB /11/18 08:00 QB /11/18 08:15 QB58 16/11/18 08:0 MAC WELL 1 WELL 2 WELL RDL Microbiological Param. Heterotrophic Plate Count Iron Bacteria Sulphate reducing bacteria Total Coliforms E. coli CFU/mL CFU/mL CFU/mL CFU/mL CFU/mL <1 <1 <25 <75 <1 <1 <25 <75 <1 <1 <25 <75 <1 < No Fill No Exceedance Grey Exceeds 1 criteria policy/level Black Exceeds both criteria/levels RDL = Reportable Detection Limit Page 4 of 16

5 Maxxam Job #: B6A568 Report : 16/11/28 CALCULATED PARAMETERS (WATER) Maxxam ID Sampling COC Number QB /11/18 08:00 QB /11/18 08:15 QB58 16/11/18 08:0 WELL 1 WELL 2 WELL Parameter Langelier Index (@ 4.4C) Langelier Index (@ 60C) Saturation ph (@ 4.4C) Saturation ph (@ 60C) N/A N/A N/A N/A Page 5 of 16

6 Maxxam Job #: B6A568 Report : 16/11/28 MISCELLANEOUS (WATER) Maxxam ID Sampling COC Number QB /11/18 08:00 QB /11/18 08:15 QB58 16/11/18 08:0 AO WELL 1 WELL 2 WELL RDL MISCELLANEOUS Total Sulphide 0.05 < No Fill No Exceedance Grey Exceeds 1 criteria policy/level Black Exceeds both criteria/levels RDL = Reportable Detection Limit Page 6 of 16

7 Maxxam Job #: B6A568 Report : 16/11/28 CSR TOTAL METALS IN WATER WITH CV HG (WATER) Maxxam ID Sampling COC Number QB /11/18 08:00 QB /11/18 08:15 QB58 16/11/18 08:0 MAC AO OG WELL 1 WELL 2 WELL RDL Calculated Parameters Total Hardness (CaCO) Total Metals by ICPMS Total Aluminum (Al) Total Antimony (Sb) Total Arsenic (As) Total Barium (Ba) Total Beryllium (Be) Total Bismuth (Bi) Total Boron (B) Total Cadmium (Cd) Total Cobalt (Co) Total Copper (Cu) Total Iron (Fe) Total Lead (Pb) Total Lithium (Li) Total Manganese (Mn) Total Molybdenum (Mo) Total Nickel (Ni) Total Selenium (Se) Total Silicon (Si) Total Silver (Ag) Total Strontium (Sr) Total Thallium (Tl) Total Tin (Sn) Total Titanium (Ti) Total Uranium (U) Total Vanadium (V) Total Zinc (Zn) Total Zirconium (Zr) Total Calcium (Ca) Total Magnesium (Mg) Total Potassium (K) < <50 < <10 < < < < <50 <0.010 <10 < < < < <50 <0.010 <10 < < < No Fill No Exceedance Grey Exceeds 1 criteria policy/level Black Exceeds both criteria/levels RDL = Reportable Detection Limit Page 7 of 16

8 Maxxam Job #: B6A568 Report : 16/11/28 CSR TOTAL METALS IN WATER WITH CV HG (WATER) Maxxam ID Sampling COC Number QB /11/18 08:00 QB /11/18 08:15 QB58 16/11/18 08:0 MAC AO OG WELL 1 WELL 2 WELL RDL Total Sodium (Na) Total Sulphur (S) 0.78 <.0.72 < < No Fill No Exceedance Grey Exceeds 1 criteria policy/level Black Exceeds both criteria/levels RDL = Reportable Detection Limit Page 8 of 16

9 Maxxam Job #: B6A568 Report : 16/11/28 GENERAL COMMENTS MAC,AO,OG: The guidelines that have been included in this report have been taken from the Canadian Drinking Water Quality Summary Table, October 14. Criteria A = Maximum Acceptable Concentration (MAC) / Criteria B = Aesthetic Objectives (AO) / Criteria C = Operational Guidance Values (OG) It is recommended to consult these guidelines when interpreting your data since there are nonnumerical guidelines that are not included on this report. Turbidity Guidelines: 1. Chemically assisted filtration: less than or equal to 0. NTU in 95 of the measurements or 95 of the time each month. Shall not exceed NTU at any time. 2. Slow sand / diatomaceous earth filtration: less than or equal to NTU in 95 of the measurements or 95 of the time each month. Shall not exceed.0 NTU at any time.. Membrane filtration: less than or equal to 0.1 NTU in of the measurements made or at least of the time each calendar month. Shall not exceed 0. NTU at any time. Results relate only to the items tested. Page 9 of 16

10 Maxxam Job #: B6A568 Report : 16/11/28 QUALITY ASSURAE REPORT QA/QC Batch Init CGP CGP CGP MM MM MM MM MM MM MM MM BO BO BO JSG JSG JSG JSG IC4 IC4 IC4 IC4 IC4 IC4 IC4 IC4 AD5 QC Type [QB589501] [QB589501] [QB589501] [QB589501] [QB589505] [QB589405] Parameter Turbidity Turbidity Turbidity ph Conductivity Conductivity Conductivity Alkalinity (Total as CaCO) Alkalinity (Total as CaCO) Alkalinity (Total as CaCO) Alkalinity (PP as CaCO) Bicarbonate (HCO) Carbonate (CO) Hydroxide (OH) Alkalinity (Total as CaCO) Alkalinity (PP as CaCO) Bicarbonate (HCO) Carbonate (CO) Hydroxide (OH) Apparent Colour Apparent Colour True Colour True Colour True Colour Total Sulphide Total Sulphide Total Sulphide Total Sulphide Total Aluminum (Al) Total Antimony (Sb) Total Arsenic (As) Total Barium (Ba) Total Beryllium (Be) Total Bismuth (Bi) Total Boron (B) Total Cadmium (Cd) Total Cobalt (Co) Total Copper (Cu) Total Iron (Fe) Total Lead (Pb) Total Lithium (Li) Total Manganese (Mn) Total Molybdenum (Mo) Total Nickel (Ni) Total Selenium (Se) Analyzed 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/21 16/11/21 16/11/21 16/11/21 16/11/21 16/11/21 16/11/21 16/11/21 16/11/21 16/11/21 16/11/21 16/11/21 Value , RDL= Recovery QC Limits 80 1 NTU us/cm Col. Unit 80 1 Col. Unit Page 10 of 16

11 Maxxam Job #: B6A568 Report : 16/11/28 QUALITY ASSURAE REPORT(CONT'D) QA/QC Batch Init AD5 AD5 QC Type Parameter Total Silver (Ag) Total Strontium (Sr) Total Thallium (Tl) Total Tin (Sn) Total Titanium (Ti) Total Uranium (U) Total Vanadium (V) Total Zinc (Zn) Total Aluminum (Al) Total Antimony (Sb) Total Arsenic (As) Total Barium (Ba) Total Beryllium (Be) Total Bismuth (Bi) Total Boron (B) Total Cadmium (Cd) Total Cobalt (Co) Total Copper (Cu) Total Iron (Fe) Total Lead (Pb) Total Lithium (Li) Total Manganese (Mn) Total Molybdenum (Mo) Total Nickel (Ni) Total Selenium (Se) Total Silver (Ag) Total Strontium (Sr) Total Thallium (Tl) Total Tin (Sn) Total Titanium (Ti) Total Uranium (U) Total Vanadium (V) Total Zinc (Zn) Total Aluminum (Al) Total Antimony (Sb) Total Arsenic (As) Total Barium (Ba) Total Beryllium (Be) Total Bismuth (Bi) Total Boron (B) Total Cadmium (Cd) Total Cobalt (Co) Total Copper (Cu) Total Iron (Fe) Total Lead (Pb) Total Lithium (Li) Total Manganese (Mn) Total Molybdenum (Mo) Total Nickel (Ni) Total Selenium (Se) Total Silicon (Si) Total Silver (Ag) Total Strontium (Sr) Analyzed Value <.0 <50 <0.010 <10 <0. < <0.0 Recovery 87 7 (1) QC Limits Page 11 of 16

12 Maxxam Job #: B6A568 Report : 16/11/28 QUALITY ASSURAE REPORT(CONT'D) QA/QC Batch Init AD5 CK CK CK CK BB BB BB BB BB BB BB BB AD5 QC Type Parameter Total Thallium (Tl) Total Tin (Sn) Total Titanium (Ti) Total Uranium (U) Total Vanadium (V) Total Zinc (Zn) Total Zirconium (Zr) Total Aluminum (Al) Total Antimony (Sb) Total Arsenic (As) Total Barium (Ba) Total Beryllium (Be) Total Bismuth (Bi) Total Boron (B) Total Cadmium (Cd) Total Cobalt (Co) Total Copper (Cu) Total Iron (Fe) Total Lead (Pb) Total Lithium (Li) Total Manganese (Mn) Total Molybdenum (Mo) Total Nickel (Ni) Total Selenium (Se) Total Silicon (Si) Total Silver (Ag) Total Strontium (Sr) Total Thallium (Tl) Total Tin (Sn) Total Titanium (Ti) Total Uranium (U) Total Vanadium (V) Total Zinc (Zn) Total Zirconium (Zr) Total Ammonia (N) Total Ammonia (N) Total Ammonia (N) Total Ammonia (N) Dissolved Chloride (Cl) Dissolved Chloride (Cl) Dissolved Chloride (Cl) Dissolved Chloride (Cl) Dissolved Sulphate (SO4) Dissolved Sulphate (SO4) Dissolved Sulphate (SO4) Dissolved Sulphate (SO4) Dissolved Sulphate (SO4) Total Aluminum (Al) Total Antimony (Sb) Total Arsenic (As) Total Barium (Ba) Total Beryllium (Be) Total Bismuth (Bi) Total Boron (B) Analyzed 16/11/21 16/11/21 16/11/21 16/11/21 16/11/21 16/11/21 16/11/21 16/11/21 16/11/21 Value < < Recovery QC Limits Page 12 of 16

13 Maxxam Job #: B6A568 Report : 16/11/28 QUALITY ASSURAE REPORT(CONT'D) QA/QC Batch Init AD5 AD5 QC Type Parameter Total Cadmium (Cd) Total Cobalt (Co) Total Copper (Cu) Total Iron (Fe) Total Lead (Pb) Total Lithium (Li) Total Manganese (Mn) Total Molybdenum (Mo) Total Nickel (Ni) Total Selenium (Se) Total Silver (Ag) Total Strontium (Sr) Total Thallium (Tl) Total Tin (Sn) Total Titanium (Ti) Total Uranium (U) Total Vanadium (V) Total Zinc (Zn) Total Aluminum (Al) Total Antimony (Sb) Total Arsenic (As) Total Barium (Ba) Total Beryllium (Be) Total Bismuth (Bi) Total Boron (B) Total Cadmium (Cd) Total Cobalt (Co) Total Copper (Cu) Total Iron (Fe) Total Lead (Pb) Total Lithium (Li) Total Manganese (Mn) Total Molybdenum (Mo) Total Nickel (Ni) Total Selenium (Se) Total Silver (Ag) Total Strontium (Sr) Total Thallium (Tl) Total Tin (Sn) Total Titanium (Ti) Total Uranium (U) Total Vanadium (V) Total Zinc (Zn) Total Aluminum (Al) Total Antimony (Sb) Total Arsenic (As) Total Barium (Ba) Total Beryllium (Be) Total Bismuth (Bi) Total Boron (B) Total Cadmium (Cd) Total Cobalt (Co) Analyzed Value <.0 <50 <0.010 Recovery QC Limits Page 1 of 16

14 Maxxam Job #: B6A568 Report : 16/11/28 QA/QC Batch Init AD5 DC6 DC6 DC6 DC6 CGP CGP CGP CGP QC Type [QB589501] QUALITY ASSURAE REPORT(CONT'D) Parameter Total Copper (Cu) Total Iron (Fe) Total Lead (Pb) Total Lithium (Li) Total Manganese (Mn) Total Molybdenum (Mo) Total Nickel (Ni) Total Selenium (Se) Total Silicon (Si) Total Silver (Ag) Total Strontium (Sr) Total Thallium (Tl) Total Tin (Sn) Total Titanium (Ti) Total Uranium (U) Total Vanadium (V) Total Zinc (Zn) Total Zirconium (Zr) Total Nitrogen (N) Total Nitrogen (N) Total Nitrogen (N) Total Nitrogen (N) Nitrate plus Nitrite (N) Nitrate plus Nitrite (N) Nitrate plus Nitrite (N) Nitrate plus Nitrite (N) Nitrite (N) Nitrite (N) Nitrite (N) Nitrite (N) Total Dissolved Solids Total Dissolved Solids Total Dissolved Solids Total Dissolved Solids Fluoride (F) Fluoride (F) Fluoride (F) Fluoride (F) Analyzed 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/19 16/11/24 16/11/24 16/11/24 16/11/24 Value <10 <0. < <0.0 <0.050 < < < < , RDL=0.010 Duplicate: Paired analysis of a separate portion of the same sample. Used to evaluate the variance in the measurement. Recovery : A sample to which a known amount of the analyte of interest has been added. Used to evaluate sample matrix interference. : A blank matrix sample to which a known amount of the analyte, usually from a second source, has been added. Used to evaluate method accuracy. : A blank matrix containing all reagents used in the analytical procedure. Used to identify laboratory contamination. (): The recovery in the matrix spike was not calculated. The relative difference between the concentration in the parent sample and the spiked amount was too small to permit a reliable recovery calculation (matrix spike concentration was less than 2x that of the native sample concentration). (Duplicate ): The duplicate was not calculated. The concentration in the sample and/or duplicate was too low to permit a reliable calculation (one or both samples < 5x RDL). (1) Recovery or for this parameter is outside control limits. The overall quality control for this analysis meets acceptability criteria QC Limits Page 14 of 16

15 Maxxam Job #: B6A568 Report : 16/11/28 VALIDATION SIGNATURE PAGE The analytical data and all QC contained in this report were reviewed and validated by the following individual(s). Andy Lu, Ph.D., P.Chem., Scientific Specialist Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section of ISO/IEC 17025:05(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page. Page 15 of 16

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