Safety Data Sheet according GB

Transcription

1 EXOLIT OP 935 Page 1 1. Identification of the substance/preparation and company Trade name EXOLIT OP 935 Material number: Identification of the company Clariant Produkte (Deutschland) GmbH Chemiepark Knapsack Hürth Telephone no. : Information about the substance/preparation Division Pigments & Additives +49(0) Emergency telephone number : Composition/information on ingredients Chemical characterization Organophosphorus salt Hazardous ingredients (China): Product contains no dangerous ingredients according to GB Hazards identification Hazards to health: Hazards to the environment: According to the present state of knowledge, provided this product is handled correctly, there is no known danger to humans. According to the present state of knowledge, provided this product is handled correctly, there is no known danger to environment. 4. First aid measures General information Remove clothing where dust collected. After inhalation Remove the casualty into fresh air and keep him calm. Ensure supply of fresh air. Take medical treatment. After contact with skin In case of contact with skin wash off immediately with soap and water After contact with eyes In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice

2 EXOLIT OP 935 Page 2 After ingestion Get medical treatment 5. Fire-fighting measures Suitable extinguishing media extinguishing measures to suit surroundings Extinguishing media that must not be used for safety reasons gaseous extinguishing media Special hazards from the substance itself, its combustion products or from its vapours In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO) Special protective equipment for firefighting Use self-contained breathing apparatus Further information Fire residues must be disposed of in a proper manner 6. Accidental release measures Personal precautions Do not inhale dust. Avoid contact with skin and eyes. Wear personal protective equipment. Unprotected persons must be kept away. Environmental precautions Do not allow to enter drains Retain and dispose of contaminated wash water. Methods for cleaning up/taking up Pick up mechanically. Rinse away rest with water. Avoid raising dust 7. Handling and storage Advice on safe handling Avoid dust formation. Provide exhaust ventilation if dust is formed. Take precautionary measures against electrostatic loading. Advice on protection against fire and explosion Dust can form an explosive mixture with air. Keep away from sources of ignition Avoid formation of dust Avoid deposition of dust Dust explosion class : Advice on storage compatibility Observe TRGS 514Ü (storage compatibility) ST1 Capable of dust explosion

3 EXOLIT OP 935 Page 3 Further information on storage conditions Keep container tightly closed in a well-ventilated place Storage stability When stored in unopened container, the product is stable for at least 12 month. 8. Exposure controls/personal protection General protective measures Do not inhale dust Avoid contact with skin Avoid contact with eyes Hygiene measures Do not eat or drink during work time. Do not smoke during work time. Clean skin thoroughly after work; apply skin cream. Respiratory protection : Hand protection : Dust mask antistatic gloves PVC or PE gloves Minimum breakthrough time (glove): not applicable Minimum thickness (glove): not determined Observe the information of the glove manufacturers on permeability and breakthrough times and other workplace requirements Eye protection : Body protection : tightly fitting safety glasses protective clothing 9. Physical and chemical properties Form : Colour : Odour : Powder white not specified Decomposition point : from 300 C Method : DTA Flash point : Ignition temperature : Self-ignition temperature : > 400 C Method : 92/69/EEC, A.16 Vapour pressure :

4 EXOLIT OP 935 Page 4 Density : Bulk density : Solubility in water : ph value : Octanol/water partition coefficient (log Pow) : Viscosity (dynamic) : Impact sensitivity : 1.35 g/cm3 (23 C) Method : 92/69/EEC, A kg/m3 (20 C) = 3 g/l approx. 5 (20 C, 10 g/l) Suspension in water Not impact-sensitive Use of the substance/preparation. Industry sector : Plastic processing industry. Type of use : flameproofing agents 10. Stability and reactivity Thermal decomposition : > 300 C (Heating rate : 5 K/min) Decomposes before melting. Hazardous reactions No hazardous reactions when stored and handled according to prescribed instructions. Risk of dust explosions. 11. Toxicological information Acute oral toxicity : Acute dermal toxicity : Irritant effect on skin : Irritant effect on eyes : LD50 > 2,000 mg/kg (rat) Method : OECD 401 LD50 > 2,000 mg/kg (rat (female)) Method : OECD 402 non-irritant (4 h, rabbit) Method : OECD 404 Source : Aventis Pharma Deutschland GmbH, ProTox slight irritant effect - does not require labelling (rabbit eye) Method : OECD 405

5 EXOLIT OP 935 Page 5 Sensitization : Repeated dose toxicity: Mutagenicity : non-sensitizing (Guinea pig) Method : OECD 406 Sub-acute oral toxicity Route of application: gavage NOAEL: > 1,000 mg/kg (Rats (male/female)) Method : OECD Guide-line 407 Not mutagenic in Ames Test. No experimental information on genotoxicity in vitro available. 12. Ecological information Biodegradability : Fish toxicity : Daphnia toxicity : Algae toxicity : Bacteria toxicity : not degradable Method : OECD 302B / ISO 9888 / EEC 88/302C Data refer to the organic component. LC50 > 100 mg/l (96 h, zebra fish) Method : OECD 203 > 100 mg/l (48 h, Daphnia magna) Method : OECD 202 NOEC > 180 mg/l (Scenedesmus subspicatus) Method : 92/69/EEC, C.3 EC50 = 1,968 mg/l (3 h, activated sludge) Method : OECD Disposal considerations Product In accordance with regulations for special waste, must be taken, after pretreatment, to an authorised special waste incineration plant Uncleaned packaging Packaging that cannot be cleaned should be disposed of as product waste 14. Transport information IATA IMDG

6 EXOLIT OP 935 Page 6 ADR RID 15. Regulatory information Labelling CN According to GB , no hazard labelling is required. Labelling in accordance with EC-Directives hazard warning labelling not compulsory 16. Other information The product is not listed in the Schedules of the Chemical Weapons Convention. The data are based on the current state of our knowledge, and are intended to describe the product with regard to the requirements of safety. The data should not be taken to imply any guarantee of a particular or general specification. It is the responsibility of the user of the product to ensure to his satisfaction that the product is suitable for the intended purpose and method of use. We do not accept responsibility for any harm caused by the use of this information. In all cases, our general conditions of sale apply.