Obstructed or Non-Vertical Oriented Toxic Air Pollutant Permitting Emission Rates (TPER) Toxicants

Transcription

1 15A NCAC 02Q.0711 EMISSION RATES REQUIRING A PERMIT (a) A permit to emit toxic air pollutants shall be required for any facility, excluding sources exempt from evaluation by 15A NCAC 02Q.0702, if one or more emission release points are obstructed or non-vertically oriented whose actual rate of emissions by pollutant from all sources is greater than any one of the following toxic air pollutant permitting emissions rates: Obstructed or Non-Vertical Oriented Toxic Air Pollutant Permitting Emission Rates (TPER) Carcinogens acetaldehyde ( ) 6.8 acetic acid ( ) 0.96 acrolein ( ) 0.02 acrylonitrile ( ) ammonia ( ) 0.68 aniline ( ) 0.25 arsenic and inorganic arsenic compounds asbestos ( ) 5.7 X 10-3 aziridine ( ) 0.13 benzene ( ) 8.1 benzidine and salts ( ) benzo(a)pyrene ( ) 2.2 benzyl chloride ( ) 0.13 beryllium ( ) 0.28 beryllium chloride ( ) 0.28 beryllium fluoride ( ) 0.28 beryllium nitrate ( ) 0.28 bioavailable chromate pigments, as chromium (VI) equivalent bis-chloromethyl ether ( ) bromine ( ) ,3-butadiene ( ) 11 cadmium ( ) 0.37 cadmium acetate ( ) 0.37 cadmium bromide ( ) 0.37 carbon disulfide ( ) 3.9 carbon tetrachloride ( ) 460 chlorine ( ) chlorobenzene ( ) 46 chloroform ( ) 290 chloroprene ( ) cresol ( ) 0.56 p-dichlorobenzene ( ) 16.8 di(2-ethylhexyl)phthalate ( ) 0.63 dimethyl sulfate ( ) ,4-dioxane ( ) 12 epichlorohydrin ( ) 5600 ethyl acetate ( ) 36 ethylenediamine ( ) ethylene dibromide ( ) 27 ethylene dichloride ( ) 260 ethylene glycol monoethyl ether ( ) ethylene oxide ( ) 1.8

2 Obstructed or Non-Vertical Oriented Toxic Air Pollutant Permitting Emission Rates (TPER) Carcinogens ethyl mercaptan ( ) fluorides formaldehyde ( ) 0.04 hexachlorocyclopentadiene ( ) hexachlorodibenzo-p-dioxin ( ) n-hexane ( ) 23 hexane isomers except n-hexane 92 hydrazine ( ) hydrogen chloride ( ) 0.18 hydrogen cyanide ( ) hydrogen fluoride ( ) hydrogen sulfide ( ) 1.7 maleic anhydride ( ) manganese and compounds 0.63 manganese cyclopentadienyl tricarbonyl ( ) manganese tetroxide ( ) 0.13 mercury, alkyl mercury, aryl and inorganic compounds mercury, vapor ( ) methyl chloroform ( ) methylene chloride ( ) methyl ethyl ketone ( ) methyl isobutyl ketone ( ) methyl mercaptan ( ) nickel carbonyl ( ) nickel metal ( ) 0.13 nickel, soluble compounds, as nickel nickel subsulfide ( ) 0.14 nitric acid ( ) nitrobenzene ( ) n-nitrosodimethylamine ( ) 3.4 non-specific chromium (VI) compounds, as chromium (VI) equivalent pentachlorophenol ( ) perchloroethylene ( ) phenol ( ) 0.24 phosgene ( ) phosphine ( ) polychlorinated biphenyls ( ) 5.6 soluble chromate compounds, as chromium (VI) equivalent styrene ( ) 2.7 sulfuric acid ( ) tetrachlorodibenzo-p-dioxin ( ) ,1,2,2-tetrachloroethane ( ) 430 toluene ( ) toluene diisocyanate,2,4-( ) and 2,6- ( ) isomers 0.003

3 Obstructed or Non-Vertical Oriented Toxic Air Pollutant Permitting Emission Rates (TPER) Carcinogens trichloroethylene ( ) 4000 vinyl chloride ( ) 26 vinylidene chloride ( ) 2.5 xylene ( ) (b) A permit to emit toxic air pollutants shall be required for any facility if all emission release points are unobstructed and vertically oriented whose actual rate of emissions from all sources is greater than any one of the following toxic air pollutant permitting emissions rates: Unobstructed Toxic Air Pollutant Permitting Emission Rates (TPER) Carcinogens acetaldehyde ( ) acetic acid ( ) 3.90 acrolein ( ) 0.08 acrylonitrile ( ) ammonia ( ) 2.84 aniline ( ) 1.05 arsenic and inorganic arsenic compounds asbestos ( ) x 10-3 aziridine ( ) 0.3 benzene ( ) benzidine and salts ( ) x 10-3 benzo(a)pyrene ( ) benzyl chloride ( ) 0.53 beryllium ( ) beryllium chloride ( ) beryllium fluoride ( ) beryllium nitrate ( ) bioavailable chromate pigments, as chromium (VI) equivalent bis-chloromethyl ether ( ) bromine ( ) ,3-butadiene ( ) cadmium ( ) cadmium acetate ( ) cadmium bromide ( ) carbon disulfide ( ) 7.8 carbon tetrachloride ( ) chlorine ( ) chlorobenzene ( ) 92.7 chloroform ( ) chloroprene ( ) cresol ( ) 2.32 p-dichlorobenzene ( ) di(2-ethylhexyl)phthalate ( ) 1.3 dimethyl sulfate ( ) 0.1

4 Unobstructed Toxic Air Pollutant Permitting Emission Rates (TPER) Carcinogens 1,4-dioxane ( ) 23.6 epichlorohydrin ( ) ethyl acetate ( ) ethylenediamine ( ) ethylene dibromide ( ) ethylene dichloride ( ) ethylene glycol monoethyl ether ( ) ethylene oxide ( ) ethyl mercaptan ( ) 0.11 fluorides formaldehyde ( ) 0.16 hexachlorocyclopentadiene ( ) 2.5 x hexachlorodibenzo-p-dioxin ( ) n-hexane ( ) 46.3 hexane isomers except n-hexane hydrazine ( ) 2.5 x 10-2 hydrogen chloride ( ) 0.74 hydrogen cyanide ( ) hydrogen fluoride ( ) hydrogen sulfide ( ) 5.1 maleic anhydride ( ) manganese and compounds 1.3 manganese cyclopentadienyl tricarbonyl 2.5 x 10-2 ( ) manganese tetroxide ( ) 0.3 mercury, alkyl 2.5 x 10-3 mercury, aryl and inorganic compounds 2.5 x 10-2 mercury, vapor ( ) 2.5 x 10-2 methyl chloroform ( ) methylene chloride ( ) methyl ethyl ketone ( ) methyl isobutyl ketone ( ) methyl mercaptan ( ) 0.05 nickel carbonyl ( ) 2.5 x 10-2 nickel metal ( ) 0.3 nickel, soluble compounds, as nickel 2.5 x 10-2 nickel subsulfide ( ) nitric acid ( ) 1.05 nitrobenzene ( ) n-nitrosodimethylamine ( ) non-specific chromium (VI) compounds, as chromium (VI) equivalent pentachlorophenol ( ) perchloroethylene ( ) phenol ( ) 1.00 phosgene ( ) 0.1 phosphine ( ) 0.14 polychlorinated biphenyls ( ) soluble chromate compounds, as chromium 2.6 x 10-2

5 Unobstructed Toxic Air Pollutant Permitting Emission Rates (TPER) Carcinogens (VI) equivalent styrene ( ) sulfuric acid ( ) tetrachlorodibenzo-p-dioxin ( ) x ,1,2,2-tetrachloroethane ( ) toluene ( ) toluene diisocyanate,2,4-( ) and 8.4 x ,6- ( ) isomers trichloroethylene ( ) vinyl chloride ( ) vinylidene chloride ( ) 5.1 xylene ( ) (c) For the following pollutants, the highest emissions occurring in any 15-minute period shall be multiplied by four and the product shall be compared to the value in Paragraph (a) or (b), as applicable: (1) acetaldehyde ( ); (2) acetic acid ( ); (3) acrolein ( ); (4) ammonia ( ); (5) bromine ( ); (6) chlorine ( ); (7) formaldehyde ( ); (8) hydrogen chloride ( ); (9) hydrogen fluoride ( ); and (10) nitric acid ( ). History Note: Authority G.S (a)(1); ; ; 143B-282; Rule originally codified as part of 15A NCAC 02H.0610; Eff. July 1, 1998; Amended Eff. May 1, 2015; May 1, 2014; January 1, 2010; June 1, 2008; April 1, 2005; February 1, 2005; April 1, 2001; Readopted Eff. July 1, 2018.