Voices. Protecting the Central and Southern Appalachian Mountain Region. March 13, 2014

Transcription

1 Voices Protecting the Central and Southern Appalachian Mountain Region Harold Ward, Director Division of Mining and Reclamation West Virginia Department of Environmental Protection th Street SE Charleston, WV Dear Mr. Ward, March 13, 2014 We are writing to share our water sampling results from Fields Creek during the Kanawha Eagle Coal, LLC (Patriot) coal slurry spill with the West Virginia Department of Environmental Protection and the Division of Mining and Reclamation. We ask the DEP consider these results in any enforcement actions against Patriot and in any future permitting decisions. We also ask that the DEP use these samples to inform their sampling procedures following similar coal slurry spills. A spill of coal slurry occurred at the Kanawha Eagle Prep Plant, a Patriot Coal facility, sometime during the early morning of February 11 th, Appalachian Voices became aware of the situation through news reports on the same morning. We arrived at Fields Creek, the site of the spill, in the early afternoon of the same day. We collected grab samples at two locations along Fields Creek at the crossing of MacCorkle Ave, just upstream of where Fields Creek enters the Kanawha ( , ), and just downstream of the prep plant, where the creek crosses under CR 77/1 ( , ). We collected grab samples to be analyzed for total suspended solids (TSS), a suite of total and dissolved metals, a suite of volatile organic compounds, and sulfate. Upon detecting the smell of crude MCHM, we also collected samples to be analyzed for 4- methylcyclohexane methanol. Based on statements made by Randy Huffman that polypropylene glycol or polyethylene glycol may have been used during coal processing at the facility, we also collected samples to be analyzed for diethylene glycol, ethylene glycol, and propylene glycol. We also collected field measurements, including ph and conductivity. All grab samples were either analyzed by Pace Analytical or by ALS. ALS is a WVDEP accredited lab, Pace Analytical is a NELAC accredited lab. We have attached the results of all laboratory testing. We have summarized the most significant findings below. We identified several NPDES permit violations, based on the permit limits found in a December 2013 discharge monitoring report submission. As expected from the obvious amount of suspended material visible in the stream, we identified total suspended solids (TSS) levels at as much as 10 times the amount allowable (table 1). Even after the flow in Fields Creek had been greatly reduced and the water was noticeably clearer on Tuesday

2 evening, the TSS level, at 94 mg/l, was still greater than the 70 mg/l allowed. We identified iron levels more than 3 times higher than allowed on the NPDES permit (Table 2). We also identified aluminum levels 2 to 7 times higher than allowed (Table 2). The highest aluminum level identified the second day was likely due at least in part to the EnviroFloc being used in remediation; nevertheless, the two earlier samples were likely directly due to the spilled slurry. The TSS, iron and aluminum test results indicate at least 3 individual violations of the company s NPDES permit. Under the Clean Water Act and West Virginia 47CSR 30, each violation should be subject to a fine of at least $2,500, and as much as $25,000. We urge the DEP to take these violations into consideration, in addition to violations #35, #36 and #37 already issued, when assessing penalties for this spill. Table 1: Total Suspended Solids (TSS) s and Violations Location Date Time Lab TSS 806 mg/l , /11/14 15:18 Pace Analytical MacCorkle Ave TSS 770 mg/l , CR77/1 Near Plant 2/11/14 16:11 Pace Analytical TSS 94 mg/l , CR77/1 Near Plant 2/11/14 19:10 ALS TSS 260 mg/l , MacCorkle Ave 2/11/14 19:28 ALS Table 2: Metals Permit Violations Location Date Time Lab Iron 18 mg/l , /11/14 16:11 Pace Analytical CR77/1 Near Plant Iron 13.9 mg/l , MacCorkle Ave 2/11/14 15:18 Pace Analytical Aluminum 8.94 mg/l , CR77/1 Near Plant 2/11/14 16:11 Pace Analytical Aluminum 9.35 mg/l , /11/14 15:18 Pace Analytical MacCorkle Ave Aluminum 28.1 mg/l , CR77/1 Near Plant 2/12/14 13:56 Pace Analytical A number of proprietary chemicals are available for use at coal processing facilities, making it difficult to know the host of chemicals that may be in coal slurry. During this particular spill, it was apparent through news reports and statements from the DEP that the DEP had some difficulty determining which chemicals to test for. According to statements made by Randy Huffman in an article in The Charleston Gazette on February 11 th, the DEP originally

3 believed that MCHM was used at the facility, and later learned that either polypropylene glycol or polyethylene glycol was used instead. Additionally, a comment was made that the smell of crude MCHM was likely from a truck transporting the material away from the facility on that day. Several issues exist with these statements. First and foremost, the DEP and DMR should ensure that they are able to obtain accurate information about operations at all mining facilities in a timely fashion, if not before spills even occur. Additionally, though Patriot claimed to have stopped using crude MCHM, the change was reported to have happened recently; therefore, it would be reasonable for the DEP to acknowledge that MCHM may still be present in the processing waste. To attribute the distinctive smell of MCHM to a tanker truck seems unlikely, and extremely coincidental that the move would have occurred on the same day as the spill. While MCHM may not be the most harmful chemical spilled that day, it is obviously an issue West Virginian citizens are very interested in currently. We did identify 4- methylcyclohexane methanol in Fields Creek on the day of the spill (Table 3). This directly contradicts the DEP s reports that no 4- methylcyclohexane methanol was found, and calls into questions the DEP s response to such spills. Table 3: 4-Methylcyclohexane Methanol s Location Date Time Lab 4- methylcyclohexane 46 µg/l , /11/14 19:28 ALS methanol MacCorkle Ave We have also included other significant and worrisome results in Table 4. We identified arsenic at a level greater than the EPA and West Virginia drinking water standards. Though Fields Creek is not directly upstream of any drinking water intakes, the creek does run directly through a residential neighborhood, where residents come in contact with the water in other way fishing, wading and using the water for domestic purposes. Beryllium and iron were also found at a level above West Virginia s drinking water standards. Lead was found at level greater that the EPA primary drinking water standard, as well as the EPA fresh water chronic standard. Chromium and iron were found at a level exceeding West Virginia s chronic warm water fishery and wetland aquatic life standard. Selenium was found at levels exceeding the West Virginia and EPA fresh water chronic standard.

4 Table 4: Other Significant s Location Date Time Lab Arsenic 11.7 µg/l , /11/14 16:11 Pace Analytical CR77/1 Near Plant Beryllium 2.5 µg/l , /12/14 13:56 Pace Analytical CR77/1 Near Plant Chromium 12 µg/l , CR77/1 Near Plant 2/11/14 16:11 Pace Analytical Chromium µg/l , MacCorkle Ave 2/11/14 15:18 Pace Analytical Lead 26.3 µg/l , /11/14 16:11 Pace Analytical CR77/1 Near Plant Lead 14.5 µg/l , /11/14 15:18 Pace Analytical MacCorkle Ave Selenium 11.3 µg/l , /11/14 16:11 Pace Analytical CR77/1 Near Plant Selenium 5.4 µg/l , /11/14 15:18 Pace Analytical MacCorkle Ave Selenium 10.3 µg/l , CR77/1 Near Plant 2/12/14 13:56 Pace Analytical Given the above results, and any additional results the DEP may have obtained during its investigation of the spill, we would like to see Patriot Coal fined as fully as allowable by law. Unfortunately, no amount of money can undo the damage done to Fields Creek, but we believe that strong enforcement of existing laws by the DEP and DMR will go a long way in preventing future spills. We recommend the following to better the agency s response to black water events in the future: 1. Test for all parameters included on discharge permits at the responsible facility 2. Test for any additional chemicals that may be present, which may pose a threat to aquatic or human life 3. Take the necessary steps to ensure that the DEP can obtain accurate and timely information about spilled substances 4. Be forthcoming to the public with any and all available information regarding chemicals spilled, amount spilled, locations impacted, possible impacts, etc. 5. Require facilities that create and dispose of coal slurry to monitor for all parameters and chemicals that exist in the coal slurry by including all parameters in the Article 3 permit monitoring requirements and discharge monitoring reports 6. Require testing of all coal slurry chemicals and parameters during discharges of discolored water

5 The violations issued by DEP thus far for Kanawha Eagle Coal facility address the cleanup of this coal slurry spill, and make some effort at preventing further spills at that facility. We believe the above steps, along with sufficiently large fines, will go further in preventing such spills across the industry as a whole. Sincerely, Erin Savage Water Quality Specialist Appalachian Voices Rob Goodwin Citizen Enforcement Specialist Coal River Mountain Watch

6 #=CL# LI USE: FR - ERIN SAVAGE LI OBJECT ID: February 28, 2014 Ms. Erin Savage Appalachian Voices 171 Grand Blvd. Boone, NC RE: Dear Ms. Savage: Enclosed are the analytical results for sample(s) received by the laboratory on February 17, The results relate only to the samples included in this report. s reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Lorri Patton lorri.patton@pacelabs.com Project Manager Enclosures without the written consent of. Page 1 of 37

7 #=CP# CERTIFICATIONS Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL Alabama Certification #: Arizona Certification #: AZ0735 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E Kentucky Certification #: Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: Maine Certification #: FL01264 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Asheville Certification IDs, Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: Mississippi Certification: FL NELAC Reciprocity Montana Certification #: Cert 0074 Nebraska Certification: NE-OS Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: North Carolina Environmental Certificate #: 667 North Carolina Certification #: Pennsylvania Certification #: Puerto Rico Certification #: FL01264 South Carolina Certification: # Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: Wyoming (EPA Region 8): FL NELAC Reciprocity North Carolina Wastewater Certification #: 40 South Carolina Certification #: West Virginia Certification #: 356 Virginia/VELAP Certification #: without the written consent of. Page 2 of 37

8 #=SA# SAMPLE ANALYTE COUNT Lab ID Sample ID Method Analysts Analytes Reported Laboratory SM 2540D WMW 1 PASI-O EPA JMW 28 PASI-A EPA JMW 28 PASI-A EPA HEA 1 PASI-O EPA JLR 4 PASI-O EPA 8260 SK 55 PASI-O SM 2540D WMW 1 PASI-O EPA JMW 28 PASI-A EPA JMW 28 PASI-A EPA HEA 1 PASI-O EPA JLR 4 PASI-O EPA 8260 SK 55 PASI-O EPA JMW 28 PASI-A EPA SAE 1 PASI-A without the written consent of. Page 3 of 37

9 #=AR# ANALYTICAL RESULTS Sample: Lab ID: 001 Collected: 02/11/14 15:18 Received: 02/17/14 11:00 Matrix: Water s s Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 806 mg/l /18/14 02:45 without the written consent of. Page 4 of 37

10 #=AR# ANALYTICAL RESULTS Sample: Lab ID: 002 Collected: 02/11/14 15:18 Received: 02/17/14 11:00 Matrix: Water s s Report Limit DF Prepared Analyzed CAS No. Qual MET ICP, Lab Filtered Analytical Method: EPA Preparation Method: EPA Aluminum, Dissolved 226 ug/l /20/14 11:40 02/20/14 20: Antimony, Dissolved 5.2 ug/l /20/14 11:40 02/20/14 20: Arsenic, Dissolved ug/l /20/14 11:40 02/20/14 20: Barium, Dissolved 75.1 ug/l /20/14 11:40 02/20/14 20: Beryllium, Dissolved ug/l /20/14 11:40 02/20/14 20: Boron, Dissolved ug/l /20/14 11:40 02/20/14 20: Cadmium, Dissolved ug/l /20/14 11:40 02/20/14 20: Calcium, Dissolved ug/l /20/14 11:40 02/20/14 20: Chromium, Dissolved ug/l /20/14 11:40 02/20/14 20: Cobalt, Dissolved ug/l /20/14 11:40 02/20/14 20: Copper, Dissolved ug/l /20/14 11:40 02/20/14 20: Iron, Dissolved 73.6 ug/l /20/14 11:40 02/20/14 20: Lead, Dissolved ug/l /20/14 11:40 02/20/14 20: Magnesium, Dissolved 8350 ug/l /20/14 11:40 02/20/14 20: Manganese, Dissolved 120 ug/l /20/14 11:40 02/20/14 20: Molybdenum, Dissolved ug/l /20/14 11:40 02/20/14 20: Nickel, Dissolved ug/l /20/14 11:40 02/20/14 20: Potassium, Dissolved ug/l /20/14 11:40 02/20/14 20: Selenium, Dissolved ug/l /20/14 11:40 02/20/14 20: Silicon, Dissolved 3280 ug/l /20/14 11:40 02/20/14 20: Silver, Dissolved ug/l /20/14 11:40 02/20/14 20: Sodium, Dissolved ug/l /20/14 11:40 02/20/14 20: Strontium, Dissolved 478 ug/l /20/14 11:40 02/20/14 20: Thallium, Dissolved ug/l /20/14 11:40 02/20/14 20: Tin, Dissolved ug/l /20/14 11:40 02/20/14 20: Titanium, Dissolved 5.8 ug/l /20/14 11:40 02/20/14 20: Vanadium, Dissolved ug/l /20/14 11:40 02/20/14 20: Zinc, Dissolved ug/l /20/14 11:40 02/20/14 20: without the written consent of. Page 5 of 37

11 #=AR# ANALYTICAL RESULTS Sample: Lab ID: 003 Collected: 02/11/14 15:18 Received: 02/17/14 11:00 Matrix: Water s s Report Limit DF Prepared Analyzed CAS No. Qual MET ICP Analytical Method: EPA Preparation Method: EPA Aluminum 9350 ug/l /19/14 22:35 02/20/14 19: Antimony ug/l /19/14 22:35 02/20/14 19: Arsenic ug/l /19/14 22:35 02/20/14 19: Barium 320 ug/l /19/14 22:35 02/20/14 19: Beryllium ug/l /19/14 22:35 02/20/14 19: Boron ug/l /19/14 22:35 02/20/14 19: Cadmium ug/l /19/14 22:35 02/20/14 19: Calcium ug/l /19/14 22:35 02/21/14 18: Chromium 10.9 ug/l /19/14 22:35 02/20/14 19: Cobalt 8.2 ug/l /19/14 22:35 02/20/14 19: Copper 30.3 ug/l /19/14 22:35 02/20/14 19: Iron ug/l /19/14 22:35 02/20/14 19: Lead 14.5 ug/l /19/14 22:35 02/20/14 19: Magnesium ug/l /19/14 22:35 02/20/14 19: Manganese 356 ug/l /19/14 22:35 02/20/14 19: Molybdenum ug/l /19/14 22:35 02/20/14 19: Nickel 22.3 ug/l /19/14 22:35 02/20/14 19: Potassium 6790 ug/l /19/14 22:35 02/20/14 19: Selenium ug/l /19/14 22:35 02/20/14 19: Silicon ug/l /19/14 22:35 02/21/14 18: Silver ug/l /19/14 22:35 02/20/14 19: Sodium ug/l /19/14 22:35 02/20/14 19: Strontium 576 ug/l /19/14 22:35 02/20/14 19: Thallium ug/l /19/14 22:35 02/20/14 19: Tin ug/l /19/14 22:35 02/20/14 19: Titanium 98.3 ug/l /19/14 22:35 02/20/14 19: Vanadium 15.4 ug/l /19/14 22:35 02/20/14 19: Zinc 64.8 ug/l /19/14 22:35 02/21/14 18: MET ICP Analytical Method: EPA Preparation Method: EPA Selenium 5.4 ug/l /20/14 16:37 02/21/14 09: without the written consent of. Page 6 of 37

12 #=AR# ANALYTICAL RESULTS Sample: Lab ID: 004 Collected: 02/11/14 15:18 Received: 02/17/14 11:00 Matrix: Water s s Report Limit DF Prepared Analyzed CAS No. Qual V Analytical Method: EPA Total-4-Methyl-1-Cyclohexaneme mg/l /25/14 20: N2 Surrogates 4-Bromofluorobenzene (S) 89 % /25/14 20: Toluene-d8 (S) 59 % /25/14 20: HS,S0 1,2-Dichloroethane-d4 (S) 103 % /25/14 20: V Analytical Method: EPA 8260 Acetone ug/l /21/14 21: Acetonitrile ug/l /21/14 21: Benzene ug/l /21/14 21: Bromochloromethane ug/l /21/14 21: Bromodichloromethane ug/l /21/14 21: Bromoform ug/l /21/14 21: Bromomethane ug/l /21/14 21: Butanone (MEK) ug/l /21/14 21: Carbon disulfide ug/l /21/14 21: Carbon tetrachloride ug/l /21/14 21: Chlorobenzene ug/l /21/14 21: Chloroethane ug/l /21/14 21: Chloroform ug/l /21/14 21: Chloromethane ug/l /21/14 21: L2 1,2-Dibromo-3-chloropropane ug/l /21/14 21: Dibromochloromethane ug/l /21/14 21: ,2-Dibromoethane (EDB) ug/l /21/14 21: Dibromomethane ug/l /21/14 21: ,2-Dichlorobenzene ug/l /21/14 21: ,4-Dichlorobenzene ug/l /21/14 21: trans-1,4-dichloro-2-butene ug/l /21/14 21: ,1-Dichloroethane ug/l /21/14 21: ,2-Dichloroethane ug/l /21/14 21: ,2-Dichloroethene (Total) ug/l /21/14 21: N2 1,1-Dichloroethene ug/l /21/14 21: cis-1,2-dichloroethene ug/l /21/14 21: trans-1,2-dichloroethene ug/l /21/14 21: ,2-Dichloropropane ug/l /21/14 21: cis-1,3-dichloropropene ug/l /21/14 21: trans-1,3-dichloropropene ug/l /21/14 21: Ethylbenzene ug/l /21/14 21: Hexanone ug/l /21/14 21: Iodomethane ug/l /21/14 21: Isopropylbenzene (Cumene) ug/l /21/14 21: Methylene Chloride ug/l /21/14 21: Methyl-2-pentanone (MIBK) ug/l /21/14 21: Methyl-tert-butyl ether ug/l /21/14 21: Styrene ug/l /21/14 21: ,1,1,2-Tetrachloroethane ug/l /21/14 21: ,1,2,2-Tetrachloroethane ug/l /21/14 21: without the written consent of. Page 7 of 37

13 #=AR# ANALYTICAL RESULTS Sample: Lab ID: 004 Collected: 02/11/14 15:18 Received: 02/17/14 11:00 Matrix: Water s s Report Limit DF Prepared Analyzed CAS No. Qual 8260 V Analytical Method: EPA 8260 Tetrachloroethene ug/l /21/14 21: Toluene ug/l /21/14 21: ,1,1-Trichloroethane ug/l /21/14 21: ,1,2-Trichloroethane ug/l /21/14 21: Trichloroethene ug/l /21/14 21: Trichlorofluoromethane ug/l /21/14 21: ,2,3-Trichloropropane ug/l /21/14 21: Vinyl acetate ug/l /21/14 21: Vinyl chloride ug/l /21/14 21: Xylene (Total) ug/l /21/14 21: m&p-xylene ug/l /21/14 21: o-xylene ug/l /21/14 21: Surrogates 4-Bromofluorobenzene (S) 99 % /21/14 21: ,2-Dichloroethane-d4 (S) 100 % /21/14 21: Toluene-d8 (S) 100 % /21/14 21: without the written consent of. Page 8 of 37

14 #=AR# ANALYTICAL RESULTS Sample: Lab ID: 005 Collected: 02/11/14 16:11 Received: 02/17/14 11:00 Matrix: Water s s Report Limit DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 770 mg/l /18/14 02:45 without the written consent of. Page 9 of 37

15 #=AR# ANALYTICAL RESULTS Sample: Lab ID: 006 Collected: 02/11/14 16:11 Received: 02/17/14 11:00 Matrix: Water s s Report Limit DF Prepared Analyzed CAS No. Qual MET ICP, Lab Filtered Analytical Method: EPA Preparation Method: EPA Aluminum, Dissolved 449 ug/l /20/14 11:40 02/20/14 20: Antimony, Dissolved 13.1 ug/l /20/14 11:40 02/20/14 20: Arsenic, Dissolved ug/l /20/14 11:40 02/20/14 20: Barium, Dissolved 56.0 ug/l /20/14 11:40 02/20/14 20: Beryllium, Dissolved ug/l /20/14 11:40 02/20/14 20: Boron, Dissolved ug/l /20/14 11:40 02/20/14 20: Cadmium, Dissolved ug/l /20/14 11:40 02/20/14 20: Calcium, Dissolved ug/l /20/14 11:40 02/20/14 20: Chromium, Dissolved ug/l /20/14 11:40 02/20/14 20: Cobalt, Dissolved ug/l /20/14 11:40 02/20/14 20: Copper, Dissolved ug/l /20/14 11:40 02/20/14 20: Iron, Dissolved 122 ug/l /20/14 11:40 02/20/14 20: Lead, Dissolved ug/l /20/14 11:40 02/20/14 20: Magnesium, Dissolved ug/l /20/14 11:40 02/20/14 20: Manganese, Dissolved 8.5 ug/l /20/14 11:40 02/20/14 20: Molybdenum, Dissolved ug/l /20/14 11:40 02/20/14 20: Nickel, Dissolved ug/l /20/14 11:40 02/20/14 20: Potassium, Dissolved 7450 ug/l /20/14 11:40 02/20/14 20: Selenium, Dissolved ug/l /20/14 11:40 02/20/14 20: Silicon, Dissolved 3360 ug/l /20/14 11:40 02/20/14 20: Silver, Dissolved ug/l /20/14 11:40 02/20/14 20: Sodium, Dissolved ug/l /20/14 11:40 02/20/14 20: Strontium, Dissolved 908 ug/l /20/14 11:40 02/20/14 20: Thallium, Dissolved ug/l /20/14 11:40 02/20/14 20: Tin, Dissolved ug/l /20/14 11:40 02/20/14 20: Titanium, Dissolved 13.6 ug/l /20/14 11:40 02/20/14 20: Vanadium, Dissolved ug/l /20/14 11:40 02/20/14 20: Zinc, Dissolved ug/l /20/14 11:40 02/20/14 20: without the written consent of. Page 10 of 37

16 #=AR# ANALYTICAL RESULTS Sample: Lab ID: 007 Collected: 02/11/14 16:11 Received: 02/17/14 11:00 Matrix: Water s s Report Limit DF Prepared Analyzed CAS No. Qual MET ICP Analytical Method: EPA Preparation Method: EPA Aluminum 8940 ug/l /19/14 22:35 02/20/14 19: Antimony 11.1 ug/l /19/14 22:35 02/20/14 19: Arsenic 11.7 ug/l /19/14 22:35 02/20/14 19: Barium 232 ug/l /19/14 22:35 02/20/14 19: Beryllium ug/l /19/14 22:35 02/20/14 19: Boron 56.2 ug/l /19/14 22:35 02/20/14 19: Cadmium ug/l /19/14 22:35 02/20/14 19: Calcium ug/l /19/14 22:35 02/21/14 18: Chromium 12.0 ug/l /19/14 22:35 02/20/14 19: Cobalt 9.9 ug/l /19/14 22:35 02/20/14 19: Copper 29.2 ug/l /19/14 22:35 02/20/14 19: Iron ug/l /19/14 22:35 02/20/14 19: Lead 26.3 ug/l /19/14 22:35 02/20/14 19: Magnesium ug/l /19/14 22:35 02/20/14 19: Manganese 875 ug/l /19/14 22:35 02/20/14 19: Molybdenum ug/l /19/14 22:35 02/20/14 19: Nickel 20.3 ug/l /19/14 22:35 02/20/14 19: Potassium ug/l /19/14 22:35 02/20/14 19: Selenium ug/l /19/14 22:35 02/20/14 19: Silicon ug/l /19/14 22:35 02/21/14 18: Silver ug/l /19/14 22:35 02/20/14 19: Sodium ug/l /19/14 22:35 02/21/14 18: Strontium 1100 ug/l /19/14 22:35 02/20/14 19: Thallium ug/l /19/14 22:35 02/20/14 19: Tin ug/l /19/14 22:35 02/20/14 19: Titanium 128 ug/l /19/14 22:35 02/20/14 19: Vanadium 16.8 ug/l /19/14 22:35 02/20/14 19: Zinc 66.3 ug/l /19/14 22:35 02/21/14 18: MET ICP Analytical Method: EPA Preparation Method: EPA Selenium 11.3 ug/l /20/14 16:37 02/21/14 09: without the written consent of. Page 11 of 37

17 #=AR# ANALYTICAL RESULTS Sample: Lab ID: 008 Collected: 02/11/14 16:11 Received: 02/17/14 11:00 Matrix: Water s s Report Limit DF Prepared Analyzed CAS No. Qual V Analytical Method: EPA Total-4-Methyl-1-Cyclohexaneme mg/l /25/14 20: N2 Surrogates 4-Bromofluorobenzene (S) 82 % /25/14 20: Toluene-d8 (S) 59 % /25/14 20: HS,S0 1,2-Dichloroethane-d4 (S) 88 % /25/14 20: V Analytical Method: EPA 8260 Acetone ug/l /21/14 22: Acetonitrile ug/l /21/14 22: Benzene ug/l /21/14 22: Bromochloromethane ug/l /21/14 22: Bromodichloromethane ug/l /21/14 22: Bromoform ug/l /21/14 22: Bromomethane ug/l /21/14 22: Butanone (MEK) ug/l /21/14 22: Carbon disulfide ug/l /21/14 22: Carbon tetrachloride ug/l /21/14 22: Chlorobenzene ug/l /21/14 22: Chloroethane ug/l /21/14 22: Chloroform ug/l /21/14 22: Chloromethane ug/l /21/14 22: L2 1,2-Dibromo-3-chloropropane ug/l /21/14 22: Dibromochloromethane ug/l /21/14 22: ,2-Dibromoethane (EDB) ug/l /21/14 22: Dibromomethane ug/l /21/14 22: ,2-Dichlorobenzene ug/l /21/14 22: ,4-Dichlorobenzene ug/l /21/14 22: trans-1,4-dichloro-2-butene ug/l /21/14 22: ,1-Dichloroethane ug/l /21/14 22: ,2-Dichloroethane ug/l /21/14 22: ,2-Dichloroethene (Total) ug/l /21/14 22: N2 1,1-Dichloroethene ug/l /21/14 22: cis-1,2-dichloroethene ug/l /21/14 22: trans-1,2-dichloroethene ug/l /21/14 22: ,2-Dichloropropane ug/l /21/14 22: cis-1,3-dichloropropene ug/l /21/14 22: trans-1,3-dichloropropene ug/l /21/14 22: Ethylbenzene ug/l /21/14 22: Hexanone ug/l /21/14 22: Iodomethane ug/l /21/14 22: Isopropylbenzene (Cumene) ug/l /21/14 22: Methylene Chloride ug/l /21/14 22: Methyl-2-pentanone (MIBK) ug/l /21/14 22: Methyl-tert-butyl ether ug/l /21/14 22: Styrene ug/l /21/14 22: ,1,1,2-Tetrachloroethane ug/l /21/14 22: ,1,2,2-Tetrachloroethane ug/l /21/14 22: without the written consent of. Page 12 of 37

18 #=AR# ANALYTICAL RESULTS Sample: Lab ID: 008 Collected: 02/11/14 16:11 Received: 02/17/14 11:00 Matrix: Water s s Report Limit DF Prepared Analyzed CAS No. Qual 8260 V Analytical Method: EPA 8260 Tetrachloroethene ug/l /21/14 22: Toluene ug/l /21/14 22: ,1,1-Trichloroethane ug/l /21/14 22: ,1,2-Trichloroethane ug/l /21/14 22: Trichloroethene ug/l /21/14 22: Trichlorofluoromethane ug/l /21/14 22: ,2,3-Trichloropropane ug/l /21/14 22: Vinyl acetate ug/l /21/14 22: Vinyl chloride ug/l /21/14 22: Xylene (Total) ug/l /21/14 22: m&p-xylene ug/l /21/14 22: o-xylene ug/l /21/14 22: Surrogates 4-Bromofluorobenzene (S) 99 % /21/14 22: ,2-Dichloroethane-d4 (S) 98 % /21/14 22: Toluene-d8 (S) 98 % /21/14 22: without the written consent of. Page 13 of 37

19 #=AR# ANALYTICAL RESULTS Sample: Lab ID: 009 Collected: 02/12/14 13:56 Received: 02/17/14 11:00 Matrix: Water s s Report Limit DF Prepared Analyzed CAS No. Qual MET ICP Analytical Method: EPA Preparation Method: EPA Aluminum ug/l /20/14 09:15 02/21/14 16: Antimony 11.6 ug/l /20/14 09:15 02/20/14 16: Arsenic ug/l /20/14 09:15 02/20/14 16: Barium 59.1 ug/l /20/14 09:15 02/20/14 16: Beryllium 2.5 ug/l /20/14 09:15 02/20/14 16: Boron ug/l /20/14 09:15 02/20/14 16: Cadmium ug/l /20/14 09:15 02/20/14 16: Calcium ug/l /20/14 09:15 02/20/14 16: Chromium ug/l /20/14 09:15 02/20/14 16: Cobalt ug/l /20/14 09:15 02/20/14 16: Copper ug/l /20/14 09:15 02/20/14 16: Iron 2530 ug/l /20/14 09:15 02/21/14 16: Lead ug/l /20/14 09:15 02/20/14 16: Magnesium ug/l /20/14 09:15 02/20/14 16: Manganese 568 ug/l /20/14 09:15 02/21/14 16: Molybdenum ug/l /20/14 09:15 02/20/14 16: Nickel ug/l /20/14 09:15 02/20/14 16: Potassium 6220 ug/l /20/14 09:15 02/20/14 16: Selenium 10.3 ug/l /20/14 09:15 02/20/14 16: Silicon 6350 ug/l /20/14 09:15 02/20/14 16: Silver ug/l /20/14 09:15 02/20/14 16: Sodium ug/l /20/14 09:15 02/21/14 16: Strontium 920 ug/l /20/14 09:15 02/20/14 16: Thallium ug/l /20/14 09:15 02/20/14 16: Tin ug/l /20/14 09:15 02/20/14 16: Titanium 44.0 ug/l /20/14 09:15 02/20/14 16: Vanadium ug/l /20/14 09:15 02/20/14 16: Zinc 39.0 ug/l /20/14 09:15 02/21/14 16: IC Anions 28 Days Analytical Method: EPA Sulfate 103 mg/l /25/14 11: without the written consent of. Page 14 of 37

20 #=QC# QUALITY CONTROL DATA QC Batch: QC Batch Method: MPRP/15264 EPA Associated Lab Samples: 003, 007 Analysis Method: Analysis Description: EPA MET METHOD BLANK: Associated Lab Samples: 003, 007 Blank Matrix: Water Reporting Limit Analyzed Aluminum ug/l /20/14 17:31 Antimony ug/l /20/14 17:31 Arsenic ug/l /20/14 17:31 Barium ug/l /20/14 17:31 Beryllium ug/l /20/14 17:31 Boron ug/l /20/14 17:31 Cadmium ug/l /20/14 17:31 Calcium ug/l /21/14 15:08 Chromium ug/l /20/14 17:31 Cobalt ug/l /20/14 17:31 Copper ug/l /20/14 17:31 Iron ug/l /20/14 17:31 Lead ug/l /20/14 17:31 Magnesium ug/l /20/14 17:31 Manganese ug/l /20/14 17:31 Molybdenum ug/l /20/14 17:31 Nickel ug/l /20/14 17:31 Potassium ug/l /20/14 17:31 Selenium ug/l /20/14 17:31 Silicon ug/l /20/14 17:31 Silver ug/l /20/14 17:31 Sodium ug/l /20/14 17:31 Strontium ug/l /20/14 17:31 Thallium ug/l /20/14 17:31 Tin ug/l /20/14 17:31 Titanium ug/l /20/14 17:31 Vanadium ug/l /20/14 17:31 Zinc ug/l /21/14 15:08 LABORATORY CONTROL SAMPLE: Spike Conc. LCS LCS Limits Aluminum ug/l Antimony ug/l Arsenic ug/l Barium ug/l Beryllium ug/l Boron ug/l Cadmium ug/l Calcium ug/l Chromium ug/l without the written consent of. Page 15 of 37

21 #=QC# QUALITY CONTROL DATA LABORATORY CONTROL SAMPLE: Spike Conc. LCS LCS Limits Cobalt ug/l Copper ug/l Iron ug/l Lead ug/l Magnesium ug/l Manganese ug/l Molybdenum ug/l Nickel ug/l Potassium ug/l J Selenium ug/l Silicon ug/l Silver ug/l Sodium ug/l Strontium ug/l Thallium ug/l Tin ug/l Titanium ug/l Vanadium ug/l Zinc ug/l MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Spike Conc. D Spike Conc D D Limits RPD Aluminum ug/l Antimony ug/l M6 Arsenic ug/l Barium ug/l Beryllium ug/l Boron ug/l Cadmium ug/l Calcium ug/l Chromium ug/l Cobalt ug/l Copper ug/l Iron ug/l Lead ug/l Magnesium ug/l Manganese ug/l Molybdenum ug/l M1 Nickel ug/l M6 Potassium ug/l Selenium ug/l Silicon ug/l M6 Silver ug/l Sodium ug/l J J M6 Strontium ug/l Qual without the written consent of. Page 16 of 37

22 #=QC# QUALITY CONTROL DATA MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Spike Conc. D Spike Conc D D Limits RPD Thallium ug/l Tin ug/l M6 Titanium ug/l Vanadium ug/l Zinc ug/l M6 Qual MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Spike Conc. D Spike Conc D D Limits RPD Aluminum ug/l mg/l Antimony ug/l Arsenic ug/l Barium ug/l Beryllium ug/l Boron ug/l M1 Cadmium ug/l mg/l Calcium ug/l Chromium ug/l Cobalt ug/l Copper ug/l mg/l Iron ug/l mg/l Lead ug/l mg/l Magnesium ug/l Manganese ug/l mg/l Molybdenum ug/l Nickel ug/l Potassium ug/l Selenium ug/l Silicon ug/l Silver ug/l Sodium ug/l M1 Strontium ug/l Thallium ug/l Tin ug/l Titanium ug/l Vanadium ug/l Zinc ug/l 1.4 mg/l Qual without the written consent of. Page 17 of 37

23 #=QC# QUALITY CONTROL DATA QC Batch: QC Batch Method: MPRP/15265 EPA Associated Lab Samples: 009 Analysis Method: Analysis Description: EPA MET METHOD BLANK: Associated Lab Samples: 009 Blank Matrix: Water Reporting Limit Analyzed Aluminum ug/l /20/14 15:47 Antimony ug/l /20/14 15:47 Arsenic ug/l /20/14 15:47 Barium ug/l /20/14 15:47 Beryllium ug/l /20/14 15:47 Boron ug/l /20/14 15:47 Cadmium ug/l /20/14 15:47 Calcium ug/l /20/14 15:47 Chromium ug/l /20/14 15:47 Cobalt ug/l /20/14 15:47 Copper ug/l /20/14 15:47 Iron ug/l /21/14 15:24 Lead ug/l /20/14 15:47 Magnesium ug/l /20/14 15:47 Manganese ug/l /21/14 15:24 Molybdenum ug/l /20/14 15:47 Nickel ug/l /20/14 15:47 Potassium ug/l /20/14 15:47 Selenium ug/l /20/14 15:47 Silicon ug/l /20/14 15:47 Silver ug/l /20/14 15:47 Sodium ug/l /20/14 15:47 Strontium ug/l /20/14 15:47 Thallium ug/l /20/14 15:47 Tin ug/l /20/14 15:47 Titanium ug/l /20/14 15:47 Vanadium ug/l /20/14 15:47 Zinc ug/l /21/14 15:24 LABORATORY CONTROL SAMPLE: Spike Conc. LCS LCS Limits Aluminum ug/l Antimony ug/l Arsenic ug/l Barium ug/l Beryllium ug/l Boron ug/l Cadmium ug/l Calcium ug/l Chromium ug/l without the written consent of. Page 18 of 37

24 #=QC# QUALITY CONTROL DATA LABORATORY CONTROL SAMPLE: Spike Conc. LCS LCS Limits Cobalt ug/l Copper ug/l Iron ug/l Lead ug/l Magnesium ug/l Manganese ug/l Molybdenum ug/l Nickel ug/l Potassium ug/l Selenium ug/l Silicon ug/l Silver ug/l Sodium ug/l Strontium ug/l Thallium ug/l Tin ug/l Titanium ug/l Vanadium ug/l Zinc ug/l MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Spike Conc. D Spike Conc D D Limits RPD Aluminum ug/l M1 Antimony ug/l Arsenic ug/l Barium ug/l Beryllium ug/l Boron ug/l Cadmium ug/l Calcium ug/l M1 Chromium ug/l Cobalt ug/l Copper ug/l M1,R1 Iron ug/l Lead ug/l Magnesium ug/l Manganese ug/l Molybdenum ug/l Nickel ug/l Potassium ug/l Selenium ug/l Silicon ug/l M1 Silver ug/l Sodium ug/l M1 Strontium ug/l Qual without the written consent of. Page 19 of 37

25 #=QC# QUALITY CONTROL DATA MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Spike Conc. D Spike Conc D D Limits RPD Thallium ug/l M1 Tin ug/l Titanium ug/l M1 Vanadium ug/l Zinc ug/l M1,R1 Qual MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Spike Conc. D Spike Conc D D Limits RPD Aluminum ug/l Antimony ug/l mg/l Arsenic ug/l Barium ug/l Beryllium ug/l Boron ug/l Cadmium ug/l Calcium ug/l M1 Chromium ug/l Cobalt ug/l Copper ug/l Iron ug/l Lead ug/l Magnesium ug/l Manganese ug/l Molybdenum ug/l Nickel ug/l Potassium ug/l Selenium ug/l Silicon ug/l Silver ug/l Sodium ug/l M1 0 Strontium ug/l M1 Thallium ug/l Tin ug/l Titanium ug/l Vanadium ug/l Zinc ug/l Qual without the written consent of. Page 20 of 37

26 #=QC# QUALITY CONTROL DATA QC Batch: QC Batch Method: MPRP/15273 EPA Associated Lab Samples: 002, 006 Analysis Method: Analysis Description: EPA MET Dissolved METHOD BLANK: Associated Lab Samples: 002, 006 Blank Matrix: Water Reporting Limit Analyzed Aluminum, Dissolved ug/l /20/14 20:03 Antimony, Dissolved ug/l /20/14 20:03 Arsenic, Dissolved ug/l /20/14 20:03 Barium, Dissolved ug/l /20/14 20:03 Beryllium, Dissolved ug/l /20/14 20:03 Boron, Dissolved ug/l /20/14 20:03 Cadmium, Dissolved ug/l /20/14 20:03 Calcium, Dissolved ug/l /20/14 20:03 Chromium, Dissolved ug/l /20/14 20:03 Cobalt, Dissolved ug/l /20/14 20:03 Copper, Dissolved ug/l /20/14 20:03 Iron, Dissolved ug/l /20/14 20:03 Lead, Dissolved ug/l /20/14 20:03 Magnesium, Dissolved ug/l /20/14 20:03 Manganese, Dissolved ug/l /20/14 20:03 Molybdenum, Dissolved ug/l /20/14 20:03 Nickel, Dissolved ug/l /20/14 20:03 Potassium, Dissolved ug/l /20/14 20:03 Selenium, Dissolved ug/l /20/14 20:03 Silicon, Dissolved ug/l /20/14 20:03 Silver, Dissolved ug/l /20/14 20:03 Sodium, Dissolved ug/l /20/14 20:03 Strontium, Dissolved ug/l /20/14 20:03 Thallium, Dissolved ug/l /20/14 20:03 Tin, Dissolved ug/l /20/14 20:03 Titanium, Dissolved ug/l /20/14 20:03 Vanadium, Dissolved ug/l /20/14 20:03 Zinc, Dissolved ug/l /20/14 20:03 LABORATORY CONTROL SAMPLE: Spike Conc. LCS LCS Limits Aluminum, Dissolved ug/l Antimony, Dissolved ug/l Arsenic, Dissolved ug/l Barium, Dissolved ug/l Beryllium, Dissolved ug/l Boron, Dissolved ug/l Cadmium, Dissolved ug/l Calcium, Dissolved ug/l Chromium, Dissolved ug/l without the written consent of. Page 21 of 37

27 #=QC# QUALITY CONTROL DATA LABORATORY CONTROL SAMPLE: Spike Conc. LCS LCS Limits Cobalt, Dissolved ug/l Copper, Dissolved ug/l Iron, Dissolved ug/l Lead, Dissolved ug/l Magnesium, Dissolved ug/l Manganese, Dissolved ug/l Molybdenum, Dissolved ug/l Nickel, Dissolved ug/l Potassium, Dissolved ug/l J Selenium, Dissolved ug/l Silicon, Dissolved ug/l Silver, Dissolved ug/l Sodium, Dissolved ug/l J Strontium, Dissolved ug/l Thallium, Dissolved ug/l Tin, Dissolved ug/l Titanium, Dissolved ug/l Vanadium, Dissolved ug/l Zinc, Dissolved ug/l MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Spike Conc. D Spike Conc D D Limits RPD Aluminum, Dissolved ug/l Antimony, Dissolved ug/l Arsenic, Dissolved ug/l Barium, Dissolved ug/l Beryllium, Dissolved ug/l Boron, Dissolved ug/l Cadmium, Dissolved ug/l Calcium, Dissolved ug/l Chromium, Dissolved ug/l Cobalt, Dissolved ug/l Copper, Dissolved ug/l Iron, Dissolved ug/l Lead, Dissolved ug/l Magnesium, Dissolved ug/l Manganese, Dissolved ug/l Molybdenum, Dissolved ug/l Nickel, Dissolved ug/l Potassium, Dissolved ug/l Selenium, Dissolved ug/l Silicon, Dissolved ug/l Silver, Dissolved ug/l Sodium, Dissolved ug/l Strontium, Dissolved ug/l Qual without the written consent of. Page 22 of 37

28 #=QC# QUALITY CONTROL DATA MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Spike Conc. D Spike Conc D D Limits RPD Thallium, Dissolved ug/l Tin, Dissolved ug/l Titanium, Dissolved ug/l Vanadium, Dissolved ug/l Zinc, Dissolved ug/l Qual without the written consent of. Page 23 of 37

29 #=QC# QUALITY CONTROL DATA QC Batch: QC Batch Method: MPRP/17155 EPA Associated Lab Samples: 003, 007 Analysis Method: Analysis Description: EPA MET METHOD BLANK: Associated Lab Samples: 003, 007 Blank Matrix: Water Reporting Limit Analyzed Selenium ug/l /21/14 09:33 LABORATORY CONTROL SAMPLE: Spike Conc. LCS LCS Limits Selenium ug/l MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Spike Conc. D Spike Conc D D Limits RPD Selenium ug/l Qual without the written consent of. Page 24 of 37

30 #=QC# QUALITY CONTROL DATA QC Batch: QC Batch Method: V/10971 EPA Associated Lab Samples: 004, 008 Analysis Method: Analysis Description: EPA V METHOD BLANK: Associated Lab Samples: Blank Matrix: Water Reporting Limit Analyzed Total-4-Methyl-1-Cyclohexaneme mg/l /25/14 19:50 N2 1,2-Dichloroethane-d4 (S) % /25/14 19:50 4-Bromofluorobenzene (S) % /25/14 19:50 Toluene-d8 (S) % /25/14 19:50 S0 LABORATORY CONTROL SAMPLE & LCSD: Spike Conc LCS LCSD LCS LCSD Limits RPD Total-4-Methyl-1-Cyclohexaneme mg/l N2 1,2-Dichloroethane-d4 (S) % Bromofluorobenzene (S) % Toluene-d8 (S) % S0 Max RPD without the written consent of. Page 25 of 37

31 #=QC# QUALITY CONTROL DATA QC Batch: QC Batch Method: V/10913 EPA 8260 Associated Lab Samples: 004, 008 Analysis Method: Analysis Description: EPA V METHOD BLANK: Associated Lab Samples: Blank Matrix: Water Reporting Limit Analyzed 1,1,1,2-Tetrachloroethane ug/l /21/14 13:10 1,1,1-Trichloroethane ug/l /21/14 13:10 1,1,2,2-Tetrachloroethane ug/l /21/14 13:10 1,1,2-Trichloroethane ug/l /21/14 13:10 1,1-Dichloroethane ug/l /21/14 13:10 1,1-Dichloroethene ug/l /21/14 13:10 1,2,3-Trichloropropane ug/l /21/14 13:10 1,2-Dibromo-3-chloropropane ug/l /21/14 13:10 1,2-Dibromoethane (EDB) ug/l /21/14 13:10 1,2-Dichlorobenzene ug/l /21/14 13:10 1,2-Dichloroethane ug/l /21/14 13:10 1,2-Dichloroethene (Total) ug/l /21/14 13:10 N2 1,2-Dichloropropane ug/l /21/14 13:10 1,4-Dichlorobenzene ug/l /21/14 13:10 2-Butanone (MEK) ug/l /21/14 13:10 2-Hexanone ug/l /21/14 13:10 4-Methyl-2-pentanone (MIBK) ug/l /21/14 13:10 Acetone ug/l /21/14 13:10 Acetonitrile ug/l /21/14 13:10 Benzene ug/l /21/14 13:10 Bromochloromethane ug/l /21/14 13:10 Bromodichloromethane ug/l /21/14 13:10 Bromoform ug/l /21/14 13:10 Bromomethane ug/l /21/14 13:10 Carbon disulfide ug/l /21/14 13:10 Carbon tetrachloride ug/l /21/14 13:10 Chlorobenzene ug/l /21/14 13:10 Chloroethane ug/l /21/14 13:10 Chloroform ug/l /21/14 13:10 Chloromethane ug/l /21/14 13:10 cis-1,2-dichloroethene ug/l /21/14 13:10 cis-1,3-dichloropropene ug/l /21/14 13:10 Dibromochloromethane ug/l /21/14 13:10 Dibromomethane ug/l /21/14 13:10 Ethylbenzene ug/l /21/14 13:10 Iodomethane ug/l /21/14 13:10 Isopropylbenzene (Cumene) ug/l /21/14 13:10 m&p-xylene ug/l /21/14 13:10 Methyl-tert-butyl ether ug/l /21/14 13:10 Methylene Chloride ug/l /21/14 13:10 o-xylene ug/l /21/14 13:10 Styrene ug/l /21/14 13:10 Tetrachloroethene ug/l /21/14 13:10 without the written consent of. Page 26 of 37

32 #=QC# QUALITY CONTROL DATA METHOD BLANK: Associated Lab Samples: Blank Matrix: Water Reporting Limit Analyzed Toluene ug/l /21/14 13:10 trans-1,2-dichloroethene ug/l /21/14 13:10 trans-1,3-dichloropropene ug/l /21/14 13:10 trans-1,4-dichloro-2-butene ug/l /21/14 13:10 Trichloroethene ug/l /21/14 13:10 Trichlorofluoromethane ug/l /21/14 13:10 Vinyl acetate ug/l /21/14 13:10 Vinyl chloride ug/l /21/14 13:10 Xylene (Total) ug/l /21/14 13:10 1,2-Dichloroethane-d4 (S) % /21/14 13:10 4-Bromofluorobenzene (S) % /21/14 13:10 Toluene-d8 (S) % /21/14 13:10 LABORATORY CONTROL SAMPLE: Spike Conc. LCS LCS Limits 1,1,1,2-Tetrachloroethane ug/l ,1,1-Trichloroethane ug/l ,1,2,2-Tetrachloroethane ug/l ,1,2-Trichloroethane ug/l ,1-Dichloroethane ug/l ,1-Dichloroethene ug/l ,2,3-Trichloropropane ug/l ,2-Dibromo-3-chloropropane ug/l ,2-Dibromoethane (EDB) ug/l ,2-Dichlorobenzene ug/l ,2-Dichloroethane ug/l ,2-Dichloroethene (Total) ug/l N2 1,2-Dichloropropane ug/l ,4-Dichlorobenzene ug/l Butanone (MEK) ug/l Hexanone ug/l Methyl-2-pentanone (MIBK) ug/l Acetone ug/l Acetonitrile ug/l Benzene ug/l Bromochloromethane ug/l Bromodichloromethane ug/l Bromoform ug/l Bromomethane ug/l Carbon disulfide ug/l Carbon tetrachloride ug/l Chlorobenzene ug/l Chloroethane ug/l Chloroform ug/l without the written consent of. Page 27 of 37

33 #=QC# QUALITY CONTROL DATA LABORATORY CONTROL SAMPLE: Spike Conc. LCS LCS Limits Chloromethane ug/l L0 cis-1,2-dichloroethene ug/l cis-1,3-dichloropropene ug/l Dibromochloromethane ug/l Dibromomethane ug/l Ethylbenzene ug/l Iodomethane ug/l Isopropylbenzene (Cumene) ug/l m&p-xylene ug/l Methyl-tert-butyl ether ug/l Methylene Chloride ug/l o-xylene ug/l Styrene ug/l Tetrachloroethene ug/l Toluene ug/l trans-1,2-dichloroethene ug/l trans-1,3-dichloropropene ug/l trans-1,4-dichloro-2-butene ug/l Trichloroethene ug/l Trichlorofluoromethane ug/l Vinyl acetate ug/l Vinyl chloride ug/l Xylene (Total) ug/l ,2-Dichloroethane-d4 (S) % Bromofluorobenzene (S) % Toluene-d8 (S) % MATRIX SPIKE SAMPLE: Spike Conc. 1,1,1,2-Tetrachloroethane ug/l 0.50U ,1,1-Trichloroethane ug/l 0.50U ,1,2,2-Tetrachloroethane ug/l 0.12U ,1,2-Trichloroethane ug/l 0.50U ,1-Dichloroethane ug/l 0.50U ,1-Dichloroethene ug/l 0.50U ,2,3-Trichloropropane ug/l 0.36U ,2-Dibromo-3-chloropropane ug/l 1.0U ,2-Dibromoethane (EDB) ug/l 0.50U ,2-Dichlorobenzene ug/l 0.50U ,2-Dichloroethane ug/l 0.50U ,2-Dichloroethene (Total) ug/l 0.50U N2 1,2-Dichloropropane ug/l 0.50U ,4-Dichlorobenzene ug/l 0.51J Butanone (MEK) ug/l 5.0U Hexanone ug/l 5.0U Methyl-2-pentanone (MIBK) ug/l 5.0U Limits without the written consent of. Page 28 of 37

34 #=QC# QUALITY CONTROL DATA MATRIX SPIKE SAMPLE: Spike Conc. Limits Acetone ug/l 10.0U Acetonitrile ug/l 5.0U Benzene ug/l 0.10U Bromochloromethane ug/l 0.50U Bromodichloromethane ug/l 0.27U Bromoform ug/l 0.50U Bromomethane ug/l 0.50U Carbon disulfide ug/l 5.0U Carbon tetrachloride ug/l 0.50U Chlorobenzene ug/l 0.50U Chloroethane ug/l 0.50U Chloroform ug/l 0.50U Chloromethane ug/l 0.62U cis-1,2-dichloroethene ug/l 0.50U cis-1,3-dichloropropene ug/l 0.25U Dibromochloromethane ug/l 0.26U Dibromomethane ug/l 0.50U Ethylbenzene ug/l 0.50U Iodomethane ug/l 0.50U Isopropylbenzene (Cumene) ug/l 0.50U m&p-xylene ug/l 0.50U Methyl-tert-butyl ether ug/l 0.50U Methylene Chloride ug/l 2.5U o-xylene ug/l 0.50U Styrene ug/l 0.50U Tetrachloroethene ug/l 0.50U Toluene ug/l 0.50U trans-1,2-dichloroethene ug/l 0.50U trans-1,3-dichloropropene ug/l 0.25U trans-1,4-dichloro-2-butene ug/l 5.0U J Trichloroethene ug/l 0.50U Trichlorofluoromethane ug/l 0.50U Vinyl acetate ug/l 1.0U Vinyl chloride ug/l 0.50U Xylene (Total) ug/l 0.50U ,2-Dichloroethane-d4 (S) % Bromofluorobenzene (S) % Toluene-d8 (S) % SAMPLE DUPLICATE: Dup 1,1,1,2-Tetrachloroethane ug/l 0.50U 1,1,1-Trichloroethane ug/l 0.50U 1,1,2,2-Tetrachloroethane ug/l 0.12U 1,1,2-Trichloroethane ug/l 0.50U 1,1-Dichloroethane ug/l 0.50U RPD without the written consent of. Page 29 of 37

35 #=QC# QUALITY CONTROL DATA SAMPLE DUPLICATE: Dup 1,1-Dichloroethene ug/l 0.50U 1,2,3-Trichloropropane ug/l 0.36U 1,2-Dibromo-3-chloropropane ug/l 1.0U 1,2-Dibromoethane (EDB) ug/l 0.50U 1,2-Dichlorobenzene ug/l 0.50U 1,2-Dichloroethane ug/l 0.50U 1,2-Dichloroethene (Total) ug/l 0.50U N2 1,2-Dichloropropane ug/l 0.50U 1,4-Dichlorobenzene ug/l 0.50U 2-Butanone (MEK) ug/l 5.0U 2-Hexanone ug/l 5.0U 4-Methyl-2-pentanone (MIBK) ug/l 5.0U Acetone ug/l 10.0U Acetonitrile ug/l 5.0U Benzene ug/l 0.10U Bromochloromethane ug/l 0.50U Bromodichloromethane ug/l 0.27U Bromoform ug/l 0.50U Bromomethane ug/l 0.50U Carbon disulfide ug/l 5.0U Carbon tetrachloride ug/l 0.50U Chlorobenzene ug/l 0.50U Chloroethane ug/l 0.50U Chloroform ug/l 0.50U Chloromethane ug/l 0.62U cis-1,2-dichloroethene ug/l 0.50U cis-1,3-dichloropropene ug/l 0.25U Dibromochloromethane ug/l 0.26U Dibromomethane ug/l 0.50U Ethylbenzene ug/l 0.50U Iodomethane ug/l 0.50U Isopropylbenzene (Cumene) ug/l 0.50U m&p-xylene ug/l 0.50U Methyl-tert-butyl ether ug/l 0.50U Methylene Chloride ug/l 2.5U o-xylene ug/l 0.50U Styrene ug/l 0.50U Tetrachloroethene ug/l 0.50U Toluene ug/l 0.50U trans-1,2-dichloroethene ug/l 0.50U trans-1,3-dichloropropene ug/l 0.25U trans-1,4-dichloro-2-butene ug/l 5.0U Trichloroethene ug/l 0.50U Trichlorofluoromethane ug/l 0.50U Vinyl acetate ug/l 1.0U Vinyl chloride ug/l 0.50U Xylene (Total) ug/l 0.50U 1,2-Dichloroethane-d4 (S) % RPD without the written consent of. Page 30 of 37

36 #=QC# QUALITY CONTROL DATA SAMPLE DUPLICATE: Dup 4-Bromofluorobenzene (S) % Toluene-d8 (S) % RPD without the written consent of. Page 31 of 37

37 #=QC# QUALITY CONTROL DATA QC Batch: QC Batch Method: WET/23490 SM 2540D Associated Lab Samples: 001, 005 Analysis Method: Analysis Description: SM 2540D 2540D Total Suspended Solids METHOD BLANK: Associated Lab Samples: Blank Matrix: Water Reporting Limit Analyzed Total Suspended Solids mg/l /18/14 02:45 LABORATORY CONTROL SAMPLE: Spike Conc. LCS LCS Limits Total Suspended Solids mg/l SAMPLE DUPLICATE: Dup Total Suspended Solids mg/l D6 RPD SAMPLE DUPLICATE: Dup Total Suspended Solids mg/l RPD without the written consent of. Page 32 of 37

38 #=QC# QUALITY CONTROL DATA QC Batch: QC Batch Method: WETA/18118 EPA Associated Lab Samples: 009 Analysis Method: Analysis Description: EPA IC Anions METHOD BLANK: Associated Lab Samples: 009 Blank Matrix: Water Reporting Limit Analyzed Sulfate mg/l /24/14 16:11 LABORATORY CONTROL SAMPLE: Spike Conc. LCS LCS Limits Sulfate mg/l MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Spike Conc. D Spike Conc D D Limits RPD Sulfate mg/l Qual MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Spike Conc. D Spike Conc D D Limits RPD Sulfate mg/l Qual without the written consent of. Page 33 of 37

39 #=QL# QUALIFIERS DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PRL - Pace Reporting Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) (D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A PASI-O Pace Analytical Services - Asheville Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS D6 HS L0 L2 M1 M6 N2 R1 S0 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. s are from sample aliquot taken from VOA vial with headspace (air bubble greater than 6 mm diameter). Analyte recovery in the laboratory control sample (LCS) was outside QC limits. Analyte recovery in the laboratory control sample (LCS) was below QC limits. s for this analyte in associated samples may be biased low. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. The lab does not hold TNI accreditation for this parameter. RPD value was outside control limits. Surrogate recovery outside laboratory control limits. without the written consent of. Page 34 of 37

40 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch EPA MPRP/15264 EPA ICP/ EPA MPRP/15264 EPA ICP/ EPA MPRP/15265 EPA ICP/ EPA MPRP/15273 EPA ICP/ EPA MPRP/15273 EPA ICP/ EPA MPRP/17155 EPA ICPM/ EPA MPRP/17155 EPA ICPM/ EPA V/ EPA V/ EPA 8260 V/ EPA 8260 V/ SM 2540D WET/ SM 2540D WET/ EPA WETA/18118 without the written consent of. Page 35 of 37

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43 21-Feb-2014 Erin Savage Appalachian Voices 171 Grand Blvd Boone, NC Re: Water Sampling W ork Order: Dear Erin, ALS Environmental received 3 samples on 12-Feb :45 AM for the analyses presented in the following report. The analytical data provided relates directly to the samples received by ALS Environmental and for only the analyses requested. Sample results are compliant with NELAP standard requirements and QC results achieved laboratory specifications. Any exceptions are noted in the Case Narrative, or noted with qualifiers in the report or QC batch information. Should this laboratory report need to be reproduced, it should be reproduced in full unless written approval has been obtained from ALS Environmental. Samples will be disposed in 30 days unless storage arrangements are made. The total number of pages in this report is 11. If you have any questions regarding this report, please feel free to contact me. Sincerely, Rebecca Kiser Electronically approved by: Rebecca Kiser Rebecca Kiser Project Manager Certificate No: MN Report of Laboratory Analysis ADDRESS th Avenue Holland, Michigan PHONE (616) FAX (616) ALS GROUP USA, CORP Part of the ALS Laboratory Group A Campbell Brothers Limited Company