ANALYTICAL REPORT. Job Number: Job Description: CETCO - DK033009

Transcription

1 ANALYTICAL REPORT Job Description: CETCO - DK For: Cetco Environmental 2870 Forbs Avenue Hoffman Estates, IL Attention: Dave Kotloski Margaret Kniest Project Manager II margaret.kniest@testamericainc.com 04/03/2009 Approved for release. Margaret Kniest Project Manager II 4/3/2009 3:41 PM These test results meet all the requirements of NELAC for accredited parameters. The Lab Certification ID# is All questions regarding this test report should be directed to the TestAmerica Project Manager whose signature appears on this report. All pages of this report are integral parts of the analytical data. Therefore, this report should be reproduced only in its entirety. Reporting limits are adjusted for sample size used, dilutions and moisture content if applicable. TestAmerica Laboratories, Inc Bond Street, University Park, IL Tel (708) Fax (708) Page 1 of 23

2 Job Narrative 500-J Comments No additional comments. Receipt All samples were received in good condition within temperature requirements. GC/MS VOA No analytical or quality issues were noted. GC/MS Semi VOA No analytical or quality issues were noted. Metals No analytical or quality issues were noted. Organic Prep Method(s) 3510C: Due to the matrix, the initial volume(s) used for the following sample(s) deviated from the standard procedure: CPPC ( ). The reporting limits (RLs) have been adjusted proportionately. No other analytical or quality issues were noted. Page 2 of 23

3 EXECUTIVE SUMMARY - Detections Client: Cetco Environmental Lab Sample ID Client Sample ID Analyte Result / Qualifier Reporting Limit Units Method CPPC Percent Moisture Percent Solids % PercentMoisture 0.10 % PercentMoisture Page 3 of 23

4 METHOD SUMMARY Client: Cetco Environmental Description Lab Location Method Preparation Method Matrix: Solid Volatile Organic Compounds (GC/MS) TCLP Extraction Purge and Trap TAL CHI TAL CHI TAL CHI SW B SW SW B Semivolatile Compounds by Gas Chromatography/Mass Spectrometry (GC/MS) TCLP Extraction Liquid-Liquid Extraction (Separatory Funnel) TAL CHI TAL CHI TAL CHI SW C SW SW C Lab References: TAL CHI = Method References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. Page 4 of 23

5 METHOD / ANALYST SUMMARY Client: Cetco Environmental Method Analyst Analyst ID SW B SW C EPA PercentMoisture Drabek, Dave J Akcakal, Duran Boyd, Cheryl L DJD DA CLB Page 5 of 23

6 SAMPLE SUMMARY Client: Cetco Environmental Lab Sample ID Client Sample ID Client Matrix Date/Time Sampled Date/Time Received CPPC Solid 03/30/ /30/ Page 6 of 23

7 SAMPLE RESULTS Page 7 of 23

8 Dave Kotloski Cetco Environmental 2870 Forbs Avenue Hoffman Estates, IL Client Sample ID: Lab Sample ID: CPPC Date Sampled: Date Received: Client Matrix: 03/30/ /30/ Solid Analyte Result/Qualifier Unit RL Dilution Method: TCLP-8260B Date Analyzed: 04/03/ Prep Method: 5030B Date Prepared: 04/03/ Benzene ND ug/l Carbon tetrachloride ND ug/l Chlorobenzene ND ug/l Chloroform ND ug/l ,2-Dichloroethane ND ug/l ,1-Dichloroethene ND ug/l Methyl Ethyl Ketone ND ug/l Tetrachloroethene ND ug/l Trichloroethene ND ug/l Vinyl chloride ND ug/l Surrogate 1,2-Dichloroethane-d4 (Surr) Toluene-d8 (Surr) 4-Bromofluorobenzene (Surr) Dibromofluoromethane 106 % 101 % 90 % 114 % Acceptance Limits Method: TCLP-8270C Date Analyzed: 04/02/ Prep Method: 3510C Date Prepared: 04/01/ Methyl-phenol ND ug/l ,4-Dichlorobenzene ND ug/l ,4-Dinitrotoluene ND ug/l Hexachlorobenzene ND ug/l Hexachloro-1,3-butadiene ND ug/l Hexachloroethane ND ug/l Nitrobenzene ND ug/l Pentachlorophenol ND ug/l Pyridine ND ug/l ,4,5-Trichlorophenol ND ug/l ,4,6-Trichlorophenol ND ug/l & 4 Methylphenol ND ug/l Surrogate 2-Fluorophenol Phenol-d5 Nitrobenzene-d5 2-Fluorobiphenyl 2,4,6-Tribromophenol Terphenyl-d14 50 % 35 % 82 % 82 % 88 % 85 % Acceptance Limits Page 8 of 23

9 Dave Kotloski Cetco Environmental 2870 Forbs Avenue Hoffman Estates, IL Client Sample ID: Lab Sample ID: CPPC Date Sampled: Date Received: Client Matrix: 03/30/ /30/ Solid Analyte Result/Qualifier Unit RL Dilution Method: PercentMoisture Date Analyzed: 03/30/ Percent Moisture 64 % Page 9 of 23

10 QUALITY CONTROL RESULTS Page 10 of 23

11 Quality Control Results Client: Cetco Environmental QC Association Summary Report Lab Sample ID Client Sample ID Basis Client Matrix Method Prep Batch GC/MS VOA Prep Batch: LB /1-A TCLP SPLPE Leachate Blank P Solid CPPC P Solid 1311 Analysis Batch: LB /1-A TCLP SPLPE Leachate Blank P Solid 8260B LCS /5 Lab Control Spike T Water 8260B MB /4 Method Blank T Water 8260B CPPC P Solid 8260B Report Basis P = TCLP T = Total GC/MS Semi VOA Prep Batch: LB /1-B TCLP SPLPE Leachate Blank P Solid 1311 LB /2-B TCLP SPLPW Leachate Blank P Solid CPPC P Solid 1311 Prep Batch: LCS /2-A Lab Control Spike T Water 3510C MB /1-A Method Blank T Water 3510C LB /1-B TCLP SPLPE Leachate Blank P Solid 3510C LB /2-B TCLP SPLPW Leachate Blank P Solid 3510C CPPC P Solid 3510C Analysis Batch: LB /1-B TCLP SPLPE Leachate Blank P Solid 8270C LB /2-B TCLP SPLPW Leachate Blank P Solid 8270C LCS /2-A Lab Control Spike T Water 8270C MB /1-A Method Blank T Water 8270C CPPC P Solid 8270C Report Basis P = TCLP T = Total Page 11 of 23

12 Quality Control Results Client: Cetco Environmental QC Association Summary Report Lab Sample ID Client Sample ID Basis Client Matrix Method Prep Batch General Chemistry Analysis Batch: CPPC T Solid PercentMoisture Report Basis T = Total Page 12 of 23

13 Quality Control Results Client: Cetco Environmental Surrogate Recovery Report 8260B Volatile Organic Compounds (GC/MS) Client Matrix: Solid TCLP Lab Sample ID Client Sample ID 12DCE TOL BFB DBFM %Rec %Rec %Rec %Rec CPPC MB / LB /1-A LCS / Surrogate Acceptance Limits 12DCE = 1,2-Dichloroethane-d4 (Surr) TOL = Toluene-d8 (Surr) BFB = 4-Bromofluorobenzene (Surr) DBFM = Dibromofluoromethane Page 13 of 23

14 Quality Control Results Client: Cetco Environmental Surrogate Recovery Report 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry (GC/MS) Client Matrix: Solid TCLP Lab Sample ID Client Sample ID 2FP PHL NBZ FBP TBP TPH %Rec %Rec %Rec %Rec %Rec %Rec CPPC MB /1-A LB /1-B LB /2-B LCS /2-A Surrogate Acceptance Limits 2FP = 2-Fluorophenol PHL = Phenol-d NBZ = Nitrobenzene-d FBP = 2-Fluorobiphenyl TBP = 2,4,6-Tribromophenol TPH = Terphenyl-d Page 14 of 23

15 Quality Control Results Client: Cetco Environmental Method Blank - Batch: Method: 8260B Preparation: 5030B Lab Sample ID: MB /4 Client Matrix: Water Dilution: 1.0 Date Analyzed: 04/03/ Date Prepared: 04/03/ Analysis Batch: Prep Batch: N/A Units: ug/l Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Agilent 6890N GC N 2M0403.D 10 ml 10 ml Analyte Result Qual RL Benzene Carbon tetrachloride Chlorobenzene Chloroform 1,2-Dichloroethane 1,1-Dichloroethene Methyl Ethyl Ketone Tetrachloroethene Trichloroethene Vinyl chloride ND 1.0 ND 1.0 ND 1.0 ND 1.0 ND 1.0 ND 1.0 ND 5.0 ND 1.0 ND 1.0 ND 1.0 Surrogate % Rec Acceptance Limits 1,2-Dichloroethane-d4 (Surr) Toluene-d8 (Surr) Bromofluorobenzene (Surr) Dibromofluoromethane Calculations are performed before rounding to avoid round-off errors in calculated results. Page 15 of 23

16 Quality Control Results Client: Cetco Environmental TCLP SPLPE Leachate Blank - Batch: Lab Sample ID: LB /1-A Client Matrix: Solid Dilution: 20 Date Analyzed: 04/03/ Date Prepared: 04/03/ Date Leached: 04/02/ Analysis Batch: Prep Batch: N/A Units: ug/l Leachate Batch: Method: 8260B Preparation: 5030B TCLP Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Agilent 6890N GC N 2X0403.D 10 ml 10 ml Analyte Result Qual RL Benzene Carbon tetrachloride Chlorobenzene Chloroform 1,2-Dichloroethane 1,1-Dichloroethene Methyl Ethyl Ketone Tetrachloroethene Trichloroethene Vinyl chloride ND 20 ND 20 ND 20 ND 20 ND 20 ND 20 ND 20 ND 20 ND 20 Surrogate % Rec Acceptance Limits 1,2-Dichloroethane-d4 (Surr) Toluene-d8 (Surr) Bromofluorobenzene (Surr) Dibromofluoromethane Calculations are performed before rounding to avoid round-off errors in calculated results. Page 16 of 23

17 Quality Control Results Client: Cetco Environmental Lab Control Spike - Batch: Method: 8260B Preparation: 5030B Lab Sample ID: LCS /5 Client Matrix: Water Dilution: 1.0 Date Analyzed: 04/03/ Date Prepared: 04/03/ Analysis Batch: Prep Batch: N/A Units: ug/l Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Agilent 6890N GC N 2S0403.D 10 ml 10 ml Analyte Spike Amount Result % Rec. Limit Qual Benzene Carbon tetrachloride Chlorobenzene Chloroform 1,2-Dichloroethane 1,1-Dichloroethene Methyl Ethyl Ketone Tetrachloroethene Trichloroethene Vinyl chloride Surrogate % Rec Acceptance Limits 1,2-Dichloroethane-d4 (Surr) Toluene-d8 (Surr) Bromofluorobenzene (Surr) Dibromofluoromethane Calculations are performed before rounding to avoid round-off errors in calculated results. Page 17 of 23

18 Quality Control Results Client: Cetco Environmental Method Blank - Batch: Method: 8270C Preparation: 3510C Lab Sample ID: MB /1-A Client Matrix: Water Dilution: 1.0 Date Analyzed: 04/02/ Date Prepared: 04/01/ Analysis Batch: Prep Batch: Units: ug/l Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Injection Volume: Agilent 6890N GC N 60748M.D 1000 ml 1.0 ml 1.0 ul Analyte Result Qual RL 2-Methyl-phenol 1,4-Dichlorobenzene 2,4-Dinitrotoluene Hexachlorobenzene Hexachloro-1,3-butadiene Hexachloroethane Nitrobenzene Pentachlorophenol Pyridine 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 3 & 4 Methylphenol ND 10 ND 10 ND 10 ND 10 ND 10 ND 10 ND 10 ND 50 ND 20 ND 50 ND 10 ND 10 Surrogate % Rec Acceptance Limits 2-Fluorophenol Phenol-d Nitrobenzene-d Fluorobiphenyl ,4,6-Tribromophenol Terphenyl-d Calculations are performed before rounding to avoid round-off errors in calculated results. Page 18 of 23

19 Quality Control Results Client: Cetco Environmental TCLP SPLPE Leachate Blank - Batch: Lab Sample ID: LB /1-B Client Matrix: Solid Dilution: 1.0 Date Analyzed: 04/02/ Date Prepared: 04/01/ Date Leached: 03/31/ Analysis Batch: Prep Batch: Units: ug/l Leachate Batch: Method: 8270C Preparation: 3510C TCLP Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Injection Volume: Agilent 6890N GC N 60699LB.D 100 ml 1.0 ml 1.0 ul Analyte Result Qual RL 2-Methyl-phenol 1,4-Dichlorobenzene 2,4-Dinitrotoluene Hexachlorobenzene Hexachloro-1,3-butadiene Hexachloroethane Nitrobenzene Pentachlorophenol Pyridine 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 3 & 4 Methylphenol ND 500 ND 200 ND 500 Surrogate % Rec Acceptance Limits 2-Fluorophenol Phenol-d Nitrobenzene-d Fluorobiphenyl ,4,6-Tribromophenol Terphenyl-d Calculations are performed before rounding to avoid round-off errors in calculated results. Page 19 of 23

20 Quality Control Results Client: Cetco Environmental TCLP SPLPW Leachate Blank - Batch: Lab Sample ID: LB /2-B Client Matrix: Solid Dilution: 1.0 Date Analyzed: 04/02/ Date Prepared: 04/01/ Date Leached: 03/31/ Analysis Batch: Prep Batch: Units: ug/l Leachate Batch: Method: 8270C Preparation: 3510C TCLP Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Injection Volume: Agilent 6890N GC N 60699LB2.D 100 ml 1.0 ml 1.0 ul Analyte Result Qual RL 2-Methyl-phenol 1,4-Dichlorobenzene 2,4-Dinitrotoluene Hexachlorobenzene Hexachloro-1,3-butadiene Hexachloroethane Nitrobenzene Pentachlorophenol Pyridine 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 3 & 4 Methylphenol ND 500 ND 200 ND 500 Surrogate % Rec Acceptance Limits 2-Fluorophenol Phenol-d Nitrobenzene-d Fluorobiphenyl ,4,6-Tribromophenol Terphenyl-d Calculations are performed before rounding to avoid round-off errors in calculated results. Page 20 of 23

21 Quality Control Results Client: Cetco Environmental Lab Control Spike - Batch: Method: 8270C Preparation: 3510C Lab Sample ID: LCS /2-A Client Matrix: Water Dilution: 1.0 Date Analyzed: 04/02/ Date Prepared: 04/01/ Analysis Batch: Prep Batch: Units: ug/l Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Injection Volume: Agilent 6890N GC N 60748BS.D 1000 ml 1.0 ml 1.0 ul Analyte Spike Amount Result % Rec. Limit Qual 2-Methyl-phenol 1,4-Dichlorobenzene 2,4-Dinitrotoluene Hexachlorobenzene Hexachloro-1,3-butadiene Hexachloroethane Nitrobenzene Pentachlorophenol Pyridine 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 3 & 4 Methylphenol ND ND Surrogate % Rec Acceptance Limits 2-Fluorophenol Phenol-d Nitrobenzene-d Fluorobiphenyl ,4,6-Tribromophenol Terphenyl-d Calculations are performed before rounding to avoid round-off errors in calculated results. Page 21 of 23

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23 Login Sample Receipt Check List Client: Cetco Environmental Login Number: Creator: Kelsey, Shawn M List Number: 1 List Source: Question T / F/ NA Comment Radioactivity either was not measured or, if measured, is at or below background The cooler's custody seal, if present, is intact. The cooler or samples do not appear to have been compromised or tampered with. Samples were received on ice. Cooler Temperature is acceptable. Cooler Temperature is recorded. COC is present. COC is filled out in ink and legible. COC is filled out with all pertinent information. There are no discrepancies between the sample IDs on the containers and the COC. Samples are received within Holding Time. Sample containers have legible labels. Containers are not broken or leaking. Sample collection date/times are provided. Appropriate sample containers are used. Sample bottles are completely filled. There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs VOA sample vials do not have headspace or bubble is <6mm (1/4") in N/A diameter. If necessary, staff have been informed of any short hold time or quick TAT needs Multiphasic samples are not present. Samples do not require splitting or compositing. Page 23 of 23