Revision Number: Issue date: 10/19/ PRODUCT AND COMPANY IDENTIFICATION 2. HAZARDS IDENTIFICATION

Transcription

1 Safety Data Sheet Revision Number: Issue date: 10/19/ PRODUCT AND COMPANY IDENTIFICATION Product type: Glue stick Restriction of Use: identified Region: Canada Company address: Contact information: Henkel AG & Co. KGaA Telephone: +49 (211) Henkelstr. 67 Düsseldorf HAZARDS IDENTIFICATION WARNING: EMERGENCY OVERVIEW CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE IRRITATION. HAZARD CLASS HAZARD CATEGORY SKIN IRRITATION 2 EYE IRRITATION 2A PICTOGRAM(S) Precautionary Statements Prevention: Response: Storage: Disposal: Wash affected area thoroughly after handling. Wear protective gloves, eye protection, and face protection. IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. Not prescribed Not prescribed 3 % of the mixture consists of ingredient(s) of unknown acute toxicity. Classification complies with Canadian Hazardous Products Regulations (WHMIS 2015) and is consistent with the provision of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Weight %* Sodium myristate Propane-1,2-diol Caprolactam epsilon Sodium hydroxide Page 1 of 5

2 Hexadecanoic acid, sodium salt * Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Skin contact: Move to fresh air in case of accidental inhalation of vapours. Wash affected area immediately with soap and water. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms develop and persist, get medical attention. Ingestion: Consult a physician if necessary. Symptoms: See Section FIRE FIGHTING MEASURES Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: carbon dioxide, foam, powder, water spray jet, fine water spray Wear protective equipment. Wear self-contained breathing apparatus. Formation of toxic gases is possible during heating or in fires. carbon oxides. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: No special environmental precautions required. Do not empty into drains / surface water / ground water. Dispose of according to Federal, State and local governmental regulations. Clean-up methods: Scrape up as much material as possible. Clean residue with soap and water. 7. HANDLING AND STORAGE Handling: Storage: Ensure adequate ventilation, especially in confined areas. Ensure adequate ventilation. Store in a dry place. Store in original container until ready to use. Ensure adequate ventilation. Store in sealed original container. Store in a dry place. For information on product shelf life, please review labels on container or check the Technical Data Sheet. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Page 2 of 5

3 Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Sodium myristate Propane-1,2-diol 10 mg/m3 TWA Aerosol. Caprolactam epsilon 5 mg/m3 TWA Inhalable fraction and vapor. Sodium hydroxide 2 mg/m3 Ceiling 2 mg/m3 PEL Hexadecanoic acid, sodium salt 10 mg/m3 TWA Engineering controls: Respiratory protection: Eye/face protection: Skin protection: No particular measures required. Ensure adequate ventilation. required in normal use. No special measures required if used properly. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Solid Color: Opaque Odor: Lemon Odor threshold: ph: 10.1 Vapor pressure: Boiling point/range: Melting point/ range: Vapor density: Flash point: > 94 C (> F) Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Flammability: Not applicable Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: Viscosity: Decomposition temperature: 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Reactivity: Conditions to avoid: Stable under normal conditions of storage and use. under normal processing. In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) are released. known Stable under recommended storage conditions. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: identified. Page 3 of 5

4 Potential Health Effects/Symptoms Inhalation: Skin contact: Eye contact: Ingestion: Not a hazard under normal conditions of use. Not a hazard under normal conditions of use. May cause slight irritation to eyes on contact. Not expected to be harmful by ingestion. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Sodium myristate Irritant Oral LD50 (Rabbit) = 18 g/kg Propane-1,2-diol Oral LD50 (Mouse) = 23.9 g/kg Irritant Oral LD50 (Rat) = 30 g/kg Oral LD50 (Mouse) = 930 mg/kg Oral LD50 (Rat) = 1.2 g/kg Oral LD50 (Rat) = 1.6 g/kg Caprolactam epsilon Oral LD50 (Mouse) = 2.1 g/kg Oral LD50 (Mouse) = 2.5 g/kg Oral LD50 (Rat) = 1,210 mg/kg Allergen, Blood, Central nervous system, Developmental, Eyes, Irritant, Kidney, Liver, Reproductive, Less weight gain and food intake. Sodium hydroxide Irritant, Corrosive, Eyes Hexadecanoic acid, sodium salt Irritant Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Sodium myristate No No No Propane-1,2-diol No No No Caprolactam epsilon No No No Sodium hydroxide No No No Hexadecanoic acid, sodium salt No No No 12. ECOLOGICAL INFORMATION Ecological information: 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. Canada Transportation of Dangerous Goods - Ground International Air Transportation (ICAO/IATA) Water Transportation (IMO/IMDG) Page 4 of 5

5 15. REGULATORY INFORMATION Canada Regulatory Information CEPA DSL/NDSL Status: One or more components are not listed on, and are not exempt from listing on either the Domestic Substances List or the Non-Domestic Substances List. United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: This Safety Data Sheet contains changes from the previous version in Section(s): 2,9,16 Prepared by: Product Safety and Regulatory Affairs Issue date: 10/19/2017 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 5 of 5