MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION Trade Name: Common Name: Synonyms/Common Name: Group Name: Formula: Molecular weight: Approved Use: GARIANE Active ingredient 1: Propanil Active ingredient 2: Triclopyr N-(3,4-dichlorophenyl)propanamide; & [(3,5,6-trichloro-2-pyridyl)oxy]acetic acid Anilide; & Pyridinecarboxylic acid C9H9Cl2NO; & C7H4Cl3NO & Contact herbicide used post-emergence in rice, to control broad-leaved and grass weeds, including Amaranthus retroflexus,digitaria spp., Echinochloa spp., Panicum spp., and Setaria spp. SHANGHAI KELINON AGROCHEMICAL CO., LTD Supplier: Emergency phone No: Issued By: SHANGHAI KELINON AGROCHEMICAL CO., LTD 2. COMPOSITION/INFORMATION ON INGREDIENTS No. Name CAS No. Content 1. Propanil g/L (Propanil) 2. Triclopyr (Presented as triclopyr-triethylammonium) ( ) 72 g/l (Triclopyr) (100.1g/L) 3. Other ingredients (Solvents & emulsifiers) To 100% 3. HAZARDS IDENTIFICATION Toxicity Class: Ⅲ (WHO) Human: Harmful if inhalation, ingestion, and skin contact. Irritant to

2 Environment: respiratory system, eyes and skins. Flammable. 4. FIRST-AID MEASURES General: Inhalation: Skin Contact: Eye Contact: Ingestion: Remove from source of exposure. Wash affected area. Remove to fresh air. Assist breathing if necessary Remove contaminated clothing and shoes. Wash affected area with soap and plenty of water. Flush eye(s) immediately with plenty of water. Get medical attention. Wash out mouth. Give some water to drink. DO NOT induce vomiting. Get medical attention. Never give anything by mouth to an unconscious person. Contact local Poison Control Center, hospital or physician. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Specific Hazards: Special protective equipment for fire-fighters: Specific methods: Water spray, CO2, chemical foam and chemical powder The product is flammable. Combustion generates toxic fumes containing CO, nitrous vapours and HCl. Vapours can give an explosive mixture. Self-contained breathing apparatus and total protection is required. Cool drums with water spray. Contain run-off with inert material 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Environmental Precautions & Methods for Cleaning Up: Wear chemical safety glasses or goggles, rubber gloves, waterproof boots, long-sleeved shirt, long pants, hat. Absorb with an inert material and put the spilled material in an appropriate waste disposal. Do not allow wash or rinse water to contaminate water supplies. 7. HANDLING AND STORAGE Handling: Storage: Further Information: Handle under adequate ventilation. Fumes or vapours may fire with temperature >27 ºC In original packaging under normal storage condition. Packages should not be exposed to direct sunlight and must be kept unopened and undamaged. Keep out of reach of children and away from fertilisers, food, drink and animal feeding stuffs. Keep containers dry. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures: Hygiene measures: Personal protective equipment: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapours below their respective threshold limit value. Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking, using lavatory, and at the end of day. Respiratory Protection: Wear suitable respiratory equipment when

3 Occupational Exposure Limits: ventilation is inadequate. Eye Protection: Users should use goggles or face-shield when handling the spray. Hand Protection: Users should use suitable gloves when handling the spray. Skin Protection: Protective clothing such as coated overall should be used to protect from contamination when dealing with spray. No information. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Brown liquid. Odour: Bulk Density: Boiling point: Flash point: Aromatic. Approximately 1.06 g/cubic 20. No Data. 20. Flammability: Flammable Solubility: Emulsion in water. ph: STABILITY AND REACTIVITY Stability: Conditions to Avoid: Materials to Avoid: Hazardous Decomposition Products: Stable at least 2 years under normal conditions. This product is unlikely to react or decompose under normal storage condition. High temperatures (overheating and sources of ignition), direct sunlight Oxidizing agents, acids and alkalines. Plastic and iron metal. Toxic and flammable fumes. 11. TOXICOLOGICAL INFORMATION Acute Toxicity (for a.i.): Oral: Rats: LD 50 > 2500 mg/kg; Mice: LD 50 > 1800 mg/kg Dermal: Rats: LD 50 > 5000 mg/kg Not irritating to skin and eyes (rabbits). Not a skin sensitiser (guinea pigs) Inhalation: Rats: LC50 > 1.25 mg/l (4 h) (for a.i.): for Propanil: NOEL (2 y) for rats 400, dogs 600 mg/kg diet. for Triclopyr: NOEL (2 y) for rats 3.0, mice 35.7 mg/kg diet. ADI (US) mg/kg b.w. Other Not mutagenic, not carcinogenic. 12. ECOLOGICAL INFORMATION For Propanil: Birds: Acute oral LD50 for mallard ducks 375, bobwhite quail 196 mg/kg. Dietary LC50 (5 d) for mallard ducks 5627, bobwhite quail 2861 ppm Fish: LC50 (48 h) for carp 8-11 mg/l. Daphnia: LC50 (48 h) 4.8 mg/l. For Triclopyr: Birds: Acute oral LD50 for mallard ducks 1698 mg/kg. Dietary LC50 (8 d) for mallard ducks >5000, Japanese quail 3278, bobwhite quail 2935 mg/kg. Fish: LC50 (96 h) for rainbow trout 117, bluegill sunfish 148 mg/l

4 Daphnia: LC50 (48 h) 133 mg/l. 13. DISPOSAL CONSIDERATIONS Product and Waste: Containers: Can be landfilled or disposed via an approved disposal contractor. The product may be safely disposed of by burning in a licensed incinerator at high temperature equipped with efficient gas scrubbing. Do not reuse containers. Crush or bury containers or dispose of in accordance with all local regulations. 14. TRANSPORT INFORMATION UN No.: 1993 Packaging group: III Marine pollutant: NO ADR/RID: Class: 3 Item: 31 Label: 3 Orange plate: Hazard id. No.: 30 Substance id. No.: 1993 IMO: Class: 3.3 IMDG CODE-PAGE: 3345 Label: FLAMMABLE LIQUID Proper shipping name: FLAMMABLE LIQUID, N.O.S. 15. REGULATORY INFORMATION R-Phrases R10 Flammable R20/21/22 Harmful if inhalation, ingestion and skin contact. R36/37/38 Irritating to respiratory system, eyes and skin. S-Phrases S2 Keep away from children. S13 Keep away from food, drink and animal feeding stuffs. S20/21 When using, do not eat, drink or smoke. S23 Do not breathe vapours. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the container or label where possible). 16. OTHER INFORMATION Packing: In 0.1, 0.25, 0.5, 1, 5, 10, 20, 25, 30, 200 Liters Bottle, Jerrycan, HDPE or Iron Drum, or as per request. Revision Date Prepared: 02/08/2012 DISCLAIMER The information in the MSDS relates to this specific material. If the product is used as a component in any other product, this MSDS may not be valid. The information contained was obtained from sources which

5 we believe are reliable. The information is provided without any warranty, expressed or implied, regarding its correctness. This Material Safety Data Sheet was prepared according to Directive 93/112/EEC.