NLB HSB, HSH NLDB. key monomer. Characteristics

Size: px
Start display at page:

Download "NLB HSB, HSH NLDB. key monomer. Characteristics"

Transcription

1 REVISION DATE Apr. 1, 2018 Page 1 of 8

2 Polycarbonatediol(PCD) is a linear polycarbonate with hydroxyl groups at both ends. It easily reacts with isocyanate compounds (e.g. MDI, TDI, IPDI, H 12 MDI) and generates polymers with superior characteristics described below. The proprietary manufacturing technology of Mitsubishi Chemical Corporation (MCC) enables production of unique composition and higher molecular weight PCDs with stable product qualities. The resins made from MCCʼs PCDs BENEBiOL TM have unique properties that existing resins have not been able to establish. In addition, some of the PCDsʼ raw materials are biomass-based. Chemical resistance Weather resistance Abrasion resistance High hardness Hydrolysis resistance Flexibility at low temperature High mechanical properties Biomass-based NLDB Crystalline NLB Non-crystalline HSB, HSH key monomer Characteristics - Flexibility at low temp. - Chemical resistance - Mechanical properties - Biomass-derived - Chemical resistance - Abrasion resisitance - Stain resistance - Hydrolysis resistance - Adhesive strength - Abrasion resisitance - High hardness - Chemical resistance - Abrasion resistance - Biomass-derived REVISION DATE Apr. 1, 2018 Page 2 of 8

3 (Character of each grade) 1 NLDB grade 2 NLB grade (Crystalline) 3 NLB grade (Non-crystalline) 4 HSB and HSH grades REVISION DATE Apr. 1, 2018 Page 3 of 8

4 (General properties of BENEBiOL TM ) NLDB NLB HSB HSH NL1010DB NL2010DB NL3010DB NL1005B NL2005B NL1030B HS0830B HS0840B HS0840H HS0850H Mn Number average molecular weight Appearance (at 25 ) Viscous Highlyviscous Highlyviscous Highlyviscous Highlyviscous Hazen APHA <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 OH Value mgkoh/g 110±10 56±5 37±3 110±10 56±5 110±10 140±10 140±10 140±10 140±10 Viscosity mpa s (at 60 ) 500 1,500 5,000 9,000 15,000 35,000 1,000 ~2,000 8,000 ~1,4000 1,500 ~4,500 5,000 ~15,000 15,000 40,000 5,000 ~15,000 10,000 30,000 Water wt% Flash point Melting point ~55 45~55 n.d. 10~20 n.d. n.d. n.d. Acid Value mgkoh/g Bio-based %* *The ASTM D6866 method Note : The values in the table are representative values, and are not specifications. REVISION DATE Apr. 1, 2018 Page 4 of 8

5 (Solubility) : soluble, : mostly soluble, : emulsion, : insoluble 1. NLDB grade PCD/solvent Toluene Methylethylketone Methanol Ethyl acetate N,N-Dimethylformamide NL1010DB NL2010DB NL3010DB 3/1 1/1 1/3 3/1 1/1 1/3 3/1 1/1 1/ NLB grade PCD/solvent Toluene Methylethylketone Methanol Ethyl acetate N,N-Dimethylformamide NL1005B NL2005B NL1030B 3/1 1/1 1/3 3/1 1/1 1/3 3/1 1/1 1/ HSB, HSH grades PCD/solvent Toluene Methylethylketone Methanol Ethyl acetate N,N-Dimethylformamide HS0830B HS0840B HS0840H HS0850H 3/1 1/1 1/3 3/1 1/1 1/3 3/1 1/1 1/3 3/1 1/1 1/ REVISION DATE Apr. 1, 2018 Page 5 of 8

6 (Viscosity vs. Temperature) 1. NLDB and NLB grades 2. HSB and HSH grades REVISION DATE Apr. 1, 2018 Page 6 of 8

7 MCCʼs PCDs BENEBiOL TM have superior characteristics for use in the soft segment of polyurethane, acrylic resins and polyester resins. The polymer obtained is durable, for use in a wide range of applications such as furniture, automobile interiors, automobile paints, plastic coatings for electronics, adhesives, films, seats and ordinary consumables and various industrial materials. Its applications are expected to increase in the future. Polyurethane applications Artificial leather / synthetic leather Paint and coating materials Waterborne urethane Polyurethane elastomers Thermoset elastomer (TSU) Thermoplastic elastomer (TPU) Adhesives / sealants Acrylic resin applications Urethane acrylated compounds and resins Diacrylated compounds and resins Polyester applications Polyester elastomers (TPEE) REVISION DATE Apr. 1, 2018 Page 7 of 8

8 BENEBiOL TM should be sealed in a container with dry nitrogen since it is moderately hygroscopic. NLDB and NLB (Crystalline) grades are at room temperature, and it can become a colorless transparent when heated. Before using BENEBiOL TM, to melt BENEBiOL TM in a drum, it should be heated at temperature above its melting point. Under transport regulations, BENEBiOL TM is not classified as UN hazard class. BENEBiOL TM has low volatility and will not spontaneously ignite at room temperature. In the event of fire, dry chemicals foam and plenty of water spray are effective for extinguishing. Safety glasses and protective gloves should be worn when handling BENEBiOL TM. For further details, please refer to Safety Data Sheets issued by Mitsubishi Chemical Corporation. BENEBiOL TM are produced for industrial applications. If the intended use for BENEBiOL TM is for body contact applications such as pharmaceuticals, foods, cosmetics, please contact MCC in advance. Drum 18-Liter square can 200 kg 18 kg Head Office Mitsubishi Chemical Corporation C4 Derivatives Department 1-1, Marunouchi 1-chome, Chiyoda-ku, Tokyo Japan Telephone:[+81] (0) Facsimile:[+81] (0) Mitsubishi Chemical Europe GmbH (EU contact) Willstaetterstr. 30, Dusseldorf, Germany Telephone:[+49] (0) Facsimile:[+49] (0) REVISION DATE Apr. 1, 2018 Page 8 of 8