Supporting Information. Photoinduced Anion Exchange in Cesium Lead Halide Perovskite Nanocrystals
|
|
- Reynard Lindsey
- 6 years ago
- Views:
Transcription
1 Supporting Information Photoinduced Anion Exchange in Cesium Lead Halide Perovskite Nanocrystals David Parobek, Yitong Dong, Tian Qiao, Daniel Rossi, Dong Hee Son* Department of Chemistry, Texas A&M University, College Station, Texas United States S1
2 Synthesis Materials and chemicals. Cesium carbonate (Cs 2 CO 3, Alfa Aesar, 99% trace metals basis), lead (II) bromide (PbBr 2, puratronic % trace metals basis, Alfa Aesar), lead (II) chloride (PbCl 2, puratronic % trace metals basis, Alfa Aesar), cadmium oxide (CdO, puratronic % trace metals basis, Alfa Aesar), sulfur (99.98%, Aldich), selenium (200 mesh % trace metals basis, Alfa Aesar), zinc stearate (ZnO %, Alfa Aesar), octylamine (99%, Aldrich), oleylamine (OAm, technical grade 70%, Aldrich), oleic acid (OA, technical grade 90%, Aldrich), 1-octadecene (ODE, technical grade 90%, Aldrich), tributyl phosphine (TBP, 95%, Alfa Aesar), dichloromethane (DCM, 99.5%, Millipore), dibromomethane (DBM, 99%, Acros Organic), acetone (Certified ACS, Fischer), hexanes (ACS grade, Millipore), toluene (HPLC grade, Fischer), methanol (99.5%, Millipore). Preparation of Cs-oleate. Cs-oleate was synthesized by adding Cs 2 CO 3 (0.234 g), OA (0.75 g), and ODE (7.04 g) to a 50-mL 3 neck round bottom flask and was evacuated and refilled with N 2 3 times before being heated to 150 C for at least 10 minutes before using. Synthesis of CsPbCl 3 and CsPbBr 3 NCs. PbCl 2 ( g) or PbBr 2 ( g), OAm (0.8 ml), OA (0.8 ml), and ODE (5 ml) were added to a 25-mL 3 neck round bottom flask. The solution was evacuated and refilled with N 2 followed by heating to 120 C for 30 minutes. The solution was then increased to 165 C and then 200 C for 10 minutes each where at 200 C, dried OAm (0.8 ml) and dried OA (0.8 ml) were consecutively injected to solubilize the solution. Then the Cs-oleate (0.4 ml) was injected and after 1 minute the solution was cooled with an ice bath. The NCs were precipitated with acetone and then centrifuged followed by dissolving in hexanes. Synthesis of CdSSe/ZnS QD. The core shell quantum dot nanocrystals were synthesized following a previously reported method. 1 The CdSSe core was synthesized by first injecting a TBP-selenium solution (0.3 ml, 29 M) into an ODE-sulfur solution (0.25 M). Then 2 ml of the mixture was injected into a solution of CdO (128 mg), ODE (12 ml) and OA (2.02g) at 250 C under N 2 protection where the reaction proceeded at 240 C for 1 minute until it was quenched. The nanocrystals were precipitated with acetone, centrifuged, and dispersed in toluene followed by additional cleaning with methanol precipitation. The ZnS shell was deposited on the prepared core following the SILAR method. The CdSSe QD was dissolved in an ODE (6 ml) and OAm (2 ml) solution and heated to 220 C under N 2 protection. Then in successive 10 minute intervals solutions of ODE-sulfur (0.25 M) and ODE-zinc stearate (0.25 M, ~5% octylamine) were added dropwise. The solution was then quenched and precipitated with acetone and dispersed in toluene followed by further precipitation with methanol. Anion Exchange Reactions. The anion exchange reactions were conducted with a home built optical setup using a 405 nm diode laser and a 445 nm diode laser with intensities of 21 mw/cm 2. For CsPbBr 3 anion exchange a mixture of DCM/hexane (2:1) with 25 μl was used and for CsPbCl 3 anion exchange a mixture of DBM/hexane (1:1) with 25 μl of oleylamine was used. All reactions were done under ambient conditions without stirring. Photoluminescence measurements were taken with a fiberoptic-coupled CCD spectrometer (Ocean Optics, QE65pro) with a 365 nm LED excitation source. The absorption S2
3 measurements were taken with an Ocean Optics USB2000 spectrometer. Control experiments were conducted for CsPbCl 3 (Figure S1a) and CsPbBr 3 (Figure S1b). Figure S1. Absence of the anion exchange under dark condition. (a) CsPbCl 3 NCs in DBM/hexane, (b) CsPbBr 3 NCs in DCM/hexane. TEM images of CsPbX 3 NCs before and after anion exchange All TEM images of CsPbX 3 NCs were collected using a FEI Tecnai G2 F20 ST FE-TEM microscope operated at 4100 kv. Figure S2. TEM image of NCs before (a) and after (b) the photoinduced anion exchange in DBM/hexane solution under 405 nm excitation. Figure S3. TEM images of CsPbBr 3 NCs before (a) and after (b) the photoinduced anion exchange in DCM/hexane solution under 405 nm excitation. S3
4 Powder X-ray Diffraction (XRD) of CsPbX 3 NCs before and after anion exchange Sample\hkl 121/ / /123 Cl Cl Br Br Figure S4. XRD patterns of CsPbCl 3 before (blue) and after (red) anion exchange in DBM/hexane solution. XRD pattern of the freshly synthesized CsPbBr 3 is shown in green. XRD patterns were obtained using a Bruker-AXS GADDS MWPC diffractometer equipped with Cu K-α x-ray radiation and a multi-wire proportional counter. Intensity dependent photoinduced anion exchange reaction Figure S5. PL emission peak shift from anion exchange of CsPbCl 3 in DBM/hexane at two different 405 nm excitation intensities. S4
5 Two-photon excitation induced anion exchange Figure S6. PL emission peak shift from anion exchange of CsPbCl 3 in DBM/hexane mixture induced by two-photon excitation at 800 nm from Titanium Sapphire laser. Exchange between CsPbBr 3 and CH 2 I 2 /toluene Figure S7. Photoinduced anion exchange from CsPbBr 3 to CsPbI 3 in diiodomethane/toluene mixture using two-photon excitation. S5
6 Energy Level Diagram of CsPbX 3 Figure S8. Energy level diagram with respect to vacuum of CsPbCl 3 and CsPbBr 3 2 compared to the reduction potential of common halogenated solvents 3. Patterning of thin film with photoinduced anion exchange Figure S9. Photoinduced anion exchange of a thin film of CsPbCl 3 in a DBM/PMMA matrix to CsPbBr 3 with spatial patterning. Three bright dots are the locations where the beam impinge on. References (1) Chen, H.-Y.; Maiti, S.; Son, D. H. ACS Nano 2012, 6, 583. (2) Ravi, V. K.; Markad, G. B.; Nag, A. ACS Energy Lett. 2016, 1, 665. (3) Isse, A. A.; Lin, C. Y.; Coote, M. L.; Gennaro, A. J. Phys. Chem. B 2010, 115, 678. S6
Supplementary Information. Solution-phase Synthesis of Cesium Lead Halide Perovskite Nanowires
Supplementary Information Solution-phase Synthesis of Cesium Lead Halide Perovskite Nanowires Dandan Zhang,,, Samuel W. Eaton,, Yi Yu, Letian Dou,, Peidong Yang*,,,, Department of Chemistry, Department
More informationSupporting Information:
Supporting Information: Radial-Position-Controlled Doping in CdS/ZnS Core/Shell Nanocrystals Yongan Yang, Ou Chen, Alexander Angerhofer and Y. Charles Cao* Department of Chemistry, University of Florida,
More informationCrystal Phase-Controlled Synthesis of Cu 2 FeSnS 4 Nanocrystals with Band Gap around 1.5 ev
Crystal Phase-Controlled Synthesis of Cu 2 FeSnS 4 Nanocrystals with Band Gap around 1.5 ev Xiaoyan Zhang, a,b Ningzhong Bao,* c Karthik Ramasamy, a Yu-Hsiang A. Wang, a Yifeng Wang, c Baoping Lin b and
More informationSupporting Information
Supporting Information Highly Stable Cesium Lead Halide Nanocrystals through Inorganic Passivation Ju Young Woo,, Youngsik Kim,, Jungmin Bae, # Tae Gun Kim,,# Jeong Won Kim,,# Doh C. Lee,*, and Sohee Jeong*,,
More informationSupporting Information
Band Edge Energies and Excitonic Transition Probabilities of Colloidal CsPbX 3 (X= Cl, Br, I) Perovskite Nanocrystals Vikash Kumar Ravi, Ganesh B. Markad, *, Angshuman Nag,, * Department of Chemistry and
More informationEmission-Tunable Near-infrared Ag 2 S Quantum Dots
Supporting Information for: Emission-Tunable Near-infrared Ag 2 S Quantum Dots Peng Jiang, Zhi-Quan Tian, Chun-Nan Zhu, Zhi-Ling Zhang and Dai-Wen Pang* Key Laboratory of Analytical Chemistry for Biology
More informationSupporting Information: Yi Liu a, Dong Yao a, Liang Shen b, Hao Zhang* a, Xindong Zhang b, Bai Yang a
Supporting Information: Alkylthiol-Enabled Se Powder Dissolution in Oleylamine at Room Temperature for the Phosphine-Free Synthesis of Copper-Based Quaternary Selenide Nanocrystals Yi Liu a, Dong Yao a,
More informationSupporting Information for:
Supporting Information for: Post-Synthesis Transformation of Insulating Cs 4 PbBr 6 Nanocrystals Into Bright Perovskite CsPbBr 3 Through Physical and Chemical Extraction of CsBr Francisco Palazon, Carmine
More informationSupporting Information
Supporting Information Wiley-VCH 2006 69451 Weinheim, Germany Single Crystal Nanoflowers with Different Chemical Composition and Physical Properties Grown by Limited Ligand Protection Arun Narayanaswamy,
More informationCollege of Chemistry and Materials Engineering, Wenzhou University, Wenzhou , China.
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Supporting Information Use of long-term stable CsPbBr 3 perovskite quantum dots in phospho-silicate
More informationZero-Dimensional Cs 4 PbBr 6 Perovskite Nanocrystals
Supporting Information Zero-Dimensional Cs 4 PbBr 6 Perovskite Nanocrystals Yuhai Zhang 1, Makhsud I. Saidaminov 1, Ibrahim Dursun 1, Haoze Yang 1, Banavoth Murali 1, Erkki Alarousu 1, Emre Yengel 1, Buthainah
More informationSupporting Information
Supporting Information White Upconversion Luminescence Nanocrystals for the Simultaneous and Selective Detection of 2,4,6,-trinitrotoluene and 2,4,6-trinitrophenol Yingxin Ma, Sheng Huang, Mingliang Deng,
More informationFacile ex-situ NaF size/morphology tuning strategy for highly monodisperse sub-5 nm β-nagdf 4 :Yb/Er
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information Facile ex-situ NaF size/morphology tuning strategy for
More informationSupporting Information. Direct-Indirect Nature of the Bandgap in Lead-Free Perovskite Nanocrystals
Supporting Information Direct-Indirect Nature of the Bandgap in Lead-Free Perovskite Nanocrystals Yuhai Zhang, Jun Yin, Manas R. Parida, Ghada H. Ahmed, Jun Pan, Osman M. Bakr, Jean-Luc Brédas, # Omar
More informationStabilizing Cesium Lead Halide Perovskite Lattice through Mn (II)- Substitution for Air-Stable Light-Emitting Diodes
Supporting Information Stabilizing Cesium Lead Halide Perovskite Lattice through Mn (II)- Substitution for Air-Stable Light-Emitting Diodes Shenghan Zou,,,,# Yongsheng Liu, *, Jianhai Li, Caiping Liu,
More informationEfficient CdSe Quantum Dot-Sensitized Solar Cells Prepared by Postsynthesis Assembly Approach
Electronic Supplementary Information Efficient CdSe Quantum Dot-Sensitized Solar Cells Prepared by Postsynthesis Assembly Approach H. Zhang, K. Cheng, Y. M. Hou, Z. Fang, Z. X. Pan, W. J. Wu, J. L. Hua
More informationFabrication of 1D Nickel Sulfide Nanocrystals with High
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Fabrication of 1D Nickel Sulfide Nanocrystals with High Capacitances and Remarkable Durability
More informationFLUORESCENCE GAS SENSOR BASED ON CdTe QUANTUM DOTS FOR DETECTION OF VOLATILE ORGANIC COMPOUNDS GAS
FLUORESCENCE GAS SENSOR BASED ON CdTe QUANTUM DOTS FOR DETECTION OF VOLATILE ORGANIC COMPOUNDS GAS Norhayati Abu Bakar 1, Aidhia Rahmi 1, Akrajas Ali Umar 1. *, Muhamad Mat Salleh 1 and Muhammad Yahaya
More informationAll Inorganic Iron Pyrite Nano-Heterojunction Solar Cells
Supporting Information All Inorganic Iron Pyrite Nano-Heterojunction Solar Cells Alec Kirkeminde, Randall Scott and Shenqiang Ren * Department of Chemistry, University of Kansas, Lawrence, Kansas 66045,
More informationSupporting Information. Solution-Processed 2D PbS Nanoplates with Residual Cu 2 S. Exhibiting Low Resistivity and High Infrared Responsivity
Supporting Information Solution-Processed 2D PbS Nanoplates with Residual Cu 2 S Exhibiting Low Resistivity and High Infrared Responsivity Wen-Ya Wu, Sabyasachi Chakrabortty, Asim Guchhait, Gloria Yan
More informationHighly Emissive and Color-tunable Perovskite Crosslinkers for
Highly Emissive and Color-tunable Perovskite Crosslinkers for Luminescent Polymer Networks Yumeng Xin 1, Wei Shen, 2 Zhengtao Deng, 2 Jiuyang Zhang 1 * 1 School of Chemistry and Chemical Engineering, Southeast
More informationQuantum-Cutting Ytterbium-Doped CsPb(Cl 1-x Br x ) 3 Perovskite Thin Films with Photoluminescence Quantum Yields over 190%
Supporting Information for: Quantum-Cutting Ytterbium-Doped CsPb(Cl 1-x Br x ) 3 Perovskite Thin Films with Photoluminescence Quantum Yields over 190% Daniel M. Kroupa, Joo Yeon Roh, Tyler J. Milstein,
More informationSupporting Information
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2014 Supporting Information Dual Nature of the Excited State in Organic-Inorganic
More informationSUPPLEMENTARY INFORMATION
Materials. GdCl 3 xh 2 O, (99.99%), YCl 3 6H 2 O (99.99%), YbCl 3 6H 2 O (99.99%), ErCl 3 6H 2 O (99.9%), NaOH (98+%), NH 4 F (98+%), 1 octadecene (90%), and oleic acid (90%) were all purchased from Sigma
More informationRoom-Temperature Synthesis of Widely Tunable Formamidinium Lead Halide. Duong Nguyen Minh, Juwon Kim, Jinho Hyon, Jae Hyun Sim, Haneen H.
Supporting Information Room-Temperature Synthesis of Widely Tunable Formamidinium Lead Halide Perovskite Nanocrystals Duong Nguyen Minh, Juwon Kim, Jinho Hyon, Jae Hyun Sim, Haneen H. Sowlih, Chunhee Seo,
More informationElectronic Supporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2018 Electronic Supporting Information An Au@Ag Nanocube based Plasmonic Nano-sensor for Rapid Detection
More informationSupporting Information
Supporting Information Au Nanowire-Striped Cu 3 P Platelet Photoelectrocatalysts Anirban Dutta, Aneeya K. Samantara, Samrat Das Adhikari, Bikash Kumar Jena and Narayan Pradhan Department of Materials Science
More informationIn Situ X-ray Scattering Guides the Synthesis of Uniform PtSn Nanocrystals
Supporting Information In Situ X-ray Scattering Guides the Synthesis of Uniform PtSn Nanocrystals Liheng Wu,, Amanda P. Fournier, Joshua J. Willis,, Matteo Cargnello,,, * and Christopher J. Tassone, *
More informationGraphene/Fe 3 O Quaternary Nanocomposites: Synthesis and Excellent Electromagnetic Absorption Properties
Graphene/Fe 3 O 4 @Fe/ZnO Quaternary Nanocomposites: Synthesis and Excellent Electromagnetic Absorption Properties Yu Lan Ren, Hong Yu Wu, Ming Ming Lu, Yu Jin Chen, *, Chun Ling Zhu, # Peng Gao *, # Mao
More informationWell-defined Colloidal 2-D Layered Transition Metal Chalcogenide Nanocrystals via Generalized Synthetic Protocols
Intensity (a.u.) Supporting Information Well-defined Colloidal 2-D Layered Transition Metal Chalcogenide Nanocrystals via Generalized Synthetic Protocols Sohee Jeong, Dongwon Yoo, Jung-tak Jang, Minkyoung
More informationSupplementary Information
Supplementary Information Reduced Carrier Recombination in PbS - CuInS2 Quantum Dot Solar Cells Zhenhua Sun, 1,2,3 Gary Sitbon, 1,2,3 Thomas Pons, 1,2,3 Artem A. Bakulin, 4 and Zhuoying Chen 1,2,3,* 1.
More informationColloidal Synthesis of Homogeneously Alloyed CdSe x S 1-x Nanorods with Compositionally Tunable Photoluminescence
Colloidal Synthesis of Homogeneously Alloyed CdSe x S 1-x Nanorods with Compositionally Tunable Photoluminescence Shalini Singh, Ajay Singh, Kumaranand Palaniappan,Kevin M. Ryan * Materials and Surface
More informationSupporting Information
Supporting Information Macroscale Lateral Alignment of Semiconductor Nanorods into Freestanding Thin Films Tie Wang, 1 Xirui Wang, 1 Derek LaMontagne, 1 Zhongwu Wang, 2 and Y. Charles Cao 1* 1 Department
More informationand Their Electrocatalysis for Oxygen Reduction Reaction
Supporting Information Monodisperse M x Fe 3-x O 4 (M = Fe, Cu, Co, Mn) Nanoparticles and Their Electrocatalysis for Oxygen Reduction Reaction Huiyuan Zhu, Sen Zhang, Yu-Xi Huang,, Liheng Wu, and Shouheng
More informationEmission Enhancement and Bandgap Reduction of a Two-Dimensional Mixed Cation Lead Halide Perovskite under High Pressure
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2019 Emission Enhancement and Bandgap Reduction of a Two-Dimensional Mixed Cation
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Thermally Induced Recrystallization of MAPbI 3 Perovskite
More informationSupporting Information for: Photochemical Electronic Doping of Colloidal CdSe Nanocrystals
for: Photochemical Electronic Doping of Colloidal CdSe Nanocrystals Jeffrey D. Rinehart, Alina M. Schimpf, Amanda L. Weaver, Alicia W. Cohn, and Daniel R. Gamelin Department of Chemistry, University of
More informationThree-dimensional binary superlattices of magnetic nanocrystals and semiconductor quantum dots
Supplementary Information Three-dimensional binary superlattices of magnetic nanocrystals and semiconductor quantum dots F.X. Redl*, K.-S. Cho *, C.B. Murray*, S. O Brien *IBM, T. J. Watson Research Center,
More informationBright White Light Emission from Ultrasmall Cadmium Selenide Nanocrystals
SUPPORTING INFORMATION Bright White Light Emission from Ultrasmall Cadmium Selenide Nanocrystals Teresa E. Rosson 1, Sarah M. Claiborne 1, James R. McBride 1, Benjamin S. Stratton 1,3, and Sandra J. Rosenthal
More informationSupporting information. High-performance CsPbX 3 Perovskite Quantum Dot. Light Emitting Devices via Solid-state Ligand. Exchange
Supporting information High-performance CsPbX 3 Perovskite Quantum Dot Light Emitting Devices via Solid-state Ligand Exchange Yo-Han Suh, Taeyun Kim, Jin Woo Choi, Chang-Lyoul Lee,*, and Jongnam Park*,
More informationRational defect passivation of Cu 2 ZnSn(S,Se) 4 photovoltaics with solution-processed Cu 2 ZnSnS 4 :Na nanocrystals
Supporting Information for Rational defect passivation of Cu 2 ZnSn(S,Se) 4 photovoltaics with solution-processed Cu 2 ZnSnS 4 :Na nanocrystals Huanping Zhou 1,2+, Tze-Bin Song 1,2+, Wan-Ching Hsu 1,2,
More informationSupporting Information for The Influence of the CTAB Surfactant on the Colloidal Seed-Mediated Synthesis of Gold Nanorods
Supporting Information for The Influence of the CTAB Surfactant on the Colloidal Seed-Mediated Synthesis of Gold Nanorods Danielle K. Smith and Brian A. Korgel* Department of Chemical Engineering, Texas
More informationPreparation of graphene oxide by solvent-free mechanochemical oxidation of graphite. Supporting Information
Preparation of graphene oxide by solvent-free mechanochemical oxidation of graphite Oleg Yu. Posudievsky, Oleksandra A. Khazieieva, Vyacheslav G. Koshechko, Vitaly D. Pokhodenko Supporting Information
More informationPolydopamine tethered enzyme/metal-organic framework composites with high stability and reusability
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2015 Supporting information for Polydopamine tethered enzyme/metal-organic framework composites with
More informationDeliverable D1.4: Report on QDs with tunable color and high quantum yield. Summary
Deliverable D.4: Report on QDs with tunable color and high quantum yield Responsible author: Dr Beata Kardynal, FZJ Summary The synthesis of the InP/ZnS nanocrystals with wavelengtnh in the range of green
More informationSupporting Information. Octopods vs. Concave Nanocrystals: Control of Morphology by Manipulating the. Kinetics of Seeded Growth via Co-reduction
Supporting Information Octopods vs. Concave Nanocrystals: Control of Morphology by Manipulating the Kinetics of Seeded Growth via Co-reduction Christopher J. DeSantis, Angela A. Peverly, Dennis G. Peters,
More informationSupporting Information
Supporting Information Colloidal Monolayer β-in 2 Se 3 Nanosheets with High Photoresponsivity Guilherme Almeida,&, Sedat Dogan, Giovanni Bertoni,, Cinzia Giannini, Roberto Gaspari,, Stefano Perissinotto,
More informationGrowth of Hexagonal Phase Sodium Rare Earth Tetrafluorides Induced by Heterogeneous Cubic Phase Core
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Growth of Hexagonal Phase Sodium Rare Earth Tetrafluorides
More informationHeteroepitaxy of Monolayer MoS 2 and WS 2
Supporting Information Seed Crystal Homogeneity Controls Lateral and Vertical Heteroepitaxy of Monolayer MoS 2 and WS 2 Youngdong Yoo, Zachary P. Degregorio, James E. Johns* Department of Chemistry, University
More informationSUPPORTING INFORMATION
SUPPORTING INFORMATION Type-II Core/Crown CdSe/CdTe Semiconductor Nanoplatelets Silvia Pedetti 1,2, Sandrine Ithurria 2, Hadrien Heuclin 1, Gilles Patriarche 3, Benoit Dubertret 2 1 Nexdot, 10 rue Vauquelin
More informationSupplementary Information
Supplementary Information Disperse fine equiaxed alpha alumina nanoparticles with narrow size distribution synthesised by selective corrosion and coagulation separation Sanxu Pu, Lu Li, Ji Ma, Fuliang
More informationChiral Structure of Thiolate-Protected 28-Gold-Atom Nanocluster Determined by X-ray Crystallography
Supporting information Chiral Structure of Thiolate-Protected 28-Gold-Atom Nanocluster Determined by X-ray Crystallography Chenjie Zeng, Tao Li, Anindita Das, Nathaniel L. Rosi, and Rongchao Jin *, Department
More informationSupporting Information
Supporting Information One-pot Synthesis of Fe 3 O 4 Nanoprisms with Controlled Electrochemical Properties Yao Zeng, a Rui Hao, a Bengang Xing, b Yanglong Hou,* a and Zhichuan Xu* c a Department of Advanced
More informationSupporting Information
Near Infrared Photolysis of a Ru Polypyridyl Complex by Upconverting Nanoparticles Emmanuel Ruggiero, a Abraha Habtemariam, abc Luis Yate, a Juan C. Mareque-Rivas, ac Luca Salassa a * lsalassa@cicbiomagune.es
More informationSupporting Information for. Direct Chemical Synthesis of Plasmonic Black Colloidal Gold Superparticles with Broadband Absorption Properties
Supporting Information for Direct Chemical Synthesis of Plasmonic Black Colloidal Gold Superparticles with Broadband Absorption Properties Nayoung Kwon,, Hwisu Oh,, Reehyang Kim, Arjyabaran Sinha, Jaeyun
More informationA general strategy for metallic nanocrystals synthesis in organic medium
Supplementary Information for A general strategy for metallic nanocrystals synthesis in organic medium Peng Huang, a Jing Lin, b Zhiming Li, a Hengyao Hu, a Kan Wang, a Guo Gao, a Rong He a and Daxiang
More informationA study on the synthesis and characterization of ternary semiconductor nanocrystals
Honors Theses Chemistry Spring 2013 A study on the synthesis and characterization of ternary semiconductor nanocrystals Tyler J. Hurlburt Penrose Library, Whitman College Permanent URL: http://hdl.handle.net/10349/1219
More informationSeed-Mediated Growth of Ultra-Thin Triangular Magnetite Nanoplates
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Supporting Information Seed-Mediated Growth of Ultra-Thin Triangular Magnetite Nanoplates Zheheng
More informationUltra-low-temperature growth of CdS quantum dots on g-c 3 N 4. nanosheets and their photocatalytic performance
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Ultra-low-temperature growth of CdS quantum dots on g-c 3 N 4 nanosheets and their photocatalytic
More informationThe Influence of Solvent Coordination on Hybrid. Organic-Inorganic Perovskite Formation. (Supporting Information)
The Influence of Solvent Coordination on Hybrid Organic-Inorganic Perovskite Formation (Supporting Information) J. Clay Hamill, Jr., Jeffrey Schwartz, and Yueh-Lin Loo, * Department of Chemical and Biological
More informationfor New Energy Materials and Devices; Beijing National Laboratory for Condense Matter Physics,
Electronic Supplementary Information Highly efficient core shell CuInS 2 /Mn doped CdS quantum dots sensitized solar cells Jianheng Luo, a Huiyun Wei, a Qingli Huang, a Xing Hu, a Haofei Zhao, b Richeng
More informationHighly Selective Synthesis of Catalytically Active Monodisperse Rhodium Nanocubes
Supporting Information for Highly Selective Synthesis of Catalytically Active Monodisperse Rhodium Nanocubes Yawen Zhang, Michael E. Grass, John N. Kuhn, Feng Tao, Susan E. Habas, Wenyu Huang, Peidong
More informationWater-Enhanced Oxidation of Graphite to Graphene Oxide with Controlled Species of Oxygenated Groups
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2015 Electronic Supporting Information Water-Enhanced Oxidation of Graphite to Graphene Oxide
More informationPolymeric Modification of Graphene through Esterification of Graphite Oxide and Poly(vinylahcohol). Experimental procedure Methods.
Polymeric Modification of Graphene through Esterification of Graphite Oxide and Poly(vinylahcohol). Horacio J. Salavagione*, Marián A. Gómez, Gerardo Martínez Experimental procedure Graphite powder, PVA
More informationCoupling Hollow Fe 3 O 4 -Fe Nanoparticles with Graphene Sheets for High-performance Electromagnetic Wave Absorbing Material
Supporting Information Coupling Hollow Fe 3 O 4 -Fe Nanoparticles with Graphene Sheets for High-performance Electromagnetic Wave Absorbing Material Bin Qu,,#,, Chunling Zhu, *, Chunyan Li, Xitian Zhang,
More informationPurification of High Aspect Ratio Gold Nanorods: Complete Removal of Platelets Bishnu P. Khanal and Eugene R. Zubarev*
Purification of High Aspect Ratio Gold Nanorods: Complete Removal of Platelets Bishnu P. Khanal and Eugene R. Zubarev* Department of Chemistry, Rice University, Houston, Texas 77005 Supporting Information
More informationSelective growth of Au nanograins on specific positions (tips, edges. heterostructures.
Selective growth of Au nanograins on specific positions (tips, edges and facets) of Cu 2 O octahedrons to form Cu 2 O-Au hierarchical heterostructures. Han Zhu b, MingLiang Du* a,b, DongLiang Yu b, Yin
More informationPhotoluminescent Quantum Dot - Cucurbituril Nanocomposites
S1 Supporting Information Photoluminescent Quantum Dot - Cucurbituril Nanocomposites Minjie Li, Md. Badruz Zaman, David Bardelang, Xiaohua Wu, Dashan Wang, James C. Margeson, Donald M. Leek, John A. Ripmeester,
More informationSupporting Information
Supporting Information Living Cell Multilifetime Encoding Based on Lifetime-Tunable Lattice-Strained Quantum Dots Li Zhang, Chi Chen, Wenjun Li, Guanhui Gao, Ping Gong, Lintao Cai* Guangdong Key Laboratory
More informationSupporting Information
Supporting Information Morphology Evolution and Degradation of CsPbBr 3 Nanocrystals under Blue Light-Emitting Diode Illumination Shouqiang Huang, Zhichun Li, Bo Wang, Nanwen Zhu, Congyang Zhang, Long
More informationSupporting Information for
Supporting Information for Improved Sodium-Ion Storage Performance of Ultrasmall Iron Selenide Nanoparticles Feipeng Zhao, 1 Sida Shen, 1 Liang Cheng, 1 Lu Ma, 2 Junhua Zhou, 1 Hualin Ye, 1 Na Han, 1 Tianpin
More informationSupplementary Information
Supplementary Information Photo-induced Emissive Trap States in Lead Halide Perovskite Semiconductors Silvia Motti a,b, Marina Gandini a,b, Alex Barker a, James M. Ball a, Ajay Ram Srimath Kandada a, Annamaria
More informationStudies on Structural and Optical Properties of Iron doped Cds Nanoparticles ABSTRACT
Studies on Structural and Optical Properties of Iron doped Cds Nanoparticles Atheek P., Vidhya M. and Balasundaram O. N Department of Physics, PSG College of Arts & Science, Coimbatore, Tamil Nadu, India
More informationPlasmon-Exciton Interactions in All-Inorganic Nanocrystal Arrays
Bowling Green State University ScholarWorks@BGSU Honors Projects Honors College Spring 4-29-2013 Plasmon-Exciton Interactions in All-Inorganic Nanocrystal Arrays Alexa Johnson Follow this and additional
More informationSupporting information for. Insights into the Liquid State of Organo-Lead Halide. Perovskites and Their New Roles. in Dye-sensitized Solar Cells
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 Supporting information for Insights into the Liquid State of Organo-Lead
More informationN-Methylformamide as a Source of Methylammonium Ions in. the Synthesis of Lead Halide Perovskite Nanocrystals and. Bulk Crystals
Supporting Information for: N-Methylformamide as a Source of Methylammonium Ions in the Synthesis of Lead Halide Perovskite Nanocrystals and Bulk Crystals Javad Shamsi,,, Ahmed L. Abdelhady,*,ǂ, Sara Accornero,,
More informationHigh Efficiency Solution Processed Sintered CdTe Nanocrystal Solar Cells: The Role of Interfaces
SUPPORTING INFORMATION High Efficiency Solution Processed Sintered CdTe Nanocrystal Solar Cells: The Role of Interfaces Matthew G. Panthani, J. Matt Kurley, Ryan W. Crisp,, Travis C. Dietz, Taha Ezzyat
More informationA high tenacity electrode by assembly of a soft sorbent and. hard skeleton for lithium-sulfur batteries
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 A high tenacity electrode by assembly of a soft sorbent and hard skeleton
More informationFacile synthesis of red-emitting lysozyme-stabilized Ag nanoclusters
Electronic Supplementary Information on Facile synthesis of red-emitting lysozyme-stabilized Ag nanoclusters Tingyao Zhou, a Yunhe Huang, a Zhimin Cai, a Feng Luo, c Chaoyong James Yang* a, and Xi Chen*
More informationQuantum Dot- Engineered M13 Virus Layer-by-layer Composite Films for Highly Selective and Sensitive Turn-on TNT Sensors
Supplementary Material (ESI) for Chemical Communications This journal is (c) The Royal Society of Chemistry 2013 Electronic Supplementary Information Quantum Dot- Engineered M13 Virus Layer-by-layer Composite
More informationEnd-only Functionalized Oligo Phenylene Ethynylenes: Synthesis, Photophysical and Biocidal Activity
1 End-only Functionalized Oligo Phenylene Ethynylenes: Synthesis, Photophysical and Biocidal Activity Zhijun Zhou, 1,2 Thomas S. Corbitt, 1 Anand Parthasarathy, 3 Yanli Tang, 1 Linnea K. Ista, 1 Kirk S.
More informationField Effect Transistors Based on Van-der-Waals. Grown and Dry Transferred All-Inorganic
Supporting Information for Field Effect Transistors Based on Van-der-Waals Grown and Dry Transferred All-Inorganic Perovskites Ultrathin Platelets Chengxue Huo #, Xuhai Liu #, Xiufeng Song, Ziming Wang,
More informationMorphology and Active-Site Engineering for Stable Round-Trip Efficiency Li-O 2 Batteries: A Search for the Most Active Catalytic Site in Co 3 O 4
Supporting information: Morphology and Active-Site Engineering for Stable Round-Trip Efficiency Li-O 2 Batteries: A Search for the Most Active Catalytic Site in Co 3 O 4 Kyeongse Song, Eunbi Cho and Yong-Mook
More informationElectronic Supplementary Information
Electronic Supplementary Information Tetragonal faceted-nanorods of anatase TiO 2 with large percentage of active {100} facets and their hierarchical structure Jianming Li, Ke Cao, Qi Li and Dongsheng
More informationand Curtis P. Berlinguette.*,, Department of Chemistry, The University of British Columbia, 2036 Main Mall, Vancouver, BC V6T1Z1.
Supplementary Materials for Photodecomposition of metal nitrate and chloride compounds yields amorphous metal oxide films Jingfu He, David M. Weekes, Wei Cheng, Kevan E. Dettelbach, Aoxue Huang, Tengfei
More informationSupporting Information. Metal-coordination-driven Mixed Ligand Binding in Supramolecular Bisporphyrin Tweezers
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Supporting Information Metal-coordination-driven Mixed Ligand Binding in Supramolecular Bisporphyrin
More informationSUPPORTING INFORMATION
SUPPORTING INFORMATION 1. SYNTHESIS OF THE MONOMERS 2-(Methylacryloyloxy)ethyl-trimethylammonium tetrafluoroborate ([MATMA][BF 4 ]) and p-vinylbenzyltrimethylammonium tetrafluoroborate ([VBTMA][BF 4 ])
More informationEffect of PbS Film Thickness on the Performance of Colloidal Quantum Dot Solar Cells
JNS 3 (2013) 17-23 Effect of PbS Film Thickness on the Performance of Colloidal Quantum Dot Solar Cells M. Mazloum-Ardakani*, M. Yavari, A.R. Khoshroo Department of Chemistry, Faculty of Science, Yazd
More informationSupporting Information. Low temperature synthesis of silicon carbide nanomaterials using
Supporting Information Low temperature synthesis of silicon carbide nanomaterials using solid-state method Mita Dasog, Larissa F. Smith, Tapas K. Purkait and Jonathan G. C. Veinot * Department of Chemistry,
More informationSupporting information. Gram scale synthesis of benzophenanthroline and its blue phosphorescent platinum
Supporting information Gram scale synthesis of benzophenanthroline and its blue phosphorescent platinum complex Patrick J. G. Saris and Mark E. Thompson* Department of Chemistry, University of Southern
More informationSupporting Information
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2017 Supporting Information A Fast Chemical Approach towards Sb 2 S 3 Film with Large Grain Size for
More informationThree-dimensionally Packed Nano-helical Phase. in Chiral Block Copolymers
Three-dimensionally Packed Nano-helical Phase in Chiral Block Copolymers Rong-Ming Ho, Yeo-Wan Chiang, Chi-Chun Tsai, Chu-Chieh Lin, Bao-Tsan Ko, Bor-Han Huang Supporting Information Table S1 Table S2
More informationSupporting Information for
Supporting Information for Hollow Carbon Nanofiber-Encapsulated Sulfur Cathodes for High Specific Capacity Rechargeable Lithium Batteries Guangyuan Zheng, Yuan Yang, Judy J. Cha, Seung Sae Hong and Yi
More informationSupporting Information
Supporting Information Conditioning-Free Electrolytes for Magnesium Batteries Using Sulfone-Ether Mixtures with Increased Thermal Stability Laura C. Merrill and Jennifer L. Schaefer*, University of Notre
More informationElectronic Supplemental Information
Electronic Supplemental Information Laser wavelength- and power-dependent plasmon-driven chemical reactions by single particle surface enhanced Raman spectroscopy Leilei Kang, a Ping Xu* a,b Bin Zhang,
More informationSupplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 Supplementary Information for Ta and Nb co-doped TiO 2, and Its Carbon-Hybrid
More informationRuthenium-catalyzed Olefin Metathesis Accelerated by Steric Effect of Backbone Substituent in Cyclic (Alkyl)(Amino)Carbenes
Electronic Supplementary Information for Ruthenium-catalyzed Olefin Metathesis Accelerated by Steric Effect of Backbone Substituent in Cyclic (Alkyl)(Amino)Carbenes Jun Zhang,* a Shangfei Song, a Xiao
More informationSupporting Information
Selective Functionalization of In 2 O 3 -Nanowire Mat Devices Marco Curreli a, Chao Li b, Yinghua Sun b, Bo Lei b, Martin A. Gundersen b, Mark E. Thompson a, *, Chongwu Zhou a,b, * a Department of Chemistry,,
More informationSupporting Information for:
Supporting Information for: Capture of Ni II, Cu I and Zn II by Thiolate Sulfurs of an N 2 S 2 Ni Complex: A Role for a Metallothiolate Ligand in the Acetyl-coenzyme A Synthase Active Site Melissa L. Golden,
More informationTunable band structure in coreshell quantum dots through alloying of the core
Tunable band structure in coreshell quantum dots through alloying of the core A. Guille ǀ D. Mourad ǀ T. Aubert ǀ A. Houtepen ǀ R. Van Deun ǀ E. Brainis ǀ Z. Hens 1. Introduction Semiconductor nanocrystals
More information