Dyneon Fluorothermoplastic Product Comparison Guide. More. Options. More. Answers

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1 Dyneon Fluorothermoplastic Product Comparison Guide Options More More Answers

A range of fluorothermoplastics that stand up to the toughest challenges.

From the low temperature processability of our THV FP products to the high temperature resistance of our PFA and FEP products, Dyneon Fluorothermoplastics are the innovative materials needed for

And along with innovative products, we have the innovative technical and support teams who work directly with you to ensure your utmost satisfaction.

2 A range of fluorothermoplastics that stand up to the toughest challenges. Dyneon is committed to supplying the broadest line of fluorothermoplastic products to its customers, and to remaining in the forefront of developing new solutions for challenging applications. From the low temperature processability of our THV FP products to the high temperature resistance of our PFA and FEP products, Dyneon Fluorothermoplastics are the innovative materials needed for applications in many industries including food packaging, chemical processing and semiconductor manufacturing. And along with innovative products, we have the innovative technical and support teams who work directly with you to ensure your utmost satisfaction. Application and Product Development When you re investigating new materials and new or improved manufacturing processes, you want smooth transitions and optimal use of your people and materials. And that s where Dyneon s APD specialists can help. Our fluoroplastic research specialists are available to help you select and handle our materials (including new grades) and ensure a smooth transition into your manufacturing process. Our worldwide research facilities have most types of fluoroplastic processing equipment. So whether it s start-up manufacturing or troubleshooting on an existing line, we can help. In addition, we can often assist by producing prototype parts for testing and end-use evaluation. Dyneon also has field personnel ready to bring you invaluable technical assistance in over 50 countries. Optimal Product Property Combinations PFA FEP ETFE THV PVDF Flexibility Chemical Resistance High Temperature Resistance Fire Resistance Electrical Insulation Mechanical Strength Low Temperature Processability Optical Properties Co-processablilty with Hydrocarbons Optimum performance - generally recommended Depends on product grade or application Not generally recommended 2

Dyneon THV Fluorothermoplastics G = Pellet A = Agglomerate Method Unit THVP THV 221G Z THV 500G Z* 2030G Z THV 221A Z THV 500A Z* THV 610G Z THV 815G Z G A, G A, G G G Specific Gravity ASTM D 792

3 Dyneon THV Fluorothermoplastics G = Pellet A = Agglomerate Method Unit THVP THV 221G Z THV 500G Z* 2030G Z THV 221A Z THV 500A Z* THV 610G Z THV 815G Z G A, G A, G G G Specific Gravity ASTM D 792 g/cm Melt Index 265/5kg ASTM D 1238 g/10 min Hardness Shore D ASTM D Tensile Strength at Break Elongation at Break Flexural Modulus Izod Impact Strength , Microtensile bars ASTM D 1708 Rate = 2''/min 3,335 2,900 4,060 4,060 4,210 23, Microtensile bars Rate = 2''/min ASTM D 1708 % , Injection Molded bars ASTM D 790 (0.5'' x 0.125'' x 5.0'') 4,640 12,000 30,000 71,000 76, notched J/m (ft-lb/in) no break no break no break no break -40 notched ASTM D 256 J/m (ft-lb/in) no break no break no break no break -40 unnotched J/m (ft-lb/in) no break no break no break no break Electrical Properties Dielectric 1 MHz, 23 ASTM D GHz Dissipation 1 MHz ASTM D GHz Dielectric Breakdown Strength.25 mm film ASTM D 149 kv/mm Dyneon THV (a polymer of tetrafluoroethylene, hexafluoropropylene and vinylidene fluoride) provides a combination of performance advantages, such as low processing temperature, ability to bond to elastomers and hydrocarbon-based plastics, flexibility and optical clarity. These combined advantages create new opportunities to make multilayer hoses, tubes, sheets and films that can be used in a variety of markets and applications such as automotive, chemical processing, semiconductor, solar energy, optical fiber and architectural and protective coatings. Dyneon THV is characterized by the following features: Exceptional optical clarity and light transmission Bondability to many elastomers and plastics Outstanding flexibility relative to other fluoroplastics Excellent permeation resistance Good chemical resistance Low temperature processability E-beam curable with or without pro-rads Limiting Oxygen Index Thermal Glass Transition (Tg) Heat Deflection Temperature ASTM D 2863 % >65 >75 >75 DSC ASTM D ASTM D Vertical Burn UL Bulletin 94 V-0 Optical Properties Refractive Index Metricon Model 2010 (100 µ film) Prism Coupler n D UV-Vis Light 300 nm %T 90** Transmission (100 µ film) 600 nm %T 91** * Also available in Electrostatic Dissipative Grade ** 250 micron film 3

Dyneon ETFE Fluorothermoplastics Dyneon ETFE (a polymer of tetrafluoroethylene and ethylene) has excellent chemical, thermal and electrical properties, and outstanding resistance to abrasion and

Applications include wiring for nuclear plant control rooms, extruded and molded valves, tubes and pipes, low permeation tubing, UV resistant films, architectural films, and films used on the front

4 Dyneon ETFE Fluorothermoplastics Dyneon ETFE (a polymer of tetrafluoroethylene and ethylene) has excellent chemical, thermal and electrical properties, and outstanding resistance to abrasion and cut-through. It is critical in a myriad of industries such as aerospace, automotive and chemical processing. Applications include wiring for nuclear plant control rooms, extruded and molded valves, tubes and pipes, low permeation tubing, UV resistant films, architectural films, and films used on the front of solar modules. Dyneon ETFE is characterized by the following features: Wide service temperature range Low flammability Excellent electrical and mechanical properties Very good resistance to solvents and chemicals Extremely high resistance to outdoor weathering High light transmission in the visible and UV ranges Non-stick characteristics Excellent tear resistance Low permeability Good resistance to radiation G = Pellet A = Agglomerate Method Unit ET 6235 Z ET 6210A Z Specific Gravity ASTM D 792 g/cm Melt Index 297/5kg ASTM D 1238 g/10 min 10 9 Hardness Shore D ASTM D Tensile Break 23, Microtensile bars 46 ASTM D 1708 Rate=2''/min 6,670 Break 23, Microtensile bars Rate=2''/min ASTM D 1708 % 5 Flexural Modulus 23, Injection Molded bars 1,100 ASTM D 790 (0.5''x0.125''x5.0'') 159, notched ASTM D 256 J/m (ft-lb/in) Izod Impact Strength -40 notched J/m (ft-lb/in) no break -40 unnotched J/m (ft-lb/in) Electrical Properties Dielectric Constant Dielectric Breakdown Strength G A MHz, ASTM D 9.4 GHz, mm film ASTM D 149 kv/mm mm film ASTM D 149 kv/mm Limiting Oxygen Index ASTM D 2863 % >30 >30 Thermal Glass Transition (Tg) DSC ASTM D Vertical Burn UL Bulletin 94 V-O Optical Properties Refractive Index (100 µ film) UV-Vis Light Transmission (100 µ film) Metricon Model 2010 Prism Coupler n D nm %T nm %T 84 4

Dyneon FEP Fluorothermoplastics G = Pellet A = Agglomerate Method Unit FEP 6301 Z FEP 6303 Z FEP 6307 Z FEP 6307R2R Z FEP 6322 Z FEP 6309 Z G G G G G G Specific Gravity ASTM D 792 g/cm 3 2.14 2.15 2.

5 Dyneon FEP Fluorothermoplastics G = Pellet A = Agglomerate Method Unit FEP 6301 Z FEP 6303 Z FEP 6307 Z FEP 6307R2R Z FEP 6322 Z FEP 6309 Z G G G G G G Specific Gravity ASTM D 792 g/cm Melt Index (372/5kg) ASTM D 1238 g/10 min Hardness Shore D ASTM D Tensile Strength at Break Elongation at Break Flexural Modulus Izod Impact Strength Electrical Properties Dielectric Constant Dissipation Factor Dielectric Breakdown Strength 23, Microtensile bars ASTM D 1708 Rate = 2''/min 4,350 4,060 3,625 2,900 3,480 23, Microtensile bars ASTM D 1708 % Rate = 2''/min 23, Injection Molded bars ASTM D 790 (0.5'' x 0.125'' x 5.0'') 77,000 84,000 84,000 84,000 84, notched ASTM D 256 J/m (ft-lb/in) notched J/m (ft-lb/in) no break no break no break 196 (3.7) no break -40 unnotched J/m 1 MHz, 23 ASTM D GHz, MHz ASTM D GHz mm film ASTM D 149 kv/mm Dyneon FEP (a polymer of tetrafluoroethylene and hexafluoropropylene) offers excellent chemical inertness, heat and weather resistance, exceptional electrical properties, toughness and durability. It is an essential component in films, linings, tapes, wires and cables in a variety of industries including telecommunications, wire and cable, semiconductor, paper, chemical, textile, food processing and packaging. Dyneon FEP is characterized by the following features: Service temperatures up to 200 (392) Excellent resistance to solvents and chemicals Outstanding electrical properties High limiting oxygen index: Does not support combustion Extremely smooth surface Limiting Oxygen Index ASTM D 2863 % >95 >95 >95 >95 >95 >95 Thermal Glass Transition (Tg) Heat Deflection Temperature DSC ASTM D ASTM D 648 Vertical Burn UL Bulletin 94 V-0 V-0 V-0 V-0 V-0 Optical Properties Refractive Index (100 µ film) UV-Vis Light Transmission (100 µ film) Metricon Model 2010 Prism Coupler n D nm %T nm %T

Dyneon PFA Fluorothermoplastics Dyneon PFA (a polymer of tetrafluoroethylene and perfluorovinylether) has exceptional heat resistance, excellent electrical properties and excellent chemical and

It is also used in several chemical industries and home appliance coatings applications.

6 Dyneon PFA Fluorothermoplastics Dyneon PFA (a polymer of tetrafluoroethylene and perfluorovinylether) has exceptional heat resistance, excellent electrical properties and excellent chemical and weather resistance. It is used in molded valves, pumps, tanks, filters and pipes, in heat trace cables and in wire for appliances, computers and in the aerospace industries. It is also used in several chemical industries and home appliance coatings applications. Our UHP (ultra high purity) grades are designed with very low metals and ion extractables for many semiconductor and pharmaceutical processing applications, in components such as wafer carriers, pipes and tubes, fittings, valves and pumps. Our PFA-FLEX grades have exceptional stress crack resistance and flex life, as well as very smooth surfaces. Dyneon PFA is characterized by the following features: Service temperatures up to 260 (500) Excellent universal resistance to solvents and chemicals Excellent weatherability Excellent electrical properties High light transmission High limiting oxygen index: Does not support combustion Extremely smooth surfaces Non-stick characteristics Good low-friction properties G = Pellet A = Agglomerate Method Unit PFA 6502N Z 6502T Z 6502UHP Z PFA 6502T Z/ 6502UHP Z* PFA 6505T Z PFA 6515N Z 6515T Z 6515UHP Z PFA 6525N Z 6525 T Z G G, A G G G Specific Gravity ASTM D 792 g/cm Melt Index 372/5kg ASTM D 1238 g/10 min Hardness Shore D ASTM D Tensile Strength at Break Elongation at Break Flexural Modulus Izod Impact Strength 23, Microtensile bars ASTM D 1708 Rate=2''/min 23, Microtensile bars Rate=2''/m 23, Injection Molded bars ASTM D 790 (0.5''x0.125''x5.0'') , , , , ,050 ASTM D 1708 % notched ASTM D 256 J/m (ft-lb/in) 0 80, , , , notched J/m (ft-lb/in) no break no break no break -40 unnotched J/m (ft-lb/in) no break no break no break Electrical Properties 1 MHz, 23 ASTM D GHz, Dissipation Factor Dielectric Breakdown 1 MHz ASTM D GHz mm film ASTM D 149 kv/mm Limiting Oxygen Index ASTM D 2863 % >95 >95 >95 >95 >95 Thermal Glass Transition (Tg) DSC ASTM D Vertical Burn UL Bulletin 94 V-O V-O V-O V-O Optical Properties Refractive Index (100 µ film) Metricon Model 2010 Prism Coupler * UHP is Ultra High Purity and T has improved thermal stability n D V-O 6

Dyneon PFA Fluorothermoplastics Method Unit PFA-FLEX 8502UHP Z PFA-FLEX 8515UHP Z G = Pellet A = Agglomerate G G Specific Gravity ASTM D 792 g/cm 3 2.145 2.

7 Dyneon PFA Fluorothermoplastics Method Unit PFA-FLEX 8502UHP Z PFA-FLEX 8515UHP Z G = Pellet A = Agglomerate G G Specific Gravity ASTM D 792 g/cm Melt Index 372/5kg ASTM D 1238 g/10 min Hardness Shore D ASTM D Tensile Break Break Flexural Modulus Izod Impact Strength 23, Microtensile bars ASTM D 1708 Rate = 2''/min 5,075 4,930 23, Microtensile bars ASTM D 1708 % Rate = 2''/min 23, Injection Molded bars ASTM D 790 (0.5'' x 0.125'' x 5.0'') 87,000 87, notched ASTM D 256 J/m (ft-lb/in) -40 notched -40 unnotched J/m (ft-lb/in) J/m (ft-lb/in) Electrical Properties Dielectric Constant Dissipation 1 MHz, 23 ASTM D GHz, 1 MHz ASTM D 150 < GHz Dielectric Breakdown Strength.25 mm film ASTM D 149 kv/mm Limiting Oxygen Index ASTM D 2863 % >95 >95 Thermal Glass Transition (Tg) DSC ASTM D 3418 Vertical Burn UL Bulletin 94 Optical Properties Refractive Index (100 µ film) Metricon Model 2010 Prism Coupler n D 7

Dyneon PVDF Fluorothermoplastics Dyneon PVDF (a polymer of vinylidene fluoride) is ideal for multiple applications across a wide array of industries.

building, electronics, chimney linings, batteries, food processing and pharmaceutical processing. Dyneon offers a range of homopolymers and copolymers with a wide variety of flexibility and strength.

8 Dyneon PVDF Fluorothermoplastics Dyneon PVDF (a polymer of vinylidene fluoride) is ideal for multiple applications across a wide array of industries. Widely used in the chemical processing industry, the semiconductor industry, and the wire and cable industry, PVDF is also gaining applications in industries as diverse asoil and gas, automotive, building, electronics, chimney linings, batteries, food processing and pharmaceutical processing. Dyneon offers a range of homopolymers and copolymers with a wide variety of flexibility and strength. Dyneon PVDF is characterized by the following features: Excellent mechanical strength Excellent dimensional stability Good chemical resistance Continuous service temperatures up to 150 (302) Excellent abrasion resistance Smooth, anti-fouling surfaces Excellent aging resistance Resistance to UV and nuclear radiation Excellent flame resistance Good permeation resistance Property G = Pellet A = Powder Method Units 1008/ / / / / /0003 G G G G G G Specific Gravity ASTM D 792 g/cm Melt Flow 230, 10 kg ASTM D 1238 g/10 min , 5 kg ASTM D 1238 g/10 min , 2.16 kg ASTM D 1238 g/10 min Hardness Shore D ASTM D Tensile Strength at Break Tensile Strength at Yield 23, 50mm/min ASTM D ASTM D , , Elongation at Break 23, 50mm/min ASTM D 638 % Elongation at Yield 23 ASTM D 638 % Flexural Modulus 23, 2mm/min ASTM D 790 2, ,000 2, ,000 1, ,000 2, ,500 2, ,500 Limiting Oxygen Index ASTM D 2863 % Heat of Fusion Brittleness Temperature 80 to end of melting 2 mm pressed sheet , ,500 ASTM D 3418 J/g ASTM D 746A Vertical Burn UL Bulletin 94 V-0 V-0 V-0 V-0 V-0 V Note: Many of the grades are available in multiple formulations - /0000 and /0001 are standard grades /0003 low smoke low flame grade /0009 high LOI grade /1001 standard powder grade /0180 plasticized grade 8

Dyneon PVDF Fluorothermoplastics Property Method Units 1012/0001 6012/0000 1015/1001 G = Pellet A = Powder G G A Specific Gravity ASTM D 792 g/cm 3 1.78 1.

9 Dyneon PVDF Fluorothermoplastics Property Method Units 1012/ / /1001 G = Pellet A = Powder G G A Specific Gravity ASTM D 792 g/cm Melt Flow 230, 10 kg ASTM D 1238 g/10 min , 5 kg ASTM D 1238 g/10 min , 2.16 kg ASTM D 1238 g/10 min Hardness Shore D ASTM D Tensile Strength at Break 23, 50mm/min ASTM D 638 Tensile Strength at Yield 23 ASTM D 638 Elongation at Break 23, 50mm/min ASTM D 638 % Elongation at Yield 23 ASTM D 638 % Flexural Modulus 23, 2mm/min ASTM D 790 2, ,500 2, , , ,000 Limiting Oxygen Index ASTM D 2863 % Heat of Fusion Brittleness Temperature 80 to end of melting 2 mm pressed sheet ASTM D 3418 J/g ASTM D 746A Vertical Burn UL Bulletin 94 V-0 V-0 na Homopolymer Poly(VF 2 ) 1000 and 6000 Series HFP Copolymer VF 2 - HFP Series CTFE Copolymer VF 2 - HFP Series Copolymer Blends Series Flexibility Elongation Mechanical Strength Hardness Impact Resistance High Temperature Resistance Base Line Improved Over Baseline Best Performance 9

Dyneon PVDF Fluorothermoplastics Property Method Units 11008/ 0001 11008/ 0003 11010/ 0000 31008/ 0003 31008/ 0009 G = Pellet A = Powder G G G G G Specific Gravity ASTM D 792 g/cm 3 1.78 1.78 1.78 1.76 1.

10 Dyneon PVDF Fluorothermoplastics Property Method Units 11008/ / / / / 0009 G = Pellet A = Powder G G G G G Specific Gravity ASTM D 792 g/cm Melt Flow 230, 10 kg ASTM D 1238 g/10 min , 5 kg ASTM D 1238 g/10 min , 2.16 kg ASTM D 1238 g/10 min Hardness Shore D ASTM D Tensile Strength at Break 23, 50mm/min ASTM D 638 Tensile Strength at Yield 23 ASTM D , , , , , , , ,480 Elongation at Break 23, 50mm/min ASTM D 638 % Elongation at Yield 23 ASTM D 638 % , ,625 Flexural Modulus 23, 2mm/min ASTM D 790 1, ,000 1, , , , ,000 Limiting Oxygen Index ASTM D 2863 % Heat of Fusion 80 to end of melting ASTM D 3418 J/g Brittleness Temperature 2 mm pressed sheet ASTM D 746A Note: Many of the grades are available in multiple formulations - /0000 and /0001 are standard grades /0003 low smoke low flame grade /0009 high LOI grade 10

Dyneon PVDF Fluorothermoplastics Property Method Units 31508/ 0003 31508/ 0009 32008/ 0009 60512/ 0000 G = Pellet A = Powder G G G G Specific Gravity ASTM D 792 g/cm 3 1.76 1.

11 Dyneon PVDF Fluorothermoplastics Property Method Units 31508/ / / / 0000 G = Pellet A = Powder G G G G Specific Gravity ASTM D 792 g/cm Melt Flow 230, 10 kg ASTM D 1238 g/10 min , 5 kg ASTM D 1238 g/10 min , 2.16 kg ASTM D 1238 g/10 min Hardness Shore D ASTM D Tensile Strength at Break 23, 50mm/min ASTM D 638 Tensile Strength at Yield 23 ASTM D , , , , , ,740 Elongation at Break 23, 50mm/min ASTM D 638 % Elongation at Yield 23 ASTM D 638 % , ,220 Flexural Modulus 23, 2mm/min ASTM D , , ,000 1, ,700 Limiting Oxygen Index ASTM D 2863 % Heat of Fusion 80 to end of melting ASTM D 3418 J/g Brittleness Temperature 2 mm pressed sheet ASTM D 746A Note: Many of the grades are available in multiple formulations - /0000 and /0001 are standard grades /0003 low smoke low flame grade /0009 high LOI grade 11

12 Imaginative Fluoropolymer Solutions At Dyneon, our goal is to provide you with solutions to make your job easier helping you with material selection now so that you can avoid problems later. Whatever your challenge, you can count on Dyneon to respond with dependable, high-performance fluoropolymer products. By working directly with our customers and exploring new technologies, we can ensure that our fluoropolymers will not only meet today s needs, but future design requirements as well. Our Worldwide Commitment to Quality Indicative of our commitment, all Dyneon design, development, production and service facilities have achieved global quality management certification. Production facilities have also received certification for their environmental management system. Please see the Dyneon website for the most up-to-date certification details. The Dyneon Product Portfolio: Dyneon PTFE, TFM PTFE, Custom PTFE Compounds Dyneon PFA, FEP, ETFE, PVDF, THV Fluoroplastics Dyneon Fluoroelastomers Dyneon Polymer Additives Dynamar Polymer Processing Additives Dynamar Elastomer Additives Dyneon Monomers Warranty, Limited Remedy, and Disclaimer: Many factors beyond Dyneon s control and uniquely within user s knowledge and control can affect the use and performance of a Dyneon product in a particular application. User is solely responsible for evaluating the Dyneon product and determining whether it is fit for a particular purpose and suitable for user s method of application. Unless a different warranty is specifically stated in the applicable product literature or packaging insert, Dyneon warrants that each Dyneon product meets the applicable Dyneon product specification at the time Dyneon ships the product. DYNEON MAKES NO OTHER WARRANTIES OR CONDITIONS, EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR ANY IMPLIED WARRANTY OR CONDITION ARISING OUT OF A COURSE OF DEALING, CUSTOM OR USAGE OF TRADE. If the Dyneon product does not conform to this warranty, then the sole and exclusive remedy is, at Dyneon s option, replacement of the Dyneon product or refund of the purchase price. Limitation of Liability: Except where prohibited by law, Dyneon will not be liable for any loss or damages arising from the Dyneon product, whether direct, indirect, special, incidental or consequential, regardless of the legal theory asserted, including warranty, contract, negligence or strict liability. Technical Information: Technical information, recommendations, and other statements contained in this document or provided by Dyneon personnel are based on tests or experience that Dyneon believes are reliable, but the accuracy or completeness of such information is not guaranteed. Such information is intended for persons with knowledge and technical skills sufficient to assess and apply their own informed judgment to the information. No license under any Dyneon or third party intellectual property rights is granted or implied with this information. Dyneon LLC Worldwide Headquarters rd Street North Oakdale, MN 128 USA Phone: Fax: Toll Free: Dyneon is a 3M company. Dyneon 2009 Printed in USA. Issued: 11/ HB All Rights Reserved. Dyneon, Dynamar, and TFM are trademarks of 3M. Used under license. Product Stewardship - Replacement Emulsifier. Dyneon fluoroplastic products identified with a Z following the product name indicate products that are made using Dyneon s replacement emulsifier. The new emulsifier is a polymerization aid used to manufacture certain fluoropolymers and is not an intended ingredient in the polymers. The emulsifier eliminates the use of the former polymerization aid, APFO (ammonium perfluorooctanoate, the ammonium salt of perfluorooctanoic acid (PFOA)), in the manufacture of these fluoropolymers. The use of the replacement emulsifier in the manufacture of these Dyneon products is consistent with Dyneon s product stewardship principles and our commitment to US EPA s Voluntary PFOA Stewardship Program under which fluoropolymer manufactures agreed to work towards eliminating PFOA in emissions and product content by the year Dyneon is pleased to report that we will have completed eliminated the use of APFO in our manufacturing processes by the end of December Dyneon LLC M Canada Company Sumitomo 3M Limited M Korea Limited Dyneon GmbH M Brazil LTDA M India Limited M China Limited M Mexico SA de CV Other Areas (U.S

Adding value to complex geometries.

3M TM Dyneon TM Fluoroplastics Adding value to complex geometries. Fluorothermoplastic Product Introduction Guide. 02 Introduction Melt processing for challenging applications. Industries such as chemical