Ingredient CAS Number Weight % ACGIH TLV PEL STEL Sulfuric acid mg/m3 1 mg/m3 3 mg/m3. Phosphoric Acid mg/m3 1 mg/m3 3 mg/m3

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1 Page 1 of 5 MSDS Document Product 1. Chemical Product and Company Identification Trade Name of this Product Manufacturer Haviland Products Company 421 Ann Street N.W. Grand Rapids, MI Phone Number (616) Emergency Phone CHEMTREC (800) CHEMTREC International (703) Revision Date 00/00/00 Health: Fire: Reactivity: Specific Composition and Information on Ingredients Ingredient CAS Number Weight % ACGIH TLV PEL STEL Sulfuric acid mg/m3 1 mg/m3 3 mg/m3 Phosphoric Acid mg/m3 1 mg/m3 3 mg/m3 3. Hazard Identification Emergency Overview Causes burns to eyes and skin. Harmful if swallowed. May be harmful if inhaled. Health Effects Exposure to mists by inhalation may cause irritation of the nose and throat with sneezing, sore throat or runny nose. Skin contact may cause skin corrosion, burns or ulcers. Eye contact may cause eye corrosion or ulceration; blindness may result. Immediate effects of ingestion may include burns of the mouth, throat, esophagus and stomach, with severe pain, bleeding, vomiting, diarrhea and collapse of blood pressure - damage may appear days after exposure. Carcinogenicity Strong inorganic acid mists containing sulfuric acid (Occupational exposures) are listed by IARC & NTP as carcinogens.

2 Page 2 of 5 IARC The International Agency for Research on Cancer (IARC) classified "strong inorganic acid mists containing sulfuric acid" as a Category 1 carcinogen, a substance that is "carcinogenic to humans". This classification is for strong inorganic acid mists only and does not apply to sulfuric acid or sulfuric acid solutions. NTP "Strong inorganic acid mists containing sulfuric acid" are also listed by The National Toxicology Program (NTP) as "known human carcinogens". This limits the classification to sulfuric acid aerosols and does not extend to the liquid product, unless the acid is used under conditions that result in the formation of mists or aerosols. Fuming acid is covered by the classification. Reproductive Effects None known Routes of Entry Inhalation, Ingestion, Skin or Eye Contact 4. First Aid Information Eye Contact Flush immediately with plenty of water for at least 15 minutes, get medical attention. Skin Contact Flush with water for at least 15 minutes while removing contaminated clothing. If irritation persists, get medical attention. Inhalation Remove to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion Call a physician immediately. Do not induce vomiting. Dilute by drinking water or milk. Never give anything by mouth to an unconscious person. 5. Fire Fighting Measures Flash Point N/A Extinguishing Media Use media appropriate for surrounding material. Use water spray to cool containers exposed to fire. DO NOT get water inside containers. Special Fire Fighting Procedures Evacuate personnel to a safe area. Keep personnel removed and upwind of fire. Generates heat upon addition of water, with possibility of spattering. Wear full protective clothing. Runoff from fire control may cause pollution. Neutralize run-off with lime, soda ash, etc., to prevent corrosion of metals and formation of hydrogen gas. Wear self-contained breathing apparatus if fumes or mists are present.

3 Page 3 of 5 Unusual Fire Hazard Reacts with most metals, especially when dilute: Hydrogen gas release (Extremely flammable, explosive). 6. Accidental Release Measures Spill and Leak Procedures Stop flow if possible. Soak up small spills with dry sand, clay or diatomaceous earth. Dike large spills, and cautiously dilute and neutralize with lime or soda ash, and transfer to waste water treatment system. Prevent liquid from entering sewers, waterways, or low areas. 7. Handling and Storage Handling Procedures Do not get in eyes, on skin, or on clothing. Wear eye protection and protective clothing. Do not breathe vapor or spray mist. Wash thoroughly after handling. As with all chemicals, good industrial hygiene practices should be followed when handling this material. Storage Procedures Keep container tightly closed and closure up to prevent leakage. Keep out of sun and away from heat, sparks, and flame. Loosen closure carefully. Relieve internal pressure when received and at least weekly thereafter. Do not use pressure to empty. Be sure closure is securely fastened before moving container. Do not wash out container or use it for other purposes. Replace closure after each withdrawal and return it with empty container. 8. Exposure Controls and Personal Protection Engineering Controls Good general ventilation should be provided to maintain vapor concentrations below the recommended limits. Eye Protection Chemical safety goggles Protective Gloves Rubber or other impervious materials. Respiratory Protection When respirators are required, select NIOSH/MSHA approved air-purifying (half-mask/full-face) respirator with cartridges/canister approved for use against acid gases. Other Protective Equipment For operations where spills or splashing may occur, use an impervious body covering and boots. A safety shower and eye bath should be available. 9. Physical and Chemical Properties Physical State Liquid

4 Page 4 of 5 Specific Gravity 1.75 Color/Appearance Clear liquid Odor Odorless ph Not Established Boiling/Cond. Point Not Available Melting/Freezing Point Not Available Solubility Complete Vapor Density Not Available Vapor Pressure Not Available 10. Stability and Reactivity Chemical Stability Stable Conditions to Avoid Avoid exposure to heat and direct sunlight. Incompatible Materials Alkaline solutions, metals, strong oxidizers, reducers, or combustible organic materials. Hazardous gases are evolved on contact with chemicals such as cyanides, sulfides, and carbides. Hazardous Decomposition Products Oxides of sulfur, hydrogen sulfide, toxic fumes of phosphorus pentoxide Hazardous Polymerization Will not occur. 11. Toxicological Information No information available. 12. Ecological Information No information available. 13. Disposal Considerations Waste Disposal Cleaned-up material may be a RCRA Hazardous Waste upon disposal due to corrosivity, or properly treat in waste treatment system. Do not flush to surface water or sanitary sewer system. Comply with all federal, state and local regulations. 14. Transportation Information DOT Shipping Name Corrosive liquid, acidic, inorganic, n.o.s. (Phosphoric Acid, Sulfuric Acid) Hazard Class 8, Corrosive

5 Page 5 of 5 UN Number UN3264 Packing Group PG II 15. Regulatory Information Reportable Quantity 2500 lb. EHS Hazardous Component(s) Contain Extremely Hazardous Substance. TSCA Hazardous Component(s) subject to reporting on the TSCA List. WHMIS Hazardous Component(s) subject to WHMIS Ingredient Disclosure. 16. Other Information This information is based upon technical information believed to be reliable. It is subject to revision as additional knowledge and experience is gained. Disclaimer Nothing contained herein grants or extends a license, express or implied, in connection with patents, issued or pending, of the manufacturer or others. The manufacturer makes no warranties, expressed or implied, as to the accuracy, completeness, or adequacy of the information contained herein. The manufacturer shall not be held liable (regardless of fault) to the vendee's employees, or anyone for any direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of such information.

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