Materials Science and Engineering: An Introduction
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1 Materials Science and Engineering: An Introduction Callister, William D. ISBN-13: Table of Contents List of Symbols. 1 Introduction. 1.1 Historical Perspective. 1.2 Materials Science and Engineering. 1.3 Why Study Materials Science and Engineering? 1.4 Classification of Materials. 1.5 Advanced Materials. 1.6 Modern Materials' Needs. 1.7 Processing/Structure/Properties/Performance Correlations. Question. 2 Atomic Structure and Interatomic Bonding. 2.1 Introduction. Atomic Structure. 2.2 Fundamental Concepts. 2.3 Electrons in Atoms. 2.4 The Periodic Table. Atomic Bonding in Solids. 2.5 Bonding Forces and Energies. 2.6 Primary Interatomic Bonds. 2.7 Secondary Bonding or van der Waals Bonding. 2.8 Molecules. Equation Processing/Structure/Properties/Performance 3 The Structure of Crystalline Solids.
2 3.1 Introduction. Crystal Structures. 3.2 Fundamental Concepts. 3.3 Unit Cells. 3.4 Metallic Crystal Structures. 3.5 Density Computations. 3.6 Polymorphism and Allotropy. 3.7 Crystal Systems. Crystallographic Points, Directions, and Planes. 3.8 Point Coordinates. 3.9 Crystallographic Directions Crystallographic Planes Linear and Planar Densities Close-Packed Crystal Structures. Crystalline and Noncrystalline Materials Single Crystals Polycrystalline Materials Anisotropy X-Ray Diffraction: Determination of Crystal Structures Noncrystalline Solids. Equation Processing/Structure/Properties/Performance 4 Imperfections in Solids. 4.1 Introduction. Point Defects. 4.2 Vacancies and Self-Interstitials. 4.3 Impurities in Solids. 4.4 Specification of Composition. Miscellaneous Imperfections. 4.5 Dislocation Linear Defects. 4.6 Interfacial Defects. 4.7 Bulk or Volume Defects. 4.8 Atomic Vibrations.
3 Microscopic Examination. 4.9 Basic Concepts of Microscopy Microscopic Techniques Grain Size Determination. Equation Processing/Structure/Properties/Performance 5 Diffusion. 5.1 Introduction. 5.2 Diffusion Mechanism. 5.3 Steady-State Diffusion. 5.4 Nonsteady-State Diffusion. 5.5 Factors That Influence Diffusion. 5.6 Diffusion in Semiconducting Materials. 5.7 Other Diffusion Paths. Equation Processing/Structure/Properties/Performance 6 Mechanical Properties of Metals. 6.1 Introduction. 6.2 Concepts of Stress and Strain. Elastic Deformation. 6.3 Stress-Strain Behavior. 6.4 Anelasticity. 6.5 Elastic Properties of Materials. Plastic Deformation. 6.6 Tensile Properties. 6.7 True Stress and Strain. 6.8 Elastic Recovery After Plastic Deformation.
4 6.9 Compressive, Shear, and Torsional Deformations Hardness. Property Variability and Design/Safety Factors Variability of Material Properties Design/Safety Factors. Equation Processing/Structure/Properties/Performance 7 Dislocations and Strengthening Mechanisms. 7.1 Introduction. Dislocations and Plastic Deformation. 7.2 Basic Concepts. 7.3 Characteristics of Dislocations. 7.4 Slip Systems. 7.5 Slip in Single Crystals. 7.6 Plastic Deformation of Polycrystalline Materials. 7.7 Deformation by Twinning. Mechanism of Strengthening in Metals. 7.8 Strengthening by grain Size Reduction. 7.9 Solid-Solution Strengthening Strain Hardening. Recovery, Recrystallization, and Grain Growth Recovery Recrystallization Grain Growth. Equation 8 Failure. 8.1 Introduction. Fracture. 8.2 Fundamentals of Fracture. 8.3 Ductile Fracture. 8.4 Brittle Fracture.
5 8.5 Principles of Fracture Mechanics. 8.6 Fracture Toughness Testing. Fatigue. 8.7 Cyclic Stresses. 8.8 The S N Curve. 8.9 Crack Initiation and Propagation Factors That Affect Fatigue Life Environmental Effects. Creep Generalized Creep Behavior Stress and Temperature Effects Data Extrapolation Methods alloys for High-Temperature Use. Equation Processing/Structure/Properties/Performance 9 Phase Diagrams. 9.1 Introduction. Definitions and Basic Concepts. 9.2 Solubility Limit. 9.3 Phases. 9.4 Microstructure. 9.5 Phase Equilibria. 9.6 One-Component (or Unary) Phase Diagrams. Binary Phase Diagrams. 9.7 Binary Isomorphous Systems. 9.8 Interpretation of Phase Diagrams. 9.9 Development of Microstructure in Isomorphous Alloys Mechanical Properties of Isomorphous Alloys Binary Eutectic Systems Development of Microstructure in Eutectic Alloys Equilibrium Diagrams Having Intermediate Phases or Compounds Eutectoid and Peritectic Reactions.
6 9.15 Congruent Phase Transformations Ceramic and Ternary Phase Diagrams The Gibbs Phase Rule. The Iron Carbon System The Iron Iron Carbide (Fe Fe 3 C) Phase Diagram Development of Microstructure in Iron Carbon Alloys The Influence of Other Alloying Elements. Equation Processing/Structure/Properties/Performance 10 Phase Transformations in Metals: Development of Microstructure and Alteration of Mechanical Properties Introduction Basic Concepts The Kinetics of Phase Transformations Metastable Versus Equilibrium States Isothermal Transformation Diagrams Continuous Cooling Transformation Diagrams Mechanical Behavior of Iron Carbon Alloys Tempered Martensite Review of Phase Transformations and Mechanical Properties for Iron Carbon Alloys. Equation Processing/Structure/Properties/Performance 11 Applications and Processing of Metal Alloys Introduction. Types of Metal Alloys Ferrous Alloys Nonferrous Alloys. Fabrication of Metals Forming Operations.
7 11.5 Casting Miscellaneous Techniques. Thermal Processing of Metals Annealing Processes Heat Treatment of Steels Precipitation Hardening. Equation Processing/Structure/Properties/Performance 12 Structures and Properties of Ceramics Introduction. Ceramic Structures Crystal Structures Silicate Ceramics Carbon Imperfections in Ceramics Diffusion in Ionic Materials Ceramic Phase Diagrams. Mechanical Properties Brittle Fracture of Ceramics Stress Strain Behavior Mechanisms of Plastic Miscellaneous Mechanical Considerations. Equation Processing/Structure/Properties/Performance 13 Applications and Processing of Ceramics Introduction.
8 Types and Applications of Ceramics Glasses Glass-Ceramics Clay Products Refractories Abrasives Cements Advanced Ceramics. Fabrication and Processing of Ceramics Fabrication and Processing of Glasses and Glass-Ceramics Fabrication and Processing of Clay Products Powder Pressing Tape Casting. Equation Processing/Structure/Properties/Performance Design Problem. 14 Polymer Structures Introduction Hydrocarbon Molecules Polymer Molecules The Chemistry of Polymer Molecules Molecular Weight Molecular Shape Molecular Structure Molecular Configurations Thermoplastic and Thermosetting Polymers Copolymers Polymer Crystallinity Polymer Crystals Defects in Polymers Diffusion in Polymeric Materials. Equation Processing/Structure/Properties/Performance
9 15 Characteristics, Applications, and Processing of Polymers Introduction. Mechanical Behavior of Polymers Stress Strain Behavior Macroscopic Deformation Viscoelastic Deformation Fracture of Polymers Miscellaneous Mechanical Characteristics. Mechanism of Deformation and for Strengthening of Polymers Deformation of Semicrystalline Polymers Factors That Influence the Mechanical Properties of Semicrystalline Polymers Deformation of Elastomers. Crystallization, Melting, and Glass Transition Phenomena in Polymers Crystallization Melting The Glass Transition Melting and Glass Transition Temperatures Factors That Influence Melting and Glass Transition Temperatures. Polymer Types Plastics Elastomers Fibers Miscellaneous Applications Advanced Polymeric Materials. Polymer Synthesis and Processing Polymerization Polymer Additives Forming Techniques for Plastics Fabrication of Elastomers Fabrication of Fibers and Films. Equation Processing/Structure/Properties/Performance
10 Design Questions. 16 Composites Introduction. Particle-Reinforced Composites Large-Particle Composites Dispersion-Strengthened Composites. Fiber-Reinforced Composites Influence of Fiber Length Influence of Fiber Orientation and Concentration The Fiber Phase The Matrix Phase Polymer-Matrix Composites Metal-Matrix Composites Ceramic-Matrix Composites Carbon Carbon Composites Hybrid Composites Processing of fiber-reinforced Composites. Structural Composites Laminar Composites Sandwich Panels. Equation Processing/Structure/Properties/Performance 17 Corrosion and Degradation of Materials Introduction. Corrosion of Metals Electrochemical Considerations Corrosion Rates Prediction for Corrosion Rates Passivity Environmental Effects.
11 17.7 Forms of Corrosion Corrosion Environments Corrosion Prevention Oxidation. Corrosion of Ceramic Materials. Degradation of Polymers Swelling and Dissolution Bond Rupture Weathering. Equation Processing/Structure/Properties/Performance 18 Electrical Properties Introduction. Electrical Conduction Ohm's Law Electrical Conductivity Electronic and Ionic Conduction Energy Band Structures in Solids Conduction in Terms of Band and Atomic Bonding Models Electron Mobility Electrical Resistivity of Metals Electrical Characteristics of Commercial Alloys. Semiconductivity Intrinsic Semiconduction Extrinsic Semiconduction The Temperature Dependence of Carrier Concentration Factors That Affect Carrier Mobility The Hall Effect Semiconductor Devices. Electrical Conduction in Ionic Ceramics and in Polymers Conduction in Ionic Materials Electrical Properties of Polymers. Dielectric Behavior.
12 18.18 Capacitance Field Vectors and Polarization Types of Polarization Frequency Dependence of the Dielectric Constant Dielectric Strength Dielectric Materials. Other Electrical Characteristics of Materials Ferroelectricity Piezoelectricity. Equation Processing/Structure/Properties/Performance 19 Thermal Properties Introduction Heat Capacity Thermal Expansion Thermal Conductivity Thermal Stresses. Equation Processing/Structure/Properties/Performance 20 Magnetic Properties Introduction Basic Concepts Diamagnetism and Paramagnetic Ferromagnetism Antiferromagnetism and Ferrimagnetism The Influence of Temperature on Magnetic Behavior Domains and Hysteresis.
13 20.8 Magnetic Anisotropy Soft Magnetic Materials Hard Magnetic Materials Magnetic Storage Superconductivity. Equation Processing/Structure/Properties/Performance 21 Optical Properties Introduction Electromagnetic Radiation Light Interactions with Solids Atomic and Electronic Interactions Refraction Reflection Absorption Transmission Color Opacity and Translucency in Insulators Luminescence Photoconductivity Lasers Optical Fibers in Communications. Equation Processing/Structure/Properties/Performance Design Problem. 22 Economic, Environmental, and Societal Issues in Materials Science and Engineering Introduction.
14 22.2 Component Design Materials Manufacturing Techniques Recycling Issues in Materials Science and Engineering. Design Questions. Appendix A The International System of Units (SI). Appendix B Properties of Selected Engineering Materials. B.1 Density. B.2 Modulus of Elasticity. B.3 Poisson's Ratio. B.4 Strength and Ductility. B.5 Plane Strain Fracture Toughness. B.6 Linear Coefficient of Thermal Expansion. B.7 Thermal Conductivity. B.8 Specific Heat. B.9 Electrical Resistivity. B.10 Metal Alloy Compositions. Appendix C Costs and Relative Costs for Selected Engineering Materials. Appendix D Repeat Unit Structures for Common Polymers. Appendix E Glass Transition and Melting Temperatures for Common Polymeric Materials. Mechanical Engineering Online Support Module. Glossary. Answers to Selected Problems. Index.
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