// Optical Immersion Probes // Fiber Optical Flow Cells. for UV/Vis/NIR spectroscopy

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1 High Precision in Spectro-Optics Immersion Probe Configurator More than 5, options to build your individual immersion probe. // Optical Immersion Probes // Fiber Optical Flow Cells for UV/Vis/ spectroscopy Solutions for: Pharma, Agriculture, Chemistry, Polymer, Food & Feed, Beverage, Oil & Gas, Water

2 Optical Immersion Probes and Fiber Optical Flow Cells. Immersion Probes and Flow Cells support engineers, researchers and analysts in several fields where process efficiency is required. // Chemical and Petrochemical Industry // Pharmacy and Life Science // Food and Beverage // Polymers Hellma Analytics offers a broad product range and 9 years of unique manufacturing experience. Standard Products Transmission // Excalibur Page 6 Fluorescence // ESPADA Page 7 Transflection // Falcata Page 8 Accessories Page 9 Transmission // Excalibur Page 12 Transflection // Falcata Page 14 REflection // Gladius Page 16 ATR // Katana Page 18 Accessories Page 2 Standard Products Custom Products Product Overview Page 22 Custom Products 3

3 UV/Vis & measurements with Immersion Probes Optical fiber Measurement principles Measuring Principle // TM FC Transmission Fluorescence Transflection Excalibur Range ESPADA Range Falcata Range TF Spectrophotometer Fiber-optic cable connector or SMA sockets Immersion probe Source Light beam Detector Benefits // Higher process efficiency and performance // Simple and safe process monitoring // Optimal control of complex reaction processes // Proactive process and quality management // Provable enhanced product and measurement quality // Fast return on investment // Professional consulting from highly educated Engineers Common fields of application Qualitative and quantitative product analysis and determination of chemical and physical parameters // Hydroxyl number // Acid number // Peroxide number // Iodine number // Octane rating // Fractioning control // Aromatics content // Alcohol concentration // Caffeine // Amino acids // Moistness, proteins and oil content in foods // Fat, water, lactose and solids in milk Measuring Principle // The world s highest quality transmission measuring head guarantees an unmatched precision for your applications. Sophisticated bonding technology and more than 9 years of experience in manufacturing optical parts guarantees a measuring head of the highest quality. Profit from the outstanding reproducibility for your measurements. Reflection Gladius Range RF By means of a 9 deflection of the incident light, the excitation and fluorescence beams are well separated. Integrated mirrors increase the light yield. ATR Katana Range ATR Path length tips can be exchanged quickly and easily to adjust the optical path length between 1 mm and 2 mm. After passing through the solution to be measured, the light beam is reflected by a rear-coated mirror and passes through the solution a second time. 4 Reaction monitoring and reaction endpoint determination // Polymerization // Hydrogenation // Hydrolysis // Esterification // Epoxidation Common sample CHARACTER // Transparent or moderately turbid solutions // Solids, powders // Pastes and slurries // Emulsion and Dispersion The spectrometric measurement of the diffused reflection is a powerful tool for qualitative and quantitative analysis of powdered or granuled solids and compounds. A part of the diffused light penetrates into the surface and thus leads to a probe-specific change in the spectrum, from which inferences for the material properties can be derived. Ideal for measurements in solvents where the use of epoxy for probe assembly is unsuitable. Probe uses a 3-bounce sapphire ATR crystal, which is directly immersed into the solution. 5

4 Standard Products. This overview shows a variety of standard products, which are very flexible in their usage and available for short term delivery. These immersion probes COVERs MANY APPLICATION FiELDS. TM TRansmisson Excalibur RANGE EXCALIBUR STANDARD IMMERSION PROBE All-QUARTZ Probe These Hellma Analytics all-quartz probes are outstanding due to its unique design which makes additional sealing material superfluous. This makes them the ideal tool for measuring aggressive samples even at the lowest temperatures measuring beyond the limits. mm (tolerance ±.1) Outer Diameter Probe Body Material Sealing Technology Fiber Optical Connection Temperature Range Pressure Range Immersion Depth 1 mm, 2 mm, 5 mm, 1 mm, 2 mm Probe head: 15 mm barrel: 18 mm Directly fused UVS/Vis approx. 4 % in air above 3 nm approx. 4 % in air above 4 nm 1.8 m external fiber optical cables with SMA connectors 5 C to 15 C (-18 C to 15 C with vacuum jack) -1 bar to 6 bar 21 mm (1 mm light path) UVS s S N S N S N S N S N-46 Price (E) 4,22 4,22 With vacuum jack for low temperature applications UVS s S N S N S N S N S N-46 Price (E) 4,862 4,862 Excalibur Flow-Through Cell for Process Control This Hellma Analytics flow-through cell was developed for on-line measurements where the diameter of the pipe is very small. mm (tolerance ±.4) 1 mm, 2 mm, 5 mm, 1 mm Outer Diameter 45 mm Sapphire Probe Body Material Stainless Steel Length 56 mm (1 mm path length) Sealing Technology Kalrez UV approx. 4 % above 3 nm approx. 4 % in air above 4 nm Fiber Optical Connection SMA connectors Temperature Range 5 C to 26 C Pressure Range -1 bar to 1 bar Process Connection Swagelok connectors UV s U N U N U N U N-85 Price (E) 4,326 4,326 EXCALIBUR STANDARD IMMERSION PROBE ALL-ROUND PROBE This classic transmission probe features a broad range of possible applications. Whether for use in the lab, for online monitoring in process environment or even for TDA-measurements it is always the right choice. mm (tolerance ±.1) 1 mm, 2 mm, 5 mm, 1 mm, 2 mm probe head 15 mm Outer Diameter probe shaft 2 mm protective sleeve 2 mm Probe Body Material Stainless steel (316 L) Sealing Technology Kalrez 6375 Kalrez 479 UVS/Vis approx. 4 % in air above 3 nm approx. 4 % in air above 4 nm Fiber Optical Connection 1.8 m external fiber optical cables with SMA connectors Temperature Range 5 C to 15 C Pressure Range -1 bar to 6 bar Immersion Depth 1 mm (1 mm light path) UVS s S N S N S N S N S N-46 Price (E) 4,27 4,27 EXCALIBUR STANDARD IMMERSION PROBE ALL-QUARTZ PROBE Tapered version with ground glass joint NS 19/35 mm (tolerance ±.1) Outer Diameter Probe Body Material Sealing Technology Fiber Optical Connection 1 mm, 2 mm, 5 mm,1 mm, 2 mm 15.5 mm (probe head) Taper NS 19/35 Directly fused UVS/Vis approx. 4 % in air above 3 nm approx. 4 % in air above 4 nm 1.8 m external fiber optical cables with SMA connectors Temperature Range 5 C to 15 C Pressure Range -1 bar to 6 bar Immersion Depth 13 mm (1 mm light path) UVS s S N S N S N S N S N-46 Price (E) 4,748 4,748 FC FLUORESCENcE ESPADA RANGE ESPADA STANDARD IMMERSION PROBE The Hellma Analytics fluorescence immersion probe makes it possible to measure fluorescence outside of a fluorimeter, directly in the medium being investigated. To achieve the best possible separation between the excitation and fluorescence beams, the fluorescent light is captured at a right angle to the incoming beam. A stainless steel casing protects the quartz glass probe head from damage and reduces the amount of incoming ambient light. probe head 15 mm Outer Diameter probe shaft 2 mm protective sleeve 2 mm Probe Body Material Stainless steel (316 L) Sealing Technology Kalrez 6375 Kalrez 479 UVS/Vis Fiber Optical Connection Temperature Range 5 C to 15 C Pressure Range -1 bar to 6 bar Immersion Depth 1 mm S-46 Price (E) 4, m external fiber optical cables with SMA connectors Standard Products 6 7

5 TRansflection FALCATA RANGE These transflection immersion probes have been specifically designed for laboratories and small volume analyses. They are available with fixed path lengths and very small outer diameters e.g. 3.2 mm/4 mm/6 mm. The 6 mm version offers increased flexibility due to interchangeable path length tips. FALCATA STANDARD IMMERSION PROBE with 3.2 mm and 4 mm diameter These micro immersion probes have been specifically developed for measurements in small volumes. Due to their slim form, less sample material is required for a measurement to be taken. Accessories standard products External Cell Holder The external cell holder is useful when the spectrophotometer does not have an internal cell holder or when measurements with cells are to be made at some distance from the spectrophotometer e.g. in a fume hood. To connect this cell holder properly to your system you will require, 2 x 1m fiber optic cables in the corresponding spectral range. You should select the option SMA-Collimator. FIBER OPTIC INTERFACE This accessory is to be used when SMA sockets are not available on your spectrophotometer. To connect this interface properly to your system you will require, in addition to your probe, 2 x 1m fiber optic cables in the corresponding spectral range. You should select the option SMA-Collimator. The SMA end is connected to your probe via a small SMA/SMA adapter and the collimating ends are plugged into the interface. mm (tolerance ±.2) 5 mm, 1 mm Outer Diameter 3.2 mm/4 mm Probe Body Material Stainless steel (316 L) Sealing Technology Epoxy glue UVS/VIS approx. 3 % in air above 3 nm approx. 3% in air above 4 nm Fiber Optical Connection FALCATA STANDARD IMMERSION PROBE with 6 mm diameter Increased flexibility due to interchangeable path length tips. mm (tolerance ±.2) Outer Diameter 1 mm, 2 mm, 5 mm, 1 mm, 2 mm through interchangeable tips 6 mm Probe Body Material Stainless Steel (316 L) Sealing Technology Epoxid glue UVS/Vis approx. 4% in air above 3 nm approx. 4% in air above 4 nm Fiber Optical Connection 1.8 m external fiber optical cables with SMA connectors Temperature Range 5 C to 15 C Pressure Range -1 bar to 6 bar Immersion Depth 75 mm/13 mm (1 mm path length) 1.8 m external fiber optical cables with SMA connectors Temperature Range 5 C to 15 C Pressure Range -1 bar to 6 bar Immersion Depth 175 mm (1 mm light path) Falcata Standard Immersion Probe 3.2 mm diameter UVS s S N S N-46 Price (E) 2,647 2,647 Falcata Standard Immersion Probe 4 mm diameter UVS s S N S N-46 Price (E) 2,647 2,647 UVS s 1/2/5/1/ set-S set-N-46 Price (E) 2,961 2, S N S N S N S N S N-46 Price (E) 2,24 2,24 Accessories interchangeable Path Length tips Path Length tips s Price (E) 18 Material Aluminium, Black Anodised Dimensions 123 mm x 4 mm x 45 mm Temperature of solution in cell Max. 12 C ( Cells Only) Ambient temperature Max. 5 C Fiber Optic Cables These must be ordered separately. Notes Suitable for cells with path length 1 mm to 2 mm Price (E) 798 STANDARD FIBER OPTIC CABLES Fiber optic cables can be supplied with either SMA connectors or special collimating lenses to suit the application that they are being used for. Fibers are protected by metal silicon coverings. Core Diameter 6 µm Nummerical Aperture.22 Beam Diameter (lens) 3.7 mm Max. Temperature 15 Effective Aperture 4 mm diameter Outside Dimensions 6 mm x 12.5 mm x 12.5 mm Center Height 8.5/15/2 mm Wavelength Range 19 nm to 23 nm, depends on cables used Notes Other center heights on request UV UV UV-46 Price (E) 587 Accessory SMA/SMA adapter Wavelength length SMA SMA SMA Collimator UV number Price (E) (E) per piece (E) per piece 1 m ALN1LSS 393 ALN1LSC m ALN2LSS 381 ALN2LSC 51 3 m ALN3LSS 478 ALN3LSC 66 4 m ALN4LSS 574 ALN4LSC 73 5 m ALN5LSS 671 ALN5LSC 8 6 m ALN6LSS 767 ALN6LSC m ALN7LSS 864 ALN7LSC m ALN8LSS 96 ALN8LSC 1,89 1 m ALU1LSS 393 ALU1LSC m ALU2LSS 381 ALU2LSC 51 3 m ALU3LSS 478 ALU3LSC 66 4 m ALU4LSS 574 ALU4LSC 73 5 m ALU5LSS 671 ALU5LSC 8 6 m ALU6LSS 767 ALU6LSC m ALU7LSS 864 ALU7LSC m ALU8LSS 96 ALU8LSC 1,89 Standard Products 8 7 m ALS7LSS 1,124 ALS7LSC 1,248 9 UVs 1 m ALS1LSS 431 ALS1LSC m ALS2LSS 448 ALS2LSC m ALS3LSS 583 ALS3LSC 77 4 m ALS4LSS 718 ALS4LSC m ALS5LSS 854 ALS5LSC m ALS6LSS 989 ALS6LSC 1,112 8 m ALS8LSS 1,259 ALS8LSC 1,383

6 . The building blocks of our modular program We offer you a wide variety of options to design and build your individualized probe. TOP-INNOVATION More than 5, options possible. Start your probe configuration now! Find your individual probe through our modular design principle. You couldn t find a suitable immersion probe in the standard program? No problem! The worlds only configurator for optical immersion probes allows you to build your individual immersion probe in a few minutes! Try it for yourself online it is so easy to use and saves a lot of time: s //» 1 mm» 2 mm» 5 mm» 1 mm» 2 mm Probe body diameters //» 6 mm» 12 mm» 2 mm» 25 mm s //» Glass: Best optical performance» Sapphire: Robust and highly resistant Temperature Range //» Several options from - 8 C to 3 C Probe Body Materials //» Stainless Steel: (316 Ti), (316 L)» Hastelloy : C 22 (2.462)» Titanium: Grade 2 (3.735)» Tantalum Sealing Technologies //» Kalrez : 6375» Kalrez : 479» Kalrez : 775» Brazed Titanium and Sapphire Choose a measuring method based on your application. Choose from Standard Series immersion probes or build your individual immersion probe. Now available online! Configuration, requests, ordering and much more information. Immersion Depth //» Choose your immersion depth up to 9 mm Pressure Range //» Several options from -1 bar to 3 bar Several flange options //» Flanges, ANSI, GOST, JIS, quick change fittings and more Material certificates upon request. spectral Range //» (/Sapphire: 4 nm to 2,3 nm)» UVS-Vis Range (: 19 nm to 1,1 nm/ Sapphire: 24 nm to 1,1 nm) Additional Options //» For further probe options see individual data sheet Immersion Probe for PAT solutions. Connection to spectrophotometer by SMA connectors or interface and fiber optical cables Kalrez is a registered trademark of DuPont Performance Elastomers L.L.C. Hastelloy is a registered trademark name of Haynes International, Inc.

7 Modular Immersion Probes Excalibur Range Use the internet configurator or the table below to configure your modular immersion probe. Base Model E2 Excalibur 12 E3 Excalibur 2 E4 Excalibur 25 The figures behind the product name indicate the different outer diameter (in mm) of the probes. Price (E) 6,226 6,446 6,72 The Excalibur Immersion probes are built for transparent and liquid solutions. They withstand extreme process conditions and due to their monolithic measuring head these probes are the best solution for highest demands. Optical Path Length A B C D E 1 mm 2 mm 5 mm 1 mm 2 mm Q S Sapphire Red = Standard configuration Common applications include: Reaction monitoring in chemical synthesis Control of process chromatography Color number determination Reaction endpoint determination Profit from clear advantages // Monolithic measuring head // Extremely high pathlength accuracy // Highly chemical resistant Probe Body Material Sealing Technology Spectral range E Stainless Steel (316 Ti) H Hastelloy C-22 (2.462) Z Kalrez 6375 Y Kalrez 775 N U (4 nm to 2,3 nm) UVS/Vis Low solarization (19 nm to 1,1 nm for quartz/ 24 nm to 1,1 nm for sapphire) S Female sockets for SMA (no external fibers) and PMA connector 1, // Easy scale up from lab to process // Easy to clean fiber optical A E Female sockets for SMA (no external fibers) and ATEX proof PMA connector 2 m external fiber optical cables and PMA housing with SMA connectors Schematic Drawing // Minimum possible stray light // Minimal service required // Compatible with most spectrophotometers Flange Standard fiber optical process B 2 m external fiber optical cables and ATEX proof PMA housing with SMA connectors A No Flange B DN 25/PN 4 Typ 5 Form A C DN 5/PN 4 Typ 5 Form A D DN 8/PN 4 Typ 5 Form A E ANSI lbs F ANSI lbs H ANSI lbs I JIS 1K2A J GOST DN 25/PN 4 K Ingold fitting (only in combination with Excalibur 25) Ti HC , , , , ,375 Ø12/2/25 mm Immersion Depth (with flange) 5 mm 98 mm temperature range Pressure range Q Quick Change Fitting, PG 13.5 (only applies to Excalibur 12) L 5 C to 18 C J -1 C to 26 C L -1 bar to 35 bar (without flange) or according to flange specifications Immersion Depth (without flange) Excalibur (Light path 2 mm) // UVS-VIS Excalibur (Light path 1 mm) // mm immersion depth Purging C -1 bar to 5 bar (without flange) 24 mm 1 mm to 239 mm 241 mm to 4 mm 41 mm to 7 mm 71 mm to 9 mm Length for quick change fittings with 12 mm Length for quick change fittings with 225 mm N Y No Yes Ti HC 22/Ti , , , TOTAL 2 2 P Example P E 2 Excalibur 12 B Q E Z N S A L L 2 4 N glass Sapphire glass Sapphire Don t forget the accessories! Fiber optical cables and other accessories can be found on page 22. Configuration options do not fit your needs? We are also able to build customized optical immersion probes suitable for virtually every process condition.

8 Modular Immersion Probes Falcata Range The Falcata Transflection probes HAVE been specifically designed for the use in laboratories and pilot plants. They provide high flexibility and can be used in a multitude of applications due to their high degree of flexibility realized through the interchangeable optical path length tips. Common applications include: use in multipurpose plants fermentation processes organic chemical process development Schematic Drawing (2 x gap distance) 25 mm Ø6/12 mm Immersion Depth (with flange) Immersion Depth (without flange) 5 mm Flange 1 mm 98 mm Falcata (light path 2 mm) // UVS-VIS Falcata (light path 2 mm) // glass & Sapphire (Falcata 12) glass & Sapphire (Falcata 6) Profit from clear advantages // Variable light paths due to interchangeable light path tips // 1 % reproducibility // due to the small diameter, only low sample volume is required // withstands even the toughest process conditions // due to the flexible design we can easily adapt to rapidly changing process conditions Standard fiber optical 5 mm Fiber Optical Cables 2, mm glass & Sapphire (Falcata 12) glass & Sapphire (Falcata 6) Use the internet configurator or the table below to configure your modular immersion probe. Base Model Optical Path Length Tip Probe Body Material Sealing Technology Spectral range fiber optical process temperature range Pressure range immersion depth Purging Example Falcata 6 P P F 1 F1 Falcata 6 F2 Falcata 12 A B C D E F 1 mm 2 mm 5 mm 1 mm 2 mm Complete Set (1 mm to 2 mm) Q S The figures behind the product name indicate the different outer diameter (in mm) of the probes. Sapphire E Stainless Steel (316 L) H Hastelloy C-22 (2.462) T Titanium Grade 2 X Tantalum Z Kalrez 6375 X Kalrez 479 B Brazed (only in combination with brazed Titanium and Sapphire and 1 single welded optical path length tip) N U (4 nm to 2,3 nm) UVS/Vis Low solarization (19 nm to 1,1 nm for quartz/ 24 nm to 1,1 nm for Sapphire) E B S A = tolerance.1 mm Sapphire = tolerance.5 mm Red = Standard configuration Only applies to non brazed configuration. 2 m external fiber optical cables and PMA housing with SMA connectors 2 m external fiber optical cables and ATEX proof PMA housing with SMA connectors Female sockets for SMA (no external fibers) and PMA connector Female sockets for SMA (no external fibers) and ATEX proof PMA connector A No Flange B DN 25/PN 4 Typ 5 Form A C DN 5/PN 4 Typ 5 Form A D DN 8/PN 4 Typ 5 Form A E ANSI lbs F ANSI lbs H ANSI lbs I JIS 1K2A J GOST DN 25/PN 4 Q Quick Change Fitting, PG 13.5 L 5 C to 18 C H -8 C to 3 C (only in combination with brazed Titanium and Sapphire) F Q E Z N E A L B 2 1 N Don t forget the accessories! Fiber optical cables and other accessories can be found on page 22. L -1 bar to 35 bar (without flange) or according to flange specifications B -1 bar to 1 bar (only applies to Falcata 6) D -1 bar to 3 bar (without flange) or according to flange specifications (only in combination with brazed Titanium and Sapphire) 21 mm 6 mm to 29 mm 211 mm to 4 mm 41 mm to 6 mm Length for quick change fittings with 12 mm Length for quick change fittings with 225 mm N Y No only applies to Falcata 12 Yes (only for fiber optical with female sockets) TOTAL Configuration options do not fit your needs? We are also able to build customized optical immersion probes suitable for virtually every process condition. Price (E) 4,29 4, , on request 11 1, L HC 22/Ti , , , , L HC 22/Ti , ,

9 Modular Immersion Probes Gladius Range Gladius reflection immersion probes are especially suitable for measurement of diffused reflection in the Vis and range with FT- spectrometers or diode array spectrometers. Schematic Drawing Common applications include: Non invasive determination of residual moisture, e.g. in dryers Qualitative and quantitative analysis of food composition Reaction monitoring in heterogeneous systems Ø12/2/25 mm Measuring spot approx. Ø3 mm Measuring Distance Immersion Depth (with flange) Immersion Depth (without flange) Flange 5 mm 98 mm 1 mm Profit from clear advantages // Uniform lighting of the probe using 7 ringform light fiber with 4 μm or 6 μm core diameter // Return of the diffused reflected light for detection in the spectrometer is via the central detector fiber(s) // Arrangement of the fiber to the central receiver fiber(s) at a 3 angle: for suppression of direct reflection and highly effective reduction of the stray light // Customer-specified adjustment of the measuring distance for optimum signal // Rugged and hygienic design enable various applications, e.g. processes in which the composition of bulk goods and compounds or the moisture content of powders and granules must be monitored // CIP-compatible (Cleaning in Place) Cleaning without expensive disassembly Standard fiber optical Fiber Optical Cables 2, mm Background signal // Typical spectrum of diffuse white standard // Use the internet configurator or the table below to configure your modular immersion probe. Base Model Measuring Mode Probe body Material Sealing Technology Fiber optical Cable configuration fiber optical process temperature range Pressure range immersion depth Purging Example Gladius 12 P P G 2 G2 Gladius 12 G3 Gladius 2 G4 Gladius 25 A B Distance (approx. 2. mm) Contact S Q Sapphire The figures behind the product name indicate the different outer diameter (in mm) of the probes. E Stainless Steel (316 L) H Hastelloy C-22 (2.462) T Titanium Grade 2 E EPDM K Kalrez 6221 B Brazed (only in combination with brazed Titanium and Sapphire) J K L M O (4 nm to 2,3 nm) 7 4/1 6 (2 SMA) (4 nm to 2,3 nm) 7 6/7 6 (2 SMA) (4 nm to 2,3 nm) 7 6/7 6 (14 SMA) UVS/Vis (24 nm to 1,1 for sapphire/ 19 nm to 1,1 nm for quartz) 7 2/1 6 UVS/Vis (24 nm to 1,1 for sapphire/ 19 nm to 1,1 nm for quartz) 7 4/1 6 E 2 m external fiber optical cables and PMA housing with SMA connectors B 2 m external fiber optical cables and ATEX proof PMA housing with SMA connectors F Female sockets for SMA (no external fibers) and PMA connector (only for 7 *2/1 * 6 configuration) A Female sockets for SMA (no external fibers) and ATEX proof PMA connector A No Flange B DN 25/PN 4 Typ 5 Form A C DN 5/PN 4 Typ 5 Form A D DN 8/PN 4 Typ 5 Form A E ANSI lbs F ANSI lbs H ANSI lbs V Varivent Typ N S 1.5 Sanitary pipe fitting K Ingold fitting (only in combination with Gladius 25) Q Quick Change Fitting, PG 13.5 (Only in combination with Gladius 12) T 5 C to 14 C I -8 C to 26 C (only in combination with brazed Titanium and Sapphire) A S E E J E A T M 2 4 N Don t forget the accessories! Fiber optical cables and other accessories can be found on page 22. Red = Standard configuration M H -1 bar to 16 bar (without flange) or according to flange specification -1 bar to 1 bar (without flange) or according to flange specifications (only in combination with brazed Titanium and Sapphire) 24 mm 6 mm to 239 mm 241 mm to 4 mm 41 mm to 7 mm 71 mm to 9 mm Length for quick change fittings with 12 mm Length for quick change fittings with 225 mm N Y No Yes TOTAL Configuration options do not fit your needs? We are also able to build customized optical immersion probes suitable for virtually every process condition. Price (E) 6,875 7,25 7, on request 1,1 1,1 55 1,1 1,1 1, L HC 22/Ti , , , ,65 33 not available 33 not available 77 1, L HC 22/Ti , , ,

10 Modular Immersion Probes Katana Range Katana ATR Immersion Probes are suitable for conditions involving the direct measurement of strongly absorbing solutions where standard transmission probes cannot be used. Common applications include: Reaction monitoring in chemical synthesis Control of process chromatography Schematic Drawing UVS-VIS Katana (only available WITH sapphire) // Color number determination Reaction endpoint determination ATR-Prism Ø6/12 mm Immersion Depth (with flange) Immersion Depth (without flange) 5 mm Flange 1 mm 98 mm Profit from clear advantages // Extremely short optical path length (approx. 1 µm) ensures maximum measuring sensitivity // Absorbance takes place in the evanescent field // Optical path length depends on wavelength, number of reflections and refractive index of solution 5 mm Fiber Optical Cables 2, mm Use the internet configurator or the table below to configure your modular immersion probe. Base Model ATR-Prism Probe Body Material Sealing Technology Spectral range fiber optical process temperature range Pressure range immersion depth Purging K1 Katana 6 K2 Katana 12 A 3-Bounce S The figures behind the product name indicate the different outer diameter (in mm) of the probes. Sapphire Red = Standard configuration E Stainless Steel (316 L) H Hastelloy C-22 (2.462) T Titanium Grade 2 Z Kalrez 6375 X Kalrez 479 B Brazed (only in combination with brazed Titanium and Sapphire) L N UVS/Vis low solarization (24 nm to 1,1 nm for sapphire) (4 nm to 2,3 nm) E 2 m external fiber optical cables and PMA housing with SMA connectors B 2 m external fiber optical cables and ATEX proof PMA housing with SMA connectors S Female sockets for SMA (no external fibers) and PMA connector A Female sockets for SMA (no external fibers) and ATEX proof PMA connector A No Flange B DN 25/PN 4 Typ 5 Form A C DN 5/PN 4 Typ 5 Form A D DN 8/PN 4 Typ 5 Form A E ANSI lbs F ANSI lbs only applies to Katana 12 H ANSI lbs I JIS 1K2A J GOST DN 25/PN 4 Q Quick Change Fitting, PG 13.5 L 5 C to 18 C H -8 C to 3 C (only in combination with brazed Titanium and Sapphire M H -1 bar to 16 bar (without flange) or according to flange specifications -1 bar to 1 bar (only without flange) or according to flange specifications (only in combination with brazed Titanium and Sapphire) 21 mm 6 mm to 29 mm 211 mm to 4 mm 41 mm to 6 mm Length for quick change fittings with 12 mm Length for quick change fittings with 225 mm N No Y Yes (only for fiber optical with female sockets) TOTAL Price (E) 6,21 6, L HC 22/Ti , , , , L HC 22/Ti , , , Katana 12 Katana 6 Example Katana 6 P A S P K 1 A S E Z L E A L M 2 1 N Don t forget the accessories! Fiber optical cables and other accessories can be found on page 22. Configuration options do not fit your needs? We are also able to build customized optical immersion probes suitable for virtually every process condition.

11 Accessories Fiber optic cables STANDARD Two cables are required to complete the fiber optical Complete your system solution with our wide range of accessories. model Spectral range length Stainless STEEL cover Rubberized cover PE Coating (E) per piece order number (E) per piece order number (E) per piece order number PMA PRODUCTS Depending upon your configuration most users will require 1 additional PMA housing and ( x m) length of PMA conduit to enclose and protect their fiber optic cable system. The PMA CONDUIT protects the fiber cables of the immersion probe. The conduit comes with an additional PMA connector which can be connected e.g. to a connector box. PMA housings are used to complete the between the PMA conduits. The housings provide a solid foundation for affixing the PMA conduit. All Hellma Analytics process probes are delivered with a PMA housing attached to the probe body. Type PMA Conduit PMA Housing Standard Features Connectors (both ends): FSMA Type Temperature Range: - 4 C to 15 C Protective Sleeve Stainless Steel Core Material: Stainless Diameter: 6 µm Numerical Aperture (NA):.22 (4 nm 2,3 nm) UV/vis (24 nm 1,1 nm) UVS/Vis (19 nm 1,1 nm) 1 m 27 ALN1S 277 ALN1R 282 ALN1T 2 m 335 ALN2S 349 ALN2R 359 ALN2T 3 m 42 ALN3S 441 ALN3R 456 ALN3T 4 m 498 ALN4S 526 ALN4R 546 ALN4T 5 m 55 ALN5S 585 ALN5R 61 ALN5T 1 m 298 ALU1S 35 ALU1R 31 ALU1T 2 m 383 ALU2S 396 ALU2R 47 ALU2T 3 m 468 ALU3S 488 ALU3R 54 ALU3T 4 m 553 ALU4S 579 ALU4R 61 ALU4T 5 m 637 ALU5S 67 ALU5R 697 ALU5T 1 m 356 ALS1S 363 ALS1R 368 ALS1T 2 m 53 ALS2S 516 ALS2R 527 ALS2T 3 m 657 ALS3S 677 ALS3R 693 ALS3T 4 m 85 ALS4S 831 ALS4R 853 ALS4T 5 m 953 ALS5S 986 ALS5R 1,13 ALS5T Description Standard NW 17/NW 23 NW = inner diameter (mm) ATEX-EX-System NW 17/NW 23 NW = inner diameter (mm) PMA process housing NW 17/NW 23 NW = inner diameter (mm) PMA ATEX-Ex-System housing (only in combination with ATEX-Ex-System PMA conduit) PMA ConduitS (immersion probe needs to be equipped with pma HOUSING) Fiber optic cables (FSMA-FSMA) MODULAR SYSTEM PMA Housing PMA Housing-Type Choose type and fill in total desired length in (m) Example APMA APMA S PMA housing NW 17 (only applies to Katana and Falcata series) A PMA housing NW 23 N No housing B E S E 2 5 PMA Standard PMA ATEX-Ex-System PMA conduit PCLT PMA ATEX Ex-System conduit (only in combination with ATEX-Ex-System PMA housing) PMA NW 17 housing + PMA ATEX + 25 m ATEX conduit TOTAL Price (E) per housing Price (E) per Meter 8 22 E 594 Length please fill in below Protective Sleeve Material N U S (4 nm to 2,3 nm) UV/Vis (24 nm to 1,1 nm) UVS/Vis low solarization (19 nm to 1,1 nm) from 6 to 1 m/price per meter from 11 to 2 m/price per meter from 2 to 6 m/price per meter from 6 to 12 m/price per meter UV/Vis From 6 to 1 m/price per meter UVS/Vis From 6 to 1 m/price per meter S Stainless Steel Included R Rubberized (only up to 1 meters) price per meter T PE coated price per meter Price (E) AL TOTAL Example AL N 6 R E 624 fibers, 6 meters length, rubberized 2 21

12 D C B Inlet mpa m/s inlet top of vessel Bypass outlet No Length C Yes Length 1 m Custom Products. CUSTOM PRODUCTS AT A GLANCE Special ideas or extraordinary requirements? We make it possible! With over 9 years of experience in building high end optical products, Hellma Analytics is able to offer customized optical immersion probes and Flow-through cells suitable for nearly every demand. These custom products are neither standard nor modular products. They are built to suit your unique specifications even if they are extraordinary. Our custom products can cover a wide variety of possible application parameters, materials, dimensions and specifications. Talk to us about your requirements and we ll create your individual solution. Use our online questionnaire for a fast quotation procedure Application // // custom fiber optic probe Questionnaire branch information regarding the process location of integration Outer diameter (mm) Optical path length Optical material Probe body material Sealing technology Spectral range Process Temperature range Pressure range Immersion depth Purging Ex zone rating Additional fiberoptic cables (6 µm/1 µm) Hellma GmbH & Co. KG // Klosterrunsstraße Müllheim/Germany // phone: // fax: pat@hellma.com Etching Baths Polymerization Food and Feed Beverages Oil, Gas, Water Pharma Chemistry ContaCt Person name Position ComPany address Phone Fax mail date/place High Precision in Spectro-Optics Food and Beverage Dedicated system continuous process bottom of vessel Immersion probe Not available in all probe models Please list materials which are currently in contact with your medium! Which O-ring materials are currently used in your production area? * used for high temp and high pressure applications Probe can be purged with inert gases to prevent fogging of the optics during below zero temperatures. PMA Conduit Standard/Atex (NW17/NW23) PMA Housing Standard/Atex (NW17/NW23) Coupling box Coupling box required Fiber optic cable protection PMA housing pcs. PMA conduit Certificates required ATEX conformity Material certificate / DIN EN 124: 3.1 Accuracy of optical path length Fill in custom information: PrInT SEnd For housing the fiberoptic cables: Fixed through flange Homogenious solution (one phase) Sheathing directly applied to the fiberoptic cable: mounting of immersion probe sample medium // Description of chemical reaction (reacting substances) solvents present during the cleaning cycle: in process: ph range maximum viscosity linear flow speed measuring method Transmission middle of vessel Current light path used or please select glass Stainless steel ( / SS 316 Ti) Kalrez 6375 UVS/Vis low solarization (19-11nm) Yes/No, (if yes please specify) Up to 35 bar -2 mm Yes : L1 m L2 m Stainless steel Stainless Steel (without certificate) Spectrometer TM TRansmission EXCALIBUR CUSTOM IMMERSION PROBE HYGIENIC DESIGN PROBE Type // Hygenic design // Electropolished // Ideal for food & beverage and pharmaceutical industry EXCALIBUR Custom Immersion Probe Polymer Probe (pair) Type // For harsh conditions // withstand extremely high temperatures and pressures // Ideal for extruder machines EXCALIBUR RANGE EXCALIBUR CUSTOM IMMERSION PROBE PTFE PROBE Type // completely made of PTFE // withstands extremely corrosive conditions // Ideal for wet processes e.g. in photovoltaic and semiconductor industries EXCALIBUR Custom Flow Through Cell PTFE Flow Through Cell Type // Combination of Sapphire optics and molded PTFE // Absolutely corrosion resistant // Broadened measuring chamber for constant flow rate Size // Minimal Diameter of Immersion probe body Ø 2.4 mm Maximal length Immersion depth 6 m Pressure // Lowest -1 bar Highest (75 bar, tested with bar) Temperature // EXCALIBUR Custom Flow Through Cell Type // Available with quartz or sapphire optics // flexible usage for inline and online analysis // easy to incorporate into pipe systems and bypass loops EXCALIBUR CUSTOM IMMERSION PROBE ALL QUARTZ PROCESS PROBE Type // Solid quartz glass probe with a bonded glass flange for extremely corrosive environments. // This probe is free of O-rings and contains a bonded quartz glass measuring head. // Due to its design and the physical properties of quartz glass this probe has a broad temperature range from -18 C to 3 C and beyond. Lowest -18 C Highest 3 C Materials // Standard Stainless Steel PTFE Titanium Tantalum Custom Solvents Range // Acids HF H2SO4 Methanol CH2CL2 CH3OH NaOH KOH Alkalines EXCALIBUR Custom Immersion Probe Vertical Slit Probe Type // Measurement of highly viscous solvents // High resistance to chemicals // Optimised flow geometry // Material Excalibur Custom Immersion Probe Double Lance Probe Type // Measures UVS and simultaneously // Extremely high lightpath accuracy // Length 1 m Custom Products 22 Talk to us about your requirements and specifications. We ll offer you an individual solution to a reasonable price!

13 TM Excalibur Custom Immersion Probe CLEANING NOZZLE PROBE Type // An external cleaning nozzle enables cleaning of the optics without removing the probe // Very useful for highly viscous mediums enabling stable measurement results TM TRansmission TRansmission EXCALIBUR RANGE EXCALIBUR RANGE Excalibur Custom Immersion Probe Ultra long Probe Type // 6 m immersion depth // Exchangable measuring head // Double barrier for total secured operation in highly dangerous mediums // Due to ultra long design probe can be placed into underground tanks RF Gladius Custom Immersion Probe Polymer Probe Type // withstand harsh conditions // high temperature and pressure usage // Ideal for polymer melt processes ATR REFLECTIon ATR KATANA RANGE GLADIUS RANGE Katana Custom Immersion Probe Carrier Type // Two ports for a sealed installation of individual immersion probes // Cleaning and calibrating in process (CIP) // Very compact construction according to hygiene regulations Demo models in quartz glass and sapphire available! In case of purchase any rental fees incurred will be credited. Your desired immersion probe is not in the program? No problem! We manufacture according to your individual needs just contact us. 19/213 E- -1 Brochure printed in Germany Subject to change without notice. Current pricing /January 213. With the publication of a new pricelist, all previous pricelists lose their validity. All prices shown are excluding VAT, transportation and packaging. TF TRansflection Falcata Custom Immersion Probe Tantalum Probe Type // Probe body made of Tantalum, Optics made of quartz glass // Extremely robust and acid resistant (even aqua regia) // Exchangable path length tips FALCATA RANGE 24

14 High Precision in Spectro-Optics Asia Hellma (Asia Pacific) Pte Ltd 8 Boon Lay Way #3-1 8@TradeHub 21 Singapore phone fax info.sg@hellma.com Hellma South Asia Pte Ltd 8 Boon Lay Way #3-1 8@TradeHub 21 Singapore phone fax info.sg@hellma.com Hellma China Pte Ltd 8 Boon Lay Way #3-1 8@TradeHub 21 Singapore phone fax info.cn@hellma.com Europe Hellma GmbH & Co. KG Klosterrunsstraße Müllheim Germany phone fax sales.analytics@hellma.com Hellma Benelux BVBA Hogen Akkerhoekstraat Kruibeke Belgium phone fax info.be@hellma.com Hellma France S.A.R.L. 35 rue de Meaux 7519 Paris France phone fax info.fr@hellma.com Hellma Italia S.r.l. Via Gioacchino Murat, Milano Italy phone fax info.it@hellma.com Hellma Hispania SL Gregal, 2 PO Box/Apartado Badalona Spain phone fax info.es@hellma.com Hellma Schweiz AG Schwäntenmos Zumikon Switzerland phone fax info.ch@hellma.com Hellma UK LTD Cumberland House Baxter Avenue Southend on Sea, Essex SS2 6HZ phone fax info.gb@hellma.com THE Americas Hellma USA INC. 8 Skyline Drive Plainview, NY 1183 USA phone fax info.us@hellma.com Hellma Canada Ltd. 63 Rivermede Road, Unit 4 Concord, Ontario L4K 2H7 Canada phone fax info.ca@hellma.com For all other countries, please see our list of representatives: