Dispersions for architectural coatings

Transcription

1 Dispersions for architectural coatings Vinavil Ravemul 03 V PC2 Vinavil 4555 Vinavil 4528 Ravemul Ravemul T33 T37 Vinavil 4425 Vinavil EVA 4612 Crilat D120S Crilat 4724 Crilat 4706 Crilat D117 Crilat 4818 Crilat 4816

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3 INDEX Vinavil 03 V page 2 Ravemul PC2 page 4 Vinavil 4555 page 6 Vinavil 4528 page 8 Ravemul T33 page 10 Ravemul T37 page 12 Vinavil 4425 page 14 Vinavil EVA 4612 page 16 Crilat D120S page 18 Crilat 4724 page 20 Crilat 4706 page 22 Crilat D117 page 24 Crilat 4818 page 26 Crilat 4816 page 28 1

4 VINAVIL 03 V VINAVIL 03 V is an anionic/non-ionic water dispersion of vinyl-acetate/vinyl-versatate copolymer with 50% solid content, free from alkylphenol-ethoxylates (APEO-free). PACKAGING VINAVIL 03 V is available in bulk quantities, 1000 L IBC and 125 Kg PE drums. STORAGE VINAVIL 03 V remains stable for at least 6 months when stored at temperatures between +5 C +40 C. The main characteristics of VINAVIL 03 V are: a) free from alkylphenol-ethoxylates (APEO-free) b) good water resistance c) high binding power with respect to pigments and fillers d) excellent compatibility with additives and fillers e) excellent rheology behaviour f) highly versatile, suitable for use in various formulates APPLICATIONS VINAVIL 03 V is suitable for formulating interior/exterior wall paints and coatings at various PVC and has excellent rheological behaviour for application of both thin and thick coats. VINAVIL 03 V is highly versatile, easy to formulate and is used in a wide range of paints at medium or high PVC. Products containing VINAVIL 03 V have excellent properties in terms of binding and adhesion capacity, colour strength and weather resistance. Thanks to all these special characteristics, VINAVIL 03 V is one of the leading dispersion products used in the building industry. VINAVIL 03 V is also used as a fixative for the temporary encapsulation of asbestos cement. 2

5 VINAVIL 03 V UNIT VALUE METHOD 1. SUPPLY SPECIFICATIONS Solid content % 50±1 MVPF 01bis Brookfield viscosity (1) mpa.s ±500 UNI EN ISO 2555 ph 4.5±0.5 ISO TYPICAL VALUES Minimum film-forming temperature C +5 UNI Particle size distribution μm MVANS 20 Density at 23 C Kg/dm³ 1.06 MVPF 18 Glass transition temperature C 28±1 MVANS 01 (1) RVT 20 rpm spindle 3, 23 C INTERIOR PAINT 75% PVC WET SCRUB RESISTANCE NORM DIN N Cycles Vinavil 03 V Competitor 1 Competitor 2 Competitor 3 3

6 RAVEMUL PC2 RAVEMUL PC2 is an anionic/non-ionic water dispersion of vinyl-acetate/vinyl-versatate copolymer with 50% solid content, free from alkylphenol-ethoxylates (APEO-free). PACKAGING RAVEMUL PC2 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums. STORAGE RAVEMUL PC2 remains stable for at least 6 months when stored at temperatures between +5 C +40 C. The main characteristics of RAVEMUL PC2 are: a) free from alkylphenol-ethoxylates (APEO-free) b) good alkali resistance c) good water resistance d) high hiding power e) excellent compatibility with additives and fillers f) excellent rheology behaviour g) highly versatile, suitable for use in various formulates APPLICATIONS RAVEMUL PC2 is suitable for formulating interior/exterior paints and coatings at various PVC. Particle size distribution has been specially designed to give paints high hiding power. RAVEMUL PC2 is characterised by its optimum combination of various parameters which have high impact on finished products for the building industry, such as binding capacity, rheological behaviour, low film sensitivity to water, compatibility with various types of fillers, pigments and additives and weather resistance. When used in exterior paints, it gives them the properties of low water absorption and good permeability to vapour. 4

7 RAVEMUL PC2 UNIT VALUE METHOD 1. SUPPLY SPECIFICATIONS Solid content % 50±1 MVPF 01 Brookfield viscosity (1) mpa.s ±500 UNI EN ISO 2555 ph 4.5±0.5 ISO TYPICAL VALUES Minimum film-forming temperature C +3 UNI Particle size distribution μm MVANS 20 Density at 23 C Kg/dm³ 1.06 MVPF 18 Glass transition temperature C 28±1 MVANS 01 (1) RVT 20 rpm spindle 3, 23 C Rif E E INTERIOR MATT PAINT WITH HIGH HIDING POWER COMPONENTS w. % FUNCTION SUPPLIERS Water Tego Foamex Defoamer Evonik Natrosol Plus Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50 Dispersant Lamberti Sodium hexametaphosphate 0.20 Dispersant Various Disponil PL Wetting agent Cognis Acticide SPX 0.28 Biocide Thor Texanol 0.70 Coalescent Eastman Ethylene glycol 0.50 Co-solvent Various TiO2 type RXL Pigment Tioxide CaCO3 type Omyacarb 10AV Filler Omya Polestar 200P 6.50 Filler Imerys Talc 9.00 Filler Luzenac Ravemul PC Binder Vinavil Tego Foamex Defoamer Evonik Water 1.00 Total

8 VINAVIL 4555 VINAVIL 4555 is an anionic/non-ionic water dispersion of vinyl-acetate/vinyl-versatate copolymer with 55% solid content, free from solvents (plasticizer and coalescing agents) and from alkylphenol-ethoxylates (APEO-free). PACKAGING VINAVIL 4555 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums. STORAGE VINAVIL 4555 remains stable for at least 6 months when stored at temperatures between +5 C +40 C. The main characteristics of VINAVIL 4555 are: a) free from alkylphenol-ethoxylates (APEO-free) b) good water resistance c) high binding power with pigments and fillers d) excellent compatibility with additives and fillers e) excellent rheology behaviour f) highly versatile, suitable for various applications g) high solid content dispersion APPLICATIONS VINAVIL 4555 is suitable for formulating interior/exterior paints and textured coatings, satin and gloss paints with good adhesion and sheen. Thanks to its special characteristics, formulates containing VINAVIL 4555 have good rheological properties and excellent dirt pick-up resistance. Thanks to its high resistance to alkalinity and good weather resistance, it may also be used in the preparation of exterior paints and textured coatings. Paints at high PVC, formulated with VINAVIL 4555, are characterised by high wet scrub resistance. When used in water paints, the binding power of VINAVIL 4555 is best expressed when coalescing agents are added to lower the filming temperature. The amount used depends on the effectiveness of the coalescing agent. For diethylenglycol monobutyl ether acetate, for example, the amount required is 2-3% on the VINAVIL 4555 in the formulation. 6

9 VINAVIL 4555 UNIT VALUE METHOD 1. SUPPLY SPECIFICATIONS Solid content % 55±1 MVPF 01 Brookfield viscosity (1) mpa.s ± UNI EN ISO 2555 ph 5.0±0.5 ISO TYPICAL VALUES Minimum film-forming temperature C +13 UNI Particle size distribution μm MVANS 20 Density at 23 C Kg/dm³ 1.1 MVPF 18 Glass transition temperature C 28±1 MVANS 01 Resistance to freeze-thaw N of cycles > 5 UNI (1) RVT 20 rpm spindle 3, 23 C INTERIOR PAINT 75% PVC WET SCRUB RESISTANCE NORM DIN N Cycles Vinavil 4555 Competitor 1 Competitor 2 Competitor 3 Competitor 4 7

10 VINAVIL 4528 VINAVIL 4528 is an anionic/non-ionic water dispersion of vinyl-acetate/vinyl-versatate copolymer with 50% solid content, free from alkylphenol-ethoxylates (APEO-free). PACKAGING VINAVIL 4528 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums. STORAGE VINAVIL 4528 remains stable for at least 6 months when stored at temperatures between +5 C +40 C. The main characteristics of VINAVIL 4528 are: a) free from alkylphenol-ethoxylates (APEO-free) b) good water resistance c) high binding power with respect to pigments and fillers d) excellent compatibility with additives and fillers e) excellent rheology behaviour f) highly versatile, suitable for various applications APPLICATIONS VINAVIL 4528 is suitable for formulating interior/exterior paints and textured coatings and is particularly versatile when used in products with low and high PVC and in wall textured coatings. VINAVIL 4528 has a high binding power in paints with a medium to high PVC and has good alkali and water resistance. Its specific low viscosity makes it particularly simple to dose when used in automatic plant equipment and makes handling easier during paint manufacturing. 8

11 VINAVIL 4528 UNIT VALUE METHOD 1. SUPPLY SPECIFICATIONS Solid content % 50±1 MVPF 01 Brookfield viscosity (1) mpa.s <500 UNI EN ISO 2555 ph 5.0±0.5 ISO TYPICAL VALUES Minimum film-forming temperature C +5 UNI Particle size distribution μm MVANS 20 Density at 23 C Kg/dm³ 1.1 MVPF 18 Glass transition temperature C 28±1 MVANS 01 Resistance to freeze-thaw N of cycles >5 UNI (1) RVT 20 rpm spindle 1, 23 C WASHABLE PAINT 75% PVC COMPONENTS w. % FUNCTION SUPPLIERS Water Comiel L 808E 0.20 Defoamer Comiel Natrosol PLUS Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Sodium hexametaphosphate (sol 10%) 2.50 Dispersant Various Disponil PL Wetting agent Cognis Acticide B Biocide Thor Texanol 0.40 Coalescent Eastman Ethylene glycol 0.50 Co-solvent Various TiO2 type RXL Pigment Huntsman Polestar 200 P 6.00 Filler Imerys CaCO3 type Omyacarb 5 AV Filler Omya Vinavil Binder Vinavil Water 0.90 Total CHARACTERISTICS VALUE METHOD Brookfield RVT Viscosity at 20rpm, 23 C (mpa.s) UNI EN ISO 2555 ph 7.5 ISO 976 Density (g/ml) 1.62 MVPF 18 Solid content (%) 64 MVPF 01 VOC content (g/l) 8.5 ISO Wet scrub resistance (n cycles) DIN

12 RAVEMUL T33 RAVEMUL T33 is a water dispersion of a special vinyl terpolymer with 55% solid content, characterised by its high glass transition temperature and low film-forming temperature. Ravemul T33 is free from alkylphenol-ethoxylates (APEO-free). PACKAGING RAVEMUL T33 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums. STORAGE RAVEMUL T33 remains stable for at least 6 months when stored at temperatures between +5 C +40 C. The main characteristics of RAVEMUL T33 are: a) free from alkylphenol-ethoxylates (APEO-free) b) excellent water resistance c) high gloss d) excellent rheology behaviour e) low dirt pick-up f) excellent blocking resistance APPLICATIONS RAVEMUL T33 is particularly suitable for use in formulates such as wall textured coatings with high gloss and low dirt pick-up, water paints with low water absorption for conventional applications, high gloss and matt wall enamels. RAVEMUL T33 is characterised by a high glass transition temperature which makes it particularly suitable for wall textured coating at low PVC, with characteristic of poor blocking tendency and low dirt pick-up retention over the years. The films obtained using RAVEMUL T33 show very high alkali resistance, even at high ph. RAVEMUL T33-based products, therefore, may be applied on substrates with a high level of alkalinity. We recommend, however, that substrates are verified beforehand to make sure they are well consolidated. RAVEMUL T33 is compatible with fillers, pigments and the most commonly used additives. 10

13 RAVEMUL T33 UNIT VALUE METHOD 1. SUPPLY SPECIFICATIONS Solid content % 55±1 MVPF 01 Brookfield viscosity (1) mpa.s ± UNI EN ISO 2555 ph 4.5±0.5 ISO TYPICAL VALUES Minimum film-forming temperature C +12 UNI Particle size distribution μm MVANS 20 Density at 23 C Kg/dm³ 1.1 MVPF 18 Glass transition temperature C 34±1 MVANS 01 Resistance to freeze-thaw N of cycles >5 UNI (1) RVT 20 rpm spindle 3, 23 C Rif E E GLOSS PAINT COMPONENTS w. % FUNCTION SUPPLIERS Water Ethylene glycol 2.00 Co-solvent Various Sodium hexametaphosphate (sol 10%) 1.00 Dispersant Various Coadis BR Dispersant Coatex Acticide SPX 0.15 Biocide Thor Tego Foamex Defoamer Evonik Butyl diglycol acetate 2.00 Coalescent Various TiO2 type R-HD Pigment Tioxide Tego Foamex Defoamer Evonik Ammonia (sol 30%) 0.60 Neutralizing agent Various Rheotech 2000 (*) 3.50 Thickener Coatex Ravemul T Binder Vinavil Water 1.00 Total (*) dilution 1:1 with water CHARACTERISTICS VALUE METHOD Brookfield RVT Viscosity at 20 rpm, 23 C (mpa.s) UNI EN ISO 2555 ICI Viscosity at s -1 (Poise) 2.97 ASTM D 4287 ph 7.56 ISO 976 Dirt pick-up (ΔL) 4.74 UNI Hiding power (RC) 0.99 UNI ISO 3905 Gloss at 20 after 24h 53.4 UNI 9389 Gloss at 60 after 24h 80.5 UNI

14 RAVEMUL T37 RAVEMUL T37 is a water dispersion of vinyl-acetate terpolymer with versatic acid esthers. Ravemul T37 is free from alkylphenol-ethoxylates (APEO-free). PACKAGING RAVEMUL T37 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums. STORAGE RAVEMUL T37 remains stable for at least 6 months when stored at temperatures between +5 C +40 C. The main characteristics of RAVEMUL T37 are: a) free from alkylphenol-ethoxylates (APEO-free) b) excellent alkali resistance c) high chemical resistance d) excellent compatibility with additives and fillers e) excellent rheology behaviour f) low water absorption APPLICATIONS RAVEMUL T37 is particularly suitable for use in lime-based paints and coatings for intumescent and fire-retardant paints. Thanks to its high alkali resistance, it is also used as an additive for cement-based systems such as repair mortars, construction joints, grout protection and thermal insulation finishing systems (EIFS). RAVEMUL T37 is particularly recommended where good hydrophobicity is required, being the polymer film highly water resistant. Moreover, thanks to the high alkali resistance and excellent compatibility with cement, it is recommended for applications where the following performance characteristics need to be improved: adhesion to the substrate, flexibility, dimensional stability during the drying phase, resistance to wear and reduction of water permeability. RAVEMUL T37 is highly compatible and stable in lime-based paints. 12

15 RAVEMUL T37 UNIT VALUE METHOD 1. SUPPLY SPECIFICATIONS Solid content % 50±1 MVPF 01 Brookfield viscosity (1) mpa.s ±500 UNI EN ISO 2555 ph 4.5±0.5 ISO TYPICAL VALUES Minimum film-forming temperature C +3 UNI Particle size distribution μm MVANS 20 Density at 23 C Kg/dm³ 1.1 MVPF 18 Glass transition temperature C 34±1 MVANS 01 (1) RVT 20 rpm spindle 2, 23 C INTUMESCENT COATINGS BEFORE AND AFTER EXPOSURE Before exposure After exposure In case of fire when exposed to flame, the coating expands to form a protective foam to the substrate where it is applied. 13

16 VINAVILL 4425 VINAVIL 4425 is an anionic/non-ionic water dispersion of vinyl-acetate/acrylate copolymer with 55% solid content, free from solvents (plasticizer and coalescing agents) and alkylphenol-ethoxylates (APEO-free). PACKAGING VINAVIL 4425 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums. STORAGE VINAVIL 4425 remains stable for at least 6 months when stored at temperatures between +5 C +40 C. The main characteristics of VINAVIL 4425 are: a) free from alkylphenol-ethoxylates (APEO-free) b) high scrub resistance, even at high PVC c) excellent dirt pick-up resistance d) excellent mechanical stability e) low water absorption of the film f) high hiding power g) good compatibility with additives most commonly used for formulating water paints APPLICATIONS VINAVIL 4425 is a vinyl/acrylic dispersion developed for formulating interior paints with high scrub resistance and excellent dirt pick-up resistance. 14

17 VINAVIL 4425 UNIT VALUE METHOD 1. SUPPLY SPECIFICATIONS Solid content % 55±1 MVPF 01 Brookfield viscosity (1) mpa.s ±500 UNI EN ISO 2555 ph 4.5±0.5 ISO TYPICAL VALUES Minimum film-forming temperature C +7 UNI Particle size distribution μm MVANS 20 Density at 23 C Kg/dm³ 1.07 MVPF 18 Glass transition temperature C 28±1 MVANS 01 (1) RVT 20 rpm spindle 1, 23 C INTERIOR PAINT 80% PVC - DIRT PICK-UP METHOD UNI VINAVIL 4425 L = 14.8 Vinyl-versatate L = 16.8 Competitor 1 L = 16.3 INTERIOR PAINT 80% PVC WET SCRUB RESISTANCE NORM DIN N Cycles Vinavil 4425 Competitor 1 Vinyl-versatate Styrene-acrylic 15

18 VINAVIL EVA 4612 VINAVIL EVA 4612 is a water dispersion of vinyl-acetate/ethylene copolymer, free from solvents (plasticizer and coalescing agents), alkylphenol-ethoxylates (APEO-free) and is characterised by very low free monomer content. PACKAGING VINAVIL EVA 4612 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums. STORAGE VINAVIL EVA 4612 remains stable for at least 6 months when stored at temperatures between +5 C +40 C. The main characteristics of VINAVIL EVA 4612 are: a) free from alkylphenol-ethoxylates (APEO-free) b) no coalescing agent for film-forming required c) good water resistance d) high binding power with respect to pigments and fillers e) excellent compatibility with additives and fillers f) excellent rheology behaviour g) low content of volatile organic compounds (VOC) APPLICATIONS VINAVIL EVA 4612 is odourless and suitable for the preparation of interior/exterior paints, including those at high PVC, satin paints and wall textured coatings where a low content of volatile organic compounds (VOC) is required. VINAVIL EVA 4612 allows the formulation of paints in accordance to Ecolabel norms, which are identified by a specific labelling. The VINAVIL EVA 4612 contained in formulates developes very good rheology to make application easier, high binding, hiding properties and excellent compatibility with pigment pastes. Thanks to the presence of ethylene in the monomer composition, VINAVIL EVA 4612 has a minimum film-forming temperature (MFFT) of 0 C. This property allows painting products to be formulated without the use of coalescing agents and plasticizer, which reduces VOC content to levels well below 1 g/l. 16

19 VINAVIL EVA 4612 UNIT VALUE METHOD 1. SUPPLY SPECIFICATIONS Solid content % 52±1 MVPF 01 Brookfield viscosity (1) mpa.s ± UNI EN ISO 2555 ph 4.5±0.5 ISO TYPICAL VALUES Minimum film-forming temperature C 0 UNI Particle size distribution μm MVANS 20 Density at 23 C Kg/dm³ 1.1 MVPF 18 Glass transition temperature C 12±1 MVANS 01 (1) RVT 20 rpm spindle 3, 23 C MEASUREMENT VOC EMISSIONS OF PAINTS WITH GC-MASS METHOD EN PART VOC (mg/m 3 ) Paint 75% PVC AcV/VeoVa Paint 75% PVC Vinavil EVA 4612 Low-VOC paint from England Low-VOC paint from Italy After 24 hours After 10 days In spite of the differences of VOC content, all tested samples are conforming to 2004/42/CE. 17

20 CRILAT D120S CRILAT D120S is a water dispersion of styrene/acrylic copolymer used as a binder in the preparation of interior/exterior wall paints and textured coatings such as quartz, silicate, siloxane and coloured renders. PACKAGING CRILAT D120S is available in bulk quantities, 1000 L IBC and 125 Kg PE drums. STORAGE CRILAT D120S remains stable for at least 6 months when stored at temperatures between +5 C +40 C. The main characteristics of CRILAT D120S are: a) free from solvents or coalescing agents and plasticizer b) high water resistance c) good compatibility with hydraulic binders, minerals and polysiloxane d) excellent adhesion e) high binding power with respect to pigments and fillers f) excellent alkali resistance g) highly versatile, suitable for various applications APPLICATIONS CRILAT D120S is a multi-purpose, styrene/acrylic dispersion used in a multitude of interior/exterior paint formulations, including those at high PVC with excellent wet scrub resistance, quartz paints, wall textured coatings and coloured renders. CRILAT D120S is highly compatible with hydraulic and mineral binders which makes it suitable for formulating cementitious and silicate-based products. The high water resistance of the CRILAT D120S film offers the best solution when formulates, characterised by high water resistance (paints, wall textured coatings, covering products for roofs and terraces) and formulates without pigments, are required. Thanks to the high binding power of CRILAT D120S, paints at high PVC with excellent wet scrub resistance may be prepared. The excellent alkali resistance allows the preparation of paints and wall textured coatings suitable for exterior applications, also on substrates with high alkalinity. 18

21 CRILAT D120S UNIT VALUE METHOD 1. SUPPLY SPECIFICATIONS Solid content % 50±1 MVPF 01 Brookfield viscosity (1) mpa.s ± UNI EN ISO 2555 ph 8.0±0.5 ISO TYPICAL VALUES Minimum film-forming temperature C +18 UNI Particle size distribution μm MVANS 20 Density at 23 C Kg/dm³ 1.06 MVPF 18 Glass transition temperature C 26±1 MVANS 01 Resistance to freeze-thaw N of cycles >5 UNI (1) RVT 20 rpm spindle 5, 23 C SILICA PAINTS: ACCELERATING STORAGE STABILITY AT 50 C Brookfield RVT viscosity at 20 rpm, 23 C (mpa.s) CRILAT 4706 CRILAT 4724 CRILAT 4818 CRILAT 4816 CRILAT D117 CRILAT D120S Days MEASUREMENT OF ADHESION BY TENSILE TEST OF A TEXTURED COATING BASED ON CRILAT D120S UNI EN ISO 4624 Dynamometer Alliance MTS RT/50 Break value: 0.9 MPa Type of break: A (break of substrate) 19

22 CRILAT 4724 CRILAT 4724 is a water dispersion of styrene/acrylic copolymer (APEO-free) used as a binder in the preparation of interior/exterior wall paints and coatings such as quartz, silicate and siloxane paints as well as wall textured coatings and paints at high PVC, with excellent scrub resistance. PACKAGING CRILAT 4724 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums. STORAGE CRILAT 4724 remains stable for at least 6 months when stored at temperatures between +5 C +40 C. The main characteristics of CRILAT 4724 are: a) free from alkylphenol-ethoxylates (APEO-free) b) high water resistance c) excellent compatibility with hydraulic binders, minerals and polysiloxane d) high binding power, also in paints at high PVC e) excellent alkali resistance f) highly versatile, suitable for various applications APPLICATIONS CRILAT 4724 has been developed for a multitude of applications in formulations for interior/exterior paints, wall textured coatings and, thanks to its excellent compatibility with hydraulic and mineral binders, it is used in cement and silicate-based systems. Even when used in paints at high PVC, because of its high binding power with respect to pigments and fillers, CRILAT 4724 offers excellent wet scrub resistance. The high water resistance of the CRILAT 4724 film offers the best solution when formulates characterised by high water repellence such as paints, wall textured coatings and covering products for roofs and terraces are required. The excellent alkali resistance allows the preparation of paints and wall textured coatings suitable for exterior applications, also on substrates with high alkalinity and in combination with polysiloxane resins. 20

23 CRILAT 4724 UNIT VALUE METHOD 1. SUPPLY SPECIFICATIONS Solid content % 50±1 MVPF 01 Brookfield viscosity (1) mpa.s ± UNI EN ISO 2555 ph 8.5±0.5 ISO TYPICAL VALUES Minimum film-forming temperature C +15 UNI Particle size distribution μm MVANS 20 Density at 23 C Kg/dm³ 1.06 MVPF 18 Glass transition temperature C 24±1 MVANS 01 (1) RVT 20 rpm spindle 5, 23 C SILOXANE PAINT BASED ON CRILAT 4724 CHARACTERISTICS METHOD UNIT VALUE CLASSIFICATION Dirt pick-up ( L) UNI Very low Liquid-water transmission rate (W24) UNI EN (Kg/(m. h 0.5 )) 0.19 Medium Water-vapour transmission rate (Sd) UNI EN ISO (m) High Künzel Theory W24 x Sd < 0.1 DIN (Kg/(m. h 0.5 )) Respected In accordance with Künzel Theory the wall is considered dry when W24 Sd < 0,1 Kg/(m. h 0.5 ) where: W24<0.5 Kg/(m. h 0.5 ) and Sd <2m The siloxane paint based on Crilat 4724 has the ability to make the surface hydrophobic by changing the surface tension reaching the drop effect. 21

24 CRILAT 4706 CRILAT 4706 is a water dispersion of styrene/acrylic copolymer free from alkylphenolethoxylates (APEO-free) and solvents, which forms a transparent, slightly sticky and flexible film, with excellent water resistance. PACKAGING CRILAT 4706 is available in bulk quantities, 1000 L IBC and 125 kg PE drums. STORAGE CRILAT 4706 remains stable for at least 6 months when stored at temperatures between +5 C +40 C. The main characteristics of CRILAT 4706 are: a) free from alkylphenol-ethoxylates (APEO-free) b) free from solvents or coalescing agents and plasticizer c) no coalescing agent for film-forming required d) high water resistance e) compatible with hydraulic and mineral binders (cement, polysiloxane and silicate) f) good flexibility g) low dirt pick-up h) excellent alkali resistance APPLICATIONS CRILAT 4706 is suitable for formulating interior/exterior paints, where more flexibility is required compared with conventional styrene/acrylics products. CRILAT 4706 is used for preparing quartz paints and wall textured coatings, water-based membranes, silicate and siloxane-based systems and solvent-free formulates. Thanks to its low film-forming temperature, CRILAT 4706 does not require the addition of coalescing agents in the formulation. The good flexibility of the film allows the preparation of wall textured coatings with no problem of cracking when applied in thick layers. Its high resistance to water, alkali and dirt pick-up, allows the formulation of liquid membranes for roofs. 22

25 CRILAT 4706 UNIT VALUE METHOD 1. SUPPLY SPECIFICATIONS Solid content % 50±1 MVPF 01 Brookfield viscosity (1) mpa.s ± UNI EN ISO 2555 ph 8.0±0.5 ISO TYPICAL VALUES Minimum film-forming temperature C 0 UNI Particle size distribution μm MVANS 20 Density at 23 C Kg/dm³ 1.06 MVPF 18 Glass transition temperature C 6±1 MVANS 01 (1) RVT 20 rpm spindle 5, 23 C Rif E E WATER PROOF MEMBRANE COMPONENTS w. % FUNCTION SUPPLIERS Water Tego Foamex Defoamer Evonik Natrosol 250 MBR 0.30 Thickener Aqualon Ammonia (sol 28%) 0.10 Neutralizing agent Various Sodium hexametaphosphate (sol 10%) 1.00 Dispersant Various Acticide MBS 0.20 Biocide Thor Disponil PL Wetting agent Cognis Reotan L 0.40 Dispersant Lamberti Propylene glycol 0.40 Co-solvent Various TiO2 type Tioxide RXL 3.00 Pigment Huntsman Crilat Binder Vinavil CaCO3 5 μm type Omyacarb 5AV 4.50 Filler Omya Plastorite Filler Luzenac Tego Foamex Defoamer Evonik Total CHARACTERISTICS VALUE METHOD Brookfield RVT Viscosity at 20 rpm, 23 C (mpa.s) UNI EN ISO 2555 ph 8.34 ISO 976 Dirt pick-up (ΔL) 5.50 low UNI Strength at break (N/mm 2 ) 1.4 UNI 8490/17 Elongation at break (%) UNI 8490/17 23

26 CRILAT D117 CRILAT D117 is a water dispersion of acrylic copolymer with 46% solid content, free from alkylphenol-ethoxylates (APEO-free). PACKAGING CRILAT D117 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums. STORAGE CRILAT D117 remains stable for at least 6 months when stored at temperatures between +5 C +40 C. The main characteristics of CRILAT D117 are: a) free from alkylphenol-ethoxylates (APEO-free) b) high water resistance c) high binding power with respect to pigments and fillers d) excellent alkali resistance e) excellent colour strength APPLICATIONS CRILAT D117 is suitable for formulating exterior paints, textured coatings and decorative interior paints (veiling, etc.). CRILAT D117 gives paints and wall textured coatings excellent characteristics of weather and strong alkali resistance, good colour fastness and low sensitivity to water. Thanks to these properties, the product allows the preparation of various formulates of high quality and of prestigious products for exterior use (building industry). 24

27 CRILAT D117 UNIT VALUE METHOD 1. SUPPLY SPECIFICATIONS Solid content % 46±1 MVPF 01 Brookfield viscosity (1) mpa.s ± UNI EN ISO 2555 ph 9.0±0.5 ISO TYPICAL VALUES Minimum film-forming temperature C +9 UNI Particle size distribution μm MVANS 20 Density at 23 C Kg/dm³ 1.06 MVPF 18 Glass transition temperature C 18±1 MVANS 01 (1) RVT 20 rpm, 23 C, spindle 3 FINISHING VEILED WITH DECORATIVE EFFECT Rif E COMPONENTS w. % FUNCTION SUPPLIERS Water Ethylene glycol 0.60 Co-solvent Various Texanol 1.00 Coalescent Eastman Tego Foamex Defoamer Evonik Acticide SPX 0.20 Biocide Thor Tego Phobe Siloxane binder Evonik Crilat D Binder Vinavil Rheothec Thickener Coatex Tego Foamex Defoamer Evonik AMP Neutralizing agent Angus Total Add the pigment pasta to get the desired colour. 25

28 CRILAT 4818 CRILAT 4818 is a water dispersion of acrylic copolymer with 47% solid content, free from alkylphenol-ethoxylates (APEO-free). PACKAGING CRILAT 4818 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums. STORAGE CRILAT 4818 remains stable for at least 6 months when stored at temperatures between +5 C +40 C. The main characteristics of CRILAT 4818 are: a) free from alkylphenol-ethoxylates (APEO-free) b) high water resistance c) high binding power with respect to pigments and fillers, also at high PVC d) excellent alkali resistance e) excellent colour strength f) high weather resistance APPLICATIONS CRILAT 4818 is suitable for formulating exterior paints and wall textured coatings with high performance of durability and weather resistance. The excellent alkali resistance, the colour fastness, the water resistance and the dirt pick-up of CRILAT 4818 allow the preparation of products where high durability class paints is required. 26

29 CRILAT 4818 UNIT VALUE METHOD 1. SUPPLY SPECIFICATIONS Solid content % 47±1 MVPF 01 Brookfield viscosity (1) mpa.s <200 UNI EN ISO 2555 ph 8.5±0.5 ISO TYPICAL VALUES Minimum film-forming temperature C +10 UNI Particle size distribution μm MVANS 20 Density at 23 C Kg/dm³ 1.06 MVPF 18 Glass transition temperature C 18±1 MVANS 01 (1) RVT 20 rpm spindle 1, 23 C Colorimetric measurements of exterior paints, after test of artificial weathering exposure with the use of UV lamps Method Exterior paint Exterior paint Exterior paint UNI EN ISO based on based on based on St/A (1) St/A (2) Crilat 4818 L a* b* hours cycle UV-CON ΔE* hours cycle UV-CON ΔE* hours cycle UV-CON ΔE* hours cycle UV-CON ΔE* hours cycle UV-CON ΔE* UV-CON Cycle: Segment 1 (4h) 2 (8h) Water spray ON OFF UV irradiance OFF ON 27

30 CRILAT 4816 CRILAT 4816 is a water dispersion of acrylic copolymer with 50% solid content, free from solvents (plasticizer and coalescing agents) and from alkylphenol-ethoxylates (APEO-free). PACKAGING CRILAT 4816 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums. STORAGE CRILAT 4816 remains stable for at least 6 months when stored at temperatures between +5 C +40 C. The main characteristics of CRILAT 4816 are: a) free from alkylphenol-ethoxylates (APEO-free) b) no coalescing agent for film-forming required c) high water resistance d) excellent alkali resistance e) excellent colour strength f) low dirt pick-up g) good adhesion on old alkyd paints h) high weather resistance APPLICATIONS CRILAT 4816 is suitable for formulating interior/exterior odourless wall paints and coatings with a low impact on the environment. CRILAT 4816 has been developed for formulating interior/exterior paints with a low VOC (volatile organic compounds) in compliance with Directive 2004/42/CE. Its high alkali resistance and excellent colour fastness allow it to be used in exterior paints with characteristics of excellent weather resistance. CRILAT 4816 remains stable in highly alkaline systems, such as lime and potassium silicate. 28

31 VINAVIL CRILAT 4816 UNIT VALUE METHOD 1. SUPPLY SPECIFICATIONS Solid content % 50±1 MVPF 01 Brookfield viscosity (1) mpa.s < UNI EN ISO 2555 ph 8.0±0.5 ISO TYPICAL VALUES Minimum film-forming temperature C 0 UNI Particle size distribution μm MVANS 20 Density at 23 C Kg/dm³ 1.06 MVPF 18 Glass transition temperature C 8±1 MVANS 01 (1) RVT 20 rpm spindle 1, 23 C LIME PAINT (Rif E E) ACCELERATED STORAGE STABILITY AT 50 C Brookfield RVT viscosity at 20 rpm, 23 C (mpa.s) Days CRILAT 4816 COMPETITOR 29

32 30 Notes:

33 Notes: 31

34 Published by Vinavil S.p.A. Graphic design Layout Pensieri e Colori Cooperativa Sociale Photos Vinavil S.p.A. / Mapei S.p.A. Printing Arti Grafiche Beta Milan, March 2011

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36 HEADQUARTERS: VINAVIL S.p.A. Via Valtellina, Milano ITALY Tel Fax HEAD OFFICES: VINAVIL AMERICAS VINAVIL EGYPT VINAVIL FAR EAST Deerfield Beach (Miami) FL U.S.A. Laval (Montreal) Qc CANADA Cairo EGYPT SINGAPORE