MATERIAL SAFETY DATA SHEET StratoTone 1901 Yellow Oxide M

Transcription

1 Page 1 of 8 Section 01 - Product Information Identification of the company: Dryvit Systems, Inc. World Headquarters 1 Energy Way West Warwick, RI USA Telephone: CHEMTREC: Domestic North America International call (collect calls accepted) Trade name: Item number: Primary product use: Colorant preparation Chemical family: C.I. Pigment Brown 24 in aqueous dispersion containing polyglycol Section 02 - Composition information on hazardous ingredients Hazardous ingredients: Component CAS-no. Concentration (Trade secret no.) Chromium (as an integral part of the dye or pigment molecule) < 60 % Chromium (III) Compound < 60 % Antimony (as an integral part of the dye or pigment molecule) < 60 % Antimony compound < 60 % Alkylether sulphate 7 EO, sodium salt 9 % NJTSR# % 7321-P PCP NJTSR# % 7321-P PCP NJTSR# % 7323-P PCP Section 03 - Hazards identification Expected Route of entry: Inhalation: Skin contact: Eye contact: no yes yes

2 Page 2 of 8 Ingestion: Skin absorption: no no Health effects of exposure: Chromium ( ) Chromium: Chromium and certain compounds of chromium have been reported to cause damage to the lungs that can result in cumulative damage. Evidence for the carcinogenicity to humans is inadequate for chromium metal and trivalent chromium compounds per IARC and NTP. Dermatitis has been reported from repeated, prolonged contact with chromium compounds. Sensitization may occur on repeated contact. There have been no reports of any of these effects from the use of this product. Antimony ( ) Antimony: May cause cardiac disturbances. May cause eye and skin irritation may cause digestive and respiratory tract irritation. Inhalation of fumes may cause metal-fume fever. None of these effects are expected with this product. Alkylether sulfate, 7 EO, sodium salt ( ) This product may cause skin and eye irritation with the risk of serious eye damage. The proprietary ingredient in this product may cause mild to severe eye irritation, mild to moderate skin irritation and mild respiratory irritation. The proprietary ingredient in this product may cause eye and skin irritation. The proprietary ingredient in this product may cause eye and skin irritation. It contains ethanol that may cause birth defects or other adverse effects on pregnancy. Known effects on other illnesses: Pre-existing skin conditions may be aggravated By exposure to this product. Listed carcinogen: HMIS: IARC: No NTP: No OSHA: No Other: No Health: 2* Flammability: 1 Reactivity: 0 Personal protection: B Section 04 - First aid measures After inhalation: Get victim to fresh air. Give artificial respiration or oxygen if breathing has stopped. Get prompt medical attention. Do not give fluids if victim is unconscious.

3 Page 3 of 8 After contact with skin: Wash thoroughly with soap and water for 15 minutes. If skin irritation occurs, seek medical attention. After contact with eyes: Flush immediately under running water for fifteen minutes. If redness or irritation occurs, seek medical attention. After ingestion: If ingested, do not induce vomiting. Do not give anything to drink. Contact physician immediately. Advice to doctor / Treatment: None known. Section 05 - Fire fighting measures Flashpoint: Ignition temperature: Hazardous combustion products: Extinguishing media: Special fire fighting procedure: Unusual fire and explosion hazards: No flash point - Measure made up to the boiling point. In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO) Carbon dioxide (CO2) water spray jet dry powder carbon dioxide alcohol-resistant foam Prevent run off to sewers and bodies of water from fire fighting involving this product as product contains Clean Water Act priority pollutants. Emits toxic fumes under fire conditions. Section 06 - Accidental release measures Steps to be taken in case of spill or leak: Contain spill. Contains heavy metals. Avoid runoff to sewers and bodies of water. Wear proper protective equipment. Absorb on suitable absorbent materials. Clean up by scrubbing with soap and water, collect cleaning wastes, or remove contaminated soils. Place in proper containers.

4 Page 4 of 8 Section 07 - Handling and storage Advice on safe handling: Avoid contact with skin, eyes, and clothing. Wash thoroughly after handling. Further info on storage conditions: Store in original container. Keep tightly sealed. Store in a cool, dry, well-ventilated area. Section 08 - Exposure controls / personal protection Occupational exposure limits: Component CHROMIUM METAL AND INSOLUBLE SALTS (AS CR) CAS number: Regulatory list US OSHA Table Z- 1 Data PEL: Type of value Values / Remarks 1 mg/m3 CHROMIUM, METAL AND INORGANIC CR III COMPOUNDS, AS CR ANTIMONY AND COMPOUNDS, AS SB ANTIMONY AND COMPOUNDS, AS SB ANTIMONY AND COMPOUNDS, AS SB ANTIMONY AND COMPOUNDS, AS SB US ACGIH Threshold Limit Values Data US ACGIH Threshold Limit Values Data US OSHA Table Z- 1 Data US ACGIH Threshold Limit Values Data US OSHA Table Z- 1 Data Time Weighted Average (TWA): Time Weighted Average (TWA): PEL: Time Weighted Average (TWA): PEL: Respiratory protection: Hand protection: Eye protection: Use NIOSH/MSHA approved respirators following manufacturer's recommendations where dust or fume may be generated. Butyl Rubber, PVC Or Neoprene. Safety glasses or chemical splash goggles. Other protective equipment: Clothing suitable to prevent skin contact. Section 09 - Physical and chemical properties Form: Liquid

5 Page 5 of 8 Color: Odor: ph: Solubility in water: Density: Boiling point: Vapor pressure: Partitioning coef. octanol/water: Viscosity / (dynamic): yellow not specified 8.1 (20 C) Determined in the undiluted form miscible 2.11 g/cm3 (20 C) > 212 F ( 1,013 hpa) 1,560 mpa.s (23 C) Section 10 - Stability and reactivity Thermal decomposition: Chemical stability: Hazardous Polymerization: > 100 C with dehydration Stable. Will not occur. Conditions to avoid: None known. Section 11 - Toxicological information Product information: Acute oral toxicity: Skin irritation: Eye irritation: LD50 > 2,000 mg/kg - Method: 1999/45/EC non-irritant non-irritant Section 12 - Ecological information Product information: Biodegradation: This property is substance-specific and therefore cannot be given for the preparation.

6 Page 6 of 8 Fish toxicity: Daphnia toxicity: Algae toxicity: Bacteria toxicity: Remarks: Do not allow to enter soil, waterways or waste water Section 13 - Disposal considerations Waste disposal information: This product contains chromium predominantly in the trivalent state. Wastes containing chromium may be D007 RCRA hazardous wastes per 40 CFR RCRA hazardous waste: See Waste Disposal Information in Section 13. RCRA number: D007 Section 14 - Transport information DOT not restricted IATA not restricted IMDG not restricted Section 15 - Regulatory information TSCA Status: All components of this product are listed on the TSCA Inventory. SARA (section 311/312): Reactive hazard: no Pressure hazard: no Fire hazard: no Immediate/acute: yes Delayed/chronic: yes SARA 313 information: This product contains toxic chemical(s) subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right- To-Know Act of 1986 and 40 CFR 372. Any such

7 Page 7 of 8 toxic chemical(s) are shown below. This information must be included in all MSDS's that are copied and distributed for this material. Component CAS-no. Concentration (Trade secret no.) Chromium (as an integral part of the dye or pigment molecule) < 60 % Chromium (III) Compound < 60 % Antimony (as an integral part of the dye or pigment molecule) < 60 % Antimony compound < 60 % Clean Water Act: Contains priority pollutant CERCLA information: Component CAS-no. (Trade secret no.) Percentage RQ CHROMIUM < 60 % 5,000 LBS CHROMIUM AND COMPOUNDS < 60 % RCRA HAZARDOUS WASTE NO. D007 UNLISTED HAZARDOUS WASTE CHARACTERISTIC OF EP TOXICITY - CHROMIUMUNLISTED HAZARDOUS WASTE CHARACTERISTIC OF EP TOXICITY CHROMIUM (VI) < 60 % 10 LBS CHROMIUM AND COMPOUNDS CHROMIUM COMPOUNDS < 60 % ANTIMONY < 60 % 5,000 LBS ANTIMONY AND COMPOUNDS < 60 % ANTIMONY < 60 % 5,000 LBS ANTIMONY AND COMPOUNDS < 60 % FDA: This product is not registered with the FDA. Section 16 - Other information Other precautions: None Known Label information: May cause skin, eye or respiratory tract irritation. Avoid contact with skin, eyes and clothing; wash thoroughly after handling; use ventilation and/or respiratory protection; keep container closed when not in use. In case of eye contact, flush immediately under running water for 15 minutes; if irritation develops, seek medical attention. In case of skin contact, wash thoroughly with soap and water for 15 minutes while removing contaminated clothing and shoes; if irritation develops,

8 Page 8 of 8 seek medical attention. If inhaled, remove individual to fresh air; if breathing is difficult, give oxygen and call a physician. If ingested, do not induce vomiting. This information is supplied under the OSHA Hazard Communication Standard, 29 CFR , and is offered in good faith based on data available to us that we believe to be true and accurate. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable to the material. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate for that use. No warranty, express or implied, is made regarding the accuracy of this data, the hazards connected with the use of the material, or the results to be obtained from the use thereof. We assume no responsibility for damage or injury from the use of the product described herein. Data provided here are typical and not intended for use as product specifications. (R) and TM indicate trademarks of Dryvit Systems, Inc., its business partners or suppliers.