Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Revision Number: Issue date: 08/04/ PRODUCT AND COMPANY IDENTIFICATION Product name: TEROSON MS 930 BK known as IDH number: TEROSTAT MS 930 Black DK310M Product use: Sealant Item number: Region: Canada Company address: Contact information: Henkel Canada Corporation 2515 Meadowpine Boulevard Mississauga, Ontario L5N 6C3 Telephone: MEDICAL EMERGENCY Phone: Poison Control Center (toll free) or TRANSPORT EMERGENCY Phone: CHEMTREC (toll free) or Internet: 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Physical state: Solid WHMIS hazard class: D.2.A, D.2.B Color: Black Odor: Characteristic CAUTION: Relevant routes of exposure: MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. Skin, Inhalation, Eyes Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: This product is irritating to the respiratory system. Prolonged and/or repeated skin contact with this product may cause irritation/dermatitis. This product may cause irritation to the eyes. Rubbing may cause abrasion of cornea. Vapors may also produce eye irritation. Ingestion of this product is unlikely. However, ingestion of product may produce gastrointestinal irritation and disturbances. Eye, skin and respiratory disorders. See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % Calcium carbonate Dimethoxymethylsilyl Propyl Derivate Silyl-Terminated Polyether Diisononyl phthalate Castor oil, hydrogenated Carbon black FIRST AID MEASURES Inhalation: Move to fresh air in case of accidental inhalation of vapours or decomposition products. If symptoms develop and persist, get medical attention. Page 1 of 5

2 Skin contact: Wipe off paste with paper towel or cloth. Wash with soap and water. If irritation persists, repeat flushing and get medical attention. Discard any shoes or clothing items that cannot be decontaminated. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If adverse health effects develop seek medical attention. Ingestion: Notes to physician: Do not induce vomiting. In case of adverse health effects seek medical advice. Treat symptomatically and supportively. 5. FIRE FIGHTING MEASURES Flash point: Autoignition temperature: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Sensitivity to Mechanical Impact: Sensitivity to static discharge: Foam, dry chemical or carbon dioxide. Prevent inhalation of fumes and gases. This product is combustible at high temperatures. Oxides of silicon. Oxides of carbon. Formaldehyde. Irritating and/or toxic fumes and gases may be emitted upon the product's decomposition. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Do not allow product to enter sewer or waterways. Scrape up as much material as possible. Maintain good ventilation for large spills. 7. HANDLING AND STORAGE Handling: Storage: Do not handle contact lenses until all sealant has been removed from hands. Residual sealant may transfer to lenses and cause eye irritation. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. For safe storage, store between 15.0 C (59 F) and 25.0 C (77 F) Protect from freezing. Keep container tightly closed and in a cool, wellventilated place away from incompatible materials. Do not pressurize, cut, heat or weld containers. Empty product containers may contain product residue. Do not reuse empty containers. For information on product shelf life contact Henkel Canada Customer Service at EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Page 2 of 5

3 Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER Calcium carbonate 10 mg/m3 TWA Total dust. 5 mg/m3 PEL Respirable fraction. 15 mg/m3 PEL Total dust. Dimethoxymethylsilyl Propyl Derivate Silyl-Terminated Polyether Diisononyl phthalate Castor oil, hydrogenated Carbon black 3 mg/m3 TWA Inhalable fraction. 3.5 mg/m3 PEL Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Breathing apparatus only if aerosol or dust is formed. Safety goggles or safety glasses with side shields. Safety showers and eye wash stations should be available. Use impermeable gloves and protective clothing as necessary to prevent skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Solid Color: Black Odor: Characteristic Odor threshold: ph: Vapor pressure: Boiling point/range: Melting point/ range: Specific gravity: 1.5 Vapor density: Flash point: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Insoluble Partition coefficient (n-octanol/water): VOC content: 0.37 %; 5.15 g/l Viscosity: mpa.s 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Conditions to avoid: Stable under normal conditions of storage and use. under normal processing. Oxides of carbon. Oxides of silicon. Formaldehyde. Hydrocarbons. Irritating fumes. Strong acids. Oxidizing agents. Bases. Avoid excessive heat and ignition sources. Exposure to moisture. 11. TOXICOLOGICAL INFORMATION Toxicologically synergistic products: Page 3 of 5

4 Refer to the following for Irritancy of Product, Sensitization to Product, Carcinogenicity, Reproductive Toxicity, Teratogenicity, and Mutagenicity. Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) ACGIH Carcinogen Calcium carbonate No No No No Dimethoxymethylsilyl Propyl Derivate No No No No Silyl-Terminated Polyether No No No No Diisononyl phthalate No No No No Castor oil, hydrogenated No No No No Carbon black No Group 2B No Group A3 Hazardous components LD50s and LC50s Health Effects/Target Organs Calcium carbonate Oral LD50 (RAT) = 6,450 mg/kg Nuisance dust Dimethoxymethylsilyl Propyl Derivate No Records Silyl-Terminated Polyether No Records Oral LD50 (RAT) = > 40,000 mg/kg Oral LD50 (RAT) = > 10 g/kg Diisononyl phthalate Dermal LD50 (RABBIT) = > 3,160 mg/kg Central nervous system, Developmental Dermal LD50 (RABBIT) = > 3.16 g/kg Inhalation LC50 (RAT, 4 h) = > 4.4 mg/l Castor oil, hydrogenated No Target Organs Carbon black Oral LD50 (RAT) = > 8,000 mg/kg Respiratory, Some evidence of carcinogenicity 12. ECOLOGICAL INFORMATION Ecological information: 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Canada Transportation of Dangerous Goods - Ground 14. TRANSPORT INFORMATION International Air Transportation (ICAO/IATA) Water Transportation (IMO/IMDG) Page 4 of 5

5 15. REGULATORY INFORMATION Canada Regulatory Information CEPA DSL/NDSL Status: Contains one or more components listed on the Non-Domestic Substances List. All other components are listed on or are exempt from listing on the Domestic Substances List. Components listed on the NDSL must be tracked by all Canadian Importers of Record as required by Environment Canada. They may be imported into Canada in limited quantities. Please contact Regulatory Affairs for additional details. United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: Reviewed MSDS. Reissued with new date. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR), and the MSDS contains all the information required by the CPR. Prepared by: Lou Fabrizio, Regulatory Affairs Specialist DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 5 of 5