Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet KEYSTONE POWDER BLEACH CLEANSER 1. Product and company identification Trade name of product Product use KEYSTONE POWDER BLEACH CLEANSER Cleaning product Product dilution information Not applicable Supplier's information Code Date of issue 2. Physical state Emergency overview Ecolab Co. 515 Tomken Road Mississauga ON L4W 2X December-213 EMERGENCY HEALTH INFORMATION Outside United States and Canada CALL (in USA) Hazards identification Routes of entry Skin contact, Eye contact, Ingestion Potential acute health effects Eyes Irritating to eyes. Skin Inhalation Ingestion Powder WARNING! CAUSES EYE AND SKIN IRRITATION. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Irritating to skin. See toxicological information (Section 11) 3. Composition/information on ingredients Name CAS number % by weight limestone SODIUM CARBONATE SODIUM DODECYLBENZENESULFONATE silica, crystalline - quartz sodium perborate, tetrahydrate Name CAS number % by weight 1/6

2 4. Eye contact Skin contact Inhalation Ingestion 5. First-aid measures In case of contact, immediately flush eyes with plenty of water. Remove contact lenses and flush again. Get medical attention if irritation persists. In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if irritation persists. Wash clothing before reuse. Clean shoes thoroughly before reuse. No special measures required. Treat symptomatically. Get medical attention if symptoms occur. Fire-fighting measures Auto-ignition temperature Flammable limits Hazardous thermal decomposition products Special remarks on fire hazards Special remarks on explosion hazards Fire-fighting media and instructions Special protective equipment for fire-fighters 6. Personal precautions Environmental precautions Methods for cleaning up Use dry chemical powder. Decomposition products may include the following materials carbon dioxide carbon monoxide sulfur oxides metal oxide/oxides Accidental release measures Move containers from fire area if this can be done without risk. Dyke area of fire to prevent runoff. Fine dust clouds may form explosive mixtures with air. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Use personal protective equipment as required. Avoid contact of large amounts of spilt material and runoff with soil and surface waterways. Use a water rinse for final clean-up. 7. Handling Storage Handling and storage Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Mixing this product with acid or ammonia releases chlorine gas. Keep out of reach of children. Store in a closed container. Store between the following temperatures and 4 C 2/6

3 8. Engineering measures Exposure controls/personal protection Personal protection Eyes Wear eye protection. Hands Skin Respiratory Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Use chemical-resistant, impervious gloves. No protective equipment is needed under normal use conditions. No special protection is required. Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations limestone AB 4/ [3] BC 4/ [a] [b] QC 9/ [c] silica, crystalline - quartz US ACGIH 3/ [d] AB 4/ [e] BC 4/ [f] ON 7/ [g] QC 9/ [h] [3]Skin sensitisation Form [a]respirable dust [b]total dust [c]total dust. [d]respirable fraction [e]respirable particulate [f]respirable [g] Respirable fraction means that size fraction of the airborne particulate deposited in the gas-exchange region of the respiratory tract and collected during air sampling with a particle size-selective device that, (a) meets the ACGIH particle size selective sampling criteria for airborne particulate matter; and (b) has the cut point of 4 µm at 5 per cent collection efficiency. [h]respirable dust. 9. Physical and chemical properties Physical state Powder Flash point > 1 C Colour White Odour Faint odour ph 9.5 to 12 [Conc. (% w/w) 1%] Boiling/ condensation point Melting/freezing point Relative density Vapour pressure Vapour density Odour threshold Evaporation rate Viscosity Dispersibility properties Solubility LogKow 1.25 Kinematic (room temperature) cm 2 /s ( cst) Easily soluble in the following materials cold water and hot water. 3/6

4 1. Stability and reactivity Stability Conditions of instability Reactivity Hazardous decomposition products Hazardous polymerisation 11. Toxicity data The product is stable. Under normal conditions of storage and use, hazardous polymerisation will not occur. Toxicological information Potential acute health effects Eyes Skin Inhalation Ingestion Carcinogenic effects Mutagenic effects Teratogenic effects Reproductive effects Sensitization to Product Synergistic products (toxicologically) Reactive or incompatible with the following materials organic materials, metals, acids and moisture. Mixing this product with acid or ammonia releases chlorine gas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Under normal conditions of storage and use, hazardous polymerisation will not occur. Product/ingredient name Test Route Result Species limestone LD5 Oral >5 mg/kg Rat sodium carbonate LD5 Dermal >2 mg/kg Rabbit LD5 Oral 28 mg/kg Rat LC5 Inhalation 1.15 mg/l Rat sodium dodecylbenzene sulfonate LD5 Dermal >2 mg/kg Rat LD5 Oral 186 mg/kg Rat sodium perborate, tetrahydrate LD5 Dermal >2 mg/kg Rabbit LD5 Oral 222 mg/kg Rat LC5 Inhalation mg/l Rat Other adverse effects Target organs Irritating to eyes. Irritating to skin. Potential chronic health effects 12. Ecological information Ecotoxicity There is no known chronic effect after exposure to this product. Not reported 4/6

5 13. Disposal considerations Waste disposal 14. Diluted product can be flushed to sanitary sewer. Discard empty container in trash. Transport information Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. TDG TDG Classification IMO/IMDG IMO/IMDG Classification 15. Not regulated. Not regulated. For transport in bulk, see shipping documents for specific transportation information. WHMIS Regulatory information Canada inventory Class D-2B Material causing other toxic effects (Toxic). All components are listed or exempted. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 16. Other information Hazardous Material Information System (U.S.A.) Health Flammability Physical hazards 1 National Fire Protection Association (U.S.A.) Health 1 Flammability Instability/Reactivity Special Date of issue Responsible name 9-December-213 Regulatory Affairs Indicates information that has changed from previously issued version. 5/6

6 16. Other information Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. 6/6