SAFETY DATA SHEET. Creation Date 10-Dec-2010 Revision Date 11-Apr-2018 Revision Number Identification

Transcription

1 SAFETY DATA SHEET Creation Date 10-Dec-2010 Revision Number 4 Product Name Glycine 1. Identification Cat No. : BP381-1; BP381-5; BP381-10; BP381-25; BP ; G45-12; G45-212; G46-1; G46-500; G48-12; G48-212; G CAS-No Synonyms Gly; Aminoacetic acid; Aminoethanoic acid; Gyn-Hydralin (Crystalline/Granules/Powder/Certified/USP/EP/BP/JP) Recommended Use Uses advised against Laboratory chemicals. Food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Company Fisher Scientific One Reagent Lane Fair Lawn, NJ Tel: (201) Emergency Telephone Number CHEMTRECÒ, Inside the USA: CHEMTRECÒ, Outside the USA: Hazard(s) identification Classification Classification under 2012 OSHA Hazard Communication Standard (29 CFR ) Based on available data, the classification criteria are not met Label Elements None required Hazards not otherwise classified (HNOC) None identified 3. Composition/Information on Ingredients Component CAS-No Weight % Glycine First-aid measures Page 1 / 6

2 Eye Contact Skin Contact Inhalation Ingestion Most important symptoms and effects Notes to Physician Suitable Extinguishing Media Unsuitable Extinguishing Media Flash Point Method - Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Wash off immediately with plenty of water for at least 15 minutes. Get medical attention immediately if symptoms occur. Move to fresh air. Get medical attention immediately if symptoms occur. If not breathing, give artificial respiration. Do not induce vomiting. Obtain medical attention.. Treat symptomatically 5. Fire-fighting measures Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Autoignition Temperature Explosion Limits Upper Lower Sensitivity to Mechanical Impact Sensitivity to Static Discharge Specific Hazards Arising from the Chemical Thermal decomposition can lead to release of irritating gases and vapors. Hazardous Combustion Products Nitrogen oxides (NOx) Carbon monoxide (CO) Carbon dioxide (CO2) Ammonia Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 1 Flammability 1 Instability 1 Physical hazards N/A Personal Precautions Environmental Precautions 6. Accidental release measures Use personal protective equipment. Ensure adequate ventilation. Avoid dust formation. See Section 12 for additional ecological information. Methods for Containment and Clean Avoid dust formation. Sweep up or vacuum up spillage and collect in suitable container for Up disposal. Handling Storage 7. Handling and storage Wear personal protective equipment. Ensure adequate ventilation. Avoid dust formation. Do not breathe dust. Avoid contact with skin, eyes and clothing. Keep containers tightly closed in a dry, cool and well-ventilated place. 8. Exposure controls / personal protection Page 2 / 6

3 Exposure Guidelines This product does not contain any known or suspected reproductive hazards Engineering Measures None under normal use conditions. Personal Protective Equipment Eye/face Protection Skin and body protection Respiratory Protection Hygiene Measures Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Wear appropriate protective gloves and clothing to prevent skin exposure. No protective equipment is needed under normal use conditions. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Physical State Powder Solid Appearance White Odor Odorless Odor Threshold ph Melting Point/Range C / F Boiling Point/Range Flash Point Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper Lower Vapor Pressure Vapor Density Specific Gravity Solubility 25g (25 C), 54.4g (75 C), 67.2 g (100 C) in 100mL Partition coefficient; n-octanol/water Autoignition Temperature Decomposition Temperature Viscosity Molecular Formula C2 H5 N O2 Molecular Weight Stability and reactivity Reactive Hazard Stability Conditions to Avoid Incompatible Materials None known, based on information available Moisture sensitive. Stable under normal conditions. Excess heat. Incompatible products. Exposure to moist air or water. Avoid dust formation. Bases, Strong oxidizing agents Hazardous Decomposition Products Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide (CO2), Ammonia Hazardous Polymerization Hazardous Reactions Hazardous polymerization does not occur. None under normal processing. Page 3 / 6

4 Acute Toxicity 11. Toxicological information Product Information Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation Glycine LD50 = 7930 mg/kg ( Rat ) Not listed Not listed Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No IARC NTP ACGIH OSHA Mexico Glycine Not listed Not listed Not listed Not listed Not listed Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard Symptoms / effects,both acute and delayed Endocrine Disruptor Information Other Adverse Effects Ecotoxicity. Persistence and Degradability Bioaccumulation/ Accumulation Mobility Waste Disposal Methods DOT... None known None known The toxicological properties have not been fully investigated. 12. Ecological information Soluble in water Persistence is unlikely based on information available.. Will likely be mobile in the environment due to its water solubility. 13. Disposal considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Part Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. 14. Transport information Page 4 / 6

5 TDG IATA IMDG/IMO 15. Regulatory information International Inventories Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Glycine X X X X X X X Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) SARA 313 SARA 311/312 Hazard Categories CWA (Clean Water Act) Clean Air Act See section 2 for more information OSHA Occupational Safety and Health Administration CERCLA California Proposition 65 U.S. State Right-to-Know Regulations This product does not contain any Proposition 65 chemicals U.S. Department of Transportation Reportable Quantity (RQ): DOT Marine Pollutant DOT Severe Marine Pollutant N N N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Other International Regulations Mexico - Grade 16. Other information Page 5 / 6

6 Prepared By Creation Date Revision Date Print Date Revision Summary Regulatory Affairs Thermo Fisher Scientific 10-Dec Apr Apr-2018 This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 6 / 6