Home Care Hard Surface Cleaning Multipurpose Solutions for Surface Clean Juraci Marques da Silva, Technical Consultant August, 2016
1 Driving Forces to Innovation and Claims to choose 2 Conclusions 8/24/2016 2
Claims to choose Convenient Cleaning High-Performance Cleaning Spotless Drying Easy-toclean-again Effect Primary Cleaning Boost Glossy & Streak-Free Convenience: Ease of Use, Emotional Purchase Performance Gentle Cleaning Sustainable Cleaning Skin Care Surface Care Renewable Base and Biodegradable Safeness: Hygiene, Material Protection Sustainable Solutions: Environmentally friendly product, water and energy efficiency, packaging/refill 3
Claims to choose Convenient Cleaning Convenient Cleaning Spotless Drying Easy-to-cleanagain Effect 4
The Polyquart Types Polyquart 149 Aqueous solution of acrylic copolymer Yellowish clear liquid 21.5 22.5 % active Stable at ph ranges from 3 10 Dosage 0.2% - 1.0% as is Polyquart Ecoclean Aerobic and anaerobic biodegradability Starch acrylic copolymer Yellowish clear liquid 21.5 22.5 % active Stable at ph ranges from 3 10 Dosage 0.5% - 1.5% as is 8/24/2016 5
Surface Modification Polyquart 149 120 100 Uniform and quick drying Untreated Surface Polyquart 149 Uniform wetting More hydrophilic Contact Angle [ ] 80 60 40 More hydrophobic 20 0 Ceramic Glass Stainless Steel Car Panel PVC PP 8/24/2016 6
Surface Modification Polyquart Ecoclean Excellent wetting & uniform drying Unchanged surface 90 Contact Angle [ ] 80 70 60 50 40 30 20 10 0 Untreated Surface Polyquart Ecoclean More hydrophilic Ceramic Glass Stainless Steel Plastics* 8/24/2016 * PVC 7
Test Method Water Drainage / Sheeting 1. Pretreatment with test solution Test solution ( e.g. 0.5% active surfactant and 0.1% active polymer or a cleaner formulation) is dropped on a ceramic tile 15x15cm by 25 drops, 5x5 drops in square. These drops are wiped via Kim Wipe in twice, 10 wiping cycles in both directions to get a homogenous film 2. Air drying Drying at roomtemperature for 24 hours 3. Rinse with water stream Pretreated plate is placed vertical and a water stream is placed on the upper end from the right to the left corner in order to rinse the ceramic. After stopping the water stream, you can evaluate the sheeting effect) 8/24/2016 8
Water Drainage / Sheeting Effect Water sheeting effect caused by hydrophilization of the surface No effect on a non treated surface Water drainage effect caused by hydrophobization of the surface 8/24/2016 9
Water Drainage / Sheeting 0.5% active surfactant 1% active surfactant 2% active surfactant without polymer Water drainage hydrophobization no effect - rip 1 1 1 1 hydrophilization Water sheeting -0.5-0.5 Lutensol Lutensol / Glucopon 425 (1:3) 8/24/2016 10
Water Drainage by Polyquart 149 0.5% active surfactant 0.5% active surfactant + 0.1% active Polyquart 149 Water drainage 4 6 hydrophobization 1 1 hydrophilization Water sheeting Lutensol Lutensol / Glucopon 425 (1:3) 8/24/2016 11
Water Sheeting by Polyquart Ecoclean 0.5% active 0.5% active + 0.1% active Polyquart Ecoclean Water drainage hydrophobization 1 1 hydrophilization Water sheeting -1-1 Lutensol Lutensol / Glucopon 425 (1:3) 8/24/2016 12
Water Drainage / Sheeting Effect on water sheeting / drainage by Polyquart types for a spotless drying: Polyquart 149 Polyquart Ecoclean spotless drying & anti-rain quick & spotless drying Strength of water sheeting / drainage effect 8/24/2016 13
Effect to choose Convenient Cleaning Convenient Cleaning Spotless Drying Easy-to-cleanagain Effect 14
Test Method Easy-to-clean-again 1. Pretreatment with test solution e.g. 1% active surfactant and 0.1% active polymer is dropped on a ceramic tile. 25 drops, 5x5 drops in square for 15x15cm tile. These drops are wiped via Kim Wipe in twice 10 wiping cycles in both directions to get a homogenous film. 2. Air drying Drying at roomtemperature for 24 hours. 3. Soiling tile with Ca-Stearate by air brush 3 ml soil is sprayed homgenous on the hole area of tile. (Soil: 5% Ca-Stearate, 10% Water, 85% Ethanol the soil should be stirred by Ultra Turrax and Ultra Sonic Bath and stored under usual stiring for 1 day) 4. Heating at for melting the Stearate layer (30 Minutes at 180 C) 5. Wiping with sponge under rinsing tap water Wiping with constant low pressure under water stream for 10 cycles. 6. Evaluation 8/24/2016 15
Easy-to-clean-again Effect Evaluation: left side of tile untreated right side of tile pretreated Grading examples (0 to 3): 0 1 2 3 8/24/2016 16
Easy-to-clean-again: Polyquart 149 3 0.5% active surfactant + 0.1% active Polyquart 149 2% active surfactant + 0.1% active Polyquart 149 2 1 No effect with 0.5% active surfactant, slight effect on Lutensol and Glucopon mixtures with 2.0% active surfactant and 0.1% Polyquart 149. 1 0 0 0 0 Lutensol Lutensol / Glucopon 425 (1:3) 8/24/2016 17
Easy-to-clean-again: Polyquart 149 3 0.5% active surfactant + 0.2% active Polyquart 149 2% active surfactant + 0.2% active Polyquart 149 2 Slight effect with 0.5% / 2.0% active surfactant and 0.2% Polyquart 149. 1 1 1 1 0 Lutensol Lutensol / Glucopon 425 (1:3) 0 8/24/2016 18
Easy-to-clean-again: Polyquart Ecoclean 3 2 0.5% active surfactant + 0.1% active Polyquart Ecoclean 2% active + 0.1% active Polyquart Ecoclean 3 Slight effect with 0.5% active surfactant, excellent effect on Lutensol but not on Glucopon mixtures with 2.0% active surfactant and 0.1% Polyquart Ecoclean. 1 1 1 1 0 Lutensol Lutensol / Glucopon 425 (1:3) 8/24/2016 19
Easy-to-clean-again: Polyquart Ecoclean 3 2 0.5% active surfactant + 0.2% active Polyquart Ecoclean 2% active + 0.2% active Polyquart Ecoclean Slight effect with 0.5% active surfactant, significant effect on Lutensol and Glucopon mixtures with 2.0% active surfactant and 0.2% Polyquart Ecoclean. 2 2 1 1 1 0 Lutensol Lutensol / Glucopon 425 (1:3) 8/24/2016 20
Easy-to-clean-again Easy-to-clean-again effect by Polyquart types: Polyquart 149 Polyquart Ecoclean Strength of easy-to-clean-again effect* *using Ca-stearate based soil 8/24/2016 21
Home Care Claims to choose High-Performance High-Performance Cleaning Primary Cleaning Boost Glossy & Streak-Free 22
Test Method Primary Cleaning Modified Gardner test method by automatic test equipment 0.5% / 1% / 2 % active surfactant in distilled water 25 C Using oil soil (IPP 83/21) on polyvinylchloride (PVC) strips (1) Soiling by brush (2) Analysis of soiled surface Evaluation of cleaned PVC strips after 10 wipes Oily Soil (IPP 83/21) % Content 17.0 Myritol 318 (caprylic / capric triglyceride) 40.0 Nytex 801 (Nynas; processing oil, naphthenic) 36.0 Benzine (80/110) 7.0 Special Carbon Black (Orion Engineered Carbons, D-60528 Francfort, Germany) (3) Applying test solution (4) Wiping with sponge 8/24/2016 (5) Rinsing with water (6) Analysis of cleaned surface 23
Primary Cleaning Performance Test in distilled water at 25 C, using the modified Gardner test on PVC with oil soil Soil Removal [%] 70 60 50 40 30 20 0.5% active surfactant 1% active surfactant 2% active surfactant 62 58 55 50 51 52 10 0 Lutensol Lutensol / Glucopon 425 (1:3)
Primary Cleaning Polyquart 149 Test in distilled water at 25 C, using modified Gardner test on PVC with oil soil Soil Removal [%] 80 70 60 50 40 30 20 1% active surfactant 0.5% active surfactant 0.5% active surfactant + 0.1% active Polyquart 149 62 63 55 50 51 Excellent primary cleaning boost of Lutensol / Glucopon combination (3:1) by 0.1% active Polyquart 149. 71 10 0 Lutensol Lutensol / Glucopon 425 (1:3)
Primary Cleaning Polyquart Ecoclean Test in distilled water at 25 C, using modified Gardner test on PVC with oil soil Soil Removal [%] 70 60 50 40 30 20 1% active surfactant 0.5% active surfactant 0.5% active surfactant + 0.1% active Polyquart Ecoclean 62 58 55 50 51 Excellent primary cleaning boost of Lutensol / Glucopon combination (3:1) by 0.1% active Polyquart Ecoclean. 54 10 0 Lutensol Lutensol / Glucopon 425 (1:3)
Primary Cleaning Boost effect on primary cleaning by Polyquart types: Polyquart 149 Polyquart Ecoclean Strength of primary cleaning boost effect 8/24/2016 27
Home Care Claims to choose High-Performance High-Performance Cleaning Primary Cleaning Boost Glossy & Streak- Free 28
Test Method Gloss Retention 1. Measure reflection of clean ceramic tile 2. Pretreatment with test solution (1% active surfactant is dropped on a ceramic tile. 25 drops, 5x5 drops in square for 15x15cm tile. These drops are wiped via Kim Wipe in twice 10 wiping cycles in both directions to get a homogenous film) 85 60 N 20 3. Air drying at room temperature 4. Measure reflection of treated ceramic tile 5. Calculate gloss retention out of 1. and 4. 8/24/2016 29
Gloss Retention Polyquart 149 Test in distilled water at 20 C on black ceramic tiles Gloss Retention [%] 100 90 80 70 60 50 40 30 20 10 0 78.2 0.5% active surfactant 0.5% active surfactant + 0.1% Polyquart 149 2.0% active surfactant 2.0% active surfactant + 0.1% Polyquart 149 91.8 96.6 95.3 79.7 80.4 85.2 88.2 Gloss retention boost by Polyquart 149 only on Lutensol types mixtures with Glucopon show already excellent gloss retention; better results with 0.5% active surfactant. Lutensol Lutensol / Glucopon 425 (1:3)
Gloss Retention Polyquart Ecoclean Test in distilled water at 20 C on black ceramic tiles Gloss Retention [%] 100 90 80 70 60 50 40 30 20 10 0 78.2 0.5% active surfactant 0.5% active surfactant + 0.1% Polyquart Ecoclean 2.0% active surfactant 2.0% active surfactant + 0.1% Polyquart Ecoclean 92.2 79.7 96.6 98.2 88 85.2 87.5 Gloss retention boost by Polyquart Ecoclean only on Lutensol types; better results at 0.5% active surfactant. Lutensol Lutensol / Glucopon 425 (1:3)
Gloss Retention / Streak-Free Effect Effect on gloss retention / streak-free boost with Polyquart types: Polyquart 149 Polyquart Ecoclean Only with alkoxylated surfactants like Lutensol types; no boost of mixtures with Glucopon types! Strength of gloss retention / streak-free effect 8/24/2016 32
Home Care Claims to choose Gentle Cleaning Gentle Cleaning Skin Care Surface Care 33
Skin Care Glucopon Glucopon surfactants are significantly less skin irritating than comparable to nonionic and anionic (LAS) surfactants. Glucopon surfactants can even reduce the skin irritation factor of other surfactants when being used in combination. Perfect mildness to skin.
Skin Care - Glucopon Test Method: Modified Duhring - Chamber Test Tested Surfactants: Alkyl Polyglucoside - APG Linear Alkylbenzene Sulphonate - LAS Fatty Alcohol Ether Sulfate - FAES Sodium Alkene Sulfate - SAS Fatty Alcohol Sulfate FAS Mixtures of other surfactants with APG Test Conditions: 20 subjects (male and female) Mode of application: once, occlusive, for 24 hours Concentration of the test solution: 1% active substance
Skin Care - Glucopon APG LAS FAES SAS FAS C12/14 LAS / APG (1:1) Test Method: Modified Duhring - Chamber Test Test Conditions: 20 subjects (male and female). Mode of Application: once, occlusive, for 24 hours The concentration of the test solution was 1% active substance. FAES / APG (1:1) SAS / APG (1:1) FAS / APG (1:1) 0 100 200 300 400 Relative irritation score (%)
Home Care Claims to choose Gentle Cleaning Gentle Cleaning Skin Care Surface Care 37
Test Method Plastic Compatibility ISO 22088-4 test method (spline / corrosion test) A test method to determine the plastic compatibility of hard surface cleaner ingredients like surfactants, solvents, acids, alkaline and further components. unchanged Methodology: The plastic test strip, containing a stainless steal pin in a hole (tension), is dipped shortly into the test solution (1% active). The test strip is checked visually after fissures 4 hours 3 days 7 days and throughcracks 14 days test period fraction 8/24/2016 38
Plastic Compatibility (PMMA) Test solution: 1% active surfactant Lutensol :Glucopon 425 (1:3) w/wo 0.2% Polyquart type Substrate: Plexiglass 8N80 (PMMA - Polymethylmethacrylat) unchanged Superior plastic compatibility with high content of Glucopon types; no influence by Polyquart types. fissures 14 days 7 days Lutensol Lutensol / Glucopon 425 Lutensol / Glucopon 425 / Polyquart 149 Lutensol / Glucopon 425 / Polyquart Ecoclean 3 days 4 hours throughcracks fraction
Plastic Compatibility (PC) Test solution: 1% active surfactant Lutensol :Glucopon 425 (1:3) w/wo 0.2% Polyquart type Substrate: Makrolon 3103 (PC - Polycarbonate) Superior plastic compatibility with high content of Glucopon types; no influence by Polyquart types. unchanged fissures 14 days 7 days 3 days throughcracks Lutensol Lutensol / Glucopon 425 Lutensol / Glucopon 425 / Polyquart 149 Lutensol / Glucopon 425 / Polyquart Ecoclean 4 hours fraction
Plastic Compatibility (ABS) Test solution: 1% active surfactant Lutensol : Glucopon 425 (1:3) w/wo 0.2% Polyquart type Substrate: Polylac PA 727 (ABS - Acrylnitril Butadien Styrol) Superior plastic compatibility with high content of Glucopon types; no influence by Polyquart types. unchanged fissures 14 days 7 days Lutensol Lutensol / Glucopon 425 Lutensol / Glucopon 425 / Polyquart 149 Lutensol / Glucopon 425 / Polyquart Ecoclean 3 days 4 hours throughcracks fraction
Claims to choose Sustainable Cleaning Sustainable Cleaning Renewable Base 42
Renewable Base Renewable Base: Glucopon types (alkyl polyglucoside) = sugar / fatty alcohol Polyquart Ecoclean = teric modified starch Existing statement for vegetable origin of Polyquart Ecoclean Aerobic and anaerobic biodegradability, no labelling for the following products: Glucopon types, Lutensol types Polyquart Ecoclean 8/24/2016 43
Home Care and I&I Glucopon types Product information Application: Home Care and I&I Focus Hard Surface Cleaning Customer industry: Consumer Goods and I&I Market: Global Sustainability performance Gloss improvement, foam stabilization Cleaning performance 100% renewable based Meets eco-label requirements aerobic and anaerobic biodegradable Registered in main chemical inventories Differentiation potential Customer Performance in modern formulations Health and safety Consumer Health & safety Material protection A balanced surfactant combining efficiency with an excellent eco-tox profile 44
Home Care and I&I Polyquart Ecoclean Product information Application: Home Care and I&I Focus Hard Surface Cleaners Customer industry: Consumer Goods and I&I Market: Global Sustainability performance Amphoteric modified starch Excellent eco-tox profile Aerobic and anaerobic biodegradable Supports sustainable convenience claims such as easy-to-clean-again, time-saving, easy-to-use Differentiation potential Customer Supported modern claims Consumer Health & safety Convenience Performance A product that supports modern consumer needs 45
1 Driving Forces to Innovation and Claims to choose 2 Conclusions 8/24/2016 46
The Elements Polyquart types Lutensol types Excellent wetting Emulsification Disperging Long-lasting effects High gloss Cleaning boost Glucopon types Skin and surface care Formulability Foam stabilization High gloss renewables Multipurpose Solutions! sustainable 8/24/2016 47
Summary Convenient Cleaning High-Performance Cleaning Easy-to-clean-again effect Quick and spotless drying Time-saving and effortless cleaning Excellent primary cleaning Glossy and streak-free surfaces Foam stability Gentle Cleaning Sustainable Cleaning Material protection Skin protection Biodegradable products Renewable based raw materials 48
Lutensol, Glucopon & Polyquart : Multipurpose Solutions for Surface Clean! Juraci M. da Silva juraci.silva@basf.com