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The Air We Breathe A report on Garfield County air quality monitoring results for 2008-2014 Morgan Hill Environmental Health Specialist Garfield County Public Health mhill@garfield-county.com Cassie Archuleta Project Scientist Air Resource Specialists carchuleta@air-resource.com Garfield County Energy Advisory Board Rifle, CO August 6, 2015

2 Presentation Content 2014 update: Monitoring site locations Data Availability Data since 2008 Criteria Pollutant summaries VOC trends Other Research Mobile monitoring station currently located in Glenwood Springs

3 2014 Monitoring Site Locations Rifle SNMOC Carbonyls O 3 PM 10 /PM 2.5 Meteorology Parachute SNMOC Carbonyls PM 10 Meteorology Glenwood Springs (Mobile) SNMOC Carbonyls Gas (O 3, NO X, THC/NMHC) PM 10 /PM 2.5 Meteorology Bell-Melton SNMOC Carbonyls Meteorology Carbondale SNMOC Carbonyls O 3 PM 2.5 Meteorology

4 2015 Monitoring Site Locations Mobile site moved from Battlement Mesa to Glenwood Springs in February, 2015 Parachute SNMOC Carbonyls PM 10 Meteorology Rifle SNMOC Carbonyls O 3 PM 10 /PM 2.5 Meteorology Glenwood Springs (Mobile) SNMOC Carbonyls Gas (O 3, NO X, THC/NMHC) PM 10 /PM 2.5 Meteorology Bell-Melton SNMOC Carbonyls Meteorology Carbondale SNMOC Carbonyls O 3 PM 2.5 Meteorology

5 Annual Air Quality Monitoring Reports Reports since 2008 published on Air Quality Management website Include summaries of: Meteorological measurements (e.g. wind speed and wind direction) Criteria pollutants (e.g. ozone and particulate matter) Volatile organic compounds (includes Hazardous Air Pollutants) http://www.garfield-county.com/air-quality

6 New Data Report: Annual Air Quality Update Newsletter Annual air quality data summary report is large and comprehensive (~ 80 pages) A short annual update newsletter draft has been developed Hybrid of Citizen s Guide to Air Quality and annual reports, which includes: What s new Annual snapshot of results and trends What s next

7 Real-Time data available on website http://www.garfield-county.com/air-quality Real-time images (Rifle) 7-day Timeline plots Air Quality Indices (Real-time Health Risk indicators)

8 Criteria Pollutants: Measurements in Garfield County Criteria pollutants are specific pollutants regulated by EPA which are considered harmful to human health and the environment. Criteria pollutants measured in Garfield County include: Ground Level Ozone (O 3 ) Nitrogen Dioxide (NO 2 ) Particulate Matter (PM) Measured values are compared to EPA National Ambient Air Quality Standards (NAAQS)

9 Criteria Pollutants: Ozone (O 3 ) Ozone is a pollutant that is not emitted directly, but formed through chemical reactions Nitrogen Oxides (e.g. NO 2 ) and Volatile Organic Compounds (VOCs) are considered O 3 precursors

10 O 3 Measurements in Garfield County Rifle- Health and Human Services Carbondale-CRMS

11 O 3 Measurements in Garfield County National Ambient Air Quality Standards (NAAQS) for Ozone: Exceedance: 8-Hour average of 75 ppb Violation: 3-year average of the 4 th highest daily maximum 8-hour > 75 ppb Two exceedances: 2008 and 2012 NO NAAQS violations Year Highest 8-hour averag e (ppb) Rifle 4 th highest 8-hour average (ppb) 2008 76 66 2009 64 62 2010 69 66 2011 68 66 2012 78 68 2013 66 63 2014 62 61 Battlement Mesa 2013 71 70 2014 64 61 Carbondale 2012 69 66 2013 67 59 2014 64 59

12 Regional Ozone (2011-2013) 3-Year Average Daily maximum 8-Hour Ozone (County maximum) > 75 ppb > 70 ppb > 65 ppb > 60 ppb <= 60 ppb Insufficient Data No monitoring data available Rural/Class I Site Class I Area

13 Criteria Pollutants: Particulate Matter Particulate Matter (PM) is a mixture of solid particles and liquid droplets small enough to be inhaled PM 2.5 and PM 10 are particle sizes regulated by EPA Can be directly emitted, or formed in the atmosphere Generally made up of complex chemical mixtures (e.g. mineral oxides, sulfates, nitrates, organic material)

14 PM 10 Measurements in Garfield County Rifle Henry Building

PM 10 Measurements in Garfield County National Ambient Air Quality Standards (NAAQS) for PM 10 Exceedance: 24-hour average of 150 µg/m 3 Violation: More than 1 24-Hour average > 150 µg/m 3 in a 3-year period 1 average >150 in 2008 Local Construction No NAAQS violations

16 PM 2.5 Measurements in Garfield County Inside the Mobile Monitor Carbondale- CRMS

PM 2.5 Measurements in Garfield County National Ambient Air Quality Standards (NAAQS) for PM 2.5 : Exceedance: 24-hour = 35 µg/m 3 Annual = 12 µg/m 3 Violation: 3-year average of 98 th percentile 24-hour > 35 µg/m 3 or 3-year average of annual mean > 12 µg/m 3 15 to 12 on Dec.14, 2012 No NAAQS violations

18 Air Quality Index (AQI) 2014 Summary Number of Days Air Quality Cautionary Statements Ozone (O3) Particulate Matter (PM2.5) Nitrogen Dioxide (NO2) Good None 357 354 333 Moderate Unhealthy for Sensitive Groups Unhealthy People who are unusually sensitive to air pollution should consider limiting prolonged or heavy exertion outdoors. Active children and adults, and people with lung disease, such as asthma, should reduce prolonged or heavy exertion outdoors. Active children and adults, and people with lung disease, such as asthma, should reduce prolonged or heavy exertion outdoors. Everyone else, especially children, should reduce prolonged or heavy exertion outdoors. 8 11 0 0 0 0 0 0 0 Missing N/A 0 0 32

19 Volatile Organic Compounds (VOCs): Measurements in Garfield County Measured at five sites since 2008 90 compounds analyzed Major HAPS (e.g. BTEX and Formaldehyde) VOCs related to natural gas exploration (e.g. propane and ethane) Highly reactive VOCs which could contribute to O 3 formation Same sampling method, laboratory and analysis methods as used for the EPA Urban Air Toxics Monitoring Network http://www.epa.gov/ttnamti1/uatm.html

20 Volatile Organic Compounds (VOCs): Speciated Non-Methane Organic Compounds (SNMOC) 78 Compounds Sampled every 6 days for 24 hours Parachute - Center for Family Learning

21 Volatile Organic Compounds (VOCs): Speciated Non-Methane Organic Compounds (SNMOC)

22 Volatile Organic Compounds (VOCs): Carbonyls Include: formaldehyde, acetone Sources: Fuel combustion, mobile sources, oil refineries Frequency: Sampled every 12 days for 24 hours

23 Volatile Organic Compounds (VOCs): Carbonyls

24 Hazardous Air Pollutants (HAPS) Approximately 190 VOC compounds considered HAPs 21 HAPS are measured in Garfield County including BTEX compounds (benzene, toluene, ethyl-benzene and xylenes) Annual data summary reports include trends in HAPs measured Trends for 20 out of 21 HAPS compounds stable or decreasing Example trend plots on following slides Styrene is only HAP with increasing trend, but there are no known sources of styrene in Garfield County

25 Volatile Organic Compounds (VOCs): Trends Benzene = Urban and O&G related (HAP) Formaldehyde = Urban and O&G Related (HAP) Statistically Significant downward trends shown in blue (5 years required to calculate trend)

26 Volatile Organic Compounds (VOCs) Trends: Propane = O&G related (not considered a HAP) Ethane = O&G Related (not considered a HAP) Statistically Significant downward trends shown in blue (5 years required to calculate trend)

27 Health Risk Garfield County Air Monitoring reports do NOT include information on health risk Air Quality Index (AQI) Health Risk Assessment Provided by the Colorado Department of Public Health and Environment (CDPHE) in 2008 Overall, the non-cancer hazards on either a chronic or short-term (average) basis do not exceed an acceptable value of one and the cancer risk estimates are at, or slightly above, the upper-end of EPA s acceptable risk range. New report including data up to 2012 will be released and presented soon

28 Other Research: Colorado State University Air Emissions Study Main Objectives: Quantify emissions of chemical compounds (especially VOCs) during well development operations Characterize how these compounds are dispersed in the atmosphere in the downwind plume near the site Current project completion set at the end of 2015

29 Summary Real-time air quality data, AQI indices and summary reports are available at http://www.garfield-county.com/air-quality Data collected through 2014 indicate that there continue to be no violations of National Ambient Air Quality Standards (NAAQS) in Garfield County Annual trends indicate most VOC species (including Hazardous Air Pollutants) continue to decrease at statistically significant measurable rates

30 Questions? Morgan Hill Environmental Health Specialist III Garfield County Public Health (970) 665-6383 mhill@garfield-county.com Cassie Archuleta Project Scientist Air Resource Specialists (970) 484-7941 carchuleta@air-resource.com