Annexure - A Product Profile Sr. No. Product Name Quantity in MT/Month CAS Existing Proposed Ultimate Number End Users 1 Acid Dyes 5.000-5.000 0.000 -- -- Solvent Yellow 82 12227-67-7 Solvent Dark Violet R 12220-53-0 Solvent Black 34 32517-36-5 Solvent Yellow 146 109945-04- 2/94279-65-9 Solvent Red 91 61901-92-6 Ink manufacturer, Solvent Red 89 61725-81-3 Wood finish, Solvent Red 8 33270-70-1 Coating of 2 Solvent Red 119 0.000 30.000 30.000 12237-27-3 various 61901-98- substance, Solvent Yellow 62 7/61910-95-9 Specialty paint, Solvent Dark Brown 5 R 61969-48-0 Stone coating Etc. Solvent Black 29 61901-87-9 Solvent Orange 58 71775-93-4 Solvent Black 27 12237-22-8 Solvent Red 127 61969-48-0 Solvent Orange 99 110342-29-5 3 Blue Liquid 48 0.000 3.000 3.000 -- 4 Blending of Dyes 0.000 5.000 5.000 -- -- Total 5.000 33.000 38.000 -- --
Raw Material Consumption Sr. No. Product Quantity in MT/Month Product Name Raw Material Name Group Existing Proposed Ultimate 1 2 Solvent Yellow 82 Diazo Compounds ANTHRANILIC ACID 3 Solvent Dark Violet OPSAMIDE 4 5-NAP,Aniline 5 Solvent Black 34 2,4 disulphonic acid, 6 N-METHYLOPSAMIDE 0.000 14.040 14.040 7 Solvent Yellow 146 4-NAP+Anthranilic acid 8 4- NAP 9 Solvent Red 91 4-NAP+5-NAP+NAAP 10 4-NAP+5-NAP 11 Solvent Red 89 1,2,4-diazo acid 12 Coupler Compounds Solvent Red 8 13 PMP 14 Beta Naphthol Group Solvent Red 119 0.000 14.769 14.769 15 No. -2 Cyano Pyridone 16 Solvent Yellow 62 M-Chloro PMP 17 3-4 -DMP 18 Solvent Dark Brown HCl 0.000 28.000 28.000 19 5 R Sodium Nitrate 0.000 5.789 5.789 20 Caustic Soda Lye 0.000 15.789 15.789 Solvent Black 29 Trivalent Cobalt 21 complex 0.000 115.789 115.789 22 23 Solvent Orange 58 Amine 0.000 0.000 204.000 57.692 204.000 57.692 24 25 Solvent Black 27 Rhodamine Chromium 0.000 0.000 14.545 8.382 14.545 8.382 26 Solvent Red 127 MEG 0.000 82.667 82.667 27 Solvent Orange 99 Mono azo 0.000 23.824 23.824 28 Group No. -3 Blue Liquid 48 Liquid Crude Blue 48 0.000 51.300 51.300 29 Dyes of 100 % Strength 0.000 2.880 2.880 Glauber Salt and 30 Group 0.000 0.060 0.060 Blending of Dyes Vacuum Salt No. -4 Tri -Sodium Phosphate 31 0.000 0.060 0.060 &Anti Dusting Oil
Annexure B Manufacturing Process Flow Diagram 1. Solvent Dye Yellow 82 Flow Diagram: ANTHRANILIC ACID Sodium Nitrate HCL Diazotization Preparation of Coupling PMP Lye Reaction Trivalent Chromium Complex Steam Amine + Heating and Cobaltination Amine condensation Filter Effluent Wet Cake Drying Losses Pulverization Blending Final Product
2. Solvent Dark Violet R Flow Diagram OPSAMIDE Sodium Nitrate HCL Diazotization Preparation of Coupling BETA NAPHTHOL Lye Reaction Trivalent Chromium Complex Steam Amine + Heating and Cobaltination Amine condensation Filter Effluent Wet Cake Drying Losses Pulverization Blending Final Product
3. Solvent Dyes Black 34 Flow Diagram: 5- NAP Sodium Nitrate HCL Diazotization Preparation of Coupling BETA NAPHTHOL Lye Reaction Trivalent Chromium Complex Steam Amine + Heating and Chromination Amine condensation Filter Effluent Wet Cake Drying Losses Pulverization Blending Final Product
4. Solvent Dyes Yellow 146 Flow Diagram: Aniline 2,4 disulphonic acid Sodium Nitrate HCL Diazotization Preparation of Coupling Cyano Pyridone Lye Reaction Amine+ Steam Heating and Chromination Filter Effluent Wet Cake Drying Losses Pulverisation Blending Final Product
5. Solvent Red 91 Flow Diagram: OPSAMIDE Sodium Nitrate HCL Diazotization Preparation of Coupling BETA NAPHTHOL Lye Reaction Trivalent Chromium Complex Steam Amine + Heating and Cobaltination Amine condensation Filter Effluent Wet Cake Drying Losses Pulverization Blending Final Product
6. Solvent Dyes Red 89 Flow Diagram : N- METHYLOPSAMIDE Sodium Nitrate HCL Diazotization Preparation of Coupling M- CHLORO PMP Lye Reaction Trivalent Cobalt Complex Steam Rhodamine Heating and Cobaltination Amine condensation Filter Effluent Wet Cake Drying Losses Pulverisation Blending Final Product
7. Solvent Red 8 Flow Diagram : 5-NAP + HCL Diazotization Preparation of Coupling PMP Lye Reaction Filtration Effluent Wet Cake Dry and Pulverise Losses Chromium MEG Mono Azo Mono azo Powder Chromination Dumping Dry yield Amine Amine addition Filter Effluent Wet Cake Drying Losses Pulverization Final Product
8. Solvent Red 119 Flow Diagram: 4-NAP+Anthranilic acid + HCL Diazotization Preparation of Coupling PMP Lye Reaction Filtration Effluent Wet Cake Dry and Pulverise Dry yield Chromium MEG Mono Azo Mono azo Powder Chromination Dumping Mono Azo Rhodamine MEG Reaction Filter Effluent Wet Cake Drying Losses Pulverisation Final Product
9. Solvent Dyes Yellow 62 Flow Diagram : N-Methyl Opsamide Sodium Nitrate HCL Diazotization Preparation of Coupling M-Chloro PMP Lye Reaction Trivalent Chromium Complex Steam Amine + Heating and Cobaltination Amine condensation Filter Effluent Wet Cake Drying Losses Pulverisation Blending Final Product
10. Solvent Dyes Dark Brown 5R Flow Diagram : N- NAP Sodium Nitrate HCL Diazotization Preparation of Coupling 3,4- DMP Lye + Soda Ash Reaction Trivalent Chromium Complex Steam Amine + HCL Heating and Chromination Amine condensation Filter Effluent Wet Cake Drying Losses Pulverisation Blending Final Product
11. Solvent Dyes Black 29 Flow Diagram: 4-NAP+5-NAP+NAAP Sodium Nitrate HCL +BETA NSA Diazotization Preparation of Coupling Beta Naphthol Lye Reaction Trivalent Chromium Complex Steam Amine + Heating and Chromination Amine condensation Filter Effluent Wet Cake Drying Losses Pulverization Blending Final Product
12. Solvent Dyes Orange 58 Flow Diagram : OPSAMIDE Sodium Nitrate HCL Diazotization Preparation of Coupling PMP Lye Reaction Trivalent Chromium Complex Steam Amine + Heating and Chromination Amine condensation Filter Effluent Wet Cake Drying Losses Pulverisation Blending Final Product
13. Solvent Dyes Black 27 Flow Diagram ; 4-NAP+5-NAP Sodium Nitrate HCL Diazotization Preparation of Coupling Beta Naphthol Lye Reaction Trivalent Chromium Complex Steam Amine + HCL Heating and Chromination Amine condensation Filter Effluent Wet Cake Drying Losses Pulverisation Blending Final Product
14. Solvent Red 127 Flow Diagram : 1,2,4-diazo acid + HCL Diazotization Preparation of Coupling PMP Lye Reaction Filtration Wet Cake Effluent Dry and Pulverise Losses Chromium MEG Mono Azo Mono azo Powder Cromination Dumping Dry yield Rhodamine Amine HCL Rhodamine addition Amine Condenation Isolation Filtration Effluent Wet Cake Drying Losses Pulverisation Final Product
15. Solvent Dyes Orange 99 Flow Diagram : 4-NAP Sodium Nitrate HCL Diazotization Preparation of Coupling PMP Lye Reaction Trivelent Chlominon Complex Steam Heating and Condensation Amine Live Steam Amine condensation Filter Effluent Wet Cake Losses Dry Blending and Pulverisation Final Product
Group 3 Crude Blue Liquid 48 Flow Diagram : Liquid Crude Blue 48 receipt through Filtration Filtration Effluent Wet Cake Losses Drying Final Product
Annexure - C Consumption & Waste water Generation Consumption Sr. Consumption in KL/D Category No.: Existing Proposed Ultimate 1 Domestic 1.00 0.50 1.50 2 Gardening 0.00 0.50 0.50 Industrial 3 (a) Process + 20.00 10.00 30.00 (b) Boiler+ Cooling 5.00 1.00 6.00 (c) Other Use 0.00 0.00 0.00 Total industrial 25.00 11.00 36.00 Total ( 1,2 &3 ) 26.00 12.00 38.00 Remark Source : GIDC Supply Waste-water Generation Sr. No.: Category Waste-water Generation in KL/D Existing Proposed Ultimate 1 Domestic 0.9 0.2 1.1 2 Gardening 0.0 0.0 0.0 Industrial 3 (a) Process + 19.00 11.98 30.98 (b) Boiler+ Cooling 0.10 0.40 0.50 (c) Other Use 0.00 0.00 0.00 Total industrial 19.10 12.38 31.48 Total (1, 2 & 3 ) 20.00 12.58 32.58 Note: Disposal Mode 16.00 KLD (daily average) will be sent to CETP (As Per Valid CC&A). 15.48 KLD concentrated stream will be sent to Common spray dryer facility. 1.1 domestic sewage disposal to soak pit 32.58 KLD Total Ultimate
Annexure - D Details of Effluent Treatment Plant Sr. No. Name of the Unit Size in m with SWD 1 Collection Tank (1 in Nos.) 3.4x2.2x3.1 2 Chemical reaction cum neutralization tank 3.0x2.5x2.8 3 Hopper Bottom Settling tank 2.5x2.5x2.0 4 Aeration tank 4.5x2.8x4.7 5 Secondary settling tank 2.5x2.5x1.8 6 Treated sump 3.0x3.0x2.5 7 Sludge drying beds (1 nos) 3.1x1.6x0.5 8 Filter Press (Plate & Frame Type) 2 No. Note : Considering increase in waste-water quantity, existing ETP facilities will be upgraded suitably as per need sludge storage area.
Annexure - E Details of Hazardous Wastes Sr. No. 1. Waste Descriptio n ETP sludge 2. Used oil 3. Discarded containers / barrels / liners/bags Generat ion Source From ETP From Plant Machine ry From Raw material s Category 34.3 of Schedule I 5.1 of Schedule I 33.3 of Schedule I Quantity Existing Proposed Ultimate 0.2 MT/M 05Lit/Ye ar 5 nos/m 2.2MT/M 0.0 lit/year 2.125 MT/Month 3.0 MT/M 05 lit/year 2.25 MT/Mont h Disposal Collection, storage & disposal to authorized TSDF site Collection, storage,transport ation and sold out to the registered recycles or reused. Collection, storage,transport ation and disposal to authorized recycles or reused.
Annexure - F Sr. No. Existing Fuel Gas Steam Boiler 1-0.8 TPH Hot Air 2 Generator 3 -- Process Gas Tray Dryer 2 (2 No.s) 3 -- 4 -- Details of Air Pollution Control Measures Stack Attached To Proposed -- -- Steam Boiler (2 TPH) -- Tray Dryer (4 No.s) Ball Mill/Pulveriz er Flue Gas Emission After Expansion Steam Boiler - 0.8 TPH Hot Air Generator Steam Boiler (2 TPH) Tray Dryer (2 No.s) Tray Dryer (4 No.s) Ball Mill/Pulverizer Stack Height (M) APCM System 15 -- Parameter Remark Existing 9 -- SPM SO2 Existing NOx 12 -- Proposed Existing -- Closed Proposed loop PM System --. Proposed Fuel Consumption Details Fuel used in stack attached to Type of Fuel Existing Quantity Proposed Steam Boiler(0.8 TPH)/Hot Air Generator Nature Gas 400 M 3 /Day -- Steam Boiler(2 TPH) Nature Gas -- 100 M 3 /Day After Expansion 500 Sq. M.q
Annexure - G Proposed Terms of Reference for EIA Study The generic structure of Environment Impact Assessment Study Report will be as under: 1. Introduction This will cover the location and justification of the proposed project profile and scoping and methodology for the EIA study. 2. Project Description It will include the below mention details. Location of the project Product profile Resource requirement Manufacturing process and raw material requirement Data on monitoring in respect with the compliance of the present environmental permissions Material handling and storage Details on existing and proposed Environmental Management System and Monitoring. Storage and handling of hazardous chemicals Implementation of systems for issues like Rain Harvesting and Green Belt development, Occupational Health monitoring, CSR etc. 3. Baseline Environmental Description The data regarding baseline environmental conditions will be collected /generated as per the guidelines of MoEF&CC, within a 10 km radial distance around the project site.
The methodology for collection of baseline data for each of the component/environmental attribute is as follows: 3.1. Air a. The study area will be of 10 Km radius considering the project site as center and study period will be of one season, except monsoon. b. For estimation of back ground concentration of PM10, PM2.5, Oxides of Nitrogen (NOx), Sulphur Dioxide (SO2), within the study area, 6 monitoring stations will be established as per the guidelines of CPCB and Ministry of Environment & Forest, Government of India. At each station, monitoring will be carried out on 24 hourly bases twice in a week for the entire study period, except monsoon. 3.2. Meteorology 3.3. 3.4. Soil 3.5. Noise Site specific hourly meteorological data like wind speed, wind direction, humidity, temperature, will be collected at the location under consideration using weather monitoring station for period of 12 week. Since the water supply is from GIDC Estate and in absence of any direct disclage. In environment sink, only water sample from GIDC supply will be collected. Project location within notified industrial estate only sample from the site will be collected to monitor contaminates of land within the premises. The noise level will be measured once in a study period in Leq. at least at 6 different locations within the study area using an integrated sound level meter. 3. 6. Land use pattern
The details of Land use pattern for the study area will be prepared based on the satellite imagery resources within a radius of 5 km from the project site. Note : Location being within the GIDC notified area study on EB, SE& Geo-hydro-logical will not be undertaken. 4. Identification and Assessment of the Impacts The activities having the potential to cause environmental impact will be identified and the degree of impact will be assessed using standard matrix methods. The following environmental attributes will be considered to establish the cause-effect relationship with the various activities of the proposed project - water, air, noise, land and occupational health & safety. 5. Environmental Management and Monitoring Plan Environmental Management and Monitoring Plan will be prepared based on the anticipated environmental impact. It will also cover details on Occupational Health programs and as well as for corporate social responsibilities and CERP policy development of Green Belt. 6. Risk Assessment: The study will include risk assessment for storage, handling, transportation etc. for the raw material(s) and products to be used in the plant. Occupational risk involved during operational phase of the plant will be assessed and necessary safety and protective measures will be recommended.
Proposed Expansion Project of Mansi Chemicals Annexure - H : Plant Lay out for Proposed expansion
Proposed Expansion Project of Mansi Chemicals Annexure - I : Topo- sheet
Annexure - J : Key plan of Proposed expansion Project
Annexure - K
Annexure - I : Membership Certificate
Annexure -M